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Keywords = illite/smectite

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13 pages, 3126 KiB  
Article
Development of Young’s Modulus of Illite/Smectite—CaCO3 Composites After Various Firing Temperatures
by Štefan Csáki, Tibor Kovács, Martin Keppert, Vojtěch Pommer, František Lukáč, Michal Knapek, Peter Minárik and Anton Trník
Crystals 2025, 15(7), 592; https://doi.org/10.3390/cryst15070592 - 23 Jun 2025
Viewed by 257
Abstract
Illitic clays are one of the most important materials used in the ceramic industry. Carbonates support the densification and the sintering of ceramics. Five mixtures of illitic clay with calcite were prepared aiming for the crystallization of anorthite ceramics. The stoichiometric ratio of [...] Read more.
Illitic clays are one of the most important materials used in the ceramic industry. Carbonates support the densification and the sintering of ceramics. Five mixtures of illitic clay with calcite were prepared aiming for the crystallization of anorthite ceramics. The stoichiometric ratio of anorthite crystallization was determined at 21.6 wt.% of calcite content. To reveal the effect of calcite on the crystallization processes, two more mixtures were prepared below the stoichiometric composition (17.6 wt.% and 19.6 wt.%) and two more mixtures above the ideal composition (23.6 wt.% and 25.6 wt.%). X-ray diffraction revealed that gehlenite and Ca-feldspar were formed, which are the intermediate phases in anorthite crystallization. However, due to the low purity of illitic clay and the low firing temperature, no anorthite formation was observed. The influence of calcite content on Young’s modulus was negligible. However, a clear effect on the open porosity was revealed. Full article
(This article belongs to the Special Issue Ceramics: Processes, Microstructures, and Properties)
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16 pages, 5841 KiB  
Article
Characterization and Suitability for Ceramics Production of Clays from Bustos, Portugal
by Carla Candeias, Isaac Santos and Fernando Rocha
Minerals 2025, 15(5), 503; https://doi.org/10.3390/min15050503 - 9 May 2025
Viewed by 787
Abstract
Clays are fundamental raw materials in the ceramics industry due to their plasticity, mineralogical composition, and thermal behavior. This study characterizes four clay samples from Bustos (Portugal), aiming to assess their suitability for ceramic applications through granulometric, geochemical, mineralogical, and technological assays, looking [...] Read more.
Clays are fundamental raw materials in the ceramics industry due to their plasticity, mineralogical composition, and thermal behavior. This study characterizes four clay samples from Bustos (Portugal), aiming to assess their suitability for ceramic applications through granulometric, geochemical, mineralogical, and technological assays, looking at aspects such as their plasticity and sintering behavior. A textural analysis of the samples revealed distinct granulometric profiles, being dominated by silty–clayey fractions and low amounts of coarse particles, indicating high plasticity potential. Three samples showed an alkaline pH (8.17–8.63), and one an acidic pH (5.11), which can significantly influence the rheology and firing behavior of the ceramic body. Samples had a predominance of phyllosilicate minerals, followed by quartz and magnetite–maghemite, and trace amounts of feldspars, anatase, bassanite, and siderite. In the clay fraction, smectite, illite, and kaolinite were identified. By combining classical analysis techniques with ceramic technology principles, this study contributes to the sustainable development of local ceramic industries, emphasizing the importance of characterizing natural raw materials for industrial applications. The plasticity tests showed strong workability in two samples, which exhibited high values of plasticity and moldability, making them suitable for shaping processes in ceramic production. Also, sintering behavior tests revealed that the same clays exhibited good densification during firing, with relatively low shrinkage. Full article
(This article belongs to the Section Clays and Engineered Mineral Materials)
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25 pages, 13898 KiB  
Article
Origin and Reservoir Significance of Authigenic Minerals in Lacustrine Shales: A Case Study from the Paleogene Dongying Sag, Bohai Bay Basin, East China
by Jihua Yan, Shiyue Chen, Zhiyun Yu, Pengfei Zhang and Guozheng Feng
Minerals 2025, 15(5), 493; https://doi.org/10.3390/min15050493 - 7 May 2025
Viewed by 602
Abstract
Authigenic minerals in shale are products of the co-evolution of organic and inorganic components, affecting the heterogeneity of shale reservoirs. However, due to their fine granularity and complex rock composition, studies on these minerals in shale are still insufficient. This research focuses on [...] Read more.
Authigenic minerals in shale are products of the co-evolution of organic and inorganic components, affecting the heterogeneity of shale reservoirs. However, due to their fine granularity and complex rock composition, studies on these minerals in shale are still insufficient. This research focuses on the lacustrine shales from the upper sub-member of the fourth member in the Eocene Shahejie Formation, Dongying Sag, East China. Utilizing core samples, thin sections, scanning electron microscope, X-ray diffraction, elemental geochemistry, and organic geochemistry, we systematically characterized the features and origins of authigenic minerals. The results identified several typical authigenic minerals, including authigenic quartz, framboidal and euhedral pyrite, ferroan dolomite, kaolinite, chlorite, and albite. Authigenic quartz is predominantly diagenetic silica formed through smectite illitization, acidic dissolution of K-feldspar, and alkaline dissolution of detrital quartz. Pyrite is a product of microbial sulfate reduction, with framboidal pyrite forming during an early diagenetic stage under conditions with sufficient solute supply and euhedral pyrite forming during a later stage under conditions with insufficient solute supply. Ferroan dolomite originates from the precipitation of Fe and Mg during smectite illitization, with slight contributions from the acidic dissolution of chlorite and calcite. Kaolinite stems from the acidic dissolution of K-feldspar, while chlorite results from the transformation of kaolinite. Albite primarily arises from the alkaline alteration of anorthite and K-feldspar. Most non-clay authigenic minerals likely enhance reservoir quality by slightly reducing the effects of compaction, whereas authigenic clay minerals typically exert detrimental effects on reservoir properties. This study constrains the genesis of authigenic minerals to assess their influence on reservoir quality in lacustrine shale. Full article
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21 pages, 7700 KiB  
Article
Reservoir Characteristics and Diagenetic Evolution of Lower Cretaceous in Baibei Sag, Erlian Basin, Northern China
by Hongwei Tian, Zhanli Ren, Kai Qi, Jian Liu, Sasa Guo, Zhuo Han, Juwen Yao and Lijun Zhu
Processes 2025, 13(5), 1391; https://doi.org/10.3390/pr13051391 - 2 May 2025
Viewed by 413
Abstract
In recent years, the exploration of the Baibei Sag, located in the west of the Erlian Basin, has remained relatively underdeveloped. The Lower Cretaceous of the Baibei Sag hosts multiple tight sandstone reservoirs; however, research on the macro- and micro-characteristics, as well as [...] Read more.
In recent years, the exploration of the Baibei Sag, located in the west of the Erlian Basin, has remained relatively underdeveloped. The Lower Cretaceous of the Baibei Sag hosts multiple tight sandstone reservoirs; however, research on the macro- and micro-characteristics, as well as the controlling factors of these reservoirs, is relatively limited. This study selected 105 Lower Cretaceous sandstone samples from the Baibei Sag for core observation, casting thin sections, scanning electron microscopy, X-ray diffraction, and high-pressure mercury intrusion analysis. The reservoir’s physical properties, pore throat structure, and diagenesis process were studied. The results indicate that the reservoir lithology is mainly composed of feldspar lithic sandstone, with an average composition of 44.3% lithic, 34.6% quartz, and 21.2% feldspar. The clay minerals in the interstitial material are primarily illite (69.3%) and illite–smectite mixed layers (12.7%), with smaller amounts of chlorite (10.9%) and kaolinite (7.2%), while smectite content is very low. The physical property analysis results indicate that the average effective porosity of the Tengger Formation sandstone is 3.3%. The average permeability is 0.01 × 10−3 μm2. The average effective porosity of the Aershan Formation sandstone is 0.86%, and the average permeability is 0.05 × 10−3 μm2. The Tengger Formation and Aershan Formation are both tight sandstone reservoirs. The analysis of pore throat structure shows that the reservoir space is mainly composed of dissolution pores. Three types of pore throat structures were identified, and corresponding pore models were established. Based on burial history and organic matter evolution characteristics, this study establishes a diagenetic evolution sequence of the Lower Cretaceous sandstone reservoir. Analysis suggests that the pore throat structure of different reservoir types is mainly controlled by material composition. In the process of diagenetic evolution, the Tengger Formation and Aershan Formation are in the Middle diagenetic stage A. Compaction and cementation are the main reasons for low porosity, while the dissolution improves reservoir performance. The intergranular and intragranular dissolution pores formed by dissolution are the main storage spaces of the reservoir. The early tectonic fractures are filled with calcite, and the residual small-scale fractures play a role in improving permeability. Full article
(This article belongs to the Section Energy Systems)
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13 pages, 3915 KiB  
Article
Mechanical Strength Degradation in Deep Coal Seams Due to Drilling Fluid Invasion
by Qin Zhang, Weiliang Wang, Mingming Zhu, Yanbing Zhang, Qingchen Wang, Huan Sun and Jiping She
Processes 2025, 13(4), 1222; https://doi.org/10.3390/pr13041222 - 17 Apr 2025
Viewed by 401
Abstract
With the rapid development of the coalbed methane (CBM) industry in China, coal seam No. 8 of the Benxi Formation in the Ordos Basin has emerged as a key target for CBM development due to its abundant deep reserves. However, wellbore instability during [...] Read more.
With the rapid development of the coalbed methane (CBM) industry in China, coal seam No. 8 of the Benxi Formation in the Ordos Basin has emerged as a key target for CBM development due to its abundant deep reserves. However, wellbore instability during deep CBM extraction has become increasingly problematic, with the degradation of coal mechanical strength caused by drilling fluid invasion being identified as a critical factor affecting drilling safety and operational efficiency. This study focuses on coal seam No. 8 of the Benxi Formation in the Sulige Gas Field, Ordos Basin. Through experimental analyses of the coal’s mineral composition, microstructure, hydration expansion properties, and mechanical strength variations, the mechanism underlying drilling fluid invasion-induced mechanical strength degradation is elucidated. The experimental results reveal that coal seam No. 8 of the Benxi Formation exhibits a high carbon content and a low absolute clay mineral content (approximately 6.11%), with minimal expansive minerals (e.g., mixed-layer illite–smectite accounts for 26.4%). Consequently, the coal demonstrates a low linear expansion rate and weak hydration dispersion properties, indicating that hydration expansion is not the dominant mechanism driving mechanical strength degradation. However, drilling fluid invasion significantly reduced coal’s Young’s modulus (from 1988.1 MPa to 1676.1 MPa, a 15.69% decrease) and compressive strength (from 7.9 MPa to 6.5 MPa, a 17.72% drop), while markedly affecting its internal friction angle. Friction coefficient tests further demonstrate that the synergistic action of water molecules and additives decreases microcrack sliding resistance by 19.22% with simulated formation water and by 25.00% with drilling fluid, thereby promoting microcrack propagation and failure. This process ultimately leads to a degradation in mechanical strength. Hence, the enhancement of sliding effects induced by drilling fluid invasion is identified as the primary factor contributing to coal mechanical strength degradation, whereas hydration expansion plays a secondary role. To mitigate these effects, optimizing the design of drilling fluid systems and selecting suitable anti-collapse additives to reduce sliding effects are critical for minimizing wellbore instability risks in coal seams. These measures will ensure safer and more efficient drilling operations for deep CBM extraction. Full article
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28 pages, 8653 KiB  
Article
Controls on the Transformation of Clay Minerals in the Miocene Evaporite Deposits of the Ukrainian Carpathian Foredeep
by Yaroslava Yaremchuk, Sofiya Hryniv and Tadeusz Peryt
Minerals 2025, 15(4), 395; https://doi.org/10.3390/min15040395 - 8 Apr 2025
Viewed by 455
Abstract
Clays deposited in marine evaporite sequences are strongly altered, and the most important factor determining their transformation is brine concentration. An X-ray diffraction study of clay minerals associated with the Lower and Middle Miocene evaporite formations of the Ukrainian Carpathian Foredeep indicated that [...] Read more.
Clays deposited in marine evaporite sequences are strongly altered, and the most important factor determining their transformation is brine concentration. An X-ray diffraction study of clay minerals associated with the Lower and Middle Miocene evaporite formations of the Ukrainian Carpathian Foredeep indicated that the clay mineral assemblages in the gypsum facies are composed of smectite and illite, and, in some samples, mixed-layer chlorite–smectite and illite–smectite, as well as chlorite. In the halite facies, illite, chlorite, and mixed-layer illite–smectite occur in rock salt of Eggenburgian age (Vorotyshcha Suite); in addition to those minerals, smectite, corrensite, and mixed-layer chlorite–smectite occur in the Badenian rock salt (Tyras Suite); and in the potash facies, illite and chlorite were recorded. Such clay mineral assemblages resulted from the aggradational transformation of unstable and labile minerals and phases (kaolinite, smectite, and mixed-layer phases) that finally pass into illite and chlorite, minerals that are stable in an evaporite environment. In addition to brine concentration control, another important factor in the transformations of clay minerals was the sorption of organic components on the mineral structure, which slows the transformation processes. The assemblage of clay minerals in the weathering zone of the evaporite deposits, besides inherited illite and chlorite, also contains mixed-layer illite–smectite and kaolinite. The appearance of those clay minerals in hypergene deposits is the consequence of two processes: degradational transformation (illite–smectite) and neoformation (kaolinite) in conditions of decreased ionic concentrations during desalination. Full article
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21 pages, 22649 KiB  
Article
Epigenetic Alteration of the Hailijin Sandstone-Hosted Uranium Deposit and Its Indications on Uranium Metallogenesis in the Songliao Basin, NE China
by Mingming Tian, Ziying Li, Licheng Jia, Jungang Liu, Jun Ning and Jimu Li
Minerals 2025, 15(4), 393; https://doi.org/10.3390/min15040393 - 8 Apr 2025
Viewed by 489
Abstract
This study focuses on the Hailijing sandstone-hosted uranium deposit in the Songliao Basin. Through a combination of petrographic analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and geochemical analysis, the epigenetic alteration of the deposit was systematically investigated, and the alteration zonation was [...] Read more.
This study focuses on the Hailijing sandstone-hosted uranium deposit in the Songliao Basin. Through a combination of petrographic analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and geochemical analysis, the epigenetic alteration of the deposit was systematically investigated, and the alteration zonation was delineated. On this basis, the metallogenic mechanisms were further explored. The results indicate that six major types of alteration can be identified in the ore-bearing strata of the Hailijing uranium deposit: hematitization, limonitization, carbonatization, pyritization, clay mineralization (including kaolinite, illite, and illite-smectite mixed-layer), and baritization. The mineral assemblages at different stages of alteration vary: during the sedimentary diagenetic stage, the assemblage consists of “hematite + clay minerals + II-type pyrite (framboidal pyrite) + III-type pyrite (euhedral granular pyrite)”; during the uranium mineralization stage, it transitions to “ankerite + barite + I-type pyrite (colloidal pyrite) + minor kaolinite”; and in the post-ore stage, alteration is characterized by calcite cementation in red sandstones. Based on petrological, mineralogical, and geochemical characteristics, as well as the spatial distribution of the host gray sandstones, it is inferred that during uranium mineralization stage, the ore-bearing strata underwent reduction by uranium-rich reducing fluids sourced from the Lower Cretaceous Jiufotang Formation. The primary red sandstones of the Lower Yaojia Formation, formed under arid to semi-arid conditions, experienced varying degrees of reduction, resulting in a color transition from light red, brownish red, and yellowish brown to grayish-yellow and gray. Accordingly, four alteration zones are distinguished in the Hailijing uranium deposit: the primary red zone, weakly reduced pink zone, moderately reduced grayish-yellow zone, and strongly reduced gray zone. Furthermore, as the uranium-rich reducing fluids migrated from a high-temperature, high-pressure deep system to the low-temperature, low-pressure ore-bearing sandstone strata near the surface, uranium was unloaded, precipitated, and enriched, ultimately forming multi-layered and tabular-shaped uranium orebodies within the gray sandstone. This study elucidates the epigenetic alteration processes and metallogenic mechanisms of the Hailijing uranium deposit, providing a critical theoretical basis for further uranium exploration in the southern Songliao Basin. Full article
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22 pages, 7662 KiB  
Article
Saturated Hydraulic Conductivity of Nine Soils According to Water Quality, Soil Texture, and Clay Mineralogy
by Clarissa Buarque Vieira, Gabriel Henrique Maximo Clarindo Silva, Brivaldo Gomes de Almeida, Luiz Guilherme Medeiros Pessoa, Fernando José Freire, Valdomiro Severino de Souza Junior, Hidelblandi Farias de Melo, Luara Gabriella Gomes de Lima, Rodrigo Francisco do Nascimento Paiva, Jorge Freire da Silva Ferreira and Maria Betânia Galvão dos Santos Freire
Agronomy 2025, 15(4), 864; https://doi.org/10.3390/agronomy15040864 - 30 Mar 2025
Viewed by 979
Abstract
Water quality affects soils by promoting their degradation by the accumulation of salts that will lead to salinization and sodification. However, the magnitude of these processes varies with soil attributes. Saturated hydraulic conductivity (Ksat) is the rate at which water passes [...] Read more.
Water quality affects soils by promoting their degradation by the accumulation of salts that will lead to salinization and sodification. However, the magnitude of these processes varies with soil attributes. Saturated hydraulic conductivity (Ksat) is the rate at which water passes through saturated soil, which is fundamental to determining water movement through the soil profile. The Ksat may differ from soil to soil according to the sodium adsorption ratio (SAR), water electrical conductivity (ECw), soil texture, and clay mineralogical assemblage. In this study, an experiment with vertical columns and constant-load permeameters was conducted to evaluate changes in soil Ksat with waters comprising five ECw values (128, 718, 1709, 2865, and 4671 µS cm−1) and five SAR values [0, 5, 12, 20, and 30 (mmolc L−1)0.5] in combination. Horizons from nine northeastern Brazilian soils (ranging from tropical to semiarid) were selected according to their texture and clay mineralogical composition. The data obtained were fit with multiple regression equations for Ksat as a function of ECw and SAR. This study also determined the null SAR at each ECw level, using Ksat = 0 on each equation, to predict the SAR needed to achieve zero drainage on each soil for each ECw level and the threshold electrolyte concentration (CTH) that would lead to a 20% reduction of maximum Ksat. Neither the ECw nor SAR of the applied waters affected the Ksat of soils with a mineralogical assemblage of oxides and kaolinite such as Ferralsol, Nitisol, and Lixisol, with an average Ksat of 2.75, 6.06, and 3.33 cm h−1, respectively. In smectite- and illite-rich soils, the Ksat increased with higher ECw levels and decreased with higher SAR levels, especially comparing the soil’s estimated Ksat for water with low ECw and high SAR in combination (ECw of 128 µS cm−1 and SAR 30) and water with high ECw and low SAR in combination (ECw of 4671 µS cm−1 and SAR 0) such as Regosol (4.95 to 10.94 cm h−1); Vertisol (0.28 to 2.04 cm h−1); Planosol (0 to 0.29 cm h−1); Luvisol (0.46 to 2.12 cm h−1); Cambisol (0 to 0.23 cm h−1); and Fluvisol (1.87 to 3.34 cm h−1). The CTH was easily reached in soils with high concentrations of highly active clays such as smectites. In sandy soils, the target CTH was only reached under extremely high SAR values, indicating a greater resistance of these soils to salinization/sodification. Due to their mineralogical assemblage, soils from tropical sub-humid/hot and semiarid climates were more affected by treatments than soils from tropical humid/hot climates, indicating serious risks of physical and chemical degradation. The results showed the importance of monitoring water quality for irrigation, mainly in less weathered, more clayey soils, with high clay activity to minimize the rate of salt accumulation in soils of the Brazilian semiarid region. Our study also proved that clay mineralogy had more influence on the Ksat than clay concentration, mainly in soils irrigated with saline and sodic waters, and that soils with highly active smectite are more prone to degradation than soils with high concentrations of kaolinite. Full article
(This article belongs to the Section Water Use and Irrigation)
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31 pages, 6101 KiB  
Article
Genesis of the Upper Jurassic Continental Red Sandstones in the Yongjin Area of the Central Junggar Basin: Evidence from Petrology and Geochemistry
by Yongming Guo, Chao Li, Likuan Zhang, Yuhong Lei, Caizhi Hu, Lan Yu, Zongyuan Zheng, Bingbing Xu, Naigui Liu, Yuedi Jia and Yan Li
Minerals 2025, 15(4), 347; https://doi.org/10.3390/min15040347 - 27 Mar 2025
Viewed by 615
Abstract
The sandstone sections in the Upper Jurassic red beds of the Yongjin area in the central Junggar Basin are important oil and gas reservoirs. The debate over whether red beds are of primary depositional or secondary diagenetic origin persists, leading to uncertainties in [...] Read more.
The sandstone sections in the Upper Jurassic red beds of the Yongjin area in the central Junggar Basin are important oil and gas reservoirs. The debate over whether red beds are of primary depositional or secondary diagenetic origin persists, leading to uncertainties in the interpretation of reservoir sedimentary facies. This study uses core samples and employs thin section microscope observations, scanning electron microscopy, X-ray diffraction, and major and trace element analyses to investigate the formation period and paleoclimate conditions of red beds and explore the origin of red sandstone. The Upper Jurassic red beds are mainly deposited in arid delta plain environments. The framework grains of the red sandstone are composed of quartz (averaging 22.6%), feldspar (averaging 16.3%), and rock fragments (averaging 36.7%). The rock fragments in the sandstone are mainly composed of intermediate basic volcanic rocks and cryptocrystalline acid volcanic rocks, which are rich in mafic silicate minerals such as olivine, pyroxene, ilmenite, and magnetite. In situ hematitization of ilmenite is observed in the rock fragments, suggesting that the in situ alteration of mafic silicate minerals in the parent rock is the main source of iron ions for hematite. Tiny hematite crystals (2.1 μm) are observed in clay mineral micropores via SEM. Abundant mixed-layer illite/smectite clay indicates early smectite transformation, providing a minor source of iron ions for hematite. Hematite in the red sandstone occurs as a grain-coating type, predating quartz overgrowth, feldspar overgrowth, and (ferroan) calcite and (ferroan) dolomite precipitation. Residual hematite coatings between detrital grain point contacts indicate that hematite is a product of syn-sedimentary or very early diagenetic precipitation, ruling out the possibility that red sandstone formation was caused by later atmospheric water leaching during the fold and thrust belt stage. The average chemical index of alteration (CIA) for the red sandstone is 52.2, whereas the CIA for the red mudstone averages 59.5, and the chemical index of weathering (CIW) reached a maximum of 69. These values indicate that the rocks have undergone mild chemical weathering in arid climates. Additionally, the ratios of trace elements indicate that the water bodies were in an oxidizing state during the sedimentary period. The arid climate and oxidative water conditions were ideal for hematite preservation, thus facilitating red bed formation. The red bed sediments in the study area represent a direct response to the Late Jurassic aridification event and can be compared to global climate change. The results have important implications for stratigraphic correlation and interpretation of reservoir sedimentary facies in the study area while also providing a valuable case study for global research on red beds. Full article
(This article belongs to the Topic Recent Advances in Diagenesis and Reservoir 3D Modeling)
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31 pages, 16566 KiB  
Article
The Role of Fluid Chemistry in the Diagenetic Transformation of Detrital Clay Minerals: Experimental Insights from Modern Estuarine Sediments
by Anas Muhammad Salisu, Abdulwahab Muhammad Bello, Abduljamiu O. Amao and Khalid Al-Ramadan
Minerals 2025, 15(3), 317; https://doi.org/10.3390/min15030317 - 19 Mar 2025
Viewed by 673
Abstract
The diagenetic transformation of detrital clay minerals significantly influences sandstone reservoir quality, with fluid chemistry and temperature playing key roles in dictating transformation pathways during burial diagenesis. While these processes are well-documented in basinal settings, the diagenetic alterations of sediments in dynamic environments [...] Read more.
The diagenetic transformation of detrital clay minerals significantly influences sandstone reservoir quality, with fluid chemistry and temperature playing key roles in dictating transformation pathways during burial diagenesis. While these processes are well-documented in basinal settings, the diagenetic alterations of sediments in dynamic environments like estuaries remain underexplored. This study investigates the impact of fluid composition on the transformation of modern estuarine sediments through hydrothermal experiments using sediments from the Gironde estuary, SW France. A range of natural and synthetic solutions including seawater (SW), 0.1 M KCl (SF1), 0.1 M NaCl, KCl, CaCl2·2H2O, MgCl2·6H2O (SF2), estuarine water (EW), and 0.1 M Na2CO3 (SF3) were used under temperatures from 50 °C to 250 °C for 14 days, with a fixed fluid-to-sediment ratio of 10:1. The results revealed distinct mineralogical transformations driven by fluid composition. Dissolution of detrital feldspars and clay materials began at lower temperatures (<100 °C). The authigenic formation of smectite and its subsequent illitization in K-rich fluids (SW, SF1) occurred between 150 °C and 250 °C, replicating potassium-driven illitization processes observed in natural sandstones. Additionally, chlorite formation occurred through the conversion of smectite in SF2 and EW. Geochemical analysis showed that SF2 produced Mg-rich chlorites, while EW yielded Fe-rich chlorites. This aligns with diagenetic trends in coastal environments, where Fe-rich chlorites are typically associated with estuarine systems. The resulting authigenic illite and chlorite exhibited morphological and chemical characteristics similar to those found in natural sandstones, forming through dissolution-crystallization and solid-state transformation mechanisms. In contrast to illite and chlorite, SF3 produced entirely different mineral phases, including halite and analcime (zeolite), attributed to the high alkalinity and Na-rich composition of the solution. These findings provide valuable insights into the role of fluid chemistry in the diagenetic alteration of modern sediments and their implications for the evolution of sandstone reservoirs, which is critical for energy exploration and transition. Full article
(This article belongs to the Section Clays and Engineered Mineral Materials)
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30 pages, 9783 KiB  
Article
Integration of Routine Core Data and Petrographic Analyses to Determine the Sandstone Reservoir Flow Units in the Bredasdorp Basin, Offshore South Africa
by Nobathembu Tyhutyhani, Moses Magoba and Oswald Gwavava
J. Mar. Sci. Eng. 2025, 13(3), 493; https://doi.org/10.3390/jmse13030493 - 2 Mar 2025
Cited by 1 | Viewed by 1106
Abstract
Routine core permeability and porosity are crucial in assessing flow units within a reservoir because they define a reservoir’s storage and flow capacities. A limited amount of work has been conducted on the lower cretaceous (Barremian to Valanginian) sandstones in the Bredasdorp Basin, [...] Read more.
Routine core permeability and porosity are crucial in assessing flow units within a reservoir because they define a reservoir’s storage and flow capacities. A limited amount of work has been conducted on the lower cretaceous (Barremian to Valanginian) sandstones in the Bredasdorp Basin, offshore South Africa, focusing on the flow zones and the possible effect of diagenetic minerals on the individual flow zones, limiting understanding of reservoir quality and fluid flow behavior across the field. Nine hundred routine core analysis datasets were used to determine the flow units within the reservoir from three wells (F-A10, F-A13, and F-O2) from independent methods, namely: the Pore Throat Radius, Flow Zone Indicator, Stratigraphic Modified Lorenz Plot, and Improved Stratigraphic Modified Lorenz Plot. The results showed six flow units: fracture, super-conductive, conductor, semi-conductor, baffle, and semi-barrier. The super-conductive flow units contributed the most flow, whereas the semi-barrier and baffle units contributed the least flow. Petrography analyses revealed that the diagenetic minerals present were smectite, illite, glauconite, siderite, micrite calcite, and chlorite. The pore-filling minerals reduced the pore spaces and affected pore connectivity, significantly affecting the flow contribution of the baffle and semi-barrier units. Micrite calcite and siderite cementation in FU5 of F-A13 and FU9 of F-O2 significantly reduced the intergranular porosity by filling up the pore spaces, resulting in tight flow units with impervious reservoir quality. It was noted that where the flow unit was classified as super-conductive, authigenic clays did not significantly affect porosity and permeability as they only occurred locally. However, calcite and silica cementation significantly affected pore connectivity, where the flow unit was classified as a very low, tight, semi-barrier, or barrier. Full article
(This article belongs to the Section Geological Oceanography)
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13 pages, 5529 KiB  
Article
Effect of Interaction Between Expandable Minerals and Glycerin-Based Fluids on the Occurrence of Accretion
by Ana P. O. Sousa, Mário C. S. Lima, Waleska R. P. Costa, Renalle C. A. M. Nascimento, João M. P. Q. Delgado, Antonio G. B. Lima and Luciana V. Amorim
Minerals 2025, 15(3), 245; https://doi.org/10.3390/min15030245 - 27 Feb 2025
Viewed by 480
Abstract
Glycerin-based fluids are proposed as a promising alternative to inhibited fluids in the drilling of highly-reactive formations. However, even with the use of these fluids, it is still possible to observe the occurrence of problems related to the balling of drill bits and [...] Read more.
Glycerin-based fluids are proposed as a promising alternative to inhibited fluids in the drilling of highly-reactive formations. However, even with the use of these fluids, it is still possible to observe the occurrence of problems related to the balling of drill bits and drill pipes, such as the agglomeration and accretion of cuttings. This study aims to analyze how the interaction between expandable minerals from reactive formations and glycerin-based drilling fluids affects the stability of oil wells, focusing on the occurrence and extent of the accretion phenomenon. For this purpose, bentonite pellets were characterized regarding their mineralogical composition and plastic behavior. In addition, accretion tests were performed in order to evaluate the interaction between bentonite pellets and glycerin-based drilling fluids containing different types of inhibitors. The results revealed that the pellets were predominantly composed of interstratified illite–smectite (IS) clay minerals and presented highly plastic properties with a high degree of expansion. Furthermore, it was found that the accretion percentages were significant for all the fluids studied, at higher than 58%. Therefore, it was found that using glycerin in drilling fluids did not stabilize expandable minerals in reactive formations, even with different expansion inhibitors, which were ineffective in reducing the rock expansibility. Full article
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16 pages, 9783 KiB  
Article
Mineralogical and Chemical Characteristics of Sediments in the Lhasa River Basin: Implications for Weathering and Sediment Transport
by Heyulu Zhang, Tianning Li, Changping Mao, Zhengjin Song and Wenbo Rao
Water 2025, 17(4), 581; https://doi.org/10.3390/w17040581 - 18 Feb 2025
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Abstract
The Lhasa River, as one of the major rivers on the Tibetan Plateau, is of great value for the study of climate and environmental changes on the Tibetan Plateau. In this paper, the grain size and the mineralogical and geochemical characteristics of the [...] Read more.
The Lhasa River, as one of the major rivers on the Tibetan Plateau, is of great value for the study of climate and environmental changes on the Tibetan Plateau. In this paper, the grain size and the mineralogical and geochemical characteristics of the sediments from the Lhasa River were investigated. The results show the following: (1) The average grain size of the Lhasa River sediments is coarse (65.5% sand, 23.6% silt), and the sorting is overall poor; the skewness is mostly positive, and the kurtosis is wide, which reflects the obvious characteristics of river sand deposition. (2) The mineral composition of the Lhasa River sediments is dominated by quartz (38.4%), feldspar, and plagioclase feldspar, followed by clay minerals, and the content of carbonate minerals is relatively low; the content of clay minerals in the illite content is as high as 83.3%, while the chlorite content is slightly higher than kaolinite, and smectite content is very low. The chemical index of illite is less than 0.4, indicating that illite is mainly iron-rich magnesium illite. (3) The value of the chemical weathering index (CIA) of the sediments is low, implying that the sediments are in a weak–moderate chemical weathering state and dominated by physical weathering. Comprehensive analyses further revealed that the weathering process of the sediments in the Lhasa River was influenced by both climate and lithology, i.e., sediment composition is influenced not only by chemical weathering in a dry, cold climate but also by physical weathering of granites exposed over large areas. The results of this study can provide scientific references for further in-depth research on the environmental and climatic effects of the Tibetan Plateau. Full article
(This article belongs to the Section Water Erosion and Sediment Transport)
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27 pages, 15613 KiB  
Article
Mineralogical and Geochemical Characterization of Argillaceous Rocks in the Upper Wuerhe Formation in the Mahu 1 Well Block of the Junggar Basin, NW China
by Hao Fu, Yongjun Li, Jianhua Qin, Fenghao Duan, Xueyi Xu, Nanhe Peng, Gaoxue Yang, Kai Liu, Xin Wang and Jing Zhang
Minerals 2025, 15(2), 157; https://doi.org/10.3390/min15020157 - 7 Feb 2025
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Abstract
The Mahu Sag, where the Mahu 1 well block is located, is one of the most important hydrocarbon-rich depressions in the Junggar Basin, NW China. The Permian Upper Wuerhe Formation (UWF) constitutes the primary layer of the unconventional tight oil reservoir in the [...] Read more.
The Mahu Sag, where the Mahu 1 well block is located, is one of the most important hydrocarbon-rich depressions in the Junggar Basin, NW China. The Permian Upper Wuerhe Formation (UWF) constitutes the primary layer of the unconventional tight oil reservoir in the Mahu Oilfield. To explore the provenance and sedimentary environment during the deposition of the UWF in the study area, we determined the clay mineralogy and whole-rock geochemical composition of argillaceous rocks. The results show that the primary minerals in argillaceous rock are feldspar, clay minerals, quartz, and a minor amount of hematite. The clay minerals identified included illite, smectite, kaolinite, chlorite, and illite/smectite mixed layers. The tectonic setting of the provenance area for the UWF is a continental island arc, associated with a cutting magmatic arc. The main provenance area is related to the Baogutu tectonic belt (the Zhayier Mountain and the Hala’alate Mountain). The bedrock primarily consists of acidic igneous rocks, with minor occurrences of intermediate–basic igneous and sedimentary rock. The chemical index of alteration (CIA) shows that the parent rocks of the argillaceous rocks have experienced moderate–strong chemical weathering. Combining the Sr/Cu and ΣLREE/ΣHREE ratios, δEu values, and clay mineral characteristics, we determined that the paleoclimate during the deposition of the UWF was generally warm and humid, with occasional short-term dry and cold periods. The UWF gradually changes, according to the relative humidity and enhanced chemical weathering from the bottom to the top. An analysis of trace elements, paleosalinity, and paleowater depth indicate that the studied argillaceous rocks were deposited in a shallow-water oxidation environment of continental fresh water with weak hydrodynamic conditions. Full article
(This article belongs to the Section Clays and Engineered Mineral Materials)
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32 pages, 13107 KiB  
Article
Terminal Fan Deposition and Diagenetic Control in the Lower Paleogene of the Shahejie Formation, Bonan Sag, Bohai Basin, China: Insights into Reservoir Quality
by Arthur Paterne Mioumnde, Liqiang Zhang, Yiming Yan, Jonathan Atuquaye Quaye, Kevin Mba Zebaze, Victor Sedziafa, Carole Laouna Bapowa, Zeeshan Zafar and Shahab Aman e Room
Minerals 2025, 15(2), 99; https://doi.org/10.3390/min15020099 - 21 Jan 2025
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Abstract
In the Bonan area, the lower fourth member of the Shahejie Formation (Es4x) is buried beneath a sedimentary pile ranging from 2500 to 5000 m. Understanding the impact of diagenetic alterations on these deeply buried reservoirs is crucial for effective hydrocarbon exploration and [...] Read more.
In the Bonan area, the lower fourth member of the Shahejie Formation (Es4x) is buried beneath a sedimentary pile ranging from 2500 to 5000 m. Understanding the impact of diagenetic alterations on these deeply buried reservoirs is crucial for effective hydrocarbon exploration and production. This study employs a terminal fan sedimentation model, encompassing depositional environments such as feeder channels, distributary channels, floodplains, and basinal zones, to provide insights into the spatial distribution of reservoir properties and their influence on the localization of optimal reservoirs within the sag. The analysis integrates diagenetic facies with well log responses, subsurface porosity trends, and permeability variations across the formation. The petrographic analysis indicates that the sandstone is composed primarily of litharenite, feldspathic litharenite, lithic arkose, and minor amounts of arkose. The dominant clay cement is illite, accompanied by mixed-layer smectite/illite, chlorite, and kaolinite. Thin section observations reveal secondary porosity formed through the dissolution of quartz grains, volcanic rock fragments, and feldspar, along with their associated cements. These sandstones exhibit relatively good sorting, with average porosity and air permeability values of 14.01% and 12.73 mD, respectively. Diagenetic alterations are categorized into three processes: porosity destruction, preservation, and generation. Key diagenetic mechanisms include compaction, cementation, replacement, and dissolution, with compaction exerting the most significant control on reservoir porosity reduction. Statistical analysis indicates that the average porosity loss due to compaction is approximately 13.3%, accounting for about 38% of the original porosity. The detrital rock cement predominantly comprises quartz (42%), feldspar (32%), clay minerals (14%), and carbonate (12%). Under the prevailing depositional conditions, porosity is enhanced by dissolution and fracturing, while late-stage diagenetic cementation by clay and carbonate minerals—excluding chlorite—adversely affects reservoir quality. Consequently, the distributary zone is identified as the primary target for exploration. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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