Search Results (138)

The development of layer-by-layer polyelectrolyte microcapsules (PMCs) with defined buffer capacity (BC) is a key task for creating stable systems in biomedicine and materials science. Manganese carbonate (MnCO₃), which shares properties with CaCO₃ and the ability to form hollow structures, represents a promising alternative. However, its interaction with polyelectrolytes and its influence on BC remain insufficiently studied. This research focuses on determining the BC of PMCs templated on MnCO₃ cores under varying ionic strength (0.22–3 M NaCl) and temperature (60–90 °C), as well as comparing the results with PMCs templated on CaCO₃ and PS cores. It was found that MnCO₃-based PMCs (PMC_Mn) exhibit hybrid behavior between CaCO₃- and PS-based PMCs: the BC dynamics of PMC_Mn and CaCO₃-based PMCs (PMC_Ca) in water are identical. At different ionic strength at pH < 5, the BC of PMCMn and PS-based PMCs (PMC_PS) remains unchanged, while at pH > 8.5, the BC of PMC_Mn increases only at 3 M NaCl. The BC of PMC_Mn remains stable under heating, whereas the BC of PMC_Ca and PMC_PS decreases. These results confirm that the choice of core material dictates PMC functionality, paving the way for adaptive systems in biosensing and controlled drug delivery. Full article

Axis definition plays a key role in the establishment of animal body plans, both in normal development and regeneration. The cnidarian Hydra can re-establish its simple body plan when regenerating from a random cell aggregate or a sufficiently small tissue fragment. At the beginning of regeneration, a hollow cellular spheroid forms, which then undergoes symmetry breaking and de novo body axis definition. In the past, we have published related work in a physics journal, which is difficult to read for scientists from other disciplines. Here, we review our work for readers not so familiar with this type of approach at a level that requires very little knowledge in mathematics. At the same time, we present a few aspects of Hydra biology that we believe to be linked to our work. These biological aspects may be of interest to physicists or members of related disciplines to better understand our approach. The proposed theoretical model is based on fluctuations of gene expression that are triggered by mechanical signaling, leading to increasingly large groups of cells acting in sync. With a single free parameter, the model quantitatively reproduces the experimentally observed expression pattern of the gene ks1, a marker for ‘head forming potential’. We observed that Hydra positions its axis as a function of a weak temperature gradient, but in a non-intuitive way. Supposing that a large fluctuation including ks1 expression is locked to define the head position, the model reproduces this behavior as well—without further changes. We explain why we believe that the proposed fluctuation-based symmetry breaking process agrees well with recent experimental findings where actin filament organization or anisotropic mechanical stimulation act as axis-positioning events. The model suggests that the Hydra spheroid exhibits huge sensitivity to external perturbations that will eventually position the axis. Full article

One of the challenges of our age is climate change and the ways in which it affects the Earth’s global ecosystem. To face the problems linked to such an issue, the international community has defined actions aimed at the reduction in greenhouse gas emissions in several sectors, including the aviation industry, which has been requested to mitigate its environmental impact. Conventional aircraft propulsion systems depend on fossil fuels, significantly contributing to global carbon emissions. For this reason, innovative propulsion technologies are needed to reduce aviation’s impact on the environment. Electric propulsion has emerged as a promising solution among the several innovative technologies introduced to face climate change challenges. It offers, in fact, a pathway to more sustainable air travel by eliminating direct greenhouse gas emissions, enhancing energy efficiency. Unfortunately, integrating electric motors into aircraft is currently a big challenge, primarily due to thermal management-related issues. Efficient heat dissipation is crucial to maintain optimal performance, reliability, and safety of the electric motor, but aeronautic applications are highly demanding in terms of power, so ad hoc Thermal Management Systems (TMSs) must be developed. The present paper explores the design and optimization of a TMS tailored for a megawatt electric motor in aviation, suitable for regional aircraft (~80 pax). The proposed system relies on coolant oil injected through a hollow shaft and radial tubes to directly reach hot spots and ensure effective heat distribution inside the permanent magnet cavity. The goal of this paper is to demonstrate how advanced TMS strategies can enhance operational efficiency and extend the lifespan of electric motors for aeronautic applications. The effectiveness of the radial tube configuration is assessed by means of advanced Computational Fluid Dynamics (CFD) analysis with the aim of verifying that the proposed design is able to maintain system thermal stability and prevent its overheating. Full article

The expansion of unobstructed floor plans has resulted in large open areas, especially in modern designs. Although these new designs are appealing and esthetically attractive, they remain at a risk of large fires which may initiate at certain location(s) and make their way along to the other parts of the compartment. Such fires are called travelling fires and are not currently covered by the design codes due to lack of available research and understanding. Unlike traditional compartment fires, travelling fires may last longer and may result in compromising the structural integrity due to prolonged fire exposure. This article studies the impact of travelling fires on structures with focus on the structural elements, oriented perpendicular to the direction of fire travel. The data presented comes from Test 1, conducted by the authors as part of the TRAFIR project at Ulster University. The details provided include the recorded gas temperatures within the compartment and the temperatures recorded in the surrounding structural elements, along gridlines ② and ③. The test compartment consisted of a steel structure with a hollow core concrete roof. The structural steelwork was supplied with additional dummy columns for data acquisition purposes. The study demonstrates that structural elements located within the fuel bed are subjected to significantly higher temperatures. The gas temperature differences within and outside the fuel bed on occasions exceed 450 °C across compartment width, while the same for columns and beams were up to 350 °C and 200 °C, respectively. Such transient heating of the structure could possibly induce the load distribution within the structure and may help achieve improved global fire resistance. The findings from this study will improve our understanding of travelling fires, their impact on structures, and will open directions to study the collapse mechanisms of structures under the influence of travelling fires and will help with devising design guidance for structures exposed to travelling fires. Full article

Printed cast models are becoming increasingly important in prosthodontics. The aim of this in vitro study was to evaluate the influence of print orientation and external shell thickness on the accuracy of stereolithography (SLA) master casts for fixed dental prostheses. Seventy-two maxillary hollow master casts were fabricated from a standard tessellation language (STL 0) reference file containing dental preparations. The casts were divided into six groups (n = 12 per group) according to internal shell thickness (2 mm and 4 mm) and print orientation (0°, 10°, and 20°). Discrepancies between STL 0 and the STL files of the printed casts were measured using the root mean square (RMS) error. Data were statistically analyzed using a one-way Kruskal–Wallis test to assess trueness, and precision was evaluated with the Levene test (α = 0.05). No statistically significant differences were found in any of the tested conditions. Print orientation and cast thickness did not influence the overall accuracy of SLA master casts for fixed dental prostheses. Full article

Supercapacitors (SCs) have garnered significant attention due to their high power density and long cycle life. Among the various electrode materials, carbon materials have emerged as a focal point of research owing to their superior conductivity, stability, and reproducibility. However, the relatively low specific capacitance and specific surface area of carbon materials result in suboptimal electrochemical performance, which seriously hinders their practical applications. This work introduces a straightforward yet effective strategy for constructing hollow nano-cage structures by tannic acid etching of ZIF-8. In this process, tannic acid releases protons that selectively etch the MOF structure, while the residual large molecules adhere to the ZIF-8 surface, stabilizing its framework and preventing structural collapse. Following high-temperature heat treatment, novel hollow nitrogen-doped carbon nano-cage structures (HNCs) are successfully synthesized. Electrochemical tests reveal that the material has a capacity of 349.3 F g⁻¹ at a current density of 0.5 A g⁻¹, and still has a coulombic efficiency of 97.61% as well as a capacity retention of 97.86% after cycling for 10,000 cycles at a current density of 3 A g⁻¹. Therefore, this study provides a novel way to explore the application of carbon materials with excellent electrochemical performance for energy storage. Full article

To address the issues of low shear strength, susceptibility to eccentricity, and alignment difficulties in post-inserted core piles, a new type of steel tube concrete integrated mixing composite pile has been independently developed. This pile type replaces the conventional mixing pile shaft with a larger diameter steel tube equipped with mixing blades. After forming the external annular cement mixing pile, the steel tube is retained, and the hollow core is filled with concrete. To thoroughly explore the vertical compressive bearing characteristics of the steel tube concrete mixing composite pile and clarify its vertical compressive behavior, static load field tests and PLAXIS 3D finite element numerical simulations were conducted on four test piles of different sizes to analyze the vertical bearing performance of the steel tube concrete mixing composite pile. The research results indicate that for a composite pile with a length of 40 m, an outer diameter of 1000 mm, and a steel tube diameter of 273 mm, the ultimate bearing capacity of a single pile is 7200 kN, with the steel tube concrete core contributing approximately 81% of the vertical bearing capacity, while the cement mixing pile contributes around 19%. Based on the characteristic that the maximum axial force is concentrated in the upper half of the pile length, an innovative variable-diameter design with a reduced wall thickness of the steel pipe in the lower part of the pile was proposed. Practical verification has shown that, despite the reduced material usage, the load-bearing capacity remains largely unchanged. This effectively validates the feasibility of the “strong upper part and weak lower part” design concept and provides an effective way to reduce construction costs. Full article

Modularised wall panels are increasingly used in building and construction. A new double-skin composite (DSC) wall system technology uses clinch seams to combine two roll-formed open section profiles into a hollow steel shell that is then filled with a light-weight concrete foam and can provide a fire-rated DSC solution for use in commercial and high-rise buildings. One important material parameter for the application is the panel performance in wind loading. This study presents a first fundamental analysis of the structural behaviour of the new DSC wall panel relevant to wind loading. For this, 3-point and 4-point bending tests combined with in situ camera analysis are performed and complimented with the analysis of seam strength and the concrete material parameters. The experimental results provide the first experimental evidence that the aerated concrete core material of the DSC panel only has a minor effect on the wall performance in bending. Most of the bending loads are absorbed by the tensile and compressive deformation of the steel outer shell and the shear deformation near the clinch seam. In this way, failure at maximum load is not initiated by concrete cracking but by steel sheet buckling or a mixed failure mode that combines steel buckling and seam opening. Full article

In recent years, the European Union has actively advocated for decarbonising hard-to-abate industries, including the glass sector. Stakeholders in both glass manufacturing and the research community have collaborated to fulfil ambitious CO₂ emission reduction objectives mandated by Brussels, in several ways. The initial strategic action to be undertaken involves reducing energy consumption through energy efficiency interventions; to achieve this goal, it is essential to be aware of own consumption indicators by comparing them with appropriate performance ones. There are not many updated references connected to real-world cases, nor are indicators specifically tied to individual phases of the production process available. After a brief presentation of the container glass sector, which is the most important subsector, in terms of production capacity in Italy and the EU and its production process, the manuscript describes a real and representative plant of the sector, which has made its data available anonymously. In this way, energy performance indices representative of a typical production of the sector have been defined: they are updated and more detailed than the ones available in the literature. This representation therefore constitutes a case study that is representative of the most common plant configuration in the hollow glass sector in the EU. Full article

Following World War II, the swift economic growth in construction and the soaring demand in urban regions led to the excessive extraction of natural resources like fossil fuels, minerals, forests and land. To tackle significant global challenges, including the consumption of natural resources, air pollution and climate change, radical changes have been suggested over the past decades. As part of this strategic initiative, prioritizing sustainability in construction has emerged as a crucial focus in the design of all projects. In order to identify the most environmentally sustainable reinforced concrete (RC) slab system, this research investigates the carbon emissions associated with various slab systems, including solid, voided slabs and precast floor systems. The results demonstrate that beam and slab floor and solid slabs have the highest embodied carbon due to the significant use of concrete and related materials, whereas voided slabs and two-way joist floors exhibit lower carbon emissions. The results indicate that the two-way joist system is the most environmentally advantageous option. For precast floor systems, post-tensioned concrete and hollow-core slabs demonstrate the lowest embodied carbon levels. This research provides practical recommendations for architects and engineers aimed at enhancing sustainable design methodologies. It emphasizes the importance of incorporating low-carbon materials as well as pioneering flooring technologies in upcoming construction initiatives to support the achievement of global sustainability objectives. Full article

The relevance of the hemodialysis procedure is increasing worldwide due to the growing number of patients suffering from chronic kidney disease. Taking into account the structure of dialysis polymer membranes is an important aspect in their development to achieve the required performance of hemodialyzers. We propose a new mathematical model of mass transfer that allows hollow-fiber membrane structural parameters to be taken into account in simulating the clearance (CL) of hemodialyzers in a way that does not require difficult to achieve close approximation to the exact geometry of the membrane porous structure. The model was verified by a comparison of calculations with experimental data on $CL$ obtained using a lab-made dialyzer as well as commercially available ones. The simulations by the model show the non-trivial behavior of the dialyzer clearance as a function of membrane porosity ($f_p$) and the arrangement of pores ($\alpha$). The analysis of this behavior allows one to consider two strategies for increasing the $CL$ of the dialyzer by optimizing the polymer membrane structure: (1) creating a membrane with a well-structured pore system (where $\alpha$ → 1) since doubling $\alpha$ at a high enough $f_p$ can lead to an almost tenfold increase in $CL$; (2) increasing the porosity of the membrane characterized by a random arrangement of pores ($\alpha$ → 0), where, at a relatively low $\alpha$, a sharp increase in $CL$ is observed with a small increase in $f_p$ over a certain threshold value. Full article

Metamaterials enable the modulation of elastic waves or acoustic waves in unprecedented ways and have a wide range of potential applications. This paper achieves the simultaneous manipulation of surface elastic waves (SEWs) and surface acoustic waves (SAWs) using two-dimensional acousto-elastic metamaterials (AEMMs). The proposed AEMMs are composed of periodic hollow cylinders on the surface of a semi-infinite substrate. The band diagrams and the frequency responses of the AEMMs are numerically calculated through the finite element approach. The band diagrams exhibit simultaneous bandgaps for the SEWs and SAWs, which can also be effectively tuned by the modification of AEMM geometry. Furthermore, we construct the AEMM waveguide by the introduction of a line defect and hence demonstrate its ability to guide the SEWs and SAWs simultaneously. We expect that the proposed AEMMs will contribute to the development of multi-functional wave devices, such as filters for dual waves in microelectronics or liquid sensors that detect more than one physical property. Full article

The production and servicing of cement-based building materials is a source of large amounts of carbon dioxide emissions globally. One of the ways to reduce its negative impact, is to reduce concrete consumption per cubic meter of building structure through the introduction of hollow concrete products. At the same time, to maintain the load-bearing capacity of the building structure, it is necessary to significantly increase the strength of the concrete used. However, an increase in strength should be achieved not by increasing cement consumption, but by increasing the efficiency of its use. This research is focused on the development of technology for the production of thin-walled hollow concrete blocks based on high-strength, self-compacting, dispersed, micro-reinforced, fine-grained concrete. The use of this concrete provides 2–2.5 times higher strength in the amount of Portland cement consumed in comparison with ordinary concrete. The formation of external contours and partitions of thin-walled hollow blocks is ensured through the use of disposable formwork or cores used as void formers obtained by FDM 3D printing. This design solution makes it possible to obtain products based on high-strength concrete with higher structural and thermal insulation properties compared to now existing lightweight concrete-based blocks. Another area of application of this technology could be the production of wall structures of free configuration and cross-section due to their division, at the digital modeling stage, into individual element-blocks, manufactured in a factory environment. Full article

Hydrogen sulfide is present in active or extinct volcanic areas (mofettas). The habitable premises in these areas are affected by the presence of hydrogen sulfide, which, even in low concentrations, gives off a bad to unbearable smell. If the living spaces considered are closed enclosures, then a system can be designed to reduce the concentration of hydrogen sulfide. This paper presents a membrane-based way to reduce the hydrogen sulfide concentration to acceptable limits using a cellulosic derivative–propylene hollow fiber-based composite membrane module. The cellulosic derivatives considered were: carboxymethyl–cellulose (NaCMC), P1; cellulose acetate (CA), P2; methyl 2–hydroxyethyl–cellulose (MHEC), P3; and hydroxyethyl–cellulose (HEC), P4. In the permeation module, hydrogen sulfide is captured with a solution of cadmium that forms cadmium sulfide, usable as a luminescent substance. The composite membranes were characterized by SEM, EDAX, FTIR, FTIR 2D maps, thermal analysis (TG and DSC), and from the perspective of hydrogen sulfide air removal performance. To determine the process performances, the variables were as follows: the nature of the cellulosic derivative–polypropylene hollow fiber composite membrane, the concentration of hydrogen sulfide in the polluted air, the flow rate of polluted air, and the pH of the cadmium nitrate solution. The pertraction efficiency was highest for the sodium carboxymethyl–cellulose (NaCMC)–polypropylene hollow fiber membrane, with a hydrogen sulfide concentration in the polluted air of 20 ppm, a polluted air flow rate (Q_H2S) of 50 L/min, and a pH of 2 and 4. The hydrogen sulfide flux rates, for membrane P1, fall between 0.25 × 10⁻⁷ mol·m²·s⁻¹ for the values of Q_H2S = 150 L/min, C_H2S = 20 ppm, and pH = 2 and 0.67 × 10⁻⁷ mol·m⁻²·s⁻¹ for the values of Q_H2S = 50 L/min, C_H2S = 60 ppm, and pH = 2. The paper proposes a simple air purification system containing hydrogen sulfide, using a module with composite cellulosic derivative–polypropylene hollow fiber membranes. Full article

At Cracow University of Technology, attempts were made to develop national truck scale platforms with a capacity of 60 tons, made from prestressed concrete. For this work, we designed slabs partially prestressed with unbonded tendons featuring a cross-section of 1.00 × 0.28 m and a span of 5.94 m. To reduce the weight of the slabs, four channels made from commonly used ø110 × 2.2 mm PVC pipes were used. In this way, we created post-tensioned hollow-core slabs. Due to the unpredictable behavior of slabs operating in a cracked state under a repetitive load, two slabs were subjected to cyclic loads amounting to 1,000,000 cycles with different load values. This paper presents the basic design principles and design details of the slabs, as well as the methodology and results of the research conducted. Lastly, we provide appropriate conclusions directed at further optimizing the slabs. Full article