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32 pages, 11230 KiB  
Article
Integration of Lattice Structures into the Boring Bars as a Passive Chatter Suppression Technique: Concepualization, Modelling and Simulation
by Ekrem Oezkaya, Kubilay Aslantas, Adem Çiçek and Hüseyin Alp Çetindağ
Vibration 2025, 8(2), 29; https://doi.org/10.3390/vibration8020029 - 5 Jun 2025
Viewed by 626
Abstract
The present study concentrates on passive damping technology, in which the damping of vibrations is accomplished by the integration of lattice structures into the boring bar. To complete this process, several steps must be followed. First, the largest possible hollow space within the [...] Read more.
The present study concentrates on passive damping technology, in which the damping of vibrations is accomplished by the integration of lattice structures into the boring bar. To complete this process, several steps must be followed. First, the largest possible hollow space within the boring bar was determined, and the two main influencing factors—stiffness and natural frequency—were harmonized. A rigorous analysis of vibration reduction was conducted on the basis of a validated simulation model. This analysis involved six distinct lattice structures designed using ANSYS SpaceClaim 19.0. In light of the findings, a specialized, application-specific CAD simulation tool was developed, employing appropriate methodologies to circumvent the limitations of conventional CAD software. For the hollow integrated into the boring bar, ellipsoidal shapes were shown to be preferable to cylindrical ones due to their superior dynamic performance. The initial lattice structure, namely a cube lattice with side cross supports, exhibited an enhancement in damping of 55.58% in comparison with the reference model. Following this result, five additional modelling steps were performed, leading to an optimal outcome with a 67.79% reduction in vibrations. Moreover, the modifications made to the beam diameter of the lattice units yielded enhanced dynamic performance, as evidenced by a vibration suppression of 69.81%. The implementation of complex modelling steps, such as the integration of a hollow and the integration of lattice structures, could be successfully achieved through the development of a suitable and user-friendly simulation tool. The effectiveness of the simulation tool in enabling parameterized modelling for scalable lattice structures was demonstrated. This approach was found to be expeditious in terms of the time required for implementation. The potential exists for the extension of this simulation tool, with the objective of facilitating research projects with a view to optimization, i.e., a large number of research projects. Full article
(This article belongs to the Special Issue Vibration Damping)
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23 pages, 14855 KiB  
Article
Selection of a Turbulence Model for Wave Evolution on a New Ecological Hollow Cube
by Haitao Zhao, Junwei Ye, Kaifang Wang, Yian Zhou, Zhen Zeng, Qiang Li and Xizeng Zhao
Water 2025, 17(8), 1149; https://doi.org/10.3390/w17081149 - 12 Apr 2025
Viewed by 384
Abstract
A suitable turbulence model is needed for numerical simulations to accurately simulate the wave evolution and hydrodynamic performance of the new ecological hollow cube. The new ecological hollow cube is an improvement upon traditional designs, as it can grow plants to dissipate wave [...] Read more.
A suitable turbulence model is needed for numerical simulations to accurately simulate the wave evolution and hydrodynamic performance of the new ecological hollow cube. The new ecological hollow cube is an improvement upon traditional designs, as it can grow plants to dissipate wave energy. In this study, the open-source computational fluid dynamics (CFD) software OpenFOAM v2206 is used as the computational platform to analyze and evaluate the numerical results of four turbulence models, i.e., the standard k-ε, steady k-ω shear stress transfer (SST), buoyancy-corrected k-ω SST, and large eddy simulation (LES) models, by using three mesh systems (with grid counts of 0.89, 2.92, and 8.91 million grids, respectively). Comparison of the numerical results from the four turbulence models reveals that the stabilized k-ω SST turbulence model provides better results for simulating the complex wave evolution process on the cube and effectively captures the wave free surface. In contrast, the other models exhibit a greater grid dependency. The stabilized k-ω SST model more accurately captures the wave run-up and reflection coefficient better than other turbulence models do. Therefore, the stabilized k-ω SST model is selected as the most suitable turbulence model for hydrodynamic modeling of the new ecological hollow cube. Full article
(This article belongs to the Special Issue Coastal Engineering and Fluid–Structure Interactions)
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27 pages, 9696 KiB  
Article
Investigations on the Deflection of Carbon-Reinforced Concrete Hollow-Core Slabs
by David Sandmann, Michael Frenzel, Steffen Marx and Manfred Curbach
Materials 2025, 18(6), 1212; https://doi.org/10.3390/ma18061212 - 8 Mar 2025
Viewed by 1009
Abstract
The article presents the experimental and computational investigations on carbon-reinforced concrete (CRC) slabs with hollow-core cross-sections. Designed for use in building construction, they combine the benefits of lightweight construction, resource efficiency, and precise prefabrication. Three geometrically identical elements were manufactured and tested until [...] Read more.
The article presents the experimental and computational investigations on carbon-reinforced concrete (CRC) slabs with hollow-core cross-sections. Designed for use in building construction, they combine the benefits of lightweight construction, resource efficiency, and precise prefabrication. Three geometrically identical elements were manufactured and tested until failure in four-point bending tests. The slabs demonstrated a high load capacity of around 50 kNm, together with high ductility due to a deformation of more than 80 mm before failure. The load-deflection curves recorded could be reproduced very well with the analytical-physical calculation model created for both the non-cracked and cracked slab states. The strengths and stiffnesses of the materials used for input were derived from small-scale, accompanying material tests. As a result, the calculation model was ultimately used to design the carbon-reinforced ceilings of the CRC technology demonstration house CUBE, which was finished in 2022 in Dresden, East Germany. Full article
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16 pages, 5129 KiB  
Article
A Rapid and Surfactant-Free Synthesis Strategy for Variously Faceted Cuprous Oxide Polyhedra
by Kaihao Liu, Yu Xin, Shikun Gao, Yadong Yu, Mengyan Dai and Zhe Liu
Nanomaterials 2025, 15(3), 240; https://doi.org/10.3390/nano15030240 - 4 Feb 2025
Viewed by 1098
Abstract
We systematically investigated the morphology-controlled synthesis of Cu2O micro-nano crystals, especially under surfactant-free conditions, targeting a simple, rapid, and morphologically controllable preparation strategy for polyhedral Cu2O micro-nano crystals. By systematically investigating the effects of NaOH concentration, types of reducing [...] Read more.
We systematically investigated the morphology-controlled synthesis of Cu2O micro-nano crystals, especially under surfactant-free conditions, targeting a simple, rapid, and morphologically controllable preparation strategy for polyhedral Cu2O micro-nano crystals. By systematically investigating the effects of NaOH concentration, types of reducing agents, and copper salt precursors on crystal growth, precise control over the morphology of Cu2O crystals under surfactant-free conditions was achieved. This method can rapidly prepare variously faceted Cu2O crystals under mild conditions (70 °C, 7 min), including regular polyhedra with low-index facets exposure including cubes, octahedra and rhombic dodecahedra, as well as more complex polyhedra with high-index facets exposure such as 18-faceted, 26-faceted, 50-faceted and 74-faceted crystals. NaOH concentration is found to be the key factor in controlling Cu2O crystal morphology: as the concentration of NaOH increases, the morphology of Cu2O crystals gradually transforms from cubes that fully expose the {100} faces to regular polyhedra that expose the {110}, {111} faces, and even other high-index faces, ultimately presenting octahedra that fully expose the {111} faces. Additionally, Cu2O crystals with unique morphologies such as hollow cubes and 18-faceted with {110} face etched can be obtained by introducing surfactants or prolonging reaction durations. This work provides new insights into the morphology control of Cu2O crystals and establishes foundation in acquiring distinct Cu2O polyhedra in a facile manner for their application in catalysis, optoelectronics, sensing, and energy conversion fields. Full article
(This article belongs to the Section Synthesis, Interfaces and Nanostructures)
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16 pages, 4067 KiB  
Article
Physical Experimental Study on the Wave Reflection and Run-Up of a New Ecological Hollow Cube
by Haitao Zhao, Feiyue Ding, Junwei Ye, Huabin Jiang, Wei Chen, Weifang Gu, Gengfeng Yu and Qiang Li
J. Mar. Sci. Eng. 2024, 12(4), 664; https://doi.org/10.3390/jmse12040664 - 17 Apr 2024
Cited by 4 | Viewed by 1828
Abstract
Implementing quadrangular hollow blocks on breakwaters is a common method for wave mitigation and ocean disaster prevention. In order to improve the wave-damping performance of conventional quadrangular hollow blocks, a new quadrangular hollow block is proposed. In this study, a series of physical [...] Read more.
Implementing quadrangular hollow blocks on breakwaters is a common method for wave mitigation and ocean disaster prevention. In order to improve the wave-damping performance of conventional quadrangular hollow blocks, a new quadrangular hollow block is proposed. In this study, a series of physical modeling experiments were conducted in a two-dimensional wave flume to investigate the wave reflection and wave run-up height of a new quadrilateral hollow block under regular wave action. Test results showed that wave reflection and wave run-up height decreased with the breakwater slope. The wave run-up height increased with wave height, and the reflection coefficient decreased with wave height. Wave reflection and run-up height increased with the wave period. The reflection coefficient of the new quadrangular hollow blocks was lower than that of the conventional quadrangular hollow blocks and decreased with frame height. In addition, this study found that the reflection coefficient and relative run-up height increased with the average wave breaking parameter. The new quadrilateral hollow block has advantages in wave mitigation compared to the conventional quadrilateral hollow block. Full article
(This article belongs to the Special Issue Wave Interactions with Coastal Structures II)
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21 pages, 4152 KiB  
Article
Full-Range Static Method of Calibration for Laser Tracker
by Chang’an Hu, Fei Lv, Liang Xue, Jiangang Li, Xiaoyin Zhong and Yue Xu
Electronics 2023, 12(22), 4709; https://doi.org/10.3390/electronics12224709 - 20 Nov 2023
Cited by 2 | Viewed by 1615
Abstract
This paper focuses on the challenge of the inability to accurately calibrate the static measurement of a laser tracker across the full scale. To address this issue, this paper proposes to add a hollow corner cube prism on a 50 m high-precision composite [...] Read more.
This paper focuses on the challenge of the inability to accurately calibrate the static measurement of a laser tracker across the full scale. To address this issue, this paper proposes to add a hollow corner cube prism on a 50 m high-precision composite guide rail to achieve a double-range measurement of the laser tracker. Data analysis indicated that, in the 77 m identical-directional double-range measurement experiment, the maximum indication error of a single-beam laser interferometer was −29.5 μm, and that of a triple-beam laser interferometer was 14.6 μm, and the measurement indication error was obviously small when the Abbe error was eliminated. The single-point repeatability of the tracker was 0.9 μm. In the 50 m identical-directional verification experiment, the results of the direct measurement outperformed those of the double-range measurement, and the indication errors under standard conditions were −4.0 μm and −8.9 μm, respectively. Overall, the method used in the experiment satisfies the requirements of the laser tracker. In terms of the identical-directional measurement, the measurement uncertainty of the tracker indication error is U ≈ 1.0 μm + 0.2L (k = 2) L = (0~77 m). The proposed method also provides insights for length measurements using other high-precision measuring instruments. Full article
(This article belongs to the Special Issue Optoelectronic Materials, Heterostructures and Devices)
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17 pages, 6326 KiB  
Article
A Tutorial on Retroreflectors and Arrays Used in Satellite and Lunar Laser Ranging
by John J. Degnan
Photonics 2023, 10(11), 1215; https://doi.org/10.3390/photonics10111215 - 31 Oct 2023
Cited by 8 | Viewed by 4990
Abstract
The present paper discusses the basics of retroreflector theory and the manner in which they are combined in arrays to service the laser tracking of artificial satellites and the Moon. We begin with a discussion of the relative advantages and disadvantages of solid [...] Read more.
The present paper discusses the basics of retroreflector theory and the manner in which they are combined in arrays to service the laser tracking of artificial satellites and the Moon. We begin with a discussion of the relative advantages and disadvantages of solid versus hollow cube corners and the functional dependence of their optical cross-sections and far-field patterns on cube diameter. Because of velocity aberration effects, the design of an array for a particular space mission depends on many factors, including the desired range accuracy and the satellite’s orbital altitude, velocity, and pass geometry relative to the tracking station. This generally requires the individual retroreflectors in the array to be “spoiled” by perturbing one or more of the 90-degree angles that define a perfect cube corner, or alternatively, by adding a curved surface to a hollow cube. In order to obtain adequate return signal strengths from all points along the satellite path, the rotational orientation of the retroreflectors within the array may need to be varied or “clocked”. Possible approaches to developing millimeter-accuracy arrays with both large cross-sections and ultrashort satellite signatures are discussed, as are new designs proposed to replace aging reflectors on the Moon. Finally, we briefly discuss methods for laser ranging beyond the Moon. Full article
(This article belongs to the Special Issue Optical Systems for Astronomy)
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11 pages, 9876 KiB  
Article
Computed Tomography Attenuation of Three-Dimensional (3D) Printing Materials—Depository to Aid in Constructing 3D-Printed Phantoms
by Yuktesh Kalidindi, Aravinda Krishna Ganapathy, Yash Nayak, Anusha Elumalai, David Z. Chen, Grace Bishop, Adrian Sanchez, Brian Albers, Anup S. Shetty and David H. Ballard
Micromachines 2023, 14(10), 1928; https://doi.org/10.3390/mi14101928 - 14 Oct 2023
Cited by 5 | Viewed by 1881
Abstract
Three-dimensionally printed phantoms are increasingly used in medical imaging and research due to their cost-effectiveness and customizability, offering valuable alternatives to commercial phantoms. The purpose of this study was to assess the computed tomography (CT) attenuation characteristics of 27 resin materials from Formlabs, [...] Read more.
Three-dimensionally printed phantoms are increasingly used in medical imaging and research due to their cost-effectiveness and customizability, offering valuable alternatives to commercial phantoms. The purpose of this study was to assess the computed tomography (CT) attenuation characteristics of 27 resin materials from Formlabs, a 3D printing equipment and materials manufacturer. Cube phantoms (both solid and hollow constructions) produced with each resin were subjected to CT scanning under varying tube current–time products with attenuation measurements recorded in Hounsfield units (HU). The resins exhibited a wide range of attenuation values (−3.33 to 2666.27 HU), closely mimicking a range of human tissues, from fluids to dense bone structures. The resins also demonstrated consistent attenuation regardless of changes in the tube current. The CT attenuation analysis of FormLabs resins produced an archive of radiological imaging characteristics of photopolymers that can be utilized to construct more accurate tissue mimicking medical phantoms and improve the evaluation of imaging device performance. Full article
(This article belongs to the Section B2: Biofabrication and Tissue Engineering)
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10 pages, 1797 KiB  
Communication
Multi-Prismatic Hollow Cube CeVO4 with Adjustable Wall Thickness Directed towards Photocatalytic CO2 Reduction to CO
by Yong Zhou, Guan Wang, Jiahao Wu, Zihao Chen, Chen Zhang, Ping Li, Yong Zhou and Wei Huang
Nanomaterials 2023, 13(2), 283; https://doi.org/10.3390/nano13020283 - 10 Jan 2023
Cited by 5 | Viewed by 2211
Abstract
Ternary orthovanadate compounds have received increasing attention due to their broad light absorption and diverse crystal structure. However, their multi-assembled crystal morphologies are limited mainly due to their initially polyatomic VO4 groups. In this study, multi-prismatic hollow cubic CeVO4 microstructures were [...] Read more.
Ternary orthovanadate compounds have received increasing attention due to their broad light absorption and diverse crystal structure. However, their multi-assembled crystal morphologies are limited mainly due to their initially polyatomic VO4 groups. In this study, multi-prismatic hollow cubic CeVO4 microstructures were fabricated by a one-step solvothermal method without any organic agents. The increase in wall thickness is in accordance with the radial direction of the quadrangular prism. Moreover, the overdose of the V precursor is favorable for the formation of hollow micro-cubic CeVO4, and the wall thickness changes from 200 to 700 nm. Furthermore, these CeVO4 microstructures were applied to photocatalytic CO2 reduction with a maximum CO generation rate of up to 78.12 μmol g−1 h−1 under visible light irradiation, which was several times higher than that of the other samples. This superior photocatalytic activity might be attributed to its good crystallinity and unique exposed interior structure. This study provides guidelines for the multi-assembled structure fabrication of ternary compounds and expands upon the exploration of the spatial structure of multivariate compounds. Full article
(This article belongs to the Section Energy and Catalysis)
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10 pages, 2123 KiB  
Article
Facile Synthesis of Urchin-like Hollow Au Crystals for In Situ SERS Monitoring of Photocatalytic Reaction
by Yuanzhao Wu, Mingjie Chen, Haohao Bai, Binjie Wang, Jiye Wang, Yazhou Qin and Weixuan Yao
Crystals 2022, 12(7), 884; https://doi.org/10.3390/cryst12070884 - 22 Jun 2022
Cited by 3 | Viewed by 2664
Abstract
Hollow urchin-like Au nanocrystals have been widely studied due to their excellent surface plasmon resonance properties and large specific surface area, but the controllable preparation of hollow urchin-like Au nanocrystals is still a challenge. In this article, we successfully prepared hollow urchin-like Au [...] Read more.
Hollow urchin-like Au nanocrystals have been widely studied due to their excellent surface plasmon resonance properties and large specific surface area, but the controllable preparation of hollow urchin-like Au nanocrystals is still a challenge. In this article, we successfully prepared hollow urchin-like Au nanocrystals using HAuCl4·3H2O and AgNO3 as precursors and ascorbic acid as the reducing agent. No surface ligands or polymer stabilizers are required in the preparation process. HAuCl4·3H2O and AgNO3 will first form AgCl cubes, then the reducing agent, ascorbic acid, will reduce the Au3+ in the solution to Au0, and Au0 will be deposited on the pre-formed AgCl cubes to form AgCl@Au nanocrystals. We characterized the morphology of the prepared Au nanocrystals by scanning electron microscopy and found that by increasing the amount of HAuCl4·3H2O in the reaction, the surface morphology of the Au nanocrystals would change from a rough spherical shape to an urchin-like shape. By further increasing the amount of the precursor HAuCl4·3H2O, urchin-like Au will convert into flake-like morphology. The AgCl in the interior was removed with ammonia water, and finally, hollow urchin-like Au crystals were formed. In addition, we used R6G molecule to explore the surface-enhanced Raman spectroscopy (SERS) enhancement effect of prepared Au crystals. The results show that the minimum detectable concentration of R6G reaches 10−8 M. Moreover, we applied hollow urchin-like Au nanocrystals as catalysts and SERS enhancing materials to detect the photocatalytic reaction of 4-NTP. We used a 785 nm laser as both the SERS light source and the catalytic light source to monitor the photocatalytic effect of the laser on 4-NTP in situ by adjusting the laser power. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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16 pages, 28595 KiB  
Article
PdAgPt Corner-Satellite Nanocrystals in Well-Controlled Morphologies and the Structure-Related Electrocatalytic Properties
by Hehe Qian, Jianzhou Wu, Yongsheng Guo and Wenjun Fang
Nanomaterials 2021, 11(2), 340; https://doi.org/10.3390/nano11020340 - 29 Jan 2021
Cited by 4 | Viewed by 2809
Abstract
The functions of heterogeneous metallic nanocrystals (HMNCs) can be undoubtedly tuned by controlling their morphologies and compositions. As a less-studied kind of HMNCs, corner-satellite multi-metallic nanocrystals (CSMNCs) have great research value in structure-related electrocatalytic performance. In this work, PdAgPt corner-satellite nanocrystals with well-controlled [...] Read more.
The functions of heterogeneous metallic nanocrystals (HMNCs) can be undoubtedly tuned by controlling their morphologies and compositions. As a less-studied kind of HMNCs, corner-satellite multi-metallic nanocrystals (CSMNCs) have great research value in structure-related electrocatalytic performance. In this work, PdAgPt corner-satellite nanocrystals with well-controlled morphologies and compositions have been developed by temperature regulation of a seed-mediated growth process. Through the seed-mediated growth, the morphology of PdAgPt products evolves from Pd@Ag cubes to PdAgPt corner-satellite cubes, and eventually to truncated hollow octahedra, as a result of the expansion of {111} facets in AgPt satellites. The growth of AgPt satellites exclusively on the corners of central cubes is realized with the joint help of Ag shell and moderate bromide, and hollow structures form only at higher reaction temperatures on account of galvanic displacement promoted by the Pd core. In view of the different performances of Pd and Pt toward formic acid oxidation (FAO), this structure-sensitive reaction is chosen to measure electrocatalytic properties of PdAgPt HMNCs. It is proven that PdAgPt CSMNCs display greatly improved activity toward FAO in direct oxidation pathway. In addition, with the help of AgPt heterogeneous shells, all PdAgPt HMNCs exhibit better durability than Pd cubes and commercial Pt. Full article
(This article belongs to the Special Issue Advanced Noble Metal Nanoparticles)
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9 pages, 1116 KiB  
Article
Hollow Silica Cubes with Customizable Porosity
by Samuel Hugh Gallagher, Olivier Trussardi, Oliver Lipp and Dominik Brühwiler
Materials 2020, 13(11), 2474; https://doi.org/10.3390/ma13112474 - 29 May 2020
Cited by 5 | Viewed by 3399
Abstract
Hollow silica cubes were synthesized by a deposition of a thin silica shell onto micrometer-sized hematite cubes. Ordered mesopores with well-defined pore diameters of 2.8 nm and 3.8 nm were introduced into the silica shell by means of pseudomorphic transformation after removal of [...] Read more.
Hollow silica cubes were synthesized by a deposition of a thin silica shell onto micrometer-sized hematite cubes. Ordered mesopores with well-defined pore diameters of 2.8 nm and 3.8 nm were introduced into the silica shell by means of pseudomorphic transformation after removal of the hematite core. The particles retained their cubic morphology upon pseudomorphic transformation, allowing for the preparation of close-packed layers of the hollow mesoporous silica cubes by drop-casting and the visualization of the hollow core by focused ion beam scanning electron microscopy. Full article
(This article belongs to the Special Issue Recent Advances in Mesoporous Materials)
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16 pages, 4252 KiB  
Article
Effects of Steam Sterilization on 3D Printed Biocompatible Resin Materials for Surgical Guides—An Accuracy Assessment Study
by Neha Sharma, Shuaishuai Cao, Bilal Msallem, Christoph Kunz, Philipp Brantner, Philipp Honigmann and Florian M. Thieringer
J. Clin. Med. 2020, 9(5), 1506; https://doi.org/10.3390/jcm9051506 - 17 May 2020
Cited by 73 | Viewed by 6186
Abstract
Computer-assisted surgery with three-dimensional (3D) printed surgical guides provides more accurate results than free-hand surgery. Steam sterilization could be one of the factors that affect the dimensions of surgical guide resin materials, leading to inaccuracies during surgeries. The purpose of this study was [...] Read more.
Computer-assisted surgery with three-dimensional (3D) printed surgical guides provides more accurate results than free-hand surgery. Steam sterilization could be one of the factors that affect the dimensions of surgical guide resin materials, leading to inaccuracies during surgeries. The purpose of this study was to evaluate the effects of steam sterilization on the dimensional accuracy of indication-specific hollow cube test bodies, manufactured in-house using Class IIa biocompatible resin materials (proprietary and third-party). To evaluate the pre- and post-sterilization dimensional accuracy, root mean square (RMS) values were calculated. The results indicate that, in all the groups, steam sterilization resulted in an overall linear expansion of the photopolymeric resin material, with an increase in outer dimensions and a decrease in inner dimensions. The effects on the dimensional accuracy of test bodies were not statistically significant in all the groups, except PolyJet Glossy (p > 0.05). The overall pre- and post-sterilization RMS values were below 100 and 200 µm, respectively. The highest accuracies were seen in proprietary resin materials, i.e., PolyJet Glossy and SLA-LT, in pre- and post-sterilization measurements, respectively. The dimensional accuracy of third-party resin materials, i.e., SLA-Luxa and SLA-NextDent, were within a comparable range as proprietary materials and can serve as an economical alternative. Full article
(This article belongs to the Special Issue Innovation in Head and Neck Reconstructive Surgery)
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8 pages, 5846 KiB  
Article
Morphology-Controllable Hydrothermal Synthesis of Zirconia with the Assistance of a Rosin-Based Surfactant
by Chen Guo, Peng Wang, Shengliang Liao, Hongyan Si, Shangxing Chen, Guorong Fan and Zongde Wang
Appl. Sci. 2019, 9(19), 4145; https://doi.org/10.3390/app9194145 - 3 Oct 2019
Cited by 10 | Viewed by 3078
Abstract
With the assistance of a rosin-based surfactant, dehydroabietyltrimethyl ammonium bromine (DTAB), well-dispersed hollow cube-like zirconia particles were firstly synthesized by the hydrothermal treatment of ZrOCl2 aqueous solutions. The introduction of DTAB is crucial for improving the dispersion and regularity of the as-synthesized [...] Read more.
With the assistance of a rosin-based surfactant, dehydroabietyltrimethyl ammonium bromine (DTAB), well-dispersed hollow cube-like zirconia particles were firstly synthesized by the hydrothermal treatment of ZrOCl2 aqueous solutions. The introduction of DTAB is crucial for improving the dispersion and regularity of the as-synthesized sample. After calcination, the crystal size of the calcined samples increased, and the edge angle of the cube-like particles became round accordingly. Finally, a hollow spherical morphology was formed for the sample calcined at 923 K. The as-synthesized sample showed big surface area of 146.78 m2/g and large pore volume of 0.23 cm3/g. With the increase of calcination temperature, the surface area and pore volume of the samples decreased significantly, and the pore size increased accordingly. Full article
(This article belongs to the Special Issue Metal-Oxide Nanostructures: From Photocatalysis to Energy)
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11 pages, 3140 KiB  
Article
Synthesis of Ni-Co Hydroxide Nanosheets Constructed Hollow Cubes for Electrochemical Glucose Determination
by Fengchao Sun, Shutao Wang, Yuqi Wang, Jingtong Zhang, Xinping Yu, Yan Zhou and Jun Zhang
Sensors 2019, 19(13), 2938; https://doi.org/10.3390/s19132938 - 3 Jul 2019
Cited by 44 | Viewed by 4549
Abstract
Hierarchical Ni-Co double transition metal hydroxide nanosheets have been explored as an effective strategy for the design of nonenzymatic glucose sensors. Ni-Co hydroxide nanosheets constructed hollow cubes were successfully synthesized by using Cu2O cubes as templates and subsequently etched by Na [...] Read more.
Hierarchical Ni-Co double transition metal hydroxide nanosheets have been explored as an effective strategy for the design of nonenzymatic glucose sensors. Ni-Co hydroxide nanosheets constructed hollow cubes were successfully synthesized by using Cu2O cubes as templates and subsequently etched by Na2S2O3 to achieve a hollow cubic structure. The molar ratio between Ni and Co was tuned by varying the precursor ratio of NiCl2 and CoCl2. It was observed by transmission electron microscopy (TEM) that the increasing Ni precursor resulted in particle morphology, and the increasing ratio of the Co precursor resulted in more lamellar morphology. The sample with the composition of Ni0.7Co0.3(OH)2 displayed the best performance for glucose sensing with high selectivity (1541 μA mM–1 cm–2), low detection limit (3.42 µM with S/N = 3), and reasonable selectivity. Similar strategies could be applied for the design of other electrode materials with high efficiency for nonenzymatic glucose determination. Full article
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