Search Results (969)

Suspended two-dimensional (2D) materials in high-performance devices exhibit unique properties that are critically important for nanoscale mechanical and electromechanical applications, while their frictional laws remain poorly understood. Here, we investigate the nanoscale frictional behavior of suspended WS₂ flakes under varying applied loads and scanning rates using atomic force microscopy (AFM), and successfully employ the Bowden–Tabor theory and the thermally activated Prandtl–Tomlinson (PTT) model to analyze the load- and scanning-rate-dependent friction characteristics of suspended 2D systems. The results show that suspended WS₂ exhibits higher friction than supported WS₂, whereas its friction increases more slowly with applied load, which can be well described by the Bowden–Tabor theory. Moreover, the friction exhibits a logarithmic dependence on scanning rate for both suspended and supported WS₂. Quantitative analysis within the framework of the PTT model demonstrates that this model can be successfully extended to describe the rate-dependent friction of suspended WS₂, providing a unified framework for both supported interfaces and suspended 2D systems. This work provides valuable guidance for understanding frictional dissipation mechanisms relevant to the design and optimization of WS₂-based devices. Full article

In this study, a hierarchical design strategy is introduced for tuning the release of rosmarinic acid (RA) from electrospun poly(L-lactide) (PLA) fibrous materials via surface engineering with chitosan/hyaluronic acid (Ch/HA) polyelectrolyte complexes (PECs). RA was selectively incorporated within the fiber bulk, the PEC coating, or both, enabling control over its spatial distribution. The PEC coating, formed by sequential dip coating, was shown to act as a diffusion-regulating layer with a dual role—either retarding RA release or promoting rapid initial release when functioning as a surface-associated reservoir. As a result, the release kinetics could be systematically tuned depending on the coating architecture and RA localization. Thorough characterization confirmed successful coating formation, enhanced surface hydrophilicity, and improved mechanical performance. All RA-loaded materials retained high antioxidant activity and exhibited pronounced antibacterial and antifungal effects against Staphylococcus aureus, Escherichia coli, and Candida albicans. This work introduces PEC-modified electrospun systems as a versatile platform for the rational design of multifunctional fibrous biomaterials with controlled release profiles, with potential applications in wound healing and drug delivery. Full article

Floods are among the most frequent and destructive natural hazards, causing significant socio-economic losses worldwide. This paper presents a comprehensive review of floodwall technologies, focusing on the integration of ultra-high-performance fibre-reinforced concrete (UHPFRC) to enhance structural and hydraulic performance. Flood protection systems are categorized into permanent, demountable, and temporary, and are evaluated based on parameters such as activation time, seepage resistance, and lifecycle cost. This review examines key structural applications, including floodwall barriers, wave-energy floaters, and retaining walls, in which UHPFRC provides significant advantages such as reduced material consumption, improved impact resistance, and increased durability in harsh environmental conditions. Additionally, recent advancements in floodwall systems are critically assessed through experimental investigations, numerical modelling, and hydraulic performance under varied loading and flow conditions. The analysis reveals that while UHPFRC systems can reduce material volumes by up to 73% and carbon emissions by 49% compared to conventional reinforced concrete, their adoption is currently limited by a lack of dedicated design standards. Based on a synthesis of peer-reviewed studies (2010–2026), findings indicate that autonomous, buoyancy-driven UHPFRC barriers offer the highest reliability in high-risk zones, whereas manual modular systems remain limited by human-factor vulnerabilities during rapid deployment. Critical research gaps are identified—specifically the need for standardized constitutive models for UHPFRC in hydrostatic environments and extensive long-term field validation—to support the transition toward resilient, smart urban flood defence infrastructure. Full article

In materials science, the increasing use of lightweight and multi-material structures has made improving the interfacial bonding characteristics of polymer-based adhesive systems increasingly important. Accordingly, chemical surface activation and interfacial engineering strategies have attracted considerable attention for enhancing polymer–fiber compatibility and adhesion performance. However, the combined effects of fiber content, surface treatment, and orientation on adhesion behavior remain insufficiently understood. In the present study, natural fibers obtained from the rachis part of the palm tree were chemically modified and incorporated into an epoxy adhesive matrix to investigate the effect of surface functionalization on polymer–fiber interfacial adhesion. In the first stage, the effects of fiber ratios (5–20 wt%) and chemical surface treatments (methanol cleaning and methanol +2–6% HNO₃) on adhesion behavior were evaluated. Tensile tests showed that specimens treated with methanol cleaning followed by 4% HNO₃ oxidation and containing 10 wt% fiber exhibited an approximately 48% increase in failure load compared to neat joints. In the second stage, the influence of fiber orientation (0–90°) was examined using the optimized parameters. The results indicate that interfacial load-transfer capability increased as the fiber orientation approached perpendicular alignment, reaching maximum performance at 90°. Based on SEM observations, nitric acid treatment was found to increase the surface roughness of the fibers and strengthen the polymer–fiber interfacial bond. FTIR, XPS and contact angle measurements suggested the development of oxygen-containing surface functionalities and improved wettability, consistent with enhanced interfacial adhesion. These findings demonstrate that appropriate chemical surface treatment, fiber content, and orientation can effectively enhance the interfacial adhesion and bonding efficiency of epoxy-based adhesive systems, providing practical guidance for the design of high-performance bonded structures. Full article

The complete removal of persistent aromatic organic pollutants from aqueous environments demands the development of sustainable and highly efficient filtration materials. In this study, novel bio-sourced mixed-matrix membranes (MMMs) were successfully fabricated by incorporating the highly porous metal–organic framework MIL-68(Al) into a biodegradable polylactic acid (PLA) matrix via a solvent-induced phase inversion method. The integration of MIL-68(Al) nanoparticles significantly tailored the membrane’s morphological structure, endowing the hybrid membranes with enhanced surface hydrophilicity (water contact angle reduced from 90.3° to 72.7°) and superior permeability. The pure water flux reached an optimal value of 42.2 L m⁻² h⁻¹ at a 15 wt.% MOF loading. Crucially, the hybrid membranes exhibited exceptionally high adsorptive removal performance for p-nitrophenol (PNP) and methylene blue (MB). Driven by the abundant accessible active sites of the MOF filler, the MIL-20/PLA membrane achieved a maximum equilibrium adsorption capacity of 121.03 μg/cm² (36.90 mg/g) for PNP, representing a remarkable 25.7-fold enhancement over the pristine PLA membrane. Kinetic analyses confirmed that the adsorption process is strictly governed by pseudo-second-order kinetics, indicating a chemisorption mechanism dominated by hydrogen bonding and π–π stacking interactions. Furthermore, the optimized membranes demonstrated outstanding dynamic filtration efficiencies (>80%) and robust regenerability over multiple continuous operating cycles. This work not only highlights the synergistic interfacial effects between MOFs and biodegradable polymers but also provides a highly effective, eco-friendly, and sustainable membrane platform for the advanced remediation of organic-contaminated wastewater. Full article

To mitigate health hazards from pathogenic bacteria (Escherichia coli, Staphylococcus aureus) and fungi (Aspergillus niger) as well as the coating mildew issue in high-humidity indoor environments, and to overcome the challenges of particle agglomeration and non-uniform distribution in conventional benzalkonium chloride (BAC)-clay composites, this study proposes a wet chemical strategy to prepare BAC-hectorite antimicrobial composites using synthetic hectorite as a high-performance carrier, which is superior to natural clays such as montmorillonite and kaolin in structural uniformity, ion-exchange efficiency, and dispersion stability. Characterization using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and Brunauer–Emmett–Teller (BET) analysis confirmed the successful intercalation of BAC cations into the hectorite interlayers through ion exchange. This resulted in a significant expansion of the interlayer spacing from 1.0–1.2 nm to 1.5–1.8 nm, a marked alleviation of particle agglomeration, and an optimized pore structure. A clear structure–activity relationship between preparation conditions, microstructure regulation, and antimicrobial performance is systematically established. Antibacterial tests revealed superior efficacy against Gram-positive bacteria; the composite exhibited an inhibition zone of 13.31 mm and a minimum inhibitory concentration (MIC) of 4 μg/mL against S. aureus, compared to 11.62 mm and 32 μg/mL against E. coli. Practical application tests demonstrated that at an ultralow addition level of 0.4%, incorporating this composite into latex paint achieved an antibacterial rate exceeding 99.9% against both pathogens. When added to putty powder, it yielded Grade 0 mold resistance with no observable growth. Furthermore, compounding with polypropylene (PP) increased the elongation at break to approximately 600%, simultaneously realizing antibacterial, antifungal, and toughening functions, thereby not only conferring antibacterial functionality but also significantly enhancing toughness—resolving the typical polymer embrittlement caused by traditional inorganic antibacterial fillers. Short-term evaluations confirm that this composite offers a stable structure, high-efficiency antimicrobial properties, and improved substrate mechanics at low loading levels. These findings provide technical support and experimental guidance for the functional upgrading of indoor decorative coatings, putties, and polymer materials used in high-humidity scenarios such as kitchens and bathrooms. Full article

The development of fusion technology requires materials that can withstand heat, erosion, and activation at the edge of fusion plasma. Thanks to its high melting point, superior thermal conductivity, and excellent resistance to sputtering and retention, tungsten (W) has been regarded as the leading candidate for the plasma-facing materials (PFMs) of the main chambers and divertors in controlled thermonuclear fusion reactors. Nevertheless, W-PFMs are prone to complex severe surface deterioration under extreme service conditions during operation in fusion reactors. This includes physical/chemical sputtering, which results in material loss and plasma contamination; He-induced blistering and fuzz formation, which reduce thermal conductivity by several orders of magnitude; thermal fatigue cracking caused by transient loads; and neutron irradiation embrittlement, which leads to hardening, swelling, and loss of ductility. To overcome these issues while maintaining core thermophysical properties, protective surface layers have been fabricated primarily via chemical vapor deposition (CVD), physical vapor deposition (PVD), and spray and plasma-based surface modification technologies. This review assesses the recent progress in the fabrication of protective surface layers on W for PFM application in fusion reactors from a technical perspective, thereby offering new insights that advance the feasibility of fusion reactors and accelerating the practical realization of sustainable fusion energy systems. Full article

Cognitive load theory-informed curriculum design in health sciences education refers to the purposeful organisation of teaching strategies and learning materials based on the principles of Cognitive Load Theory (CLT), a framework developed by John Sweller in the late 1980s. CLT is grounded in cognitive psychology and recognises that the working memory has a limited capacity for processing new information. It identifies three types of cognitive load: intrinsic load, which refers to the inherent complexity of the material being learned; extraneous load, which results from ineffective instructional design or irrelevant information; and germane load, which reflects the mental effort directed toward understanding, integrating, and organising information into long-term memory. In health sciences education, students frequently engage with tasks that require the simultaneous processing of multiple interacting elements, placing high demands on working memory at specific points in time. This includes foundational biomedical sciences such as anatomy, physiology, and pathophysiology extending to applied clinical skills, diagnostic reasoning under uncertainty, health service management within complex systems, and ethically grounded decision-making. Without thoughtful instructional design, learners may be overwhelmed by excessive information and cognitive demands, which can hinder understanding, retention, and performance. Applying CLT-informed strategies, educators can reduce unnecessary cognitive burden, sequence learning activities to align with learners’ cognitive capacity, and promote deeper learning. This approach supports more effective knowledge acquisition and transfer and is particularly valuable in content dense academic environments such as medicine, nursing, allied health education, public health and health service management education. Therefore, integrating CLT-informed principles into curriculum design can help optimise learning experiences and support the development of competent health professionals. Full article

Manganese dioxide (MnO₂) modified biochar catalysts derived from biomass and waste polymer feedstocks were synthesized and evaluated as heterogeneous Fenton-like catalysts for solar-driven degradation of Rhodamine B (RhB) in aqueous systems. Biochars produced from maple wood and plastic waste (high-density polyethylene) provided porous carbon matrices with oxygen-rich surface functionalities that enabled effective MnO₂ loading and catalytic activity. Photocatalytic experiments conducted under real sunlight using a solar-collector reactor demonstrated faster RhB degradation compared to a conventional ultraviolet (UV) system, confirming the advantage of solar-driven operation. Complete RhB removal was achieved at initial concentrations of 100–300 ppm, whereas higher dye concentrations (500 ppm) exceeded the catalytic capacity within the tested reaction time. Kinetic analysis revealed catalyst-dependent reaction behaviors, indicating that degradation pathways were strongly influenced by the biopolymer-derived carbon structure and MnO₂ dispersion. Degradation efficiency was correlated with solar irradiance and reactor temperature, with higher UV index conditions enhancing catalytic performance. Reusability tests showed that the catalysts remained active over multiple cycles, although gradual decreases in reaction rates and catalyst recovery were observed. These results demonstrate the potential of biopolymer-derived carbon materials as effective solar-driven catalysts for wastewater treatment applications. Full article

Severe heavy metal contamination affects the karst landscapes of Guangxi Zhuang Autonomous Region, China, which are highly polluted and complex. However, integrated assessments of heavy metal sources, distribution, ecological risks, and speciation in karst agricultural soils remain limited. Additionally, there is a gap regarding the interactions between cadmium (Cd), zinc (Zn), and selenium (Se) in natural rice fields. This study employed the pollution load index (PLI), ecological risk index (RI), and Positive Matrix Factorization (PMF) models to evaluate the sources and characteristics of heavy metal contamination in farmland soils. The results showed significant pollution in agricultural soils of Guangxi karst due to Cd, chromium (Cr), copper (Cu), and nickel (Ni). Among these, Cd poses the highest ecological risk. Heavy metal accumulation in the surface soil far exceeds that in deeper layers, and the main sources of Cd were contributed from soil parent material and agricultural activities. Speciation analysis revealed the high bioavailability of Cd, while Zn and Se existed in more stable forms. Despite elevated soil Cd levels, rice grains remained within the safety limits. Using transmission electron microscopy (TEM), Cd was primarily detected in the cell walls of rice stems and husks, which was attributed to Zn’s competitive uptake, reducing Cd absorption and Se forming complexes with Cd to enhance its fixation. Statistical correlations revealed positive associations between Cd in soil and rice. Cd also demonstrated a positive correlation with Se, but a negative correlation with Zn, suggesting a synergistic mechanism between Zn and Se that acts to mitigate the absorption of Cd. This study provides practical guidance for managing farmland soil heavy metal contamination and protecting agricultural soil resources in the karst areas. Full article

Geopolymer concretes are increasingly regarded as advanced construction materials for applications requiring high thermal and chemical resistance. This article is a continuation of previously published research and focuses on the mechanical behaviour of geopolymer concretes containing aggregates made of foamed geopolymers and lightweight mineral aggregates, such as expanded clay and perlite, intended for use in chimney flue components. The aim of the study was to determine the influence of lightweight aggregates on the relationship between thermal insulation and the strength parameters of geopolymer concretes intended for use at elevated temperatures. Foamed geopolymer aggregates were produced by a controlled chemical foaming process, followed by grinding to specific grain sizes, yielding highly porous aggregates with low thermal conductivity, reaching approximately 0.075–0.099 W/(m·K). These aggregates were used as lightweight fillers in geopolymer concretes based on class F fly ash activated with alkaline solutions. The resulting composites were designed to combine low density and high thermal insulation with adequate mechanical strength. The mechanical properties of the developed concretes were assessed on the basis of compressive strength tests on cubic specimens and tensile strength in beam bending tests, carried out in accordance with standards. The results presented confirm that the use of foamed geopolymer aggregates enables a simultaneous increase in thermal insulation and the design of ultra-lightweight structural elements with sufficient load-bearing capacity for chimney systems (including suspended ones). This combination of low thermal conductivity, reduced mass, and appropriate mechanical properties makes geopolymer concretes with lightweight mineral and geopolymer aggregates a promising alternative to traditional ceramic materials. Full article

Citral exhibits favorable broad-spectrum antibacterial activity; however, it is prone to oxidative degradation or structural changes. To improve its stability and practical applicability, citral-loaded microcapsules were prepared using sodium carboxymethyl starch (CMS) and sodium caseinate (CS) via emulsification and freeze-drying. We then investigated the effects of the CMS-to-CS mass ratio on the physicochemical properties and microstructure of the microcapsules, and systematically evaluated the antibacterial activity and underlying mechanisms of the citral-loaded microcapsules against typical foodborne pathogenic bacteria and food-related bacteria. The results showed that when the CMS-to-CS mass ratio was 3:1, the microcapsules prepared exhibited the highest encapsulation efficiency (83.87%). The molecular interactions between citral and the wall materials were confirmed. The citral-loaded microcapsules demonstrated good thermal stability and a compact morphology with dense blocks. Furthermore, treatment with the citral-loaded microcapsules led to the leakage of intracellular contents and compromised the cell membrane integrity of Staphylococcus aureus, thereby inhibiting its normal physiological functions, as well as effectively disrupting bacterial aggregation at high concentrations. These findings offer a valuable reference for future studies aimed at improving the stability of citral when used as an antibacterial agent and at enhancing its practical application value. Full article

In this paper, we utilized sodium titanate as a substrate to fabricate a supported antifungal repair agent capable of inhibiting fungi through the release of silver ions, and applied it to the preservation and restoration of wooden materials. The structural and material properties of sodium titanate were characterized using transmission electron microscopy (TEM), scanning electron microscopy (SEM), and adsorption kinetic modeling. Furthermore, its effectiveness in wood restoration as well as its antifungal performance were evaluated. Results indicate that the synthesized sodium titanate exhibits a distinctive tubular structure, with a diameter of approximately 12 nm, a pore size of 7 nm, and a specific surface area as high as 310.91 m²/g. The abundant ion exchange active sites on the material surface provide conditions for the loading of silver ions. At 25 °C, the maximum adsorption capacity for silver ions reaches 515.5 mg/g, with an adsorption amount accounting for 34.0 wt.%. When combined with polyvinyl alcohol (PVA) for reinforcing wooden materials, it significantly increases the packing density of the reinforcing agent, ultimately enhancing the compressive strength of wood from 155.0 MPa to 412.2 MPa. Furthermore, owing to the antifungal effect of silver ions, the treated wood demonstrates effective resistance against the growth of Aspergillus niger. Full article

Biodegradable poly(lactide)/poly(ε-caprolactone) (PLA/PCL) systems functionalized with TiO₂-SiO₂ were synthesized via in situ ring-opening polymerization of a eutectic L-lactide/ε-caprolactone system. This work introduces a TiO₂-SiO₂ composite with a dual function, acting as a catalytic initiator that governs polymerization and microstructure, while simultaneously serving as a reinforcing and photocatalytic phase. The system exhibits high polymerization efficiency, reaching conversions up to 99% with low filler loadings (0.1–1.0 wt%). Structural analyses confirm polymer formation and reveal modifications in ester groups associated with coordination-driven mechanisms. Notably, the presence of TiO₂-SiO₂ promotes increased PLA tacticity, directly influencing mechanical performance. The resulting materials show enhanced tensile strength (~250,000 Pa) and Young’s modulus (1.5–2.0 MPa) compared to conventional systems. In addition, excellent photocatalytic activity was achieved, with up to 99.7% degradation of methyl orange. These findings demonstrate a synergistic strategy to simultaneously control polymer structure and functionality, positioning PLA/PCL–TiO₂-SiO₂ systems as promising multifunctional materials for environmental applications. Full article

Under long-term heavy load and complex service environments, polyurethane-modified asphalt (PUMA) struggles to simultaneously satisfy the requirements of rutting and cracking resistance of asphalt pavements, as cyclic stress loading reduces the elastic recovery and low-temperature toughness of polyurethane (PU). To address this issue, this study employed hydroxylated crumb rubber (HCR), which is obtained by activating the surface of crumb rubber (CR) and can chemically crosslink with PU in asphalt to form a crosslinked network structure. The aim was to enhance the rutting and cracking resistance of PUMA by utilizing the elasticity and low-temperature toughness of CR. An orthogonal design was employed to systematically design a modified asphalt formulation with PU and HCR (PU/HCRMA) by controlling the isocyanate index and the contents of PU and HCR. The basic properties, rheological properties, and viscoelastic properties of PU/HCRMA were systematically investigated. The results demonstrate that the rutting and cracking resistance of PU/HCRMA are substantially enhanced, with an improvement of 28.91% in the rutting factor at 64 °C compared to PUMA and a reduction of 49.93 MPa in the stiffness modulus at −24 °C. Simultaneously, incorporating HCR in PUMA enhances its viscosity and flow resistance while reducing temperature susceptibility. Furthermore, by providing load-bearing sites, HCR endows PU/HCRMA with exceptional elastic recovery and deformation resistance. Results from FTIR and FM confirm the reaction between isocyanate groups in the PU prepolymer and the hydroxyl groups on the surface of HCR and the formation of HCR-PU crosslinked networks. Finally, PU/HCRMA asphalt mixtures demonstrate significant improvements in both rutting and cracking resistance. This research outcome provides a new direction for the development of high-performance road asphalt materials. Full article