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Search Results (450)

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Keywords = heat-transfer phenomena

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22 pages, 5293 KiB  
Article
Membrane Distillation for Water Desalination: Assessing the Influence of Operating Conditions on the Performance of Serial and Parallel Connection Configurations
by Lebea N. Nthunya and Bhekie B. Mamba
Membranes 2025, 15(8), 235; https://doi.org/10.3390/membranes15080235 - 4 Aug 2025
Viewed by 164
Abstract
Though the pursuit of sustainable desalination processes with high water recovery has intensified the research interest in membrane distillation (MD), the influence of module connection configuration on performance stability remains poorly explored. The current study provided a comprehensive multiparameter assessment of hollow fibre [...] Read more.
Though the pursuit of sustainable desalination processes with high water recovery has intensified the research interest in membrane distillation (MD), the influence of module connection configuration on performance stability remains poorly explored. The current study provided a comprehensive multiparameter assessment of hollow fibre membrane modules connected in parallel and series in direct contact membrane distillation (DCMD) for the first time. The configurations were evaluated under varying process parameters such as temperature (50–70 °C), flow rates (22.1–32.3 mL·s−1), magnesium concentration as scalant (1.0–4.0 g·L−1), and flow direction (co-current and counter-current), assessing their influence on temperature gradients (∆T), flux and pH stability, salt rejection, and crystallisation. Interestingly, the parallel module configuration maintained high operational stability with uniform flux and temperature differences (∆T) even at high recovery factors (>75%). On one hand, the serial configuration experienced fluctuating ∆T caused by thermal and concentration polarisation, causing an early crystallisation (abrupt drop in feed conductivity). Intensified polarisation effects with accelerated crystallisation increased the membrane risk of wetting, particularly at high recovery factors. Despite these changes, the salt rejection remained relatively high (99.9%) for both configurations across all tested conditions. The findings revealed that acidification trends caused by MgSO4 were configuration-dependent, where the parallel setup-controlled rate of pH collapse. This study presented a novel framework connecting membrane module architecture to mass and heat transfer phenomena, providing a transformative DCMD module configuration design in water desalination. These findings not only provide the critical knowledge gaps in DCMD module configurations but also inform optimisation of MD water desalination to achieve high recovery and stable operation conditions under realistic brine composition. Full article
(This article belongs to the Special Issue Membrane Distillation: Module Design and Application Performance)
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18 pages, 1583 KiB  
Article
Heat Transfer Characteristics of Thermosyphons Used in Vacuum Water Heaters
by Zied Lataoui, Adel M. Benselama and Abdelmajid Jemni
Fluids 2025, 10(8), 199; https://doi.org/10.3390/fluids10080199 - 31 Jul 2025
Viewed by 94
Abstract
A two-phase closed thermosyphon (TPCT), a gravity-assisted heat pipe, is a highly efficient heat transmitter involving liquid–vapor phase change. It is used in many applications, including heat spreading, thermal management and control, and energy saving. The main objective of this study is to [...] Read more.
A two-phase closed thermosyphon (TPCT), a gravity-assisted heat pipe, is a highly efficient heat transmitter involving liquid–vapor phase change. It is used in many applications, including heat spreading, thermal management and control, and energy saving. The main objective of this study is to investigate the effects of the operating conditions for a thermosyphon used in solar water heaters. The study particularly focuses on the influence of the inclination angle. Thus, a comprehensive simulation model is developed using the volume of fluid (VOF) approach. Complex and related phenomena, including two-phase flow, phase change, and heat exchange, are taken into account. To implement the model, an open-source CFD toolbox based on finite volume formulation, OpenFOAM, is used. The model is then validated by comparing numerical results to the experimental data from the literature. The obtained results show that the simulation model is reliable for investigating the effects of various operating conditions on the transient and steady-state behavior of the thermosyphon. In fact, bubble creation, growth, and advection can be tracked correctly in the liquid pool at the evaporator. The effects of the designed operating conditions on the heat transfer parameters are also discussed. In particular, the optimal tilt angle is shown to be 60° for the intermediate saturation temperature (<50 °C) and 90° for the larger saturation temperature (>60 °C). Full article
(This article belongs to the Special Issue Convective Flows and Heat Transfer)
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17 pages, 1915 KiB  
Article
Thermocouple Sensor Response in Hot Airstream
by Jacek Pieniazek
Sensors 2025, 25(15), 4634; https://doi.org/10.3390/s25154634 - 26 Jul 2025
Viewed by 235
Abstract
The response of a temperature sensor in a gas stream depends on several heat transfer phenomena. The temperature of the thermocouple’s hot junction in the hot stream is lower than the measured temperature, which causes a measurement error. Compensation for this error and [...] Read more.
The response of a temperature sensor in a gas stream depends on several heat transfer phenomena. The temperature of the thermocouple’s hot junction in the hot stream is lower than the measured temperature, which causes a measurement error. Compensation for this error and interpretation of the values indicated by the temperature sensor are possible by using a sensor dynamics model. Changes over time of the hot junction temperature as well as the entire thermocouple temperature in a stream are solved using the finite element method. Fluid flow and heat transfer equations are solved for a particular sensor geometry. This article presents a method for identifying a temperature sensor model using the results of numerical modeling of the response to temperature changes of the fluid stream, in which the input and output signal waveforms are recorded and then used by the estimator of a model coefficient. It is demonstrated that the dynamics of a bare-bead thermocouple sensor are well-described by a first-order transfer function. The proposed method was used to study the influence of stream velocity on the reaction of two sensors differing in the diameter of the wires, and the effect of radiative heat transfer on the model coefficients was examined by enabling and disabling selected models. The results obtained at several calculation points show the influence of the stream outflow velocity and selected geometric parameters on the value of the transfer function coefficients, i.e., transfer function gain and time constant. This study provides quantitative models of changes in sensor dynamics as functions of the coefficients. Full article
(This article belongs to the Section Industrial Sensors)
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13 pages, 3880 KiB  
Article
Low-Velocity Impact Damage Behavior and Failure Mechanism of 2.5D SiC/SiC Composites
by Jianyong Tu, Xingmiao Duan, Xingang Luan, Dianwei He and Laifei Cheng
J. Compos. Sci. 2025, 9(8), 388; https://doi.org/10.3390/jcs9080388 - 22 Jul 2025
Viewed by 265
Abstract
Continuous SiC fiber-reinforced SiC matrix composites (SiC/SiC), as structural heat protection integrated materials, are often used in parts for large-area heat protection and sharp leading edges, and there are a variety of low-velocity impact events in their service. In this paper, a drop [...] Read more.
Continuous SiC fiber-reinforced SiC matrix composites (SiC/SiC), as structural heat protection integrated materials, are often used in parts for large-area heat protection and sharp leading edges, and there are a variety of low-velocity impact events in their service. In this paper, a drop hammer impact test was conducted using narrow strip samples to simulate the low-velocity impact damage process of sharp-edged components. During the test, different impact energies and impact times were set to focus on investigating the low-velocity impact damage characteristics of 2.5D SiC/SiC composites. To further analyze the damage mechanism, computed tomography (CT) was used to observe the crack propagation paths and distribution states of the composites before and after impact, while scanning electron microscopy (SEM) was employed to characterize the differences in the micro-morphology of their fracture surfaces. The results show that the in-plane impact behavior of a 2.5D needled SiC/SiC composite strip samples differs from the conventional three-stage pattern. In addition to the three stages observed in the energy–time curve—namely in the quasi-linear elastic region, the severe load drop region, and the rebound stage after peak impact energy—a plateau stage appears when the impact energy is 1 J. During the impact process, interlayer load transfer is achieved through the connection of needled fibers, which continuously provide significant structural support, with obvious fiber pull-out and debonding phenomena. When the samples are subjected to two impacts, damage accumulation occurs inside the material. Under conditions with the same total energy, multiple impacts cause more severe damage to the material compared to a single impact. Full article
(This article belongs to the Special Issue Functional Composites: Fabrication, Properties and Applications)
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26 pages, 6864 KiB  
Review
Key Factors, Degradation Mechanisms, and Optimization Strategies for SCO2 Heat Transfer in Microchannels: A Review
by Lianghui Guo, Ran Liu, Xiaoqin Xiong, Xinzhe Li, Aoxiang Yin, Runyao Han, Jiahao Zhang, Zhuoqian Liu and Keke Zhi
Energies 2025, 18(14), 3864; https://doi.org/10.3390/en18143864 - 20 Jul 2025
Viewed by 245
Abstract
Despite a growing body of research on supercritical carbon dioxide (SCO2) heat transfer in microchannels, comprehensive reviews remain scarce. Existing studies predominantly focus on isolated experiments or simulations, yielding inconsistent findings and lacking a unified theory or optimization framework. This review [...] Read more.
Despite a growing body of research on supercritical carbon dioxide (SCO2) heat transfer in microchannels, comprehensive reviews remain scarce. Existing studies predominantly focus on isolated experiments or simulations, yielding inconsistent findings and lacking a unified theory or optimization framework. This review systematically consolidates recent SCO2 microchannel heat transfer advancements, emphasizing key performance factors, degradation mechanisms, and optimization strategies. We critically analyze over 260 studies (1962–2024), evaluating the experimental and numerical methodologies, heat transfer deterioration (HTD) phenomena, and efficiency enhancement techniques. Key challenges include the complexity of heat transfer mechanisms, discrepancies in experimental outcomes, and the absence of standardized evaluation criteria. Future research directions involve refining predictive models, developing mitigation strategies for HTD, and optimizing microchannel geometries to enhance thermal performance. This work not only integrates the current knowledge but also provides actionable insights for advancing SCO2-based technologies in energy systems. Full article
(This article belongs to the Section J1: Heat and Mass Transfer)
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31 pages, 7931 KiB  
Article
Enhanced Pool Boiling via Binder-Jetting 3D-Printed Porous Copper Structures: CHF and HTC Investigation
by Lilian Aketch Okwiri, Takeshi Mochizuki, Kairi Koito, Noriaki Fukui and Koji Enoki
Appl. Sci. 2025, 15(14), 7892; https://doi.org/10.3390/app15147892 - 15 Jul 2025
Viewed by 268
Abstract
The escalating heat flux densities in high-performance electronics necessitate superior thermal management. This study enhanced pool-boiling heat transfer, a method offering high heat removal capacity, by leveraging Binder Jetting 3D Printing (BJ3DP) to create complex porous copper structures without the need for chemical [...] Read more.
The escalating heat flux densities in high-performance electronics necessitate superior thermal management. This study enhanced pool-boiling heat transfer, a method offering high heat removal capacity, by leveraging Binder Jetting 3D Printing (BJ3DP) to create complex porous copper structures without the need for chemical treatments. This approach enables a reliable utilization of phenomena like capillarity for improved performance. Three types of porous copper structures, namely Large Lattice, Small Lattice, and Staggered, were fabricated on pure copper substrates and tested via pool boiling of de-ionized and de-gassed water at atmospheric pressure. Compared to a plain polished copper surface, which exhibited a critical heat flux (CHF) of 782 kW/m2 at a wall superheat of 18 K, the 3D-printed porous copper surfaces showed significantly improved heat transfer performance. The Staggered surface achieved a conventional CHF of 2342.4 kW/m2 (a 199.7% enhancement) at a wall superheat of 24.6 K. Notably, the Large Lattice and Small Lattice structures demonstrated exceptionally stable boiling without reaching the typical catastrophic CHF within the experimental parameters. These geometries continued to increase in heat flux, reaching maximums of 2397.7 kW/m2 (206.8% higher at a wall superheat of 55.6 K) and 2577.2 kW/m2 (229.7% higher at a wall superheat of 39.5 K), respectively. Subsequently, a gradual decline in heat flux was observed with an increasing wall superheat, demonstrating an outstanding resistance to the boiling crisis. These improvements are attributed to the formation of distinct vapor–liquid pathways within the porous structures, which promotes the efficient rewetting of the heated surface through capillary action. This mechanism supports a highly efficient, self-sustaining boiling configuration, emphasizing the superior rewetting and vapor management capabilities of these 3D-printed porous structures, which extend the boundaries of sustained high heat flux performance. The porous surfaces also demonstrated a higher heat transfer coefficient (HTC), particularly at lower heat fluxes (≤750 kW/m2). High-speed digital camera visualization provided further insight into the boiling phenomenon. Overall, the findings demonstrate that these BJ3DP structured surfaces produce optimized vapor–liquid pathways and capillary-enhanced rewetting, offering significantly superior heat transfer performance compared to smooth surfaces and highlighting their potential for advanced thermal management. Full article
(This article belongs to the Section Energy Science and Technology)
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27 pages, 4704 KiB  
Article
Chemical Composition and Corrosion—Contributions to a Sustainable Use of Geothermal Water
by Ioana Maior, Gabriela Elena Badea, Oana Delia Stănășel, Mioara Sebeșan, Anca Cojocaru, Anda Ioana Graţiela Petrehele, Petru Creț and Cristian Felix Blidar
Energies 2025, 18(14), 3634; https://doi.org/10.3390/en18143634 - 9 Jul 2025
Viewed by 336
Abstract
The utilization of geothermal resources as renewable energy is a subject of interest for the regions that possess these resources. The exploitation of geothermal energy must consider local geological conditions and an integrated approach, which should include practical studies on the chemistry of [...] Read more.
The utilization of geothermal resources as renewable energy is a subject of interest for the regions that possess these resources. The exploitation of geothermal energy must consider local geological conditions and an integrated approach, which should include practical studies on the chemistry of geothermal waters and their effect on thermal installations. Geothermal waters from Bihor County, Romania, have a variable composition, depending on the crossed geological layers, but also on pressure and temperature. Obviously, water transport and heat transfer are involved in all applications of geothermal waters. This article aims to characterize certain geothermal waters from the point of view of composition and corrosion if used as a thermal agent. Atomic absorption spectroscopy (AAS) and UV–Vis spectroscopy were employed to analyze water specimens. Chemical composition includes calcite (CaCO3), chalcedony (SiO2), goethite (FeO(OH)), and magnetite (Fe3O4), which confirms the corrosion and scale potential of these waters. Corrosion resistance of mild carbon steel, commonly used as pipe material, was studied by the gravimetric method and through electrochemical methodologies, including chronoamperometry, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization method, and open circuit potential measurement (OCP). Statistical analysis shows that the medium corrosion rate of S235 steel, expressed as penetration rate, is between 0.136 mm/year to 0.615 mm/year. The OCP, EIS, and chronoamperometry experiments explain corrosion resistance through the formation of a passive layer on the surface of the metal. This study proposes an innovative methodology and a systematic algorithm for analyzing chemical processes and corrosion phenomena in geothermal installations, emphasizing the necessity of individualized assessments for each aquifer to optimize operational parameters and ensure sustainable resource utilization. Full article
(This article belongs to the Special Issue The Status and Development Trend of Geothermal Resources)
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27 pages, 3398 KiB  
Review
A Comprehensive Review on Studies of Flow Characteristics in Horizontal Tube Falling Film Heat Exchangers
by Zhenchuan Wang and Meijun Li
Energies 2025, 18(13), 3587; https://doi.org/10.3390/en18133587 - 7 Jul 2025
Viewed by 379
Abstract
The horizontal tube falling film heat exchangers (HTFFHEs), which exhibit remarkable advantages such as high efficiency in heat and mass transfer, low resistance, and a relatively simple structural configuration, have found extensive applications. Complex flow phenomena and the coupled processes of heat and [...] Read more.
The horizontal tube falling film heat exchangers (HTFFHEs), which exhibit remarkable advantages such as high efficiency in heat and mass transfer, low resistance, and a relatively simple structural configuration, have found extensive applications. Complex flow phenomena and the coupled processes of heat and mass transfer take place within it. Given that the heat and mass transfer predominantly occur at the gas-liquid interface, the flow characteristics therein emerge as a significant factor governing the performance of heat and mass transfer. This article elaborates on the progress of experimental and simulation research approaches with respect to flow characteristics. It systematically reviews the influence patterns of various operating parameters, namely parameters of gas, solution and internal medium, as well as structural parameters like tube diameter and tube spacing, on the flow characteristics, such as the flow regime between tubes, liquid film thickness, and wettability. This review serves to furnish theoretical underpinnings for optimizing the heat and mass transfer performance of the horizontal tube falling film heat exchanger. It is further indicated that the multi-dimensional flow characteristics and their quantitative characterizations under the impacts of different airflow features will constitute the focal research directions for horizontal tube falling film heat exchangers in the foreseeable future. Full article
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37 pages, 6674 KiB  
Article
Marangoni Convection of Self-Rewetting Fluid Layers with a Deformable Interface in a Square Enclosure and Driven by Imposed Nonuniform Heat Energy Fluxes
by Bashir Elbousefi, William Schupbach and Kannan N. Premnath
Energies 2025, 18(13), 3563; https://doi.org/10.3390/en18133563 - 6 Jul 2025
Viewed by 273
Abstract
Fluids that exhibit self-rewetting properties, such as aqueous long-chain alcohol solutions, display a unique quadratic relationship between surface tension and temperature and are marked by a positive gradient. This characteristic leads to distinctive patterns of thermocapillary convection and associated interfacial dynamics, setting self-rewetting [...] Read more.
Fluids that exhibit self-rewetting properties, such as aqueous long-chain alcohol solutions, display a unique quadratic relationship between surface tension and temperature and are marked by a positive gradient. This characteristic leads to distinctive patterns of thermocapillary convection and associated interfacial dynamics, setting self-rewetting fluids apart from normal fluids (NFs). The potential to improve heat transfer using self-rewetting fluids (SRFs) is garnering interest for use in various technologies, including low-gravity conditions and microfluidic systems. Our research aims to shed light on the contrasting behaviors of SRFs in comparison to NFs regarding interfacial transport phenomena. This study focuses on the thermocapillary convection in SRF layers with a deformable interface enclosed inside a closed container modeled as a square cavity, which is subject to nonuniform heating, represented using a Gaussian profile for the heat flux variation on one of its sides, in the absence of gravity. To achieve this, we have enhanced a central-moment-based lattice Boltzmann method (LBM) utilizing three distribution functions for tracking interfaces, computing two-fluid motions with temperature-dependent surface tension and energy transport, respectively. Through numerical simulations, the impacts of several characteristic parameters, including the viscosity and thermal conductivity ratios, as well as the surface tension–temperature sensitivity parameters, on the distribution and magnitude of the thermocapillary-driven motion are examined. In contrast to that in NFs, the counter-rotating pair of vortices generated in the SRF layers, due to the surface tension gradient at the interface, is found to be directed toward the SRF layers’ hotter zones. Significant interfacial deformations are observed, especially when there are contrasts in the viscosities of the SRF layers. The thermocapillary convection is found to be enhanced if the bottom SRF layer has a higher thermal conductivity or viscosity than that of the top layer or when distributed, rather than localized, heating is applied. Furthermore, the higher the magnitude of the effect of the dimensionless quadratic surface tension sensitivity coefficient on the temperature, or of the effect of the imposed heat flux, the greater the peak interfacial velocity current generated due to the Marangoni stresses. In addition, an examination of the Nusselt number profiles reveals significant redistribution of the heat transfer rates in the SRF layers due to concomitant nonlinear thermocapillary effects. Full article
(This article belongs to the Section J1: Heat and Mass Transfer)
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15 pages, 5932 KiB  
Article
Numerical Simulation of Fluid Flow, Heat Transfer, and Solidification in AISI 304 Stainless Steel Twin-Roll Strip Casting
by Jingzhou Lu, Wanlin Wang and Kun Dou
Metals 2025, 15(7), 749; https://doi.org/10.3390/met15070749 - 2 Jul 2025
Viewed by 314
Abstract
The production of AISI 304 stainless steel (a corrosion-resistant alloy prone to solidification defects from high alloy content) particularly benefits from twin-roll strip casting—a short-process green technology enabling sub-rapid solidification (the maximum cooling rate exceeds 1000 °C/s) control for high-performance steels. However, the [...] Read more.
The production of AISI 304 stainless steel (a corrosion-resistant alloy prone to solidification defects from high alloy content) particularly benefits from twin-roll strip casting—a short-process green technology enabling sub-rapid solidification (the maximum cooling rate exceeds 1000 °C/s) control for high-performance steels. However, the internal phenomena within its molten pool remain exceptionally challenging to monitor. This study developed a multiscale numerical model to simulate coupled fluid flow, heat transfer, and solidification in AISI 304 stainless steel twin-roll strip casting. A quarter-symmetry 3D model captured macroscopic transport phenomena, while a slice model resolved mesoscopic solidification structure. Laboratory experiments had verified that the deviation between the predicted temperature field and the measured average value (1384.3 °C) was less than 5%, and the error between the solidification structure simulation and the electron backscatter diffraction (EBSD) data was within 5%. The flow field and flow trajectory showed obvious recirculation zones: the center area was mainly composed of large recirculation zones, and many small recirculation zones appeared at the edges. Parameter studies showed that, compared with the high superheat (110 °C), the low superheat (30 °C) increased the total solid fraction by 63% (from 8.3% to 13.6%) and increased the distance between the kiss point and the bottom of the molten pool by 154% (from 6.2 to 15.8 mm). The location of the kiss point is a key industrial indicator for assessing solidification integrity and the risk of strip fracture. In terms of mesoscopic solidification structure, low superheat promoted the formation of coarse columnar crystals (equiaxed crystals accounted for 8.9%), while high superheat promoted the formation of equiaxed nucleation (26.5%). The model can be used to assist in the setting of process parameters and process optimization for twin-roll strip casting. Full article
(This article belongs to the Special Issue Advances in Metal Rolling Processes)
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36 pages, 6029 KiB  
Review
Research Progress of Computational Fluid Dynamics in Mixed Ionic–Electronic Conducting Oxygen-Permeable Membranes
by Jun Liu, Jing Zhao, Yulu Liu, Yongfan Zhu, Wanglin Zhou, Zhenbin Gu, Guangru Zhang and Zhengkun Liu
Membranes 2025, 15(7), 193; https://doi.org/10.3390/membranes15070193 - 27 Jun 2025
Viewed by 599
Abstract
Mixed ionic–electronic conducting (MIEC) oxygen-permeable membranes have emerged as a frontier in oxygen separation technology due to their high efficiency, low energy consumption, and broad application potential. In recent years, computational fluid dynamics (CFD) has become a pivotal tool in advancing MIEC membrane [...] Read more.
Mixed ionic–electronic conducting (MIEC) oxygen-permeable membranes have emerged as a frontier in oxygen separation technology due to their high efficiency, low energy consumption, and broad application potential. In recent years, computational fluid dynamics (CFD) has become a pivotal tool in advancing MIEC membrane technology, offering precise insights into the intricate mechanisms of oxygen permeation, heat transfer, and mass transfer through numerical simulations of coupled multiphysics phenomena. In this review, we comprehensively explore the application of CFD in MIEC membrane research, heat and mass transfer analysis, reactor design optimization, and the enhancement of membrane module performance. Additionally, we delve into how CFD, through multiscale modeling and parameter optimization, improves separation efficiency and facilitates practical engineering applications. We also highlight the challenges in current CFD research, such as high computational costs, parameter uncertainties, and model complexities, while discussing the potential of emerging technologies, such as machine learning, to enhance CFD modeling capabilities. This study underscores CFD’s critical role in bridging the fundamental research and industrial applications of MIEC membranes, providing theoretical guidance and practical insights for innovation in clean energy and sustainable technologies. Full article
(This article belongs to the Section Membrane Applications for Energy)
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16 pages, 3298 KiB  
Article
Microstructure Evolution of Ni3Al-Based Intermetallic Alloy Strips After Hot Rolling
by Paweł Jóźwik, Wojciech Polkowski, Andrzej J. Panas and Zbigniew Bojar
Materials 2025, 18(13), 3016; https://doi.org/10.3390/ma18133016 - 25 Jun 2025
Viewed by 314
Abstract
The effect of the temperature and strain rate during the hot rolling process on the microstructural evolution in fine-grained Ni3Al intermetallic alloy doped with Zr and B was examined in this work. The hot rolling process was carried out at an [...] Read more.
The effect of the temperature and strain rate during the hot rolling process on the microstructural evolution in fine-grained Ni3Al intermetallic alloy doped with Zr and B was examined in this work. The hot rolling process was carried out at an initial temperature range of 1000, 1100, and 1280 °C and at a strain rate between 3.9 × 10−1 s1 and 2.5 s1. The results of the EBSD microstructural analyses revealed that dynamic recrystallization phenomena are initiated at the rolling temperature of 1100 °C, while a fraction of the dynamically recrystallized grains further increases with both the rising temperature and strain rate of the deformation process. Furthermore, to estimate the heat losses during the hot rolling processing, a non-stationary heat transfer model was formulated and then used to evaluate the experimentally received data. Full article
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15 pages, 2144 KiB  
Article
Optimizing Porous Transport Layers in PEM Water Electrolyzers: A 1D Two-Phase Model
by Lu Zhang, Jie Liu and Shaojie Du
Batteries 2025, 11(6), 222; https://doi.org/10.3390/batteries11060222 - 6 Jun 2025
Viewed by 734
Abstract
The proton exchange membrane electrolyzer (PEMWE) has been regarded as a promising technology for converting surplus intermittent renewable energy into green hydrogen through electrochemical water splitting. However, the multiphase mass and charge transport processes with countercurrent flow within the PEMWE create complex structure–property [...] Read more.
The proton exchange membrane electrolyzer (PEMWE) has been regarded as a promising technology for converting surplus intermittent renewable energy into green hydrogen through electrochemical water splitting. However, the multiphase mass and charge transport processes with countercurrent flow within the PEMWE create complex structure–property relationships that are difficult to optimize. The interdependent effects of multiple structural parameters on the coupled heat transfer, mass transfer, and charge transfer processes further obscure performance optimization mechanisms. To decouple these phenomena and elucidate the underlying mechanisms, a multiphase one-dimensional mathematical model was developed and experimentally validated. Based on the model, the mass transfer, charge conduction, and heat transfer processes inside the PEMWE have been systematically investigated, with a particular focus on the performance-related parameters of the porous transport layer (PTL). The results reveal that PTL thickness and porosity exhibit opposite effects on activation and ohmic overpotential at an elevated current density. Furthermore, a sharp performance decline occurs when PTL gas permeability falls below the critical threshold. These findings provide quantitative guidelines for multiphysics-informed component optimization in high-performance PEMWEs. Full article
(This article belongs to the Special Issue Challenges, Progress, and Outlook of High-Performance Fuel Cells)
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15 pages, 831 KiB  
Article
Microstructure and Thermophysical Characterization of Tetra-Arsenic Biselenide As4Se2 Alloy Nanostructured by Mechanical Milling
by Oleh Shpotyuk, Andrzej Kozdras, Yaroslav Shpotyuk, Guang Yang and Zdenka Lukáčová Bujňáková
Materials 2025, 18(11), 2422; https://doi.org/10.3390/ma18112422 - 22 May 2025
Viewed by 408
Abstract
Nanomilling-driven effects on polyamorphic transitions are examined in tetra-arsenic biselenide As4Se2 alloy, which is at the boundary of the glass-forming region in the As-Se system, using multifrequency temperature-modulated DSC-TOPEM® technique, supported by X-ray powder diffraction (XRPD) and micro-Raman spectroscopy [...] Read more.
Nanomilling-driven effects on polyamorphic transitions are examined in tetra-arsenic biselenide As4Se2 alloy, which is at the boundary of the glass-forming region in the As-Se system, using multifrequency temperature-modulated DSC-TOPEM® technique, supported by X-ray powder diffraction (XRPD) and micro-Raman spectroscopy analysis. As shown by XRPD analysis, this alloy reveals a glassy–crystalline nature due to rhombohedral As and cubic As2O3 (arsenolite) inclusions, which especially grew after milling in a PVP (polyvinylpyrrolidone) water solution. At the medium-range structure level, nanomilling-driven changes are revealed as the disruption of intermediate-range ordering and enhancement of extended-range ordering. The generalized molecular-to-network amorphization trend in this alloy is confirmed by the microstructure response revealed in the broadened and obscured features in micro-Raman scattering spectra collected for nanomilled specimens. Thermophysical heat-transfer phenomena are defined by molecular-to-network polyamorphic transformations activated under nanomilling. The domination of thioarsenide-type As4Sen entities in this alloy results in an abnormous nanomilling-driven network-enhanced glass transition temperature increase. The nanomilled alloys become notably stressed owing to the destruction of molecular thioarsenide and incorporation of their remnants into the newly polymerized arsenoselenide network. This effect is more pronounced in As4Se2 alloy subjected to dry nanomilling, while it is partly counterbalanced when this alloy is additionally subjected to wet milling in a PVP water solution, accompanied by the stabilization of the As4Se2/PVP nanocomposite. Full article
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20 pages, 8468 KiB  
Article
Numerical Investigation of Fuel Cooling in Sudden Expansion Structures of Scramjet Engines
by Qingjun Wang, Minglei Hu, Zongjie Quan and Yu Chen
Aerospace 2025, 12(6), 456; https://doi.org/10.3390/aerospace12060456 - 22 May 2025
Viewed by 364
Abstract
Local overheating in cavities seriously threatens the safe operation of scramjet engines. To investigate the formation mechanism and control methods of local overheating, this paper conducts numerical simulations on the cooling process of cavity sudden expansion (S-E) structures. A three-dimensional numerical model coupled [...] Read more.
Local overheating in cavities seriously threatens the safe operation of scramjet engines. To investigate the formation mechanism and control methods of local overheating, this paper conducts numerical simulations on the cooling process of cavity sudden expansion (S-E) structures. A three-dimensional numerical model coupled with pyrolysis reactions is established and validated through experiments. The effects of thermal pyrolysis reactions and cooling channel parameters on flow distribution are analyzed, and comparative studies with different channel parameters are performed. The results show that S-E structures are prone to uneven fuel flow distribution, leading to local over-temperature phenomena, and thermal pyrolysis reactions will aggravate this phenomenon to a certain extent. Increasing the aspect ratio of the channel can enhance the pressure drop at the inlet of the S-E structure and improve the uniformity of flow distribution. When the aspect ratio increases from one to eight, the mass flow distribution deviation ϕm decreases from 0.954 to 0.181. More uniform flow distribution under a larger aspect ratio avoids local over-temperature in the S-E structure, and reduces the coking risk caused by local excessive pyrolysis. This work reveals the fundamental characteristics of cooling heat transfer in the S-E structure of Scramjet engines and can provide recommendations for the design of cooling channels. Full article
(This article belongs to the Section Aeronautics)
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