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Search Results (24,056)

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Keywords = hardness.

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23 pages, 1050 KiB  
Article
Lattice-Based Certificateless Proxy Re-Signature for IoT: A Computation-and-Storage Optimized Post-Quantum Scheme
by Zhanzhen Wei, Gongjian Lan, Hong Zhao, Zhaobin Li and Zheng Ju
Sensors 2025, 25(15), 4848; https://doi.org/10.3390/s25154848 (registering DOI) - 6 Aug 2025
Abstract
Proxy re-signature enables transitive authentication of digital identities across different domains and has significant application value in areas such as digital rights management, cross-domain certificate validation, and distributed system access control. However, most existing proxy re-signature schemes, which are predominantly based on traditional [...] Read more.
Proxy re-signature enables transitive authentication of digital identities across different domains and has significant application value in areas such as digital rights management, cross-domain certificate validation, and distributed system access control. However, most existing proxy re-signature schemes, which are predominantly based on traditional public-key cryptosystems, face security vulnerabilities and certificate management bottlenecks. While identity-based schemes alleviate some issues, they introduce key escrow concerns. Certificateless schemes effectively resolve both certificate management and key escrow problems but remain vulnerable to quantum computing threats. To address these limitations, this paper constructs an efficient post-quantum certificateless proxy re-signature scheme based on algebraic lattices. Building upon algebraic lattice theory and leveraging the Dilithium algorithm, our scheme innovatively employs a lattice basis reduction-assisted parameter selection strategy to mitigate the potential algebraic attack vectors inherent in the NTRU lattice structure. This ensures the security and integrity of multi-party communication in quantum-threat environments. Furthermore, the scheme significantly reduces computational overhead and optimizes signature storage complexity through structured compression techniques, facilitating deployment on resource-constrained devices like Internet of Things (IoT) terminals. We formally prove the unforgeability of the scheme under the adaptive chosen-message attack model, with its security reducible to the hardness of the corresponding underlying lattice problems. Full article
(This article belongs to the Special Issue IoT Network Security (Second Edition))
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17 pages, 3157 KiB  
Article
Research on Online Traceability Methods for the Causes of Longitudinal Surface Crack in Continuous Casting Slab
by Junqiang Cong, Qiancheng Lv, Zihao Fan, Haitao Ling and Fei He
Materials 2025, 18(15), 3695; https://doi.org/10.3390/ma18153695 - 6 Aug 2025
Abstract
In the casting and rolling production process, surface longitudinal cracks are a typical casting defect. Tracing the causes of longitudinal cracks online and controlling the key parameters leading to their formation in a timely manner can enhance the stability of casting and rolling [...] Read more.
In the casting and rolling production process, surface longitudinal cracks are a typical casting defect. Tracing the causes of longitudinal cracks online and controlling the key parameters leading to their formation in a timely manner can enhance the stability of casting and rolling production. To this end, the influencing factors of longitudinal cracks were analyzed, a data integration storage platform was constructed, and a tracing model was established using empirical rule analysis, statistical analysis, and intelligent analysis methods. During the initial production phase of a casting machine, longitudinal cracks occurred frequently. The tracing results using the LightGBM-SHAP method showed that the relative influence of the narrow left wide inner heat flow ratio of the mold was significant, followed by the heat flow difference on the wide symmetrical face of the mold and the superheat of the molten steel, with weights of 0.135, 0.066, and 0.048, respectively. Based on the tracing results, we implemented online emergency measures. By controlling the cooling intensity of the mold, we effectively reduced the recurrence rate of longitudinal cracks. Root cause analysis revealed that the total hardness of the mold-cooling water exceeded the standard, reaching 24 mg/L, which caused scaling on the mold copper plates and uneven cooling, leading to the frequent occurrence of longitudinal cracks. After strictly controlling the water quality, the issue of longitudinal cracks was brought under control. The online application of the tracing method for the causes of longitudinal cracks has effectively improved efficiency in resolving longitudinal crack problems. Full article
(This article belongs to the Special Issue Advanced Sheet/Bulk Metal Forming)
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20 pages, 821 KiB  
Article
The Role of Phoneme Discrimination in the Variability of Speech and Language Outcomes Among Children with Hearing Loss
by Kerry A. Walker, Jinal K. Shah, Lauren Alexander, Stacy Stiell, Christine Yoshinaga-Itano and Kristin M. Uhler
Behav. Sci. 2025, 15(8), 1072; https://doi.org/10.3390/bs15081072 - 6 Aug 2025
Abstract
This research compares speech discrimination abilities between 17 children who are hard-of-hearing (CHH) and 13 children with normal hearing (CNH), aged 9 to 36 months, using either a conditioned head turn (CHT) or condition play paradigm, for two phoneme pairs /ba-da/ and /sa-ʃa/. [...] Read more.
This research compares speech discrimination abilities between 17 children who are hard-of-hearing (CHH) and 13 children with normal hearing (CNH), aged 9 to 36 months, using either a conditioned head turn (CHT) or condition play paradigm, for two phoneme pairs /ba-da/ and /sa-ʃa/. As CHH were tested in the aided and unaided conditions, CNH were also tested on each phoneme contrast twice to control for learning effects. When speech discrimination abilities were compared between CHH, with hearing aids (HAs), and CNH, there were no statistical differences observed in performance on stop consonant discrimination, but a significant statistical difference was observed for fricative discrimination performance. Among CHH, significant benefits were observed for /ba-da/ speech discrimination while wearing HAs, compared to the no HA condition. All CHH were early-identified, early amplified, and were enrolled in parent-centered early intervention services. Under these conditions, CHH demonstrated the ability to discriminate speech comparable to CNH. Additionally, repeated testing within 1-month did not result in a change in speech discrimination scores, indicating good test–retest reliability of speech discrimination scores. Finally, this research explored the question of infant/toddler listening fatigue in the behavioral speech discrimination task. The CHT paradigm included returning to a contrast (i.e., /a-i/) previously shown to be easier for both CHH and CNH to discriminate to examine if failure to discriminate /ba-da/ or /sa-ʃa/ was due to listening fatigue or off-task behavior. Full article
(This article belongs to the Special Issue Language and Cognitive Development in Deaf Children)
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20 pages, 1448 KiB  
Article
In Vitro Evaluation of Chemical and Microhardness Alterations in Human Enamel Induced by Three Commercial In-Office Bleaching Agents
by Berivan Laura Rebeca Buzatu, Atena Galuscan, Ramona Dumitrescu, Roxana Buzatu, Magda Mihaela Luca, Octavia Balean, Gabriela Vlase, Titus Vlase, Iasmina-Mădălina Anghel, Carmen Opris, Bianca Ioana Todor, Mihaela Adina Dumitrache and Daniela Jumanca
Dent. J. 2025, 13(8), 357; https://doi.org/10.3390/dj13080357 - 6 Aug 2025
Abstract
Background/Objectives: In-office bleaching commonly employs high concentrations of hydrogen peroxide (HP) or carbamide peroxide (CP), which may compromise enamel integrity. This in vitro paired-design study aimed to compare the chemical and mechanical effects of three commercial bleaching agents—Opalescence Boost (40% HP), Opalescence [...] Read more.
Background/Objectives: In-office bleaching commonly employs high concentrations of hydrogen peroxide (HP) or carbamide peroxide (CP), which may compromise enamel integrity. This in vitro paired-design study aimed to compare the chemical and mechanical effects of three commercial bleaching agents—Opalescence Boost (40% HP), Opalescence Quick (45% CP), and BlancOne Ultra+ (35% HP)—on human enamel. The null hypothesis assumed no significant differences between the control and treated samples. Given the ongoing debate over pH, active ingredients, and enamel impact, comparing whitening systems remains clinically important. Methods: Forty-two extracted teeth were assigned to three experimental groups (n = 14) with matched controls. Each underwent a single bleaching session per manufacturer protocol: Opalescence Boost (≤60 min), Opalescence Quick (15–30 min), and BlancOne Ultra+ (three light-activated cycles of 8–10 min). Enamel chemical changes were analyzed by Fourier transform infrared (FTIR) spectroscopy (phosphate and carbonate bands), and surface hardness by Vickers microhardness testing. Paired t-tests (α = 0.05) assessed statistical significance. Results: FTIR analysis revealed alterations in phosphate and carbonate bands for all agents, most notably for Opalescence Boost and BlancOne Ultra+. Microhardness testing showed significant reductions in enamel hardness for Opalescence Boost (control: 37.21 ± 1.74 Hv; treated: 34.63 ± 1.70 Hv; p = 0.00) and Opalescence Quick (control: 45.82 ± 1.71 Hv; treated: 39.34 ± 1.94 Hv; p < 0.0001), whereas BlancOne Ultra+ showed no significant difference (control: 51.64 ± 1.59 HV; treated: 51.60 ± 2.34 Hv; p = 0.95). Conclusions: HP-based agents, particularly at higher concentrations, caused greater enamel alterations than CP-based products. While clinically relevant, the results should be interpreted cautiously due to in vitro limitations and natural enamel variability. Full article
(This article belongs to the Special Issue Advances in Esthetic Dentistry)
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21 pages, 1442 KiB  
Article
Enzyme Modifications of Red Deer Fat to Adjust Physicochemical Properties for Advanced Applications
by Tereza Novotná, Jana Pavlačková, Robert Gál, Ladislav Šiška, Miroslav Fišera and Pavel Mokrejš
Molecules 2025, 30(15), 3293; https://doi.org/10.3390/molecules30153293 - 6 Aug 2025
Abstract
Red deer fat makes up approximately 7–10% of the animal’s weight and is not currently used. Regarding sustainability in the food industry, it is desirable to look for opportunities for its processing and use, not only in the food industry. The aim of [...] Read more.
Red deer fat makes up approximately 7–10% of the animal’s weight and is not currently used. Regarding sustainability in the food industry, it is desirable to look for opportunities for its processing and use, not only in the food industry. The aim of this study is the enzymatic modification of red deer fat, leading to modification of its physicochemical properties, and the study of changes in phase transitions of modified fat, its structure, color, and texture. Hydrolysis was performed using sn-1,3-specific lipase at different water concentrations (10–30%) and reaction times (2–6 h). The results showed that there was a significant decrease in melting and crystallization temperatures with an increasing degree of hydrolysis, which was confirmed by differential scanning calorimetry. FTIR spectra revealed a decrease in the intensity of the ester bonds, indicating cleavage of triacylglycerols. Texture analysis of the modified fats confirmed a decrease in hardness of up to 50% and an increase in spreadability. The color parameter values remained within an acceptable range. The results show that enzymatic modification is an effective tool for targeted modification of red deer fat properties, and this expands the possibilities of its application in cosmetic matrices and food applications as functional lipids. Full article
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12 pages, 4963 KiB  
Article
Effect of Bias Voltage and Cr/Al Content on the Mechanical and Scratch Resistance Properties of CrAlN Coatings Deposited by DC Magnetron Sputtering
by Shahnawaz Alam, Zuhair M. Gasem, Nestor K. Ankah and Akbar Niaz
J. Manuf. Mater. Process. 2025, 9(8), 264; https://doi.org/10.3390/jmmp9080264 - 6 Aug 2025
Abstract
Chromium–aluminum nitride (CrAlN) coatings were deposited on polished H13 tool steel substrates using direct current (DC) magnetron sputtering. The Cr/Al composition in the target was varied by inserting either four or eight chromium (Cr) plugs into cavities machined into an aluminum (Al) plate [...] Read more.
Chromium–aluminum nitride (CrAlN) coatings were deposited on polished H13 tool steel substrates using direct current (DC) magnetron sputtering. The Cr/Al composition in the target was varied by inserting either four or eight chromium (Cr) plugs into cavities machined into an aluminum (Al) plate target. Nitrogen was introduced as a reactive gas to facilitate the formation of the nitride phase. Coatings were deposited at substrate bias voltages of −30 V, −50 V, and −60 V to study the combined effects of composition and ion energy on coating properties. Compositional analysis of coatings deposited at a −50 V bias revealed Cr/Al ratios of approximately 0.8 and 1.7 for the 4- and 8-plug configurations, respectively. This increase in the Cr/Al ratio led to a 2.6-fold improvement in coating hardness. Coatings produced using the eight-Cr-plug target exhibited a nearly linear increase in hardness with increasing substrate bias voltage. Cross-sectional scanning electron microscopy revealed a uniform bilayer structure consisting of an approximately 0.5 µm metal interlayer beneath a 2–3 µm CrAlN coating. Surface morphology analysis indicated the presence of coarse microdroplets in coatings with the lower Cr/Al ratio. These microdroplets were significantly suppressed in coatings with higher Cr/Al content, especially at increased bias voltages. This suppression is likely due to enhanced ion bombardment associated with the increased Cr content, attributed to Cr’s relatively higher atomic mass compared to Al. Coatings with lower hardness exhibited greater scratch resistance, likely due to the influence of residual compressive stresses. The findings highlight the critical role of both Cr/Al content and substrate bias in tailoring the tribo-mechanical performance of PVD CrAlN coatings for wear-resistant applications. Full article
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16 pages, 7134 KiB  
Article
The Impact of an Object’s Surface Material and Preparatory Actions on the Accuracy of Optical Coordinate Measurement
by Danuta Owczarek, Ksenia Ostrowska, Jerzy Sładek, Adam Gąska, Wiktor Harmatys, Krzysztof Tomczyk, Danijela Ignjatović and Marek Sieja
Materials 2025, 18(15), 3693; https://doi.org/10.3390/ma18153693 - 6 Aug 2025
Abstract
Optical coordinate measurement is a universal technique that aligns with the rapid development of industrial technologies and new materials. Nevertheless, can this technique be consistently effective when applied to the precise measurement of all types of materials? As shown in this article, an [...] Read more.
Optical coordinate measurement is a universal technique that aligns with the rapid development of industrial technologies and new materials. Nevertheless, can this technique be consistently effective when applied to the precise measurement of all types of materials? As shown in this article, an analysis of optical measurement systems reveals that some materials cause difficulties during the scanning process. This article details the matting process, resulting, as demonstrated, in lower measurement uncertainty values compared to the pre-matting state, and identifies materials for which applying a matting spray significantly improves the measurement quality. The authors propose a classification of materials into easy-to-scan and hard-to-scan groups, along with specific procedures to improve measurements, especially for the latter. Tests were conducted in an accredited Laboratory of Coordinate Metrology using an articulated arm with a laser probe. Measured objects included spheres made of ceramic, tungsten carbide (including a matte finish), aluminum oxide, titanium nitride-coated steel, and photopolymer resin, with reference diameters established by a high-precision Leitz PMM 12106 coordinate measuring machine. Diameters were determined from point clouds obtained via optical measurements using the best-fit method, both before and after matting. Color measurements using a spectrocolorimeter supplemented this study to assess the effect of matting on surface color. The results revealed correlations between the material type and measurement accuracy. Full article
(This article belongs to the Section Optical and Photonic Materials)
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33 pages, 1043 KiB  
Article
Uncovering the Psychometric Properties of Statistics Anxiety in Graduate Courses at a Minority-Serving Institution: Insights from Exploratory and Bayesian Structural Equation Modeling in a Small Sample Context
by Hyeri Hong, Ryan E. Ditchfield and Christian Wandeler
AppliedMath 2025, 5(3), 100; https://doi.org/10.3390/appliedmath5030100 - 6 Aug 2025
Abstract
The Statistics Anxiety Rating Scale (STARS) is a 51-item scale commonly used to measure college students’ anxiety regarding statistics. To date, however, limited empirical research exists that examines statistics anxiety among ethnically diverse or first-generation graduate students. We examined the factor structure and [...] Read more.
The Statistics Anxiety Rating Scale (STARS) is a 51-item scale commonly used to measure college students’ anxiety regarding statistics. To date, however, limited empirical research exists that examines statistics anxiety among ethnically diverse or first-generation graduate students. We examined the factor structure and reliability of STARS scores in a diverse sample of students enrolled in graduate courses at a Minority-Serving Institution (n = 194). To provide guidance on assessing dimensionality in small college samples, we compared the performance of best-practice factor analysis techniques: confirmatory factor analysis (CFA), exploratory structural equation modeling (ESEM), and Bayesian structural equation modeling (BSEM). We found modest support for the original six-factor structure using CFA, but ESEM and BSEM analyses suggested that a four-factor model best captures the dimensions of the STARS instrument within the context of graduate-level statistics courses. To enhance scale efficiency and reduce respondent fatigue, we also tested and found support for a reduced 25-item version of the four-factor STARS scale. The four-factor STARS scale produced constructs representing task and process anxiety, social support avoidance, perceived lack of utility, and mathematical self-efficacy. These findings extend the validity and reliability evidence of the STARS inventory to include diverse graduate student populations. Accordingly, our findings contribute to the advancement of data science education and provide recommendations for measuring statistics anxiety at the graduate level and for assessing construct validity of psychometric instruments in small or hard-to-survey populations. Full article
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21 pages, 1212 KiB  
Article
A Semi-Supervised Approach to Characterise Microseismic Landslide Events from Big Noisy Data
by David Murray, Lina Stankovic and Vladimir Stankovic
Geosciences 2025, 15(8), 304; https://doi.org/10.3390/geosciences15080304 - 6 Aug 2025
Abstract
Most public seismic recordings, sampled at hundreds of Hz, tend to be unlabelled, i.e., not catalogued, mainly because of the sheer volume of samples and the amount of time needed by experts to confidently label detected events. This is especially challenging for very [...] Read more.
Most public seismic recordings, sampled at hundreds of Hz, tend to be unlabelled, i.e., not catalogued, mainly because of the sheer volume of samples and the amount of time needed by experts to confidently label detected events. This is especially challenging for very low signal-to-noise ratio microseismic events that characterise landslides during rock and soil mass displacement. Whilst numerous supervised machine learning models have been proposed to classify landslide events, they rely on a large amount of labelled datasets. Therefore, there is an urgent need to develop tools to effectively automate the data-labelling process from a small set of labelled samples. In this paper, we propose a semi-supervised method for labelling of signals recorded by seismometers that can reduce the time and expertise needed to create fully annotated datasets. The proposed Siamese network approach learns best class-exemplar anchors, leveraging learned similarity between these anchor embeddings and unlabelled signals. Classification is performed via soft-labelling and thresholding instead of hard class boundaries. Furthermore, network output explainability is used to explain misclassifications and we demonstrate the effect of anchors on performance, via ablation studies. The proposed approach classifies four landslide classes, namely earthquakes, micro-quakes, rockfall and anthropogenic noise, demonstrating good agreement with manually detected events while requiring few training data to be effective, hence reducing the time needed for labelling and updating models. Full article
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9 pages, 1214 KiB  
Article
The Effect of Frankincense and Myrrh on the Sealing Ability and Hardness of Glass Ionomer Cement
by Hala Hanna, Nsar Azeez, Diyar Khalid Bakr and Media Saeed
Ceramics 2025, 8(3), 101; https://doi.org/10.3390/ceramics8030101 - 6 Aug 2025
Abstract
Efforts to enhance the mechanical and physicochemical properties of conventional glass ionomer cement (GIC) are ongoing. This study aimed to evaluate the effect of incorporating varying concentrations of frankincense and myrrh liquids into conventional GIC on its microhardness and sealing ability. Frankincense and [...] Read more.
Efforts to enhance the mechanical and physicochemical properties of conventional glass ionomer cement (GIC) are ongoing. This study aimed to evaluate the effect of incorporating varying concentrations of frankincense and myrrh liquids into conventional GIC on its microhardness and sealing ability. Frankincense and myrrh liquids were prepared by dissolving 25 g of each ground resin in 50 mL of distilled water at 60 °C and allowing the solutions to stand for 8 h. Five experimental groups were evaluated: Group A (conventional GIC), Group B (15% frankincense-modified GIC), Group C (25% frankincense-modified GIC), Group D (15% myrrh-modified GIC), and Group E (25% myrrh-modified GIC). Microhardness was evaluated using a Vickers hardness tester, and sealing ability was evaluated via interfacial gap measurements using scanning electron microscopy (SEM). SEM analysis revealed that all modified GIC groups exhibited significantly smaller interfacial gap sizes (Groups B–E: 6.1, 5.22, 5.9, and 5.34 µm, respectively) compared to conventional GIC (Group A: 6.88 µm). However, there were no statistically significant differences in microhardness among the groups (p > 0.5). The incorporation of 15% and 25% concentrations of frankincense or myrrh liquids into conventional GIC significantly improved sealing ability without compromising hardness. Full article
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18 pages, 9049 KiB  
Article
Study on the Wear Performance of 20CrMnTi Gear Steel with Different Penetration Gradient Positions
by Yingtao Zhang, Shaokui Wei, Wuxin Yang, Jiajian Guan and Gong Li
Materials 2025, 18(15), 3685; https://doi.org/10.3390/ma18153685 - 6 Aug 2025
Abstract
This study investigates the wear performance of 20CrMnTi steel, a commonly used material for spiral bevel gears, after heat treatment, with a focus on the microstructural evolution and wear behavior in both the surface and gradient direction of the carburized layer. The results [...] Read more.
This study investigates the wear performance of 20CrMnTi steel, a commonly used material for spiral bevel gears, after heat treatment, with a focus on the microstructural evolution and wear behavior in both the surface and gradient direction of the carburized layer. The results show that the microstructure composition in the gradient direction of the carburized layer gradually transitions from martensite and residual austenite to a martensite–bainite mixed structure, and eventually transforms to fully bainitic in the matrix. With the extension of carburizing time, both the effective carburized layer depth and the hardened layer depth significantly increase. Wear track morphology analysis reveals that the wear track depth gradually becomes shallower and narrower, and the wear rate increases significantly with increasing load. However, the friction coefficient shows little sensitivity to changes in carburizing time and load. Further investigations show that as the carburized layer depth increases, the carbon concentration and hardness of the samples gradually decrease, resulting in an increase in the average wear rate and a progressive worsening of wear severity. After the wear tests, different depths of plowing grooves, spalling, and fish-scale-like features were observed in the wear regions. Additionally, with the increase in load and carburized layer depth, both the width and depth of the wear tracks significantly increased. The research results provide a theoretical basis for optimizing the surface carburizing process of 20CrMnTi steel and improving its wear resistance. Full article
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32 pages, 1320 KiB  
Systematic Review
Theory of Mind Development in Deaf and Hard-of-Hearing Individuals: A Systematic Review
by Leire Martín, Mario Figueroa, Beatriz de Diego-Lázaro, Raquel Balboa-Castells and Gary Morgan
Behav. Sci. 2025, 15(8), 1065; https://doi.org/10.3390/bs15081065 - 6 Aug 2025
Abstract
Theory of Mind (ToM) is a construct that includes a range of connected abilities linked to the understanding of others’ mental states. During the last three decades, ToM development has been studied extensively in deaf and hard of hearing (DHH) individuals and performances [...] Read more.
Theory of Mind (ToM) is a construct that includes a range of connected abilities linked to the understanding of others’ mental states. During the last three decades, ToM development has been studied extensively in deaf and hard of hearing (DHH) individuals and performances compared to the typically hearing (TH) population. Given the advances in the early diagnosis of deafness, interventions, and hearing devices over this period, variations in task performance among DHH participants might have been reduced. The current systematic review aims to synthesize all studies of ToM in DHH individuals and answer the following question: Do DHH individuals (Population), compared to a control sample of TH and/or among themselves (Comparator), in an assessment of ToM (Intervention), have differentiated results (Outcome)? After a search of the literature, 97 papers were included. We found that, in general, TH participants outperformed their DHH peers in ToM measures; however, there was a wide range of results. Explanations for this variability included the quality of early interactions and early exposure to both signed and spoken language. The review also indicates that the understanding of false belief was the most studied component within ToM, while other components, such as understanding intention and irony, require further research. Implications of these findings for clinical practice are discussed. Full article
(This article belongs to the Special Issue Language and Cognitive Development in Deaf Children)
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14 pages, 5840 KiB  
Article
Paint Removal Performance and Sub-Surface Microstructural Evolution of Ti6Al4V Alloy Using Different Process Parameters of Continuous Laser Cleaning
by Haoye Zeng, Biwen Li, Liangbin Hu, Yun Zhang, Ruiqing Li, Chaochao Zhou and Pinghu Chen
Coatings 2025, 15(8), 916; https://doi.org/10.3390/coatings15080916 (registering DOI) - 6 Aug 2025
Abstract
Laser cleaning technology has been increasingly applied in the removal of damaged protective coatings from aircraft components due to its environmental friendliness and high efficiency. Appropriate laser cleaning process parameters improve cleaning efficiency while preventing substrate damage. In this study, a Gaussian continuous-wave [...] Read more.
Laser cleaning technology has been increasingly applied in the removal of damaged protective coatings from aircraft components due to its environmental friendliness and high efficiency. Appropriate laser cleaning process parameters improve cleaning efficiency while preventing substrate damage. In this study, a Gaussian continuous-wave laser was used to remove the 120 μm coating on the surface of Ti6Al4V alloy. The influence of laser power (100 W to 200 W) and scanning speed (520 mm/min to 610 mm/min) on the paint removal effect was explored based on paint removal rate, surface roughness, microstructural evolution, and the hardness’ change in the direction of heat transfer. The results reveal that optimal paint removal parameters are achieved at a laser power of 100 W with a scanning speed of 550 mm/min. The surface roughness of the sample after paint removal (55 nm) is similar to that of the original substrate (56 nm). Through EBSD analysis, the influence of laser thermal accumulation on the microstructure of the substrate is relatively small. The average hardness of the cross-section after cleaning was 347 HV, which was only 3.41% higher than that of the original substrate. This confirms that parameter-controlled laser cleaning can effectively remove ~120 μm thick paint layers without inflicting damage on the substrate. Full article
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19 pages, 1493 KiB  
Article
Development of Biodegradable Foam Trays from Brewer’s Malt Bagasse and Potato Residues from Agricultural Crops
by Evelyn F. Vásquez-Bacilio, Cesar I. Mejia-Llontop, Carlos E. Tirado-Rodríguez, María de Fátima Arévalo-Oliva, Beetthssy Z. Hurtado-Soria, Eudes Villanueva, Gilbert Rodriguez, Delia Rita Tapia-Blácido and Elza Aguirre
Polymers 2025, 17(15), 2146; https://doi.org/10.3390/polym17152146 - 6 Aug 2025
Abstract
In light of the environmental impact of disposable products made from petroleum-based plastics, this study focused on developing biodegradable foam trays made from a starch (PS) derived from potato waste and beer malt flour (BMBF). The objective of this study was to evaluate [...] Read more.
In light of the environmental impact of disposable products made from petroleum-based plastics, this study focused on developing biodegradable foam trays made from a starch (PS) derived from potato waste and beer malt flour (BMBF). The objective of this study was to evaluate the effect of the concentration of BMBF on the physical and mechanical properties of potato starch-based foam trays prepared by the thermoforming process at temperatures of 150 °C (upper plate) and 145 °C (lower plate) for 5 min and 40 s. The results showed that increasing the BMBF concentration from 0 to 40% reduced the moisture content from 4.68% to 3.42%, increased the thickness from 2.63 cm to 4.77 cm, and decreased the density from 0.28 g.cm−3 to 0.15 g.cm−3. Meanwhile, the water absorption capacity increased from 38.7% to 69.7%. In terms of mechanical properties, increasing the BMBF concentration in the PS foam tray resulted in a decrease in hardness from 5.61 N to 2.87 N, a decrease in tensile strength from 2.92 MPa to 0.85 MPa, and a decrease in elongation from 1.42% to 0.59%. Meanwhile, fracturability increased from 2.04 mm to 3.68 mm. FTIR analysis revealed interactions between BMBF and PS in the composite foam tray. Thermogravimetric analysis (TGA) showed two thermal events: one between 20.96 °C and 172.89 °C, and another between 189.14 °C and 517.69 °C, with weight losses of 5.53% and 74.23%, leaving an ash residue of 20.24%. Differential calorimetry analysis (DSC) showed a glass transition at 152.88 °C and a melting at 185.94 °C, with an enthalpy of fusion of 74.11 J.g−1. Higher concentrations of BMBF (>10%) decreased the water resistance, mechanical strength, and flexibility of the PS foam trays. Therefore, a formulation of 90% PS and 10% BMBF was better for producing a foam tray with improved mechanical properties and water resistance, which could be used as a sustainable alternative to conventional single-use plastic. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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42 pages, 7526 KiB  
Review
Novel Nanomaterials for Developing Bone Scaffolds and Tissue Regeneration
by Nazim Uddin Emon, Lu Zhang, Shelby Dawn Osborne, Mark Allen Lanoue, Yan Huang and Z. Ryan Tian
Nanomaterials 2025, 15(15), 1198; https://doi.org/10.3390/nano15151198 - 5 Aug 2025
Abstract
Nanotechnologies bring a rapid paradigm shift in hard and soft bone tissue regeneration (BTR) through unprecedented control over the nanoscale structures and chemistry of biocompatible materials to regenerate the intricate architecture and functional adaptability of bone. This review focuses on the transformative analyses [...] Read more.
Nanotechnologies bring a rapid paradigm shift in hard and soft bone tissue regeneration (BTR) through unprecedented control over the nanoscale structures and chemistry of biocompatible materials to regenerate the intricate architecture and functional adaptability of bone. This review focuses on the transformative analyses and prospects of current and next-generation nanomaterials in designing bioactive bone scaffolds, emphasizing hierarchical architecture, mechanical resilience, and regenerative precision. Mainly, this review elucidated the innovative findings, new capabilities, unmet challenges, and possible future opportunities associated with biocompatible inorganic ceramics (e.g., phosphates, metallic oxides) and the United States Food and Drug Administration (USFDA) approved synthetic polymers, including their nanoscale structures. Furthermore, this review demonstrates the newly available approaches for achieving customized standard porosity, mechanical strengths, and accelerated bioactivity to construct an optimized nanomaterial-oriented scaffold. Numerous strategies including three-dimensional bioprinting, electro-spinning techniques and meticulous nanomaterials (NMs) fabrication are well established to achieve radical scientific precision in BTR engineering. The contemporary research is unceasingly decoding the pathways for spatial and temporal release of osteoinductive agents to enhance targeted therapy and prompt healing processes. Additionally, successful material design and integration of an osteoinductive and osteoconductive agents with the blend of contemporary technologies will bring radical success in this field. Furthermore, machine learning (ML) and artificial intelligence (AI) can further decode the current complexities of material design for BTR, notwithstanding the fact that these methods call for an in-depth understanding of bone composition, relationships and impacts on biochemical processes, distribution of stem cells on the matrix, and functionalization strategies of NMs for better scaffold development. Overall, this review integrated important technological progress with ethical considerations, aiming for a future where nanotechnology-facilitated bone regeneration is boosted by enhanced functionality, safety, inclusivity, and long-term environmental responsibility. Therefore, the assimilation of a specialized research design, while upholding ethical standards, will elucidate the challenge and questions we are presently encountering. Full article
(This article belongs to the Special Issue Applications of Functional Nanomaterials in Biomedical Science)
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