Search Results (23)

Hard anodizing is used to improve the anodic films’ mechanical qualities and aluminum alloys’ corrosion resistance. Applications for anodic oxide coatings on aluminum alloys include the space environment. In this work, the aluminum alloys 2024-T3 (Al-Cu), 6061-T6 (Al-Mg-Si), and 7075-T6 (Al-Zn) were prepared by hard anodizing electrochemical treatment using citric and sulfur acid baths at different concentrations. The aim of the work is to observe the effect of citric acid on the microstructure of the substrate, the mechanical properties, the corrosion resistance, and the morphology of the hard anodic layers. Hard anodizing was performed on three different aluminum alloys using three citric–sulfuric acid mixtures for 60 min and using current densities of 3.0 and 4.5 A/dm². Vickers microhardness (HV) measurements and scanning electron microscopy (SEM) were utilized to determine the mechanical characteristics and microstructure of the hard anodizing material, and electrochemical techniques to understand the corrosion kinetics. The result indicates that the aluminum alloy 6061-T6 (Al-Mg-Si) has the maximum hard-coat thickness and hardness. The oxidation of Zn and Mg during the anodizing process found in the 7075-T6 (Al-Zn) alloy promotes oxide formation. Because of the high copper concentration, the oxide layer that forms on the 2024-T6 (Al-Cu) Al alloy has the lowest thickness, hardness, and corrosion resistance. Citric and sulfuric acid solutions can be used to provide hard anodizing in a variety of aluminum alloys that have corrosion resistance and mechanical qualities on par with or better than traditional sulfuric acid anodizing. Full article

Colorless polyimide (PI)-based flexible cover windows are a critical component of flexible electronics to protect devices from unwanted chemical and mechanical damage. The integration of flexible colorless PI-based windows into electronics applications is limited by the embrittlement of some colorless PI films when they are coated with hard coats. Here, we investigate the embrittlement mechanism of hard-coated colorless PI films and the role of interlayers in toughening the colorless PI-based cover windows for flexible electronics applications. A fracture mechanics approach combined with finite element analysis (FEA) models is employed to compute fracture strain, ε_c, for different crack cases in the bilayer (hard coated colorless PI) and trilayer (with an additional interlayer) cover windows. For the model inputs and validation, the material properties of the cover windows are characterized. We show that the embrittlement is attributed to the fracture behavior of the cover windows, and placing a ductile interlayer increases the ε_c of colorless PI films. Using the fracture analysis as a design guide, we fabricate a trilayer cover window with an acrylic thermoset interlayer and demonstrate an improvement of the ε_c of the colorless PI cover window by ~42%. We believe our analysis provides insights into design guides for mechanically robust cover windows using colorless PI films and flexible HCs for emerging flexible electronics. Full article

Hard coatings are widely employed on blades to enhance impact resistance and mitigate fatigue failure caused by vibration. While previous studies have focused on the dynamic characteristics of beams and plates, research on real blades remains limited. Specifically, there is a lack of investigation into the dynamic characteristics of hard-coated blades under base excitation. In this paper, the finite element model (FEM) of blade-hard coating (BHC) composite structure is established based on finite element methods in which the hard coating (HC) material and the substrate are considered as the isotropic material. Harmonic response analysis is conducted to calculate the resonance amplitude of the composite under base excitation. Numerical simulations and experimental tests are performed to examine the effects of various HC parameters, including energy storage modulus, loss factors, coating thickness, and coating positions, on the dynamic characteristics and vibration reduction of the hard-coated blade composite structures. The results indicate that the difference in natural frequency and modal loss factor of blades increases with higher storage modulus and HC thickness. Moreover, the vibration response of the BHC decreases with higher storage modulus, loss factor, and coating thickness of the HC material. Blades with a complete coating exhibit superior damping effects compared to other coating distributions. These findings are significant for establishing accurate dynamic models of HC composite structures, assessing the effectiveness of HC vibration suppression, and guiding the selection and preparation of HC materials. Full article

Hard-coated surfacing of a few micrometers is widely applied to increase the efficiency of tools, e.g., for cutting, forming, and casting applications. Therefore, the base thermodiffusion surface treatment is a practical solution to these issues by hardening surface layers with interstitial elements such as carbon, nitrogen, and boron. In particular, within this study, the growth kinetics of an iron boride layer on ASTM 283 steel were investigated with two diffusion models of the powder-pack boriding technique in the temperature range of 1123–1273 K with different treatment periods. The first model, called the steady-state diffusion model, used the modified version of the mass balance equations at the Fe₂B/substrate growth interface, the parabolic growth law, and the solution of Fick’s second law without time dependence. At the same time, the second diffusion model was based on Goodman’s method, also called the integral heat balance method. Afterward, the diffusion coefficient of boron in the Fe₂B phase was calculated by fitting the experimental data to the models. Nevertheless, the estimated value for the activation energy of ASTM A238 steel in both diffusion models was coincident (168.2 kJ∙mol⁻¹). A mathematical analysis was implemented by means of a power series (Taylor series) to explain this similarity. The SEM examinations showed a solid tendency to saw-tooth morphology at the growth interface with the formation of the Fe₂B layer, whose presence was verified by XRD analysis. The tribological characterizations, including the tests of Rockwell-C indentation, pin-on-disc, and Vickers hardness test method, were used to analyze the antiwear features of the Fe₂B layers. Finally, this value of energy was compared to the literature for its experimental validation. Full article

Aviation hydraulic pipelines are an important channel for power transmission in aviation hydraulic systems. Due to long-term exposure to complex vibration environments, hydraulic pipeline systems are susceptible to accumulated fatigue damage failure, which poses a great threat to aircraft safety and reliability. At present, there are only passive ways to reduce hydraulic pipeline vibration, such as adding vibration isolators and damping bearings. These methods have a poor vibration damping effect and are not safe. In this study, a hard coating was used as a new vibration reduction method for aviation hydraulic pipelines to reduce the damage caused by vibrations. For this purpose, three different hard-coating materials were optimally selected, and model creation, finite element analysis, and experimental research were carried out to study the vibration responses of hard-coated aviation hydraulic pipelines under the actual working conditions of an aircraft. The optimal solution was obtained through orthogonal experiments. The vibration reduction rate of the aviation hydraulic pipelines could reach 20.33% under the constant-frequency excitation of the low-pressure rotor of the engine, and the vibration reduction rate under the constant-frequency excitation of the high-pressure rotor could reach 26.60%. The rationality of the model was verified, and it was proven that the hard coating could meet the demands of vibration control in practical engineering and provide a reference for the vibration analysis and vibration control design of aviation hydraulic piping systems. Full article

Polyimides (PIs) are widely utilized polymeric materials for high-temperature plastics, adhesives, dielectrics, nonlinear optical materials, flexible hard-coating films, and substrates for flexible electronics. PIs can be facilely mass-produced through factory methods, so the industrial application value is limitless. Herein, we synthesized a typical poly(amic acid) (PAA) precursor-based solution through an industrialized reactor for mass production and applied the prepared solution to form thin films of PI using thermal imidization. The deposited PI thin films were successfully applied as gate dielectrics for organic field-effect transistors (OFETs). The PI layers showed suitable characteristics for dielectrics, such as a smooth surface, low leakage current density, uniform dielectric constant (k) values regardless of frequency, and compatibility with organic semiconductors. Utilizing this PI layer, we were able to fabricate electrically stable operated OFETs, which exhibited a threshold voltage shift lower than 1 V under bias-stress conditions and a field-effect mobility of 4.29 cm² V⁻¹ s⁻¹. Moreover, integrated logic gates were manufactured using these well-operated OFETs and displayed suitable operation behavior. Full article

At present, hard coating structures are widely studied as a new passive damping method. Generally, the hard coating material is completely covered on the surface of the thin-walled structure, but the local coverage cannot only achieve better vibration reduction effect, but also save the material and processing costs. In this paper, a topology optimization method for hard coated composite plates is proposed to maximize the modal loss factors. The finite element dynamic model of hard coating composite plate is established. The topology optimization model is established with the energy ratio of hard coating layer to base layer as the objective function and the amount of damping material as the constraint condition. The sensitivity expression of the objective function to the design variables is derived, and the iteration of the design variables is realized by the Method of Moving Asymptote (MMA). Several numerical examples are provided to demonstrate that this method can obtain the optimal layout of damping materials for hard coating composite plates. The results show that the damping materials are mainly distributed in the area where the stored modal strain energy is large, which is consistent with the traditional design method. Finally, based on the numerical results, the experimental study of local hard coating composites plate is carried out. The results show that the topology optimization method can significantly reduce the frequency response amplitude while reducing the amount of damping materials, which shows the feasibility and effectiveness of the method. Full article

In this study, we prepared a polyhedral oligomeric silsesquioxane (POSS)-linking polyamide (POSS polyamide) by a polycondensation of ammonium-functionalized POSS (POSS-A) and carboxyl-functionalized POSS (POSS-C) in dehydrated dimethyl sulfoxide (DMSO) using 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride (EDC) and N-hydroxysuccinimide (NHS) as condensing agents. The obtained POSS polyamide was soluble in various highly polar solvents, and it could form a self-standing film. FT-IR, ¹H NMR, and ²⁹Si NMR analyses showed that POSS polyamide is a polymer in which POSS-A and POSS-C are linked almost linearly by amide bonds. Furthermore, the cast film obtained by heat-treating the polymer at 150 °C for 30 min exhibited excellent transparency and hard-coating (pencil scratch test: 5H) and antifogging properties (evaluation by water vapor exposure). Full article

This work presents fundamental understanding of the correlation between nanoindentation hardness and practical scratch resistance for mechanically tunable anti-reflective (AR) hardcoatings. These coatings exhibit a unique design freedom, allowing quasi-continuous variation in the thickness of a central hardcoat layer in the multilayer design, with minimal impact on anti-reflective optical performance. This allows detailed study of anti-reflection coating durability based on variations in hardness vs. depth profiles, without the durability results being confounded by variations in optics. Finite element modeling is shown to be a useful tool for the design and analysis of hardness vs. depth profiles in these multilayer films. Using samples fabricated by reactive sputtering, nanoindentation hardness depth profiles were correlated with practical scratch resistance using three different scratch and abrasion test methods, simulating real world scratch events. Scratch depths from these experiments are shown to correlate to scratches observed in the field from consumer electronics devices with chemically strengthened glass covers. For high practical scratch resistance, coating designs with hardness >15 GPa maintained over depths of 200–800 nm were found to be particularly excellent, which is a substantially greater depth of high hardness than can be achieved using previously common AR coating designs. Full article

Prickly pear (Opuntia ficus-indica (L.) Mill. 1768) is cultivated in several dry and semi-dry areas of the world to produce fresh fruit, bioenergy, cosmetics, medicine, and forage. One of the main production constraints is the presence of many seeds within the fruit, which can negatively influence both the fresh-fruit market price and industrial transformation processes. In this study, different gibberellic acid (GA₃) concentrations were tested for their ability to produce well-formed and seedless fruits. Different application methods (injection and spraying) and concentrations of GA₃ (0, 100, 200, 250, and 500 ppm) combined with floral-bud emasculation were applied to a commercial plantation in southern Italy to evaluate their effects on the weight, length, and diameter of the fruits, total seed number, hard-coated viable seed number, and seed weight per fruit. The results indicated that the application of 500 ppm GA₃ sprayed on emasculated floral buds was the most effective method for reducing seed numbers of prickly pear fruits (−46.0%). The injection method resulted in a very low number of seeds (−50.7%) but produced unmarketable fruit. Observed trends suggest the need to investigate the impact of higher GA₃ concentrations and the applicability of a maximum threshold. Further studies are needed to increase our understanding of the physiological effects of the gibberellic acid pathway through productive tissue in terms of organoleptic and fruit quality. Full article

Laser-induced periodic surface structures (LIPSS) are often present when processing solid targets with linearly polarized ultrashort laser pulses. The different irradiation parameters to produce them on metals, semiconductors and dielectrics have been studied extensively, identifying suitable regimes to tailor its properties for applications in the fields of optics, medicine, fluidics and tribology, to name a few. One important parameter widely present when exposing the samples to the high intensities provided by these laser pulses in air environment, that generally is not considered, is the formation of a superficial laser-induced oxide layer. In this paper, we fabricate LIPSS on a layer of the oxidation prone hard-coating material chromium nitride in order to investigate the impact of the laser-induced oxide layer on its formation. A variety of complementary surface analytic techniques were employed, revealing morphological, chemical and structural characteristics of well-known high-spatial frequency LIPSS (HSFL) together with a new type of low-spatial frequency LIPSS (LSFL) with an anomalous orientation parallel to the laser polarization. Based on this input, we performed finite-difference time-domain calculations considering a layered system resembling the geometry of the HSFL along with the presence of a laser-induced oxide layer. The simulations support a scenario that the new type of LSFL is formed at the interface between the laser-induced oxide layer and the non-altered material underneath. These findings suggest that LSFL structures parallel to the polarization can be easily induced in materials that are prone to oxidation. Full article

To improve the reliability and safety of the mistuned blisk (integrally bladed disk), a novel strategy for passive vibration reduction by the hard coating was developed, and the vibration and damping characteristics of the HCM (hard-coating mistuned) blisk were investigated in this work. Firstly, by the proposed criterion called FDSD (frequency difference and its standard deviation), a classical reduced-order model established by the component mode synthesis method was modified to carry out modal analysis for high computational efficiency. Then, forced vibration responses of the HCM blisk were achieved by the Rayleigh damping model. Next, a specific benchmark of a mistuned blisk deposited NiCoCrAlY + YSZ hard coating was chosen to conduct numerical calculations, and the results were compared with those obtained from the FOM (full-order model) and experimental test, respectively. Finally, the influence of the hard coating and coating thickness on the mistuned blisk were investigated, in particular. Full article

For this study, a novel resistance heating system for microforming was developed using surfaces of forming dies as heating resources. The electrical resistance of the die surfaces was designed and the hard-coating material AlCrSiN was selected to coat the die surfaces for heating. To clarify the effects of the thickness and modified surfaces on heating efficiency, the temperature and stress reduction were evaluated in a micro-compression test using dies coated with 0.5 and 1 μm AlCrSiN films. Furthermore, the formability was also demonstrated using 1 μm thick AlCrSiN-coated tools in a microforging test. By applying surface-modified dies to the forming processes, we found that not only was the heating efficiency improved, but also the dependence of heating on the product’s shape and the material’s electrical properties was reduced. Full article

A sandwich-structured bottom hard-coat/silver nanowire/top hard-coat (BHC/AgNW/THC) transparent conductive film (TCF) has been prepared by embedding the functional AgNW layer between two HC layers. The BHC/AgNW/THC TCFs show high scratch resistance with a hardness of 3H due to the enhanced adhesion to the substrate. In addition, the BHC/AgNW/THC TCFs exhibit a transmittance of 90.6% and a haze of 1% at 550 nm under a sheet resistance of 72 Ω/sq. Furthermore, highly enhanced long-term stability has been guaranteed by the HC layers due to their excellent gas barrier property. The amazing fact is that hard coating has little effect on the flexibility of AgNW films especially under extreme bending conditions and negligible resistance change could be observed after bending over thousands of times. Consequently, the greatly improved performance of BHC/AgNW/THC TCFs provided by employing hard coating layers paves the way for real-world applications of flexible AgNWs in vast areas that rigid indium tin oxide is not suitable. Full article

Due to the constant need for better functionalized surfaces or smaller, function integrated components, precise and efficient manufacturing processes have to be established. Micro milling with micro end mills is one of the most promising processes for this task as it combines a high geometric flexibility in a wide range of machinable materials with low set-up costs. A downside of this process is the wear of the micro end mills. Due to size effects and the relatively low cutting speed, the cutting edge is especially subjected to massive abrasive wear. One possibility to minimize this wear is coating of micro end mills. This research paper describes the performance of eight different hard coatings for micro end mills with a diameter <40 µm and discusses some properties for the best performing coating type. With this research, it is therefore possible to boost the possibilities of micro milling for the manufacture of next generation products. Full article