Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (27)

Search Parameters:
Keywords = hand ray-casting

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
28 pages, 3228 KiB  
Article
Examination of Eye-Tracking, Head-Gaze, and Controller-Based Ray-Casting in TMT-VR: Performance and Usability Across Adulthood
by Panagiotis Kourtesis, Evgenia Giatzoglou, Panagiotis Vorias, Katerina Alkisti Gounari, Eleni Orfanidou and Chrysanthi Nega
Multimodal Technol. Interact. 2025, 9(8), 76; https://doi.org/10.3390/mti9080076 - 25 Jul 2025
Viewed by 374
Abstract
Virtual reality (VR) can enrich neuropsychological testing, yet the ergonomic trade-offs of its input modes remain under-examined. Seventy-seven healthy volunteers—young (19–29 y) and middle-aged (35–56 y)—completed a VR Trail Making Test with three pointing methods: eye-tracking, head-gaze, and a six-degree-of-freedom hand controller. Completion [...] Read more.
Virtual reality (VR) can enrich neuropsychological testing, yet the ergonomic trade-offs of its input modes remain under-examined. Seventy-seven healthy volunteers—young (19–29 y) and middle-aged (35–56 y)—completed a VR Trail Making Test with three pointing methods: eye-tracking, head-gaze, and a six-degree-of-freedom hand controller. Completion time, spatial accuracy, and error counts for the simple (Trail A) and alternating (Trail B) sequences were analysed in 3 × 2 × 2 mixed-model ANOVAs; post-trial scales captured usability (SUS), user experience (UEQ-S), and acceptability. Age dominated behaviour: younger adults were reliably faster, more precise, and less error-prone. Against this backdrop, input modality mattered. Eye-tracking yielded the best spatial accuracy and shortened Trail A time relative to manual control; head-gaze matched eye-tracking on Trail A speed and became the quickest, least error-prone option on Trail B. Controllers lagged on every metric. Subjective ratings were high across the board, with only a small usability dip in middle-aged low-gamers. Overall, gaze-based ray-casting clearly outperformed manual pointing, but optimal choice depended on task demands: eye-tracking maximised spatial precision, whereas head-gaze offered calibration-free enhanced speed and error-avoidance under heavier cognitive load. TMT-VR appears to be accurate, engaging, and ergonomically adaptable assessment, yet it requires age-specific–stratified norms. Full article
(This article belongs to the Special Issue 3D User Interfaces and Virtual Reality—2nd Edition)
Show Figures

Figure 1

25 pages, 5055 KiB  
Article
FlickPose: A Hand Tracking-Based Text Input System for Mobile Users Wearing Smart Glasses
by Ryo Yuasa and Katashi Nagao
Appl. Sci. 2025, 15(15), 8122; https://doi.org/10.3390/app15158122 - 22 Jul 2025
Viewed by 350
Abstract
With the growing use of head-mounted displays (HMDs) such as smart glasses, text input remains a challenge, especially in mobile environments. Conventional methods like physical keyboards, voice recognition, and virtual keyboards each have limitations—physical keyboards lack portability, voice input has privacy concerns, and [...] Read more.
With the growing use of head-mounted displays (HMDs) such as smart glasses, text input remains a challenge, especially in mobile environments. Conventional methods like physical keyboards, voice recognition, and virtual keyboards each have limitations—physical keyboards lack portability, voice input has privacy concerns, and virtual keyboards struggle with accuracy due to a lack of tactile feedback. FlickPose is a novel text input system designed for smart glasses and mobile HMD users, integrating flick-based input and hand pose recognition. It features two key selection methods: the touch-panel method, where users tap a floating UI panel to select characters, and the raycast method, where users point a virtual ray from their wrist and confirm input via a pinch motion. FlickPose uses five left-hand poses to select characters. A machine learning model trained for hand pose recognition outperforms Random Forest and LightGBM models in accuracy and consistency. FlickPose was tested against the standard virtual keyboard of Meta Quest 3 in three tasks (hiragana, alphanumeric, and kanji input). Results showed that raycast had the lowest error rate, reducing unintended key presses; touch-panel had more deletions, likely due to misjudgments in key selection; and frequent HMD users preferred raycast, as it maintained input accuracy while allowing users to monitor their text. A key feature of FlickPose is adaptive tracking, which ensures the keyboard follows user movement. While further refinements in hand pose recognition are needed, the system provides an efficient, mobile-friendly alternative for HMD text input. Future research will explore real-world application compatibility and improve usability in dynamic environments. Full article
(This article belongs to the Special Issue Extended Reality (XR) and User Experience (UX) Technologies)
Show Figures

Figure 1

13 pages, 9140 KiB  
Article
Effect of Heat Treatment on Corrosion of an AlCoCrFeNi2.1 Eutectic High-Entropy Alloy in 3.5 wt% NaCl Solution
by Jun Jiang, Haijing Sun and Jie Sun
Metals 2025, 15(6), 681; https://doi.org/10.3390/met15060681 - 19 Jun 2025
Viewed by 462
Abstract
This paper studies how heat treatments influence the corrosion of an AlCoCrFeNi2.1 eutectic high-entropy alloy (EHEA) in a 3.5 wt% NaCl solution, by comparing the corrosion behaviors of as-cast, 600 °C heat-treated, and 1000 °C heat-treated samples using microstructure characterization, electrochemical measurements, [...] Read more.
This paper studies how heat treatments influence the corrosion of an AlCoCrFeNi2.1 eutectic high-entropy alloy (EHEA) in a 3.5 wt% NaCl solution, by comparing the corrosion behaviors of as-cast, 600 °C heat-treated, and 1000 °C heat-treated samples using microstructure characterization, electrochemical measurements, and surface characterization. The electrochemical results show that the pitting potential rises and the passive current density and passive film resistance are almost changeless with an increasing heat treatment temperature. The enhancement in the pitting corrosion resistance results from the increased amount of the Cr-rich FCC phase and decreased amount of the B2 phase rich in the Al element, which are induced by the heat treatment. On one hand, this microstructure evolution can make the passive film have more Cr2O3 and less Al2O3, thereby enhancing its protective properties, as confirmed by the X-ray photoelectron spectroscopy analysis. On the other hand, the decreased amount of the Al-rich B2 phase can make the pitting corrosion less prone to initiate since the B2 phase can act as the pit initiation site, which is supported by the observation of corrosion morphologies, due to its higher electrochemical activity. In a summary, the heat treatment is beneficial for improving the pitting corrosion resistance of the AlCoCrFeNi2.1 EHEA. Full article
(This article belongs to the Special Issue High-Entropy Alloy and Films: Design, Properties and Application)
Show Figures

Figure 1

13 pages, 5096 KiB  
Article
Quantitative Study of Internal Defects in Copper Iron Alloy Materials Using Computed Tomography
by Junli Guo, Qiang Hu and Kai Hu
Alloys 2025, 4(2), 8; https://doi.org/10.3390/alloys4020008 - 29 Apr 2025
Viewed by 742
Abstract
Semi-continuous casting is an important method for the large-scale production of high-strength conductive copper-iron (Cu-Fe) alloys in the future. However, serious peeling defects were found on the surface of cold-rolled strips during industrial trials. Due to the multi-step complexity of the manufacturing process [...] Read more.
Semi-continuous casting is an important method for the large-scale production of high-strength conductive copper-iron (Cu-Fe) alloys in the future. However, serious peeling defects were found on the surface of cold-rolled strips during industrial trials. Due to the multi-step complexity of the manufacturing process (from casting to final product), identifying the root cause of defect formation remains challenging. X-ray computed tomography (X-CT) was used to quantitatively characterize the pores and defects in the horizontal continuous casting Cu-Ni-Sn slab, the semi-continuous casting Cu-Fe alloy slab, and the hot-rolled slab of Cu-Fe, and the relationship between the defect characteristics and processes was analyzed. The results showed that the internal defect sphericity distribution of the Cu-Fe alloy slab after hot rolling was similar to that of the reference Cu-Ni-Sn slab. The main difference lies in the low sphericity range (<0.4). The volume of pore defects inside the Cu-Fe alloy after hot rolling was significantly larger than in the reference sample, with a 52-fold volume difference. This phenomenon may be the source of surface-peeling defects in the subsequent cold-rolling process. The occurrence of internal defects in the Cu-Fe alloy is related to both the composition characteristics and casting processes of the Cu-Fe alloy; on the other hand, it is also related to the hot-rolling process. Full article
Show Figures

Figure 1

16 pages, 6192 KiB  
Article
Combined Use of Non-Destructive Analysis Techniques to Investigate Ancient Bronze Statues
by Loredana Luvidi, Annalaura Casanova Municchia, Eleni Konstantakopoulou, Noemi Orazi, Marco Ferretti and Giovanni Caruso
Sensors 2025, 25(6), 1727; https://doi.org/10.3390/s25061727 - 11 Mar 2025
Viewed by 755
Abstract
Non-destructive portable techniques for the analysis of cultural heritage items are essential for enhancing our understanding of these objects and providing valuable information for potential restoration interventions. This paper presents a combined use of pulsed thermography, X-ray fluorescence, and Raman spectroscopy to investigate [...] Read more.
Non-destructive portable techniques for the analysis of cultural heritage items are essential for enhancing our understanding of these objects and providing valuable information for potential restoration interventions. This paper presents a combined use of pulsed thermography, X-ray fluorescence, and Raman spectroscopy to investigate the ancient bronze “Il Togato”, yielding complementary information concerning the techniques used for creating this artefact and its conservation status. Specifically, thermographic analysis has highlighted the presence of many patches of different size used for emending superficial cast defects, weldings used to connect parts separately cast to the main structure, cracks, and defects located in the bronze thickness. On the other hand, XRF provided information on the composition of the gilding which characterises the statue, and supplied an estimate of its thickness through the use of a stratification model. Additionally, Raman spectroscopy has been applied to identify corrosion products. The experimental results presented in the paper provide a comprehensive knowledge of the bronze under investigation and assess the effectiveness of the portable non-destructive techniques employed in the analysis. Full article
Show Figures

Figure 1

19 pages, 12690 KiB  
Article
TouchView: Mid-Air Touch on Zoomable 2D View for Distant Freehand Selection on a Virtual Reality User Interface
by Woojoo Kim and Shuping Xiong
Sensors 2024, 24(22), 7202; https://doi.org/10.3390/s24227202 - 11 Nov 2024
Viewed by 1219
Abstract
Selection is a fundamental interaction element in virtual reality (VR) and 3D user interfaces (UIs). Raycasting, one of the most common object selection techniques, is known to have difficulties in selecting small or distant objects. Meanwhile, recent advancements in computer vision technology have [...] Read more.
Selection is a fundamental interaction element in virtual reality (VR) and 3D user interfaces (UIs). Raycasting, one of the most common object selection techniques, is known to have difficulties in selecting small or distant objects. Meanwhile, recent advancements in computer vision technology have enabled seamless vision-based hand tracking in consumer VR headsets, enhancing accessibility to freehand mid-air interaction and highlighting the need for further research in this area. This study proposes a new technique called TouchView, which utilizes a virtual panel with a modern adaptation of the Through-the-Lens metaphor to improve freehand selection for VR UIs. TouchView enables faster and less demanding target selection by allowing direct touch interaction with the magnified object proxies reflected on the panel view. A repeated-measures ANOVA on the results of a follow-up experiment on multitarget selection with 23 participants showed that TouchView outperformed the current market-dominating freehand raycasting technique, Hybrid Ray, in terms of task performance, perceived workload, and preference. User behavior was also analyzed to understand the underlying reasons for these improvements. The proposed technique can be used in VR UI applications to enhance the selection of distant objects, especially for cases with frequent view shifts. Full article
(This article belongs to the Section Sensing and Imaging)
Show Figures

Figure 1

13 pages, 1503 KiB  
Article
Effect of Cobalt on the Microstructure of Fe-B-Sn Amorphous Metallic Alloys
by Daniel G. Grey, Martin Cesnek, Marek Bujdoš and Marcel B. Miglierini
Metals 2024, 14(6), 712; https://doi.org/10.3390/met14060712 - 16 Jun 2024
Cited by 3 | Viewed by 1463
Abstract
Fe78B15Sn7 and (Fe3Co1)78B15Sn7 amorphous metallic alloys were prepared using the method of planar flow casting. The amorphous nature of ribbons containing 7 at. % Sn was verified by X-ray [...] Read more.
Fe78B15Sn7 and (Fe3Co1)78B15Sn7 amorphous metallic alloys were prepared using the method of planar flow casting. The amorphous nature of ribbons containing 7 at. % Sn was verified by X-ray diffraction. The resulting chemical composition was checked by flame atomic absorption spectroscopy and by mass spectrometry with inductively coupled plasma. The microstructure of the as-quenched metallic glasses was investigated by 57-Fe and 119-Sn Mössbauer spectrometry. The experiments were performed with transmission geometry at 300 K, 100 K, and 4.2 K, and in an external magnetic field of 6 T. The replacement of a quarter of the Fe by Co did not cause significant modifications of the hyperfine interactions in the 57-Fe nuclei. The observed minor variations in the local magnetic microstructure were attributed to alterations in the topological short-range order. However, the in-field 57-Fe Mössbauer spectra indicated a misalignment of the partial magnetic moments. On the other hand, the presence of Co considerably affected the local magnetic microstructure of the 119-Sn nuclei. This was probably due to the higher magnetic moment of Co, which induces transfer fields and polarization effects on the diamagnetic Sn atoms. Full article
Show Figures

Graphical abstract

23 pages, 12642 KiB  
Article
Assessing Learning in an Immersive Virtual Reality: A Curriculum-Based Experiment in Chemistry Education
by Sam Qorbani, Shadi Dalili, Ali Arya and Christopher Joslin
Educ. Sci. 2024, 14(5), 476; https://doi.org/10.3390/educsci14050476 - 30 Apr 2024
Cited by 9 | Viewed by 4163
Abstract
Despite the recent advances in Virtual Reality technology and its use in education, the review of the literature shows several gaps in research on how immersive virtual environments impact the learning process. In particular, the lack of curriculum-specific experiments along with investigations of [...] Read more.
Despite the recent advances in Virtual Reality technology and its use in education, the review of the literature shows several gaps in research on how immersive virtual environments impact the learning process. In particular, the lack of curriculum-specific experiments along with investigations of the effects of different content, activity, and interaction types in the current VR studies has been identified as a significant shortcoming. This has been more significant in STEM fields, where VR has the potential to offer engaging experiential learning opportunities. The study reported here was designed to address this gap by assessing the effect of authentic visualization and interaction types on learning a particular scientific concept. A use case scenario of “orbital hybridization” in chemistry education was selected to create this experiment and to collect data for analysis. We collected data on learning outcomes, task-completion efficiency, accuracy, and subjective usability. A combination of learning content and tasks designed based on the relevant educational theories was presented to three groups: 2D, VR interaction type 1 (hand gestures), and VR interaction type 2 (ray casting). The results showed that VR could improve learning and that interaction type could influence efficiency and accuracy depending on the task. Full article
(This article belongs to the Special Issue Teaching and Learning with Virtual/Augmented Reality)
Show Figures

Figure 1

12 pages, 3417 KiB  
Article
Influence of Nd Substitution on the Phase Constitution in (Zr,Ce)Fe10Si2 Alloys with the ThMn12 Structure
by Mieszko Kołodziej, Jean-Marc Grenèche, Sandy Auguste, Bogdan Idzikowski, Maciej Zubko, Lotfi Bessais and Zbigniew Śniadecki
Materials 2023, 16(4), 1522; https://doi.org/10.3390/ma16041522 - 11 Feb 2023
Cited by 1 | Viewed by 1828
Abstract
Iron-based compounds with a ThMn12-type structure have the potential to bridge the gap between ferrites and high performance Nd2Fe14B magnets. From the point of view of possible applications, the main advantage is their composition, with about 10 [...] Read more.
Iron-based compounds with a ThMn12-type structure have the potential to bridge the gap between ferrites and high performance Nd2Fe14B magnets. From the point of view of possible applications, the main advantage is their composition, with about 10 wt.% less rare earth elements in comparison with the 2:14:1 phase. On the other hand, the main issue delaying the development of Fe-rich alloys with a ThMn12-type structure is their structural stability. Therefore, various synthesis methods and stabilizing elements have been proposed to stabilize the structure. In this work, the influence of increasing Nd substitution on the phase constitution of Zr0.4−xNdxCe0.6Fe10Si2 (0 ≤ x ≤ 0.3) alloys was analyzed. X-ray diffraction and 57Fe Mössbauer spectrometry were used as the main methods to derive the stability range and destabilization routes of the 1:12 structure. For the arc-melted samples, an increase in the lattice parameters of the ThMn12-type structure was observed with the simultaneous growth of bcc-(Fe,Si) content with increasing Nd substitution. After isothermal annealing, the ThMn12-type structure (and the coexisting bcc-(Fe,Si)) were stable over the whole composition range. While the formation of a 1:12 phase was totally suppressed in the as-cast state for x = 0.3, further heat treatment resulted in the growth of about 45% of the ThMn12-type phase. The results confirmed that the stability range of ThMn12-type structure in the Nd-containing alloys was well improved by other substitutions and the heat treatment, which in turn, is also needed to homogenize the ThMn12-type phase. After further characterization of the magnetic properties and optimization of microstructure, such hard/soft magnetic composites can show their potential by exploiting the exchange spring mechanism. Full article
Show Figures

Figure 1

20 pages, 5083 KiB  
Article
The Role of Dissolution Time on the Properties of All-Cellulose Composites Obtained from Oil Palm Empty Fruit Bunch
by Mohd Zaim Jaafar, Farah Fazlina Mohd Ridzuan, Mohamad Haafiz Mohamad Kassim and Falah Abu
Polymers 2023, 15(3), 691; https://doi.org/10.3390/polym15030691 - 30 Jan 2023
Cited by 4 | Viewed by 2646
Abstract
All-cellulose composite (ACC) films from oil palm empty fruit bunches (OPEFBs) were successfully fabricated through the surface selective dissolution of cellulose fibers in 8 wt% LiCl/DMAc via the solution casting method. The effect of dissolution time on the properties of the ACC films [...] Read more.
All-cellulose composite (ACC) films from oil palm empty fruit bunches (OPEFBs) were successfully fabricated through the surface selective dissolution of cellulose fibers in 8 wt% LiCl/DMAc via the solution casting method. The effect of dissolution time on the properties of the ACC films was assessed in the range of 5–45 min. The results showed that under the best conditions, there were sufficiently dissolved fiber surfaces that improved the interfacial adhesion while maintaining a sizable fraction of the fiber cores, acting as reinforcements for the material. The ACC films have the highest tensile strength and modulus of elasticity of up to 35.78 MPa and 2.63 GPa after 15 min of dissolution. Meanwhile, an X-ray diffraction analysis proved that cellulose I and II coexisted, which suggests that the crystallite size and degree of crystallinity of the ACC films had significantly declined. This is due to a change in the cellulose structure, which results in fewer voids and enhanced stress distribution in the matrix. Scanning electron microscopy revealed that the interfacial adhesion improved between the reinforcing fibers and matrices as the failure behavior of the film composite changed from fiber pullout to fiber breakage and matrix cracking. On the other hand, the thermal stability of the ACC film showed a declining trend as the dissolution time increased. Therefore, the best dissolution time to formulate the ACC film was 15 min, and the obtained ACC film is a promising material to replace synthetic polymers as a green composite. Full article
(This article belongs to the Special Issue Natural-Based Biodegradable Polymeric Materials)
Show Figures

Figure 1

15 pages, 4093 KiB  
Article
Properties Evaluation of Composite Materials Based on Gypsum Plaster and Posidonia Oceanica Fibers
by Abdessalam Guedri, Kawthar Yahya, Noureddine Hamdi, Oscar Baeza-Urrea, Jean-Frank Wagner and Mohamed Faouzi Zagrarni
Buildings 2023, 13(1), 177; https://doi.org/10.3390/buildings13010177 - 9 Jan 2023
Cited by 8 | Viewed by 2405
Abstract
Estimating the amount of material without significant losses at the end of hybrid casting is a problem addressed in this study. To minimize manufacturing costs and improve the accuracy of results, a correction factor (CF) was used in the formula to estimate the [...] Read more.
Estimating the amount of material without significant losses at the end of hybrid casting is a problem addressed in this study. To minimize manufacturing costs and improve the accuracy of results, a correction factor (CF) was used in the formula to estimate the volume percent of the material in order to reduce material losses during the sample manufacturing stage, allowing for greater confidence between the approved blending plan and the results obtained. In this context, three material mixing schemes of different sizes and shapes (gypsum plaster, sand (0/2), gravel (2/4), and Posidonia oceanica fibers (PO)) were created to verify the efficiency of CF and more precisely study the physico-mechanical effects on the samples. The results show that the use of a CF can reduce mixing loss to almost 0%. The optimal compressive strength of the sample (S1B) with the lowest mixing loss was 7.50 MPa. Under optimal conditions, the addition of PO improves mix volume percent correction (negligible), flexural strength (5.45%), density (18%), and porosity (3.70%) compared with S1B. On the other hand, the addition of PO thermo-chemical treatment by NaOH increases the compressive strength (3.97%) compared with PO due to the removal of impurities on the fiber surface, as shown by scanning electron microscopy. We then determined the optimal mixture ratio (PO divided by a mixture of plaster, sand, and gravel), which equals 0.0321 because Tunisian gypsum contains small amounts of bassanite and calcite, as shown by the X-ray diffraction results. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
Show Figures

Figure 1

14 pages, 3276 KiB  
Article
Highlighting the Compositional Changes of the Sm2O3/MgO-Containing Cellulose Acetate Films for Wound Dressings
by Yousef A. A. Alghuwainem, Mohamed Gouda, Mai M. Khalaf, Fakiha El-Taib Heakal, Hanan A. Albalwi, Abraham Elmushyakhi and Hany M. Abd El-Lateef
Polymers 2022, 14(22), 4964; https://doi.org/10.3390/polym14224964 - 16 Nov 2022
Cited by 12 | Viewed by 2083
Abstract
The development of wound dressing materials with appropriate specifications is still a challenge to overcome the current limitations of conventional medical bandages. In this regard, simple and fast methods are highly recommended, such as film casting. In addition, deliverable nanoparticles that can act [...] Read more.
The development of wound dressing materials with appropriate specifications is still a challenge to overcome the current limitations of conventional medical bandages. In this regard, simple and fast methods are highly recommended, such as film casting. In addition, deliverable nanoparticles that can act to accelerate wound integration, such as samarium oxide (Sm2O3) and magnesium oxide (MgO), might represent a potential design with a novel compositional combination. In the present research, the casted film of cellulose acetate (CA) was mixed with different ratios of metal oxides, such as samarium oxide (Sm2O3) and magnesium oxide (MgO). The tests used for the film examination were X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The SEM graphs of CA films represent the surface morphology of Sm2O3@CA, MgO@CA, and Sm2O3/MgO/GO@CA. It was found that the scaffolds’ surface contained a high porosity ratio with diameters of 1.5–5 µm. On the other hand, the measurement of contact angle exhibits a variable trend starting from 27° to 29° for pristine CA and Sm2O3/MgO/GO@CA. The cell viability test exhibits a noticeable increase in cell growth with a decrease in the concentration. In addition, the IC50 was determined at 6 mg/mL, while the concentration of scaffolds of 20 mg/mL caused cellular growth to be around 106%. Full article
Show Figures

Figure 1

20 pages, 7822 KiB  
Article
ZDDP Tribofilm Formation from a Formulated Oil on Textured Cylinder Liners
by Leonardo C. Dias, Giuseppe Pintaude, Alessandro A. O. F. Vittorino and Henara L. Costa
Lubricants 2022, 10(6), 118; https://doi.org/10.3390/lubricants10060118 - 7 Jun 2022
Cited by 8 | Viewed by 3589
Abstract
Surface texturing can improve lubrication and entrap wear debris but increases the effective roughness of the surfaces, which can induce higher contact pressures. On the one hand, this can be detrimental, but on the other hand, the increase in contact pressure could be [...] Read more.
Surface texturing can improve lubrication and entrap wear debris but increases the effective roughness of the surfaces, which can induce higher contact pressures. On the one hand, this can be detrimental, but on the other hand, the increase in contact pressure could be used to activate the formation of a ZDDP tribofilm from fully-formulated lubricants. This work investigates the synergistic effect between surface texturing via Maskless Electrochemical Texturing (MECT) and ZDDP additive. The surface texture consisted of an array of annular pockets manufactured on a gray cast iron cylinder liner. These textured surfaces were evaluated by scanning electron microscope (SEM) and energy-dispersive X-ray spectroscopy (EDX). The results indicated that surface texturing via MECT changes the chemical composition of the surfaces, by inducing a preferential dissolution of the metal matrix. Consequently, it exposed the carbon present in the material. The tribological performance was evaluated by a ring-on-cylinder-liner tribometer in reciprocating sliding under boundary lubrication conditions using both a base oil and a commercial formulated oil containing ZDDP additive. For comparison, a commercially honed liner was also tested. After the tribological tests, the surfaces were evaluated by white light interferometry and SEM/EDX. Although the textured surfaces showed higher friction, they induced more ZDDP-tribofilm formation than conventional cylinder liner finish. Full article
(This article belongs to the Special Issue Automotive Tribology II)
Show Figures

Figure 1

12 pages, 4086 KiB  
Article
Characterization and Hazard Identification of Respirable Cement and Concrete Dust from Construction Activities
by Akshay Gharpure, James William Heim and Randy L. Vander Wal
Int. J. Environ. Res. Public Health 2021, 18(19), 10126; https://doi.org/10.3390/ijerph181910126 - 27 Sep 2021
Cited by 14 | Viewed by 4381
Abstract
Construction is an important segment of the economy that employs millions of people. Construction dust is an occupational health hazard to millions of construction workers worldwide. The hazards associated with respirable dust depend upon its particulate size distribution and chemical composition, as these [...] Read more.
Construction is an important segment of the economy that employs millions of people. Construction dust is an occupational health hazard to millions of construction workers worldwide. The hazards associated with respirable dust depend upon its particulate size distribution and chemical composition, as these determine the deposition pattern in the respiratory tract and reactivity, respectively. This study presents characterization of the size and composition of the dust from two key construction materials—cast cement and poured concrete. The dust was generated by cutting the cured cement and concrete blocks using an 18” hand-held circular saw as used in highway and building construction. Transmission electron microscopy, scanning electron microscopy, dynamic light scattering, and laser diffraction were performed for the size analysis of the particles. Energy dispersive spectroscopy and X-ray photoelectron spectroscopy were used for chemical analysis. X-ray diffraction was used for phase identification. Electron diffraction patterns were obtained to assess the crystallinity of individual particles. They confirm the crystallinity of particles of different size and shapes. With a particle size range between 0.5 μm and 10 μm, greater than 90% of particles fell below 2.5 μm, presenting a respirable health concern. Crystalline compounds including the metals Al, Ca, Fe, Mg, Na, and K were detected. The concrete particles were most enriched in crystalline silica with a concentration of more than 30% by weight. The presence of metals and high crystalline silica content pose a serious health concern to construction workers. Full article
(This article belongs to the Topic Air Pollution and Occupational Exposure)
Show Figures

Figure 1

16 pages, 4552 KiB  
Article
Metal Organic Frameworks Derived Sustainable Polyvinyl Alcohol/Starch Nanocomposite Films as Robust Materials for Packaging Applications
by Naveed Ahmed Khan, Muhammad Bilal Khan Niazi, Farooq Sher, Zaib Jahan, Tayyaba Noor, Ofaira Azhar, Tazien Rashid and Naseem Iqbal
Polymers 2021, 13(14), 2307; https://doi.org/10.3390/polym13142307 - 14 Jul 2021
Cited by 74 | Viewed by 5980
Abstract
Bio-nanocomposites-based packaging materials have gained significance due to their prospective application in rising areas of packaged food. This research aims to fabricate biodegradable packaging films based upon polyvinyl alcohol (PVA) and starch integrated with metal-organic frameworks (MOFs) or organic additives. MOFs offer unique [...] Read more.
Bio-nanocomposites-based packaging materials have gained significance due to their prospective application in rising areas of packaged food. This research aims to fabricate biodegradable packaging films based upon polyvinyl alcohol (PVA) and starch integrated with metal-organic frameworks (MOFs) or organic additives. MOFs offer unique features in terms of surface area, mechanical strength, and chemical stability, which make them favourable for supporting materials used in fabricating polymer-based packaging materials. zeolitic imidazolate frameworks (ZIFs) are one of the potential candidates for this application due to their highly conductive network with a large surface area and high porosity. Present research illustrates a model system based on ZIF-67 (C8H10N4Co) bearing 2–10 wt.% loading in a matrix of PVA/starch blend with or without pyrolysis to probe the function of intermolecular interaction in molecular packing, tensile properties, and glass transition process. ZIF-67 nanoparticles were doped in a PVA/starch mixture, and films were fabricated using the solution casting method. It was discovered through scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and Fourier transform infrared spectroscopy (FTIR) that addition of ZIF-67 and pyrolyzed ZIF-67 changed and enhanced the thermal stability of the membrane. Moreover, 2–10 wt.% loading of ZIF-67 effected the thermal stability, owing to an interlayer aggregation of ZIF-67. The membranes containing pyrolyzed ZIF-67 showed mechanical strength in the order of 25 MPa in a moderate loading of pyrolyzed ZIF-67 (i.e., at 4 wt.%). The crystallinity enhanced by an increment in ZIF-67 loading. On the other hand, pyrolyzed ZIF-67 carbon became amorphous because of the inert environment and elevated temperature. The surface area also increased after the pyrolysis, which helped to increase the strength of the composite films. Full article
Show Figures

Graphical abstract

Back to TopTop