Search Results (263)

Understanding the hydrochemical characteristics of groundwater in coal mining subsidence areas is of critical scientific significance for water environment protection and ecological restoration in mining regions. A systematic hydrochemical campaign was undertaken in the Luwa collapse zone (Jining city, Shandong Province) to decipher the composition, evolutionary behavior, and governing factors of groundwater within a high-water-table subsidence context. The analytical protocol comprised three complementary components: conventional hydrochemical profiling, ion-ratio-based source identification, and multivariate statistical modeling. The findings revealed that the groundwater in the study area was weakly alkaline (pH = 7.33 ± 0.217), with total dissolved solids (TDS) ranging from 1180 to 2280 mg/L, and all sampled sites exceeded the Class III groundwater quality standard of China. Na⁺, SO₄²⁻, and Cl⁻ were identified as the predominant pollutants, with exceedance rates of 91.3%, 95.7%, and 91.3%, respectively, which were primarily attributed to coal mine drainage and domestic sewage input. The groundwater chemical composition was governed by the combined effects of rock weathering, evaporation–concentration processes, and anthropogenic activities. Specifically, Na⁺ and Cl⁻ originated mainly from the dissolution of silicate minerals and halite, as well as domestic sewage input; SO₄²⁻ was primarily controlled by evaporite dissolution and industrial wastewater discharge; carbonate and silicate mineral weathering was identified as the primary source of Ca²⁺ and Mg²⁺; and NO₃⁻ was predominantly influenced by agricultural activities. Principal component analysis (PCA) extracted three major controlling factors shaping the groundwater hydrochemistry in this area, namely: (1) evaporite dissolution and sewage input, (2) carbonate dissolution and pH buffering processes, and (3) agricultural input. This study reveals a dual-driven evolutionary model of groundwater in high-water-table coal mining subsidence areas, characterized by “natural enrichment superimposed by anthropogenic input,” whose work contributes to the knowledge base for sustainable groundwater stewardship and contamination risk reduction in mining-affected areas with analogous conditions. Full article

Afghanistan’s Panjshir Valley is an important emerald-producing region in Asia. In this study, emeralds from Kamar Safid in Southeastern Panjshir were investigated by Fourier-transform infrared (FTIR), Raman spectroscopy, ultraviolet–visible–near-infrared (UV-Vis-NIR) spectroscopy, and laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS). These Kamar Safid emeralds are generally small, light-green-to-green crystals. Microscopic observations revealed abundant acicular and tubular three- or two-phase fluid inclusions, with transparent feldspar-group mineral inclusions. Solid phases in the fluid inclusions commonly consist of carbonate crystals or several transparent halite daughter crystals. FTIR spectra of samples indicated that the absorption of type II H₂O was higher than type I H₂O in the emeralds from Kamar Safid. The UV-Vis-NIR spectra are characterized by Cr- and V-related absorption bands, which are stronger than Fe-related absorptions. LA-ICP-MS results indicate slightly higher V contents and lower Cr contents than emeralds from other Panjshir mining areas. The relatively low total Cr and V contents of Kamar Safid emeralds account for the overall lighter color, suggesting that Cr and V are the principal chromophores, whereas Fe secondarily modifies hue. Rb, Cs, and Sc contents are 6.2–24.3 ppm, 11.9–141.6 ppm, and 92–1461 ppm, with total alkali contents of 4903.10–14,257.18 ppm. Cs-Rb, Cs-Sc, Li-Cs, and Li-Sc binary logarithmic diagrams indicate enrichment in Sc and Rb and depletion in Li and Cs. Full article

Understanding the formation of high-total-dissolved-solids (TDS) groundwater is essential for mine-water source identification, treatment, and resource utilization in arid and semi-arid coal mining areas. However, previous studies have commonly focused on individual aquifers and have not adequately explained the hydrochemical differentiation and evolutionary relationships within shallow-to-deep multi-aquifer systems. Taking the Xiaojihan Coal Mine in northern Shaanxi as a case study, 90 surface-water and groundwater samples were analyzed using self-organizing maps (SOM), hydrochemical diagrams, major-ion ratios, chlor-alkali indices, mineral saturation indices, X-ray diffraction data, and permeability-TDS relationships. SOM identified three hydrochemical units broadly corresponding to shallow surface water and groundwater from the Quaternary and Luohe formations, groundwater from the Anding Formation, and deep groundwater dominated by the Zhiluo and Yan’an formations. Their mean TDS concentrations increased from 348.69 to 1341.80 and 2510.00 mg/L, respectively. Groundwater evolved from low-TDS, HCO₃-Ca-dominated shallow water to high-TDS, SO₄-Ca/Na-rich deep water. Shallow groundwater was mainly controlled by carbonate and silicate weathering, whereas deep groundwater was increasingly affected by prolonged water-rock interaction, gypsum and anhydrite dissolution, pyrite oxidation, and reverse cation exchange. The increase in deep-groundwater TDS was primarily associated with the enrichment of SO₄²⁻, Na⁺ + K⁺, and Ca²⁺. Lower permeability with depth slowed groundwater circulation, prolonged residence time, and enhanced mineralization. XRD data confirmed the occurrence of exchange-active clay minerals, while saturation indices showed that carbonate minerals were generally near saturation to supersaturated, whereas gypsum, anhydrite, and halite remained undersaturated and retained dissolution potential. These findings clarify the shallow-to-deep evolution mechanism of high-TDS groundwater and provide a scientific basis for mine-water source identification and targeted management in arid and semi-arid coal mining areas. Full article

To elucidate the mechanisms responsible for the low strength, pronounced variability, and long-term deformation of carnallitite, and to provide a basis for stope parameter design in deep potash mines, two carnallitite seams from a potash mine were investigated. Group C carnallitite and Group D halite-dominated rock salt were subjected to short-term compression tests and multiscale comparative analyses, while Groups A and B carnallitite specimens were tested under multistage creep loading. Particle Flow Code (PFC) simulations were conducted to evaluate the influence of particle size distribution. The results indicate the following: (1) The representative Group C specimens exhibited an average uniaxial compressive strength of 7.83 MPa, which was substantially lower than that of Group D. The acoustic emission (AE), scanning electron microscopy (SEM), and computed tomography (CT) analyses revealed greater heterogeneity in damage evolution and failure behavior, mainly associated with polymineralic composition, weak particle–matrix interfaces, local pores, and insufficient particle connectivity. (2) Particle-scale heterogeneity influenced the load-bearing capacity of carnallitite. In the PFC sensitivity analysis, narrowing the prescribed particle-size-distribution range from 0.4–8.0 mm to 4.0–4.0 mm at a mean particle size of 4.0 mm was associated with an increase in simulated strength from 7.82 to 10.40 MPa. Because quantitative contact-network descriptors were not extracted, the corresponding contact-network interpretation is treated as mechanistic rather than direct quantitative evidence. (3) The long-term uniaxial strengths of Groups A and B were estimated as 3.3 MPa and 4.8 MPa, respectively, using the adopted specific-failure-energy method. The modified Burgers model provided a good fit to the creep data within the tested stress levels, yielding coefficients of determination of 0.957 and 0.964 and root-mean-square error (RMSE) values of 0.0803 and 0.0552 percentage points. Based on the long-term strength constraints and the site-specific design assumptions adopted in this study, the calculated inter-room pillar widths were 6 m for Group A and 4 m for Group B. These findings provide insights into the multiscale damage mechanisms and long-term stability assessment of carnallitite stopes in deep potash mines. Full article

This study assessed the effects of groundwater interacting with aggregate produced from steel slag, used as a ballast material in a waterproofing system protecting the road surface under high groundwater table conditions. Field investigations were carried out, with hydrochemical analyses of groundwater and water draining through the structure, mineralogical characterisation of the slag, and geochemical modelling using the PHREEQC programme with inverse modelling. The results showed that water flow through the slag aggregate caused strong alkalisation of the solution and changes in the concentrations of Ca, Mg, Na, Cl, sulphates and carbonate components. Inverse modelling enabled the identification of eight acceptable mass balance models. The main primary phases involved in the transformations were larnite, merwinite, mayenite, halite and, locally, slag glass. Their dissolution contributed Ca, Mg, Al, Si, Na and Cl to the solution. The increases in Na and Cl concentrations were interpreted primarily as the result of an external influx of road salt, rather than as an intrinsic property of the slag. The secondary products were dominated by amorphous silica, calcite, ettringite and brucite, indicating silica removal, carbonation, sulphate fixation and the partial immobilisation of Mg. The results confirm that slag aggregate remains geochemically active in contact with groundwater; however, simultaneous carbonation and secondary mineralisation favour the gradual stabilisation of the water–slag system. Full article

This study presents an integrated multidisciplinary framework for evaluating the reuse of abandoned underground mining infrastructure in Bosnia and Herzegovina as sustainable underground energy storage systems that support the energy transition and decarbonization. The research focuses on the Central Bosnia and Tuzla coal basins, using case studies from the Zenica and Tuzla mining regions to assess Underground Pumped Hydroelectric Energy Storage (UPHES), Compressed Air Energy Storage (CAES), and gravity-based energy storage technologies. The methodology integrates geological and geotechnical characterization, thermo-hydro-mechanical (THM) analysis, thermodynamic calculations, and Multi-Criteria Decision Analysis (MCDA) to evaluate technical, operational, and safety performance. Methane mitigation, smart ventilation, thermal stability, and geomechanical behavior under cyclic loading were also considered. The results indicate that sedimentary coal basins are well suited for UPHES and gravity-based storage systems, with UPHES capacities reaching 1.75 GWh per cycle under optimized conditions, while the separately evaluated solid-mass gravity storage system provides a capacity of 6.15 MWh. Evaporite formations in the Tuzla Basin offer favorable conditions for CAES because of the low permeability and plasticity of halite, enabling storage capacities exceeding several GWh. THM analysis confirmed acceptable geomechanical stability during cyclic operation, while the economic assessment based on the Levelized Cost of Storage (LCOS) demonstrated the long-term competitiveness of Abandoned Mine Energy Storage (AMES) compared with battery technologies. Overall, the findings highlight abandoned mines as strategic low-carbon assets for renewable energy integration and regional post-mining transition. Full article

Inland rivers in arid regions are important water resources that support ecosystem stability and human activities. This study comparatively investigated the hydrochemical characteristics, controlling factors, and irrigation suitability of six glacier-fed inland rivers along the southern margin of the Tarim Basin using hydrochemical analysis, Gibbs and Piper diagrams, ion-ratio analysis, principal component analysis (PCA), and PHREEQC inverse mass-balance modeling. The six rivers exhibited distinct hydrochemical characteristics despite their common origin in the Kunlun Mountains. Carbonate weathering dominated the Bostan and Nur rivers, while the Kaxi River exhibited relatively stable hydrochemical characteristics mainly associated with rock weathering. In contrast, evaporite dissolution and evaporative concentration exerted stronger influences on the Uruksayi and Buzang rivers, which also showed more pronounced longitudinal variations in major ion concentrations. The Keriya River showed an overall transition from silicate-weathering-dominated conditions in the upper reaches toward stronger evaporite dissolution and evaporative concentration downstream. PHREEQC inverse mass-balance modeling suggested that halite dissolution, gypsum dissolution, dolomite dissolution, calcite precipitation, and cation exchange contributed to the hydrochemical evolution of the Keriya River. Several abrupt variations in ion concentrations were observed along the river courses, suggesting that localized processes, including tributary mixing, groundwater inputs, or potential anthropogenic influences, may contribute to these hydrochemical changes. PCA extracted two principal components explaining 86.0% of the total variance. PC1 (70.5%) represented overall ion enrichment and mineralization, whereas PC2 (15.5%) reflected carbonate-related hydrochemical variations. Irrigation suitability assessment showed that all rivers exhibited low sodium hazards, while salinity was the main factor limiting irrigation suitability in the middle and lower reaches of the Keriya River and in the Uruksayi and Buzang rivers. This study improves the understanding of hydrochemical evolution and water quality assessment of arid inland rivers and provides scientific support for sustainable water resource management and oasis ecosystem protection in the southern Tarim Basin. Full article

To elucidate the geochemical features of produced water in coalbed methane (CBM) wells of the Gujiao Block and their indicative significance for production, systematic testing of ion composition and total dissolved solids (TDS) of produced water from ten CBM wells was conducted through five discrete sampling campaigns over an 18-month period. Combined with production performance data, the spatiotemporal evolution patterns, controlling factors, and the response relationship with productivity were analyzed. The results show that the water chemistry type of produced water in the study area is mainly identified as the Na-HCO₃ type. The TDS averages 1716.62 mg/L. The hydrochemical characteristics are primarily controlled by water/rock interactions, with Na⁺ and K⁺ mainly derived from silicate mineral weathering and dissolution, coupled with cation exchange processes. The Na/Cl ratio suggests that halite dissolution contributes to both Na⁺ and Cl⁻, whereas the excess Na⁺ relative to Cl⁻ likely reflects cation exchange or dissolution of Na-bearing silicate minerals. As drainage proceeded, Na⁺ and K⁺ concentrations increased, Ca²⁺ decreased, Cl⁻ increased, and SO₄²⁻ first increased and then decreased. Spatially, TDS increases from north to south, with the central-southern region representing a stagnant groundwater zone. Productivity response analysis reveals that Na⁺, HCO₃⁻, and TDS all show a trend of initially slow increase followed by rapid increase with increasing gas production. A negative trend is observed between gas production and the concentrations of Cl⁻, Ca²⁺, Mg²⁺, and SO₄²⁻. The productivity response index for the Gujiao Block ranges from 3.75 to 42.43, with an average of 17.78. As the productivity response index increases, gas production initially decreases and then increases. The findings clarify the geochemical evolution mechanisms of produced water in the Gujiao Block, providing a scientific basis for productivity evaluation of CBM wells. Full article

Groundwater systems sharing similar major-ion facies may still differ in their hydrochemical organization and mineralization pathways, particularly in structurally complex aquifer settings. This study evaluated multivariate chemometric approaches for investigating two hydrochemically similar groundwater systems (MAJA and MAJA2) examined within the regulatory framework for natural mineral water recognition. The dataset consisted of a 13-month monitoring campaign complemented by an independent multi-year validation dataset. Hydrochemical variables were organized into chemical and process-related blocks, including major ions, physicochemical parameters, D’Amore indices, and mineral saturation indices. SIMCA was applied to evaluate the intra-class hydrochemical structure, and OPLS-DA was used to investigate predictive and orthogonal sources of variability. Model robustness and parameter reproducibility were assessed using jackknife resampling, Leave-One-Month-Out cross-validation, repeated double cross-validation, and permutation testing. SIMCA identified PC1 as the only consistently reproducible latent component across resampling iterations. An exploratory Structural Response Coefficient ($R_j$) was introduced as a model-derived descriptor integrating explained and residual variance within the SIMCA model. OPLS-DA models showed stable class-related latent structures under nested validation conditions. Electrical conductivity, sulphate, potassium, SI_gypsum, SI_halite, and D’Amore index A were the variables most consistently associated with discriminant variability. Stable isotope data indicated a common meteoric origin and similar recharge conditions for both systems. The results illustrate how multivariate chemometric analysis, combined with stability-oriented validation procedures, may aid the interpretation of hydrochemical variability in compositionally similar groundwater systems. Full article

Salt precipitation and pore clogging near CO₂ injection wells can reduce injectivity during geological storage in saline formations; yet, the combined effects of CO₂ phase state, flow rate, and humidity remain insufficiently resolved at the core scale. This study investigated CO₂-induced pore-structure alteration in brine-saturated artificial sandstone containing shale/clay interbeds and carbonate cementation. Eight CO₂ core-flooding experiments were conducted under controlled phase-state, flow-rate, and humidity conditions, and each core was imaged before and after displacement using X-ray CT. Pressure response, apparent flow resistance, CT-derived porosity change, and salt-enriched phase distribution were evaluated. CO₂ flooding caused substantial porosity loss in all tests. In the phase-state series, porosity reductions ranged from 40.75% to 50.21%, with the largest reduction under supercritical CO₂. In the flow-rate series, the largest porosity reduction was 56.52%, whereas the highest apparent flow resistance occurred at the lowest flow rate. The humidity comparison showed the strongest contrast: dry supercritical CO₂ reduced porosity by 46.45%, whereas wet supercritical CO₂ reduced it by only 15.68%. These results indicate that CO₂ humidity strongly controls pore-volume preservation and that humidified CO₂ can mitigate evaporation-driven salt-related injectivity impairment. Full article

Against the background of global carbon reduction initiatives and ongoing energy transition, this study addresses the technical challenges of constructing salt cavern storage facilities in bedded salt formations. Typical bedded salt rocks in Southwest China were taken as the research object, and systematic core sampling and multi-dimensional laboratory tests were conducted to investigate their geomechanical and petrophysical properties. The tests included mechanical experiments such as direct shear, uniaxial and triaxial compression, as well as physical property measurements including permeability, porosity, SEM, XRD, and mercury intrusion porosimetry (MIP). The results show that halite exhibits excellent plasticity and tight sealing performance, interlayers have high compressive strength, and mudstone is characterized by significant brittleness. All lithologies possess low permeability and dense internal structures. For this reason, they are well suited for salt cavern energy storage utilization. Furthermore, the research findings provide key basic data and a solid scientific basis. This study supports the construction of salt cavern gas storage and compressed air energy storage (CAES) plants in bedded salt rock areas. Full article

In recent years, the distribution of potassium salt resources in the Central Asia–Tarim Basin salt lake chain has shown an asymmetric pattern, and exploration efforts in the northwestern Tarim Basin have not seen significant progress. This study focuses on the central Bachu Uplift within the Central Asia–Tarim Basin salt lake chain. The characteristics of subsurface brines and indicators of potash formation are investigated. By examining various potassium exploration indices, such as the potassium–chlorine coefficient and magnesium–chlorine coefficient, along with comprehensive analysis of hydrogen–oxygen, sulfur, and strontium isotopes, this research serves to evaluate the potential for potash formation in the central Bachu Uplift. Analysis shows a brine salinity of 12.69–88.46 g/L and a potassium concentration of 0.07–0.65 g/L. The hydrochemical coefficients indicate a high nNa/nCl value, with low K × 10³/Cl values. All brine samples plot within the halite phase field of the 25 °C Na⁺,K⁺,Mg²⁺//C1⁻-H₂O Quaternary metastable phase diagram, clustering towards the Na-rich end. This indicates that the brine likely originated from halite dissolution. In the Na⁺,K⁺,Mg²⁺//C1⁻,SO₄²⁻-H₂O Quinary metastable phase diagram, the majority of samples project within the mirabilite phase field, trending toward the sylvite field. This suggests that the shallow subsurface brine may still be in the early to middle stages of sylvite deposition. Hydrogen and oxygen isotopes indicate that the brine samples were influenced by water–rock interaction and strong evaporative concentration; strontium isotopes reveal their marine–continental transitional characteristics; and sulfur isotopes suggest that the sulfur in the samples was derived from the weathering of Meso-Cenozoic gypsum in the western Tarim Basin. This integrated evidence implies that the brines in the central Bachu Uplift contain a deep-seated potassium anomaly, with fault zones likely conveying information about deep potash resources. This provides preliminary evidence for potassium exploration in the area and holds significant indicative value for identifying key prospective targets. Full article

The evolution of groundwater in the Puhe River Basin is closely related to the ecological security of the Beijing–Tianjin–Hebei water source conservation zone. Based on 122 groundwater samples, this study systematically investigated the hydrochemical characteristics, evolution mechanisms, and water quality of shallow groundwater using mathematical statistics, Piper diagrams, ionic ratio analysis, and a variable fuzzy pattern recognition model. The results showed that shallow groundwater in the middle and upper reaches is generally weakly alkaline, fresh to hard water, with HCO₃–Ca and HCO₃·SO₄–Ca as the dominant hydrochemical facies. Groundwater hydrochemistry is primarily controlled by rock weathering, and the dissolution of silicate and carbonate rocks is the main source of major ions. Calcite and dolomite are in dynamic equilibrium between dissolution and precipitation, whereas gypsum and halite remain undersaturated. Overall, groundwater quality is generally good; however, anthropogenic activities in cultivated and construction lands have altered local hydrochemical composition and caused water quality deterioration in some areas. These findings improved the understanding of groundwater hydrochemical evolution in typical small watersheds of the northern Hebei hilly region and provided a scientific basis for the sustainable management and protection of groundwater resources in the Beijing–Tianjin–Hebei water source conservation area. Full article

Compressed CO₂ energy storage (CCES) in deep sedimentary basins offers a promising option to integrate carbon management with long-duration energy storage. However, most existing subsurface energy-storage studies focus on salt caverns or generic porous reservoirs, while the potential of evaporite-bounded carbonate reservoirs remains insufficiently explored. This study presents the first application-oriented numerical assessment of CCES in Southern Ontario. It investigates the feasibility of CCES in the Upper Silurian Salina Group beneath offshore Lake Huron, focusing on a porous A-2 carbonate interval vertically confined by B and A-2 halite caprocks. A fully coupled three-dimensional thermo-hydro-mechanical model is developed in COMSOL Multiphysics 6.3 to simulate two-phase (brine-CO₂) Darcy flow, heat transfer, and poroelastic deformation under a realistic Michigan Basin stress, pressure and geothermal regime. After an initial cushion-gas stage at 8 kg/s that establishes a caprock-parallel supercritical CO₂ wedge beneath the B-salt, 24 h injection-production cycles are imposed for two years, followed by a five-month high-resolution window. Three well completion strategies are compared: full-length, upper-only, and split (upper + lower) perforations. Results indicate that in all simulations the CO₂ plume stabilizes as a persistent gas cap beneath the B-salt, far-field pressures remain close to hydrostatic, and reservoir deformations are very small, pointing to a substantial geomechanical safety margin. Among the three completion strategies, the split completion provides the best compromise: it maintains high and relatively stable CO₂ production while avoiding the stronger lower-zone depressurisation seen in the full-length case and the more limited working volume of the upper-only case. These findings suggest that a Salina A-2 carbonate reservoir bounded by B and A-2 salts can accommodate cyclic CCES under realistic basin conditions, and that appropriately designed split completions offer a practical balance between storage utilisation and operational robustness in this setting. Full article

Located in eastern China, the Nanshu area is abundant in groundwater resources with favorable water quality, acting as a critical water supply source for the region. In recent years, the regional groundwater environment has been significantly disturbed by continuous anthropogenic activities, which has aroused widespread concern. In this study, correlation analysis, principal component analysis, hydrochemical methods, the Entropy Weight Water Quality Index, and the Human Health Risk Assessment model were comprehensively applied to systematically investigate groundwater in the Nanshu area. The research objectives are to determine the health risk levels of regional groundwater and provide a scientific basis for the protection and rational utilization of groundwater resources. The results indicate that groundwater in the study area is weakly alkaline freshwater, dominated by the HCO₃-Ca hydrochemical type. With favorable groundwater circulation conditions and weak evaporative concentration effects, it generally exhibits the typical natural hydrogeochemical characteristics of shallow groundwater in the piedmont regions of northern China. The chemical composition of groundwater is mainly controlled by water–rock interactions. The dissolution of silicate minerals, gypsum, halite and sepiolite, together with significant reverse cation exchange, collectively shape the hydrochemical composition, and natural hydrogeological conditions form the basic pattern of regional water quality. The overall potability of groundwater in the study area is moderate. Approximately 30% of the groundwater is unsuitable for direct drinking due to anthropogenic pollution, and agricultural activities and domestic sewage discharge have become key factors causing local water quality degradation. Non-carcinogenic health risks posed by groundwater nitrate vary significantly among different populations. The risk level for infants and young children is much higher than that for adults, posing a substantial health threat to sensitive populations. According to the findings, it is recommended to focus on controlling the groundwater risk sources in the central area, strengthen the dynamic monitoring of water quality in water source zones, and strictly regulate regional development activities, so as to achieve the sustainable utilization of groundwater resources. Full article