Search Results (7,182)

Urban expansion in Europe is accelerating, increasing impermeable surfaces and intensifying climate-related pressures, while reducing the capacity of natural and semi-natural habitats to regulate climate. Despite growing interest in ecosystem service (ES), the assessment of resilience, and thus the stability of ES providers, as well as their integration into spatial planning tools, remain limited. This study develops and tests a comprehensive assessment framework that (i) evaluates the current performance of selected ecosystem functions underpinning key regulating ES important for climate adaptation using a look-up table method; (ii) assesses ecosystem resilience by quantification its preconditions; and (iii) applies spatial prioritization to identify and prioritize climate adaptation measures that enhance ecosystem functions and strengthen resilience. The framework was applied to the cadastral area of Liberec (Czech Republic). Results indicate that areas with the highest urgency for intervention were identified consistently across urban and peri-urban zones. However, proposed measures were more diverse and spatially differentiated in peri-urban and rural areas, whereas a single dominant measure prevailed in urban areas, suggesting higher practical applicability outside densely built environments. The approach supports evidence-based spatial planning and contributes to the implementation of the EU Adaptation Strategy by promoting resilient green infrastructure in urban and peri-urban landscapes. Full article

Hospitals play a central role in promoting health and well-being, yet they are also among the most resource-intensive institutions, contributing significantly to environmental degradation through high energy and water consumption, extensive waste generation, and reliance on single-use materials. This conceptual paper explores how principles of the circular economy and green economy can be integrated into hospital operations through a strategic Corporate Social Responsibility (CSR) framework, reframing sustainability as a strategic management issue rather than a compliance-driven activity. Drawing on environmental economics, sustainability studies, and institutional theory, the paper develops an integrated conceptual model structured around the environmental, social, and economic pillars of sustainability. Within this framework, four interconnected operational domains are identified: waste management and circular practices, energy consumption and renewable integration, sustainable procurement and circular supply chains, and economic and policy incentives. The social dimension explicitly encompasses healthcare staff and patients, addressing issues of workforce well-being, health education, safety, quality of life, and equitable care delivery. This advances theory by positioning strategic CSR as a function of circular and green economy, yielding a new model for hospitals, S-CSR = f(CE, GE). The paper also examines institutional and cultural barriers that constrain sustainability implementation and highlights the role of strategic leadership, governance, and system-wide innovation in overcoming these challenges. While not empirical, the study provides a theoretical foundation to inform future research, policy development, and strategic decision-making aimed at advancing sustainable, low-carbon, and resilient healthcare systems. Full article

Street seating serves as a critical medium for stimulating spatial vitality and holds substantial design value in the refined planning of commercial upgrading and quality enhancement in aging districts. As urban regeneration and the optimization of existing built environments have become dominant paradigms in global urban development, the improvement of street quality—given its role as the primary setting for everyday public life—has increasingly depended on the fine-grained design and precise regulation of micro-scale environmental elements. This study takes Pingdeng Street in Zhengzhou, China, and its 33 seating installations as an empirical case. A multi-level analytical framework—comprising the seating ontology level, the seating space level, and the street environment level—was developed to quantitatively examine the relationships between multi-level spatial elements and street vitality intensity. Through correlation and regression analyses, the study systematically investigated the mechanisms by which seating-related elements at different levels influence street vitality. The results indicate that the Green View Index (GVI) is the core driver of street vitality, with the most significant enhancement observed when GVI ranges between 28% and 35%. The synergistic coupling of multi-level seating elements is essential for maximizing street vitality, while optimization pathways vary across different functional seating types. In design practice, high-comfort seating with backrests is recommended, with seating continuity controlled within 0.63–0.90. Seating spaces should adopt moderately enclosed spatial forms, such as eave-covered areas, and be supplemented with adequate lighting facilities. At the street environment level, a GVI of 28–35% and spatial openness of 9–18% should be maintained. The multi-level analytical framework and quantified indicator thresholds established in this study offer a new perspective on the mechanisms linking seating and street vitality. The findings provide a scientific theoretical basis and offer context-sensitive design guidance for the refined renewal of aging urban districts under comparable conditions. Full article

Rapid urbanization-induced extreme rainstorms severely disrupt social functions. Previous research often focused on “de-densification” strategies, which are difficult to adapt to high-density Sponge City Stormwater Management Units (SMUs) that carry core development functions. This study uses Shenzhen as a case study, utilizing Keep movement big data as a “social sensor” for system function perception and introducing the Socio-Ecological-Technological Systems (SETS) theory to construct a “recovery (RCN)–resistance (MI)” binary assessment framework. Through systematic clustering and hierarchical regression models, the driving mechanisms of blue landscape patterns, topography, road networks, and the built environment on social behavioral resilience are systematically parsed. The results show: (1) Road network morphology dominates resistance, while multi-dimensional elements collaborate for recovery. Resistance (MI) is primarily dominated by macro road network detour resistance (TPD2000, β = 0.956), while recovery depends on the synergistic support of blue space interspersion (Blue_IJI), topography, and micro-circulation road networks. (2) Green infrastructure fails in the model due to efficiency bottlenecks, empirical evidence of weakened regulation caused by green space fragmentation in ultra-high-density environments. (3) Low-density, eco-centric built environments provide dual synergistic gains for resilience. Based on this, a “Bidirectional Socio-Ecological Resilience Needs Pyramid” model is constructed, identifying four governance types such as the “Synergistic Balanced Type”. This study provides a quantitative basis for the transition from administrative control to precise morphological governance in high-density cities. Full article

Irreversible anterior segment blindness with preserved retinal integrity (e.g., dense corneal opacity) remains a major clinical challenge because effective sight-restoring options are limited. Here, we describe an intraocular micro-light-emitting diode (Micro-LED) epiretinal microdisplay intended to deliver patterned optical stimulation to intact photoreceptors by bypassing opaque anterior optics. The prototype was based on a color-capable VGA microdisplay (640 × 480 pixels) and operated at <30 mW under typical conditions. An ultra-thin flexible cable and a copper-mesh–reinforced polydimethylsiloxane (PDMS) encapsulation provided a compact, conformable intraocular package with high pixel density. We evaluated a monochromatic (green) prototype in a single beagle eye $(n=1)$ using a transscleral implantation approach and performed 7 days of postoperative follow-up with slit-lamp examination and multimodal imaging. Patterned stimulation via the implanted display elicited flash-evoked visual evoked potentials (VEPs) with consistent within-session waveform morphology, providing preliminary neurophysiological surrogate evidence of upstream visual pathway activation under the tested conditions in this single-animal pilot. The short-term postoperative course included transient hypotony and anterior segment inflammation, and implant rotation with associated inferior retinal detachment was observed by day 7, highlighting current biomechanical limitations. Beyond anterior segment opacity, the same intraocular optical interface could be explored as a modular light-delivery platform to pair with emerging retinal therapies (e.g., optogenetics), pending chronic safety and functional validation. This pilot large-animal study therefore provides a translationally relevant testbed while delineating key engineering constraints that must be addressed next. Full article

This paper investigates a nonlinear Bitsadze–Samarskii type boundary value problem for an elliptic-hyperbolic operator. First, we establish necessary and sufficient conditions for the unique solvability of the corresponding linear mixed-type problem using the abstract theory of correct restrictions and extensions of operators. Explicit solution formulas are obtained via Green’s function for the elliptic part and integral representations for the hyperbolic part. These results are then extended to a nonlinear mixed operator of power-law type by applying a bijective transformation that reduces the nonlinear problem to the linear case. The key condition for solvability is the continuity and invertibility of a functional coefficient in the boundary condition. Our work provides a systematic framework for handling non-standard boundary conditions in mixed-type problems and highlights the role of operator-theoretic methods in nonlinear settings. Full article

The transition from petrochemical plastics to sustainable biopolymers has created a critical demand for functional materials that do not compromise on performance. Starch and zein, due to their abundance and complementary nature, represent not just a chemical pair, but a techno-economic symbiosis: zein provides the hydrophobic shield, while starch offers the cost-effective structural volume. This review adopts a “Puzzle Theory” framework to synthesize over 80 peer-reviewed studies published between 2014 and 2025, categorizing the literature into established structural knowledge and unresolved functional limitations. Our analysis reveals that while fabrication protocols and molecular synergy are well-defined in approximately 65% of the surveyed literature, critical functional data remain largely absent. Specifically, fewer than 15% of studies investigate hydro-stability in high-humidity environments or bio-interface behavior, creating a disconnect between laboratory success and industrial application. We identify that current research disproportionately prioritizes dry-state morphology over wet-state mechanical integrity. To bridge the gap between academic prototypes and industrial reality, this article moves beyond general recommendations to propose concrete experimental benchmarks, including specific targets for wet mechanical integrity (>1 MPa), regulatory solvent compliance (<50 ppm), and scalable throughput. This article concludes by providing a strategic roadmap to bridge these gaps, arguing that future research must pivot from simple morphological characterization to developing “smart response” mechanisms and “green manufacturing” protocols to ensure commercial viability. Full article

Rising urban temperatures have become a critical constraint to urban ecosystem resilience and livability due to rapid urbanization. This study proposes a novel intra-city zoning scheme, named component morphological blocks (CMBs), which classifies built-up areas into six types characterized by multidimensional urban canopy morphologies. The XGBoost-SHAP model, optimized via Bayesian tuning, was employed to examine the relative contributions of 16 potential driving variables to block-scale land surface temperature (LST). The results show that: (1) LST gradually increases with increasing building density in the warm seasons. The average building height (BH) exhibits a positive correlation with shaded area, thereby reducing LST on the block scale; (2) hotspots are mainly concentrated in function-oriented blocks with hotspot distribution indices of 1.85, 1.96, 1.24, and 1.14, respectively. Coldspots are largely observed in blue–green space in the warm seasons; (3) BH dominates the LST across seasons, while the building-related factors make a prominent impact on LST in warm seasons. The contribution of vegetation canopy density is followed by BH during autumn and winter (12.2%, 10.9%); (4) a distinct transition occurs between summer normalized difference built-up index (NDBI) and fractional vegetation cover around an NDBI of 0.1. In winter, the interaction between 2D and 3D vegetation factors indicates a shift in their relative contributions from negative to positive as they increase. This study demonstrates that CMBs serve as an effective choice for characterizing LST patterns at the block scale, providing insights for sustainable urban development aimed at mitigating the urban heat island effect. Full article

Cities worldwide are turning to green infrastructure (GI) as a potential decentralized pathway to stormwater management, heat abatement, and other climate adaptation and wellbeing benefits. As with environmental governance, public engagement in GI planning—from design to implementation and maintenance—is necessary to incorporate diverse perspectives, better understand the potential impact of environmental policies, and ensure fair and equitable outcomes. However, GI is different from broader environmental governance approaches in that it demands on-the-ground labor and long-term maintenance, which are crucial for ecosystem function. In this paper, we conduct a comprehensive literature review of 46 articles published between 2014 and 2024 to provide a more nuanced understanding of public engagement for GI in municipal settings. Results reveal diverse and innovative approaches to engagement that involve integrating social and environmental data, on-the-ground activities, and working groups. We further highlight four key characteristics of GI engagement: (1) the multifunctionality of GI, (2) the incorporation of public and private land, (3) effects on community-building and sense of place, and (4) environmental and social justice. By embracing the multifunctionality of GI and centering justice, engagement efforts are more likely to recruit diverse community members, maintain long-term engagement, and simultaneously address multiple social and environmental needs. Full article

Natural deep eutectic solvents (NADES) offer sustainable alternatives to conventional solvents for plant extraction, yet their influence on extract composition and bioactivity preservation requires further study. Here, choline chloride-based NADES with lactic acid or propylene glycol were evaluated for ultrasound-assisted extraction (60 °C, 30 min, 1:20 w/v) of polyphenol-rich fractions from Sanguisorba officinalis and Symphytum officinale. Spectrophotometric analysis yielded total phenolic contents of 6.49–9.67 mg GAE g⁻¹ and total flavonoids of 0.08–0.52 mg g⁻¹, with values dependent on the plant matrix and the NADES formulation. Targeted HPLC-MS/MS enabled identification of representative phenolic acids (chlorogenic, caffeic, ferulic, rosmarinic) and flavonoid markers (rutin, quercetin derivatives), showing qualitative differences in the detected marker profiles between solvents and matrices. Functional assays demonstrated pronounced antioxidant-related effects, including DPPH radical scavenging at 0.5–25 µg mL⁻¹ (polyphenols), inhibition of lipid peroxidation in rat erythrocytes at 0.25–1.20 µg mL⁻¹, and modulation of mitochondrial respiration and permeability transition in isolated rat liver mitochondria. Overall, the results indicate that choline chloride-based NADES can be used to obtain polyphenol-rich plant extracts compatible with the applied analytical workflow while preserving redox-active fractions, supporting their utility in green analytical sample preparation. Full article

The green synthesis of nanomaterials has emerged as a sustainable and environmentally friendly approach, gaining significant attention in recent years for its potential in a wide range of multifunctional applications. Among these materials, zinc oxide nanoparticles (ZnO NPs) stand out due to their remarkable versatility and effectiveness in fields such as industry (food, chemistry, and cosmetics), nanomedicine, cancer therapy, drug delivery, optoelectronics, sensors, and environmental remediation. This study focuses on bioinspired strategies for the facile synthesis of ZnO NPs, employing natural polysaccharide gums as mediators. Acting as both reducing and stabilizing agents, natural gums not only facilitate the eco-friendly production of ZnO NPs but also enhance their stability and functionality. Natural gum-mediated green synthesis typically yields stable, spherical ZnO particles, often in the 10–100 nm range. Typical reaction conditions are the use of zinc acetate dihydrate or zinc nitrate (0.01–0.5 M) as precursors, with low gum concentrations of 0.1–1.0% (w/v) in distilled water, alkaline conditions (pH from 8 to 12), often achieved by adding NaOH, which aids in the reduction and capping by the gum, at reaction temperature between 60 °C and 80 °C, under continuous stirring. The dried precipitate is often calcined at 400 °C to 600 °C to remove organic residues and enhance crystallinity. This approach underscores the potential of biopolymer-assisted synthesis in advancing green nanotechnology for sustainable and practical applications. Utilizing environmentally benign materials such as natural gums for the synthesis of ZnO NPs offers significant advantages, including enhanced eco-friendliness and biocompatibility, making them suitable for a wide range of applications without the involvement of toxic reagents. This review provides an in-depth analysis of the synthesis and characterization techniques employed in the eco-friendly production of ZnO NPs using different natural gums from biological sources and its environmental applications (e.g., pollutant removal and increased agriculture sustainability). Full article

As a new class of green functional liquids, deep eutectic solvents (DESs) have attracted increasing attention as alternatives to conventional solvents, such as mineral acids, organic solvents and ionic liquids (ILs), in nuclear chemistry. Owing to their low cost, easy preparation, structural tunability, and adjustable physicochemical properties, DESs provide unique solvation and coordination environments that enable various applications. This review summarizes recent research advances in the application of DESs for the chemical processes of the nuclear fuel cycle. Particular emphasis is focused on dissolution, extraction and separation, electrochemical deposition and redox processes, radionuclide capture, decontamination and detection. This review highlights the fundamental advantages and current limitations of DES-based systems and outlines future trends. Full article

As a novel organic–inorganic hybrid porous crystalline material, metal–organic frameworks (MOFs) are ideal sensitive materials for detecting gases, antibiotics, and ions, owing to their ultra-high specific surface area, tunable pore structures, abundant active sites, and tailorable architectures. This review systematically summarizes the core structural features, preparation methods, and modification strategies of MOFs, elaborates on the adsorption and signal conversion mechanisms in target detection, and highlights typical applications, performance advantages, and practical scenarios of MOF-based sensors, clarifying their structure–activity relationships and performance differences from traditional semiconductor sensors. It further analyzes key challenges, including insufficient stability, poor conductivity, large-scale preparation difficulties, and real-sample interference, as well as industrialization bottlenecks such as batch-to-batch reproducibility, instrument integration, and high costs. Additionally, it supplements cross-field synergistic innovations and industrialization progress, and prospects future directions: function-oriented precise design, multifunctional composite optimization, portable intelligent devices, green large-scale synthesis, and standardization promotion. This review provides a comprehensive reference for advancing MOF-based detection research and applications in environmental monitoring, industrial safety, food safety, and healthcare. Full article

Soil fungi play a pivotal role in maintaining ecosystem functions and regulating plant health. Although plant root traits can significantly impact the abundance and diversity of different fungal groups, the mechanism by which plant root strategies drive the assembly of soil fungal guilds remains limited. Utilizing Root Economics Space theory, this study investigates how four green manures (hairy vetch, rye, radish, and rapeseed) with contrasting root functional strategies (along the ‘fast–slow’ and ‘outsourcing–DIY’ axes) regulate the composition and functional structure of soil fungal communities. Community characteristics of three functional guilds (plant pathogens, saprophytes, and arbuscular mycorrhizal fungi), as well as relationships between these communities and plant root traits, were evaluated using a combination of Illumina high-throughput sequencing, functional annotation, and multivariate statistical analysis. Overall, different root strategies were associated with distinct fungal community patterns, potentially related to differences in root-derived resource inputs and soil properties. The ‘slow’ and ‘DIY’ strategies were associated with lower relative abundance of plant pathogenic fungi and higher relative abundance of saprotrophic fungi, whereas the ‘fast’ and ‘outsourcing’ strategies were associated with higher relative abundance of plant pathogens and AMF. These findings suggest that root functional strategies may help explain variation in fungal guild composition under different green manure species. From a practical perspective, the results provide a basis for selecting green manure species to help manage soil-borne disease risk, regulate beneficial soil microbial communities, and support more sustainable soil management in agricultural production. Full article

The development of new materials that are inherently safe and sustainable has become a critical objective in the context of the green transition. This challenge is especially significant for plastics, which often contain complex mixtures of chemicals that may be released during various stages of their life cycle and that can pose risks to human health and the environment. Within this context, the Safe and Sustainable by Design (SSbD) framework was followed to support the design of an innovative epoxy–vitrimer composite that integrates non-releasable fire-retardant functionalities, aiming to produce safer, sustainable, and recyclable materials suitable for railway applications. A simple methodology was developed to identify release hotspots potentially affecting workers, consumers, and environmental species and organisms. Based on this, experimental simulations were conducted to evaluate the release of materials such as flame retardants, non-intentionally added substances, and microplastics at hotspots and to compare release profiles between a benchmark material and an SSbD alternative. The results demonstrate that the newly developed recyclable and less hazardous composites can also reduce material release under weathering and abrasion conditions. Full article