Search Results (352)

In the article we investigated the effectiveness of a synergistic system designed to reduce the fire hazard of flexible polyurethane (PUR) foams. The examined system consisted of a carbon-based filler graphene (G), carbon nanotubes (CNTs), or expanded graphite (EG) combined with melamine polyphosphate (MPP). The investigated polyurethane foams (PUR) were synthesized at room temperature via a polycondensation reaction between a polyol and an isocyanate, with an OH: NCO molar ratio of 2:1. Both the carbon fillers and melamine polyphosphate were homogeneously dispersed within the polyol component. Thermogravimetric analysis (TGA), cone calorimetry, and microcalorimetry were used to evaluate the influence of the fillers on the thermal stability and flammability of the PUR foams. The toxicity of the gaseous products was assessed using a coupled TG-gas analysis system, while the optical density of the evolved gases was determined using a Smoke Density Chamber (SDC). The obtained results demonstrated that the applied synergistic carbon-phosphorus filler system significantly reduced the fire hazard of the tested PUR foams. In particular, the EG5-MPP system enabled the formation of self-extinguishing materials. Full article

As a critical sealing component in aero-engines, the segmented annular seal is prone to friction and wear during the running-in stage, which seriously impairs its sealing performance and service life. To address this issue, this study takes the three-petal segmented annular seal made of T482 graphite as the research object, adopting a combined method of high-speed ring-block friction and wear tests and thermal–fluid–solid coupling simulation to investigate its friction and wear mechanisms and optimize its structural design. The results show that the segmented annular seal undergoes more severe friction and wear in the low-speed running-in stage; the wear rate increases with the rise in loading force and decreases with the increase in rotational speed, and the variation trend of surface roughness is consistent with that of the friction coefficient. Frictional heat and wear-induced scratches intensify the deformation and leakage of the seal, thereby leading to the risk of seal failure. Optimizing the depth of radial dynamic pressure grooves can significantly improve the opening performance of the seal, while optimizing the width of axial grooves mainly affects the seal leakage. This research provides a theoretical basis for improving the service life and sealing performance of segmented annular seals in aero-engines. Full article

Water pollution poses a pressing global environmental threat, driving an urgent need for efficient, stable, and eco-friendly water treatment techniques. Semiconductor photocatalysis has emerged as a highly promising solution, utilizing solar energy to thoroughly degrade pollutants under mild conditions without secondary pollution. Among numerous photocatalysts, the graphitic carbon nitride (g-C₃N₄)/layered double hydroxides (LDHs) heterostructures represent a kind of high-performance photocatalysts that combine the integrated advantages of both components. These composites exhibit enhanced visible-light absorption, a highly efficient charge separation and transfer, and a significantly increased specific surface area that promotes the enrichment and degradation of pollutants. The synergistic interaction between g-C₃N₄ and LDHs not only mitigates their individual limitations but also creates a superior photocatalytic system with improved adsorption capacity and reaction kinetics. This review systematically summarizes recent advances in g-C₃N₄/LDHs composite photocatalysts for aquatic pollutant removal. It elaborates on the structural synergies, synthesis routes, and optimization strategies, with a particular focus on applications and mechanistic insights into the degradation of various pollutants-including organic dyes, drugs, and phenolics. Finally, the review outlines current challenges and future research directions, such as deepening mechanistic understanding, designing multifunctional systems, and advancing toward scalable implementation, providing a valuable reference for developing next-generation photocatalytic water treatment technologies. Full article

In this study, we present the synthesis and characterization of graphene oxide (GO)-based hydrogels reinforced with hydroxyapatite (HA), titanium dioxide (TiO₂), zinc oxide (ZnO), silicon oxide (SiO₂), silver (Ag), and graphitic carbon nitride (g-C₃N₄). The aim is to develop multifunctional hydrogels with enhanced structural and biological performance and photocatalytic activity, opening the way for applications in regenerative medicine. The structure and composition of the hydrogels were investigated using FTIR and UV–Vis spectroscopy, which highlighted the chemical interactions between GO and the incorporated nanoparticles. The morphology was analyzed through scanning electron microscopy (SEM) and metallographic optical microscopy (MOM), confirming a uniform distribution of the inorganic phases and an internal architecture optimized for stability and bioactivity. Antibacterial activity was evaluated against Gram-positive and Gram-negative strains, both in the absence and presence of photodynamic therapy. The latter was activated by a Woodpecker laser at a 420 nm wavelength. The results showed significant bacterial inhibition, further enhanced by laser exposure, suggesting a synergistic effect between photocatalytic activation and the hydrogel components. Overall, the obtained hydrogels demonstrate robust mechano-structural properties and promising biological activity, supporting their potential for innovative biomedical applications in the tissue regeneration field and for the emerging biofunctional technologies. Full article

The adoption of silicon-graphite composites as anode materials for the next generation of lithium-ion batteries with enhanced specific capacity requires complex technological efforts in order to mitigate the problem of the quick performance fading of electrodes due to the mechanical degradation of materials. The matter is currently being addressed in terms of electrolyte components, polymer binders, materials structure and morphology itself, as well as current collector design, which differ greatly in cost and scalability. The present work describes the efficacy of Cu foil perforation—a simple, low-cost, and easily scalable approach—as a means of Si/C composite anode performance stabilization during extensive charge-discharge cycling. The NMC||Si/C pouch-type full cells demonstrated over 90% of initial capacity retention after 100 charge-discharge cycles in the case of a 250 µm perforated Cu foil used as a current collector, compared to only 60% capacity left in the same conditions for plain Cu foil as an anode. The obtained result is related to the prevention of anode material delamination off the foil surface as a result of silicon expansion and contraction, which is achieved through the formation inter-penetrating metal-composite structure and the presence of “stitches”, connecting and holding both sides of the electrode tightly attached to the current collector. Full article

The structural integrity of nuclear graphite is paramount for the lifespan of High-Temperature Gas-Cooled Reactors. The nuclear graphite components operate under extreme conditions involving high temperature, pressure, and intense neutron irradiation, leading to complex service behavior that is difficult to characterize only by experimental methods. This study employs the finite element method (FEM) to assess component stress and failure risk. The ManUMAT simulation method was first validated against irradiation data for Gilsocarbon graphite from an Advanced Gas-Cooled Reactor and was subsequently applied to stress–strain analysis of the nuclear graphite bricks in the HTR-PM side reflector layer. The 3D micropore structure of nuclear graphite was obtained via X-μCT and reconstructed in Avizo to establish an FEM model based on the actual pore geometry. Simulations of nuclear graphite over a 30 full-power-year service period predicted a significant contraction on the core-side and minimal thermal expansion on the out-side driven by the neutron doses. This research establishes a finite element framework that extends the ManUMAT approach by integrating a realistic pore structure model, thereby providing a foundation for quantifying the microstructural effects on macroscopic performance. Full article

Ductile iron—also known as spheroidal graphite iron (SGI)—is a versatile material that exhibits a wide range of applications. In addition to the matrix structure itself, graphite morphology and material defects, such as graphite degenerations, also have a decisive influence on its mechanical properties. Missing or incomplete classifications of these deviating graphite morphologies in common standards, alongside insufficient knowledge regarding their effects, leads to a more complicated lifetime assessment and often results in rejection of SGI components. Therefore, relevant material parameters were derived from experimental quasi-static and fatigue investigations on SGI materials with different graphite degenerations and correlated with microstructural parameters quantified by an optimized digital image analysis method. While a linear correlation between the amount and mechanical properties was identified for spiky graphite, for chunky graphite, the presence in general can lead to a detrimental reduction in mechanical properties. Full article

A novel hydraulically actuated uniform clamping flange connection mechanism is proposed to address the long-standing challenges in high-pressure natural gas flowmeter calibration, including cumbersome bolt-by-bolt assembly/disassembly, high leakage risk, and severe non-uniform gasket contact pressure associated with conventional multi-bolt flanges. Unlike traditional discrete bolt loading, the proposed mechanism generates a continuous and actively adjustable circumferential clamping force via an integrated hydraulic annular piston, ensuring excellent sealing uniformity and rapid installation within minutes. A high-fidelity transient finite element model of the hydraulic clamping flange assembly is established, incorporating the nonlinear compression/rebound behavior of flexible graphite–stainless steel spiral-wound gaskets and one-way fluid–structure interaction under water hammer loading. Parametric studies reveal that reducing the effective clamping area to below 80% of the original design significantly intensifies stress concentration and compromises sealing integrity, while clamping force below 80% or above 120% of the nominal value leads to leakage or component overstress, respectively. Under steady 10 MPa pressurization, the flange exhibits a maximum stress of 150.57 MPa, a minimum gasket contact stress exceeding 30 MPa, and a rotation angle below 1°, demonstrating robust sealing performance. During a severe water hammer event induced by rapid valve closure, the peak flange stress remains acceptable at 140.41 MPa, while the minimum gasket contact stress stays above the critical sealing threshold (38.051 MPa). However, repeated water hammer cycles increase the risk of long-term gasket fatigue. This study introduces, for the first time, a hydraulic uniform-clamping flange solution that dramatically improves sealing reliability, installation efficiency, and operational safety in high-pressure flowmeter calibration and similar temporary high-integrity piping connections, providing crucial technical guidance for field applications. Full article

This study examines the structural, chemical, and thermal properties of biochars from slow pyrolysis of hardwood (HW), corn cob (CC), and wheat straw (WS) at 400 °C and 700 °C, evaluating their potential in environmental and industrial applications. A combination of spectroscopic, crystallographic, thermal, and microscopic techniques was employed to monitor the degradation of biomass components and the development of the carbonaceous matrix. The results show that pyrolysis temperature has a significant impact on the properties of biochar. Higher temperatures (700 °C) increased the pH (up to 10.3 for WS700), the carbon content (e.g., 89.8% for HW700), the ash content (up to 24.8% for WS700), and the specific surface area (e.g., 306.87 m²/g for CC700) while decreasing polar functional groups and volatile matter (as confirmed by FTIR). SEM showed enhanced porosity at 700 °C, which was supported by BET analysis. XRD and Raman showed increased graphitization and structural order with temperature, especially for HW and CC biochars, while WS biochars retained mineral components like SiO₂ and CaCO₃. TGA analysis showed improved thermal stability at 700 °C only for biochar derived from wheat straw, while HW and CC biochars showed similar total mass loss regardless of pyrolysis temperature. These biochars exhibit high potential for soil remediation (high pH), water purification (large surface area), and carbon storage (high aromaticity), with HW700 and CC700 also suitable for high-temperature industrial applications due to their stability. Full article

All-medium metamaterial absorbers (MMAs) have attracted considerable attention for ultra-broadband electromagnetic wave (EMW) absorption. Herein, a lightweight graphene aerogel (GA) was synthesized through a low-temperature, atmospheric-pressure reduction route. Benefiting from its 3D porous network, enriched oxygen-containing functional groups, and improved graphitization, the GA offers diverse intrinsic attenuation pathways and a limited effective absorption bandwidth (EAB) of only 6.46 GHz (11.54–18.00 GHz at 1.95 mm). To clarify its attenuation mechanism, nonlinear least-squares fitting was used to quantitatively separate electrical loss contributions. Compared with graphene, the GA shows markedly superior attenuation capability, making it a more suitable medium for MMA design. Guided by equivalent circuit modeling, a stacked frustum-configured GA-based MMA (GA-MMA) was developed, where structure-induced resonances compensate for the intrinsic absence of magnetic components in the GA, thereby substantially broadening its absorption range. The GA-MMA achieves an EAB of 40.7 GHz (9.1–49.8 GHz, reflection loss < −10 dB) and maintains stable absorption under incident angles up to ± 70°. Radar cross-section simulations further indicate its potential in electromagnetic interference mitigation, human health protection, and defense information security. This work provides a feasible route for constructing ultralight and broadband MMAs by coupling electrical loss with structural effects. Full article

Silicon-graphite anodes offer a practical route to increase the energy density of lithium-ion batteries (LIBs), but their widespread adoption is hampered by cyclic instability due to huge volume changes of silicon during lithiation/delithiation process. Another fallout of LIBs capacity gain is growing safety concerns due to fire risks, associated with the uncontrolled release of chemical energy. Herein, we test a hexakis(fluoroethoxy)phosphazene (HFEPN) as a multifunctional electrolyte additive designed to mitigate both issues. The flammability of HFEPN-containing electrolytes was evaluated using a self-extinguishing time test, while the electrochemical performance was assessed in Si/C composite||NMC pouch cells under a progressively accelerated cycling protocol. It is shown that the additive fully imparts flame-retardant properties to the electrolyte at a 15 wt% loading. Despite forming a more stable solid–electrolyte interphase (SEI) with enhanced interfacial kinetics the additive did not improve the cycling stability of the Si/C-based cells. The cells with 15 wt% HFEPN retained 43% of capacity after 70 cycles, comparable to 46.5% for the reference electrolyte. The diffusion limitations imposed by the increased electrolyte viscosity are assumed to offset the interfacial benefits of the additive. Thus, alongside the improved synthetic route, this study demonstrates that while HFEPN functions as an effective flame retardant and SEI modifier, its practical benefits for silicon anodes are limited at high concentrations by detrimental effects on electrolyte transport properties and should be improved in future molecular design efforts. Full article

The injection compression molding using dynamic mold control (ICM-DT) represents a promising technological approach to the manufacturing of highly filled, modified thermoplastic components with tight geometric tolerances. While the numerical prediction of flow states is, to date, predominantly based on the Cross–WLF modeling of viscoelastic characteristics of the melt, new material-related developments necessitate the assessment of process- and material-related boundaries. The present paper employs a highly filled graphite–polypropylene system, exhibiting a graphite mass fraction of 80%, for the quantitative comparison of Cross–WLF predictions and experimentally derived flow states. Based on coupled counter pressure-chamber high-pressure capillary rheometry (CPC-HCR) and counterpressurized viscometry (CPV) alongside the ICM-DT of thin-walled specimens, pressure-induced crystallization was identified to induce significant deviations from Cross–WLF predictions. Cross–WLF modeling strongly overestimates the processability of the applied graphite–polypropylene system under both injection molding (IM) and ICM regimes. We therefore observe a predominant influence of pressure-induced crystallization mechanisms in dynamic mold temperature process domains, in which the pressure-induced, crystallization-related exponential viscosity increase cannot be adequately modeled through both pressure-dependent and pressure-agnostic Cross–WLF models. The numerical approximation of flow states under dynamic mold temperature regimes hence necessitates the consideration of solidification-induced, self-intensifying pressure excursions. Full article

This study investigates the influence of quenching and partitioning (Q&P) on the microstructure, hardness, wear resistance, and impact toughness of GG25 gray cast iron, in comparison with as-cast, quenched, quenched-and-tempered, and austempered conditions. Q&P treatment promotes a significant fraction of retained austenite, with carbon enrichment stabilizing the austenite at room temperature. Microstructural analysis reveals a multiphase matrix composed of partitioned martensite, bainitic ferrite and carbon-enriched retained austenite, while the morphology and distribution of graphite flakes remain unchanged. Mechanical testing shows that Q&P enhances impact toughness without substantial loss of hardness, achieving a balance not observed in conventional quenching and tempering treatments. Tribological evaluation indicates that wear resistance is slightly lower than quenched and tempered samples but superior to as-cast iron, with deformation of retained austenite and tribofilm formation influencing wear behavior. These results demonstrate that Q&P represents a promising route for developing gray cast irons with enhanced toughness and maintained hardness, suitable for components subjected to impact and wear loading. Full article

The integration of electrically conductive functionalities into polymer components via additive manufacturing has gained increasing relevance across fields such as sensing, energy storage, and structural electronics. Achieving reliable performance in such applications requires a deeper understanding of how processing conditions affect the internal structure of conductive thermoplastic composites—particularly the orientation and distribution of anisotropic fillers. This study analyzes a PLA-based composite containing carbon nanotubes, carbon black, and graphite flakes to evaluate the influence of extrusion temperature on electrical resistivity and micromechanical properties. To complement scanning electron microscopy, a novel micromechanical mapping approach based on nanoindentation was applied, enabling spatially resolved analysis of local stiffness and hardness. Results show that increasing extrusion temperature improves filler dispersion and alignment, enhancing conductivity and mechanical homogeneity—up to a threshold of 210 °C. Even small temperature changes significantly affect particle orientation and distribution. Unlike global resistivity measurements, the combined use of nanoindentation and microscopic imaging reveals location-specific structural phenomena and filler behavior within the matrix. This newly established method provides high-resolution insight into internal composite architecture and offers a robust foundation for optimizing process-structure-property relationships in conductive polymer systems. Full article

The recovery of critical metals from spent lithium-ion batteries (LIBs) is essential to reduce environmental impacts and promote circular economy strategies. This study developed a sustainable and scalable process for the recovery and complete valorization of lithium, cobalt, and other valuable components from end-of-life LIBs. Hydrometallurgical treatment using biodegradable citric and oxalic acids was employed as a green alternative to conventional inorganic acids, achieving high selectivity and reduced environmental impact. Experimental work was conducted on 3 kg of LIBs from discarded laptop batteries (Dell and HP). After safe discharge and dismantling, the cathode materials were thermally treated at 300 °C to detach active components, followed by acid leaching in 1 M citric acid at 30 °C, pH 2.5, and 6 h of reaction. Lithium and cobalt were recovered as oxalates with efficiencies of 90% and 85%, respectively, while copper, aluminum, and graphite were separated through mechanical and thermal processes. Beyond metal recovery, the process demonstrates a circular upcycling approach, transforming recovered materials into functional products such as aluminum keychains, copper jewelry, and graphite-based pencils. This integrated strategy connects hydrometallurgical extraction with material reuse, advancing toward a zero-waste, closed-loop system for sustainable LIB recycling and local resource valorization. Full article