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  • Article
  • Open Access
14 Citations
4,568 Views
15 Pages

Electrochemical Behavior of Reduced Graphene Oxide Supported Germanium Oxide, Germanium Nitride, and Germanium Phosphide as Lithium-Ion Battery Anodes Obtained from Highly Soluble Germanium Oxide

  • Alexey A. Mikhaylov,
  • Alexander G. Medvedev,
  • Dmitry A. Grishanov,
  • Timur M. Fazliev,
  • Vasilii Chernyshev,
  • Elena A. Mel’nik,
  • Tatiana A. Tripol’skaya,
  • Ovadia Lev and
  • Petr V. Prikhodchenko

Germanium and germanium-based compounds are widely used in microelectronics, optics, solar cells, and sensors. Recently, germanium and its oxides, nitrides, and phosphides have been studied as active electrode materials in lithium- and sodium-ion bat...

  • Article
  • Open Access
1 Citations
2,174 Views
12 Pages

Thermodynamic Study on Hydrogen Reduction of Germanium Tetrachloride to Germanium

  • Dingfang Cui,
  • Zhiying Ding,
  • Tongbo Wang,
  • Bin Kou,
  • Fengyang Chen,
  • Yanqing Hou,
  • Bin Yang and
  • Gang Xie

27 February 2024

This study elucidates the thermodynamic reaction mechanism of the GeCl4 hydrogen reduction process for Ge preparation. Five independent reactions in the Ge-Cl-H ternary system were identified, utilizing the phase law, mass conservation principles, an...

  • Review
  • Open Access
3 Citations
3,464 Views
26 Pages

Germanium Single Crystals for Photonics

  • Grigory Kropotov,
  • Vladimir Rogalin and
  • Ivan Kaplunov

9 September 2024

Germanium (Ge) is a system-forming material of IR photonics for the atmospheric transparency window of 8–14 µm. For optics of the 3–5 µm range, more widespread silicon (Si), which has phonon absorption bands in the long-wave r...

  • Article
  • Open Access
22 Citations
3,158 Views
15 Pages

Extraction of Germanium from Low-Grade Germanium-Bearing Lignite by Reductive Volatilization

  • Rengao Yang,
  • Weifeng Song,
  • Shuai Rao,
  • Jinzhang Tao,
  • Dongxing Wang,
  • Hongyang Cao and
  • Zhiqiang Liu

31 July 2023

Germanium (Ge) as an important strategic metal is widely used in many modern-technology fields such as optical fiber and thermal solar cells. In this study, the volatilization behavior of Ge from low-grade germanium-bearing lignite was investigated i...

  • Article
  • Open Access
16 Citations
4,483 Views
13 Pages

The States and Properties of Germanium in Sulfuric Acid Solution

  • Leiting Song,
  • Haokai Di,
  • Ming Liang,
  • Yan Hong,
  • Yiner Zeng,
  • Kun Yang and
  • Libo Zhang

26 April 2023

In recent years, with the development of science and technology, the strategic position of germanium is becoming more and more important, and the global demand for germanium is also increasing. At present, there is no unified description of the exist...

  • Article
  • Open Access
5 Citations
3,465 Views
11 Pages

Inhibiting the Segregation of Germanium in Silver Nanolayers

  • Arkadiusz Ciesielski,
  • Marek Trzcinski and
  • Tomasz Szoplik

1 April 2020

It is generally acknowledged that using germanium as a wetting film for silver nanolayers decreases the surface roughness of the metal. However, germanium atoms also tend to segregate towards the surface of silver films, increasing ohmic losses in th...

  • Article
  • Open Access
1,003 Views
10 Pages

Terahertz Spectroscopy of Germanium with Different Doping Levels

  • Alexey Shakhmin,
  • Victoria Gerasimova,
  • Sergey Musikhin and
  • Grigory Kropotov

30 September 2025

Transmission and reflection spectra of single-crystal germanium plates were experimentally measured in the terahertz spectral range. The optical parameters of germanium were determined at various Sb-doping levels. Saturation of the absorption index w...

  • Review
  • Open Access
16 Citations
6,748 Views
14 Pages

Some Recent Advances in Germanium Recovery from Various Resources

  • Francisco Jose Alguacil and
  • Jose Ignacio Robla

9 May 2024

Though nowadays germanium does not reach the range of popularity of other metals, i.e., rare earth elements, its utility in target industries makes it a strategic metal. Though germanium can be found in a series of raw materials, the principal source...

  • Communication
  • Open Access
12 Citations
1,795 Views
9 Pages

29 August 2024

In this work, the integration of graphene nanoplatelets (GNPs) with amorphous germanium (Ge) substrates is explored. The optical properties were characterized using Variable-Angle Spectroscopic Ellipsometry (VASE). The findings of this study reveal a...

  • Review
  • Open Access
14 Citations
9,677 Views
19 Pages

Germanium is an essential microelement, and its deficiency can result in numerous diseases, particularly oncogenic conditions. Consequently, water-soluble germanium compounds, including inorganic and coordination compounds, have attracted significant...

  • Feature Paper
  • Review
  • Open Access
5 Citations
8,465 Views
19 Pages

Recovery of Lesser-Known Strategic Metals: The Gallium and Germanium Cases

  • Jose Ignacio Robla,
  • Manuel Alonso and
  • Francisco Jose Alguacil

14 November 2024

Being not as popular as other elements, such as cobalt, lithium, and rare earth elements, both gallium and germanium have wide use in target developments/industries, thus making them valuable and strategically critical metals. The principal sources f...

  • Article
  • Open Access
4 Citations
2,901 Views
10 Pages

Thermodynamic Formation Properties of Point Defects in Germanium Crystal

  • Jinping Luo,
  • Chenyang Zhou,
  • Qihang Li and
  • Lijun Liu

6 June 2022

Point defects are crucial in determining the quality of germanium crystals. A quantitative understanding of the thermodynamic formation properties of the point defects is necessary for the subsequent control of the defect formation during crystal gro...

  • Article
  • Open Access
8 Citations
2,999 Views
20 Pages

18 October 2021

Among the several experiments and techniques conceived of to search for neutrinoless double β decay (0ν2β) in a handful of isotopes, presently the best lower limit on the half-life for this rare process, is provided by those using 76Ge, a rare isotop...

  • Review
  • Open Access
3 Citations
1,759 Views
16 Pages

22 July 2025

Interest in germanium electronic devices is experiencing a comeback thanks to their suitability for a wide range of new applications, like CMOS transistors, quantum technology or infrared photonics. Among these applications, Ge-based thermophotovolta...

  • Article
  • Open Access
8 Citations
3,700 Views
13 Pages

Solvent Extraction of Gallium and Germanium Using a Novel Hydroxamic Acid Extractant

  • Zong Guo,
  • Zhixing Qin,
  • Sanping Liu,
  • Wei Zhang,
  • Chaozhen Zheng and
  • Haibei Wang

12 November 2024

The rare metals gallium and germanium are key strategic metals that are widely used in emerging industries. In this work, a novel hydroxamic acid extractant, BGYW, with low toxicity, was used for the selective solvent extraction of Ga ions and Ge ion...

  • Article
  • Open Access
10 Citations
2,659 Views
13 Pages

Alpha-Germanium Nanolayers for High-Performance Li-ion Batteries

  • Laura Sierra,
  • Carlos Gibaja,
  • Iñigo Torres,
  • Elena Salagre,
  • Juan Ramón Avilés Moreno,
  • Enrique G. Michel,
  • Pilar Ocón and
  • Félix Zamora

26 October 2022

The exfoliation of tridimensional crystal structures has recently been considered a new source of bidimensional materials. The new approach offers the possibility of dramatically enlarging the library of bidimensional materials, but the number of nan...

  • Article
  • Open Access
1 Citations
1,034 Views
23 Pages

27 December 2024

After the deposition process, the lattice structure of doped germanium remains low. Post-processing annealing reorders the structure and increases the output parameters. Thin films of germanium doped with gold (Ge:Au) and vanadium (Ge:V) were magnetr...

  • Article
  • Open Access
18 Citations
4,054 Views
10 Pages

Effects of Temperature on the Morphology and Optical Properties of Spark Discharge Germanium Nanoparticles

  • Anna Lizunova,
  • Anastasia Mazharenko,
  • Bulat Masnaviev,
  • Egor Khramov,
  • Alexey Efimov,
  • Andrei Ramanenka,
  • Ivan Shuklov and
  • Viktor Ivanov

5 October 2020

We report the spark discharge synthesis of aerosol germanium nanoparticles followed by sintering in a tube furnace at different temperatures varying from 25 to 800 °C. The size, structure, chemical composition and optical properties were studied....

  • Review
  • Open Access
4 Citations
2,581 Views
23 Pages

Unlocking Germanium Potential: Stabilization Strategies Through Wet Chemical Functionalization

  • Alessia Arrigoni,
  • Benedetta Maria Squeo and
  • Mariacecilia Pasini

23 December 2024

Germanium (Ge) has long been recognized for its superior carrier mobility and narrower band gap compared to silicon, making it a promising candidate in microelectronics and optoelectronics. The recent demonstration of good biocompatibility, combined...

  • Article
  • Open Access
2 Citations
3,859 Views
13 Pages

RHEED Study of the Epitaxial Growth of Silicon and Germanium on Highly Oriented Pyrolytic Graphite

  • Kirill A. Lozovoy,
  • Vladimir V. Dirko,
  • Olzhas I. Kukenov,
  • Arseniy S. Sokolov,
  • Konstantin V. Krukovskii,
  • Mikhail S. Snegerev,
  • Alexey V. Borisov,
  • Yury V. Kistenev and
  • Andrey P. Kokhanenko

10 April 2024

Two-dimensional silicon (silicene) and germanium (germanene) have attracted special attention from researchers in recent years. At the same time, highly oriented pyrolytic graphite (HOPG) and graphene are some of the promising substrates for growing...

  • Article
  • Open Access
30 Citations
5,211 Views
10 Pages

Precipitation of Germanium from Sulphate Solutions Containing Tin and Indium Using Tannic Acid

  • Michał Drzazga,
  • Andrzej Chmielarz,
  • Grzegorz Benke,
  • Katarzyna Leszczyńska-Sejda,
  • Magdalena Knapik,
  • Patrycja Kowalik and
  • Mateusz Ciszewski

7 March 2019

The precipitation of tannin complex of germanium from sulfuric solutions obtained after dross leaching was investigated. The tested solutions contained mainly zinc, germanium, indium, and tin. The influence of temperature, time, amount of added tanni...

  • Article
  • Open Access
6 Citations
3,305 Views
19 Pages

15 March 2022

Nanoindentation and atomistic molecular dynamics simulations of the loading surface of monocrystalline germanium were used to investigate the evolution of the key structure, the force model, the temperature, the potential, and the deformable layer th...

  • Review
  • Open Access
6 Citations
5,191 Views
13 Pages

Seventy-Five Years since the Point-Contact Transistor: Germanium Revisited

  • Efstratia N. Sgourou,
  • Aspassia Daskalopulu,
  • Lefteri H. Tsoukalas,
  • George Stamoulis,
  • Ruslan V. Vovk and
  • Alexander Chroneos

24 November 2022

The advent of the point-contact transistor is one of the most significant technological achievements in human history with a profound impact on human civilization during the past 75 years. Although the first transistor was made of germanium it was so...

  • Article
  • Open Access
2 Citations
1,899 Views
11 Pages

1 November 2023

High-purity germanium detectors, widely employed in fields such as aerospace applications based on radiation detection principles, have garnered attention due to their broad detection range and fast response time. However, these detectors often requi...

  • Feature Paper
  • Review
  • Open Access
55 Citations
8,958 Views
22 Pages

Zintl Phases as Reactive Precursors for Synthesis of Novel Silicon and Germanium-Based Materials

  • Matt Beekman,
  • Susan M. Kauzlarich,
  • Luke Doherty and
  • George S. Nolas

8 April 2019

Recent experimental and theoretical work has demonstrated significant potential to tune the properties of silicon and germanium by adjusting the mesostructure, nanostructure, and/or crystalline structure of these group 14 elements. Despite the promis...

  • Article
  • Open Access
10 Citations
3,026 Views
14 Pages

Optical and Thermal Behavior of Germanium Thin Films under Femtosecond Laser Irradiation

  • Ahmed Abdelmalek,
  • Lebogang Kotsedi,
  • Zeyneb Bedrane,
  • El-Hachemi Amara,
  • Marco Girolami and
  • Malik Maaza

27 October 2022

In this study, we theoretically investigate the response of a germanium thin film under femtosecond pulsed laser irradiation. Electron and lattice temperatures, as well as material-specific optical properties such as dielectric function and reflectiv...

  • Review
  • Open Access
25 Citations
8,233 Views
14 Pages

Diffusion and Dopant Activation in Germanium: Insights from Recent Experimental and Theoretical Results

  • E. N. Sgourou,
  • Y. Panayiotatos,
  • R. V. Vovk,
  • N. Kuganathan and
  • A. Chroneos

15 June 2019

Germanium is an important mainstream material for many nanoelectronic and sensor applications. The understanding of diffusion at an atomic level is important for fundamental and technological reasons. In the present review, we focus on the descriptio...

  • Article
  • Open Access
8 Citations
3,821 Views
13 Pages

17 February 2021

In this paper, we model the electrical properties of germanium nanowires with a particular focus on physical mechanisms of electrical molecular sensing. We use the Tibercad software to solve the drift-diffusion equations in 3D and we validate the mod...

  • Article
  • Open Access
2,009 Views
13 Pages

15 March 2024

This work focused on developing optical coatings for decorative applications that remain transparent in the radiofrequency range. To achieve this, a combination of dielectric material (silicon-aluminum nitride, SiAlNx) and low-electrical-conductivity...

  • Article
  • Open Access
12 Citations
5,152 Views
10 Pages

Recovery of Germanium from Sulphate Solutions Containing Indium and Tin Using Cementation with Zinc Powder

  • Michał Drzazga,
  • Grzegorz Benke,
  • Mateusz Ciszewski,
  • Magdalena Knapik,
  • Adrian Radoń,
  • Sylwia Kozłowicz,
  • Karolina Goc,
  • Patrycja Kowalik and
  • Katarzyna Leszczyńska-Sejda

17 April 2020

Cementation of germanium from sulphate solution obtained after the leaching of GeIn dross using zinc dust was investigated. The composition of the examined solution was 5.15 Ge, 1.52 In, and 5.81 g/dm3 Zn. In order to resemble the solution before det...

  • Review
  • Open Access
7 Citations
8,078 Views
19 Pages

27 November 2019

Various theoretical as well as empirical considerations about how to achieve lasing between the conduction and valence bands in indirect band gap semiconductors (germanium and silicon) are reviewed, starting from the dawn of the laser epoch in the be...

  • Review
  • Open Access
561 Views
38 Pages

Germanium in Carbon Fullerenes: Quantum-Chemical Insights into Substitution, Adsorption, and Encapsulation Phenomena

  • Monika Zielińska-Pisklak,
  • Adrianna Jakubiec,
  • Łukasz Szeleszczuk and
  • Marcin Gackowski

15 December 2025

Germanium (Ge) incorporation profoundly modifies the structural and electronic characteristics of carbon fullerenes, giving rise to a diverse landscape of substitutional, exohedral, and endohedral Ge–fullerene architectures. Although experiment...

  • Article
  • Open Access
13 Citations
7,019 Views
11 Pages

Crystallization of Electrodeposited Germanium Thin Film on Silicon (100)

  • Mastura Shafinaz Zainal Abidin,
  • Ryo Matsumura,
  • Mohammad Anisuzzaman,
  • Jong-Hyeok Park,
  • Shunpei Muta,
  • Mohamad Rusop Mahmood,
  • Taizoh Sadoh and
  • Abdul Manaf Hashim

6 November 2013

We report the crystallization of electrodeposited germanium (Ge) thin films on n-silicon (Si) (100) by rapid melting process. The electrodeposition was carried out in germanium (IV) chloride: propylene glycol (GeCl4:C3H8O2) electrolyte with constant...

  • Article
  • Open Access
5 Citations
2,919 Views
14 Pages

Germanium–Cobalt–Indium Nanostructures as Anodes of Lithium-Ion Batteries for Room- and Low-Temperature Performance

  • Sergey A. Gavrilov,
  • Ilya M. Gavrilin,
  • Irina K. Martynova,
  • Tatiana L. Kulova,
  • Evgeniya V. Kovtushenko,
  • Alexander M. Skundin,
  • Maksim V. Poliakov,
  • Lidiya S. Volkova and
  • Svetlana A. Novikova

30 August 2023

Germanium–cobalt–indium nanostructures were synthesized via cathodic electrodeposition from aqueous complex solutions of Ge (IV) and Co (II) with drop-like indium crystallization centers. This approach features simplicity, avoids heating...

  • Article
  • Open Access
1 Citations
2,615 Views
11 Pages

Vibration Reduction in a Pulse Tube-Cooled High Purity Germanium Detector

  • Hongyan Wei,
  • Yuqiang Xun,
  • Jinghui Cai and
  • Lijuan Wang

10 February 2022

High-purity germanium (HPGe) is a vibration-sensitive, high-resolution detector. It has been found that microphonic noise induced by vibration and electromagnetic interference from EMC causes energy resolution degradation in HPGe detectors. In this p...

  • Review
  • Open Access
478 Views
25 Pages

On-Chip Strained Germanium Lasers: A Review

  • Ronghuan Liu,
  • Weiqi Song and
  • Zi-Wei Zheng

14 March 2026

The 100 GHz-class ultrafast photonic integrated circuit (PIC) positions itself as a promising technology in the post-Moore era, when the bandwidth limit of metallic interconnections constrains current electronic integrated circuits. Nevertheless, the...

  • Article
  • Open Access
14 Citations
4,495 Views
13 Pages

Simulation of Field Assisted Sintering of Silicon Germanium Alloys

  • Anastasiia Tukmakova,
  • Anna Novotelnova,
  • Kseniia Samusevich,
  • Andrey Usenko,
  • Dmitriy Moskovskikh,
  • Alexandr Smirnov,
  • Ekaterina Mirofyanchenko,
  • Toshiyuki Takagi,
  • Hiroyuki Miki and
  • Vladimir Khovaylo

14 February 2019

We report a numerical study of the field assisted sintering of silicon germanium alloys by a finite element method, which takes into account contact resistances, thermal expansion and the thermoelectric effect. The distribution of electrical and ther...

  • Article
  • Open Access
45 Citations
9,037 Views
16 Pages

Characterization of Germanium Speciation in Sphalerite (ZnS) from Central and Eastern Tennessee, USA, by X-ray Absorption Spectroscopy

  • Julien Bonnet,
  • Jean Cauzid,
  • Denis Testemale,
  • Isabelle Kieffer,
  • Olivier Proux,
  • Andreï Lecomte and
  • Laurent Bailly

16 May 2017

X-ray absorption near edge structure (XANES) spectroscopy was used on zoned sphalerites (ZnS) from two world-class Mississippi Valley Type deposits, the Central and Eastern Tennessee Mining district, USA, in order to investigate germanium oxidation s...

  • Article
  • Open Access
4 Citations
3,978 Views
11 Pages

Interlayer Bound Wannier Excitons in Germanium Sulfide

  • Sara Postorino,
  • Jianbo Sun,
  • Saskia Fiedler,
  • Laurent O. Lee Cheong Lem,
  • Maurizia Palummo and
  • Luca Camilli

12 August 2020

We report a cathodoluminescence (CL) study of layered germanium sulfide (GeS) where we observe a sharp emission peak from flakes covered with a thin hexagonal boron nitride film. GeS is a material that has recently attracted considerable interest due...

  • Article
  • Open Access
12 Citations
3,011 Views
14 Pages

The treatment of infective or potentially infectious bone defects is a critical problem in the orthopedic clinic. Since bacterial activity and cytocompatibility are always contrary factors, it is hard to have them both in one material. The developmen...

  • Article
  • Open Access
17 Citations
5,047 Views
11 Pages

3 February 2020

This paper presents a germanium-around-source gate-all-around tunnelling field-effect transistor (GAS GAA TFET). The electrical characteristics of the device were studied and compared with those of silicon gate-all-around and germanium-based-source g...

  • Feature Paper
  • Article
  • Open Access
6 Citations
4,857 Views
15 Pages

18 July 2020

This paper focuses on the principle study and application of a fractional crystallization methodology using a rotating and internally gas cooled crystallizer (so called cooled finger, developed at IME/RWTH Aachen) first applied to the refining of ger...

  • Article
  • Open Access
13 Citations
2,641 Views
12 Pages

2 October 2020

We analyze the efficiency in terms of a thermoelectric system of a one-dimensional Silicon–Germanium alloy. The dependency of thermal conductivity on the stoichiometry is pointed out, and the best fit of the experimental data is determined by a...

  • Review
  • Open Access
10 Citations
4,548 Views
26 Pages

Neutrinoless Double Beta Decay with Germanium Detectors: 1026 yr and Beyond

  • Valerio D’Andrea,
  • Natalia Di Marco,
  • Matthias Bernhard Junker,
  • Matthias Laubenstein,
  • Carla Macolino,
  • Michele Morella,
  • Francesco Salamida and
  • Chiara Vignoli

10 September 2021

In the global landscape of neutrinoless double beta (0νββ) decay search, the use of semiconductor germanium detectors provides many advantages. The excellent energy resolution, the negligible intrinsic radioactive contamination, the possibility of en...

  • Article
  • Open Access
18 Citations
3,645 Views
9 Pages

Effects of MOVPE Growth Conditions on GaN Layers Doped with Germanium

  • Dario Schiavon,
  • Elżbieta Litwin-Staszewska,
  • Rafał Jakieła,
  • Szymon Grzanka and
  • Piotr Perlin

13 January 2021

The effect of growth temperature and precursor flow on the doping level and surface morphology of Ge-doped GaN layers was researched. The results show that germanium is more readily incorporated at low temperature, high growth rate and high V/III rat...

  • Article
  • Open Access
13 Citations
4,474 Views
10 Pages

Refractive Index of Heavily Germanium-Doped Gallium Nitride Measured by Spectral Reflectometry and Ellipsometry

  • Dario Schiavon,
  • Robert Mroczyński,
  • Anna Kafar,
  • Grzegorz Kamler,
  • Iryna Levchenko,
  • Stephen Najda and
  • Piotr Perlin

30 November 2021

Gallium nitride (GaN) doped with germanium at a level of 1020 cm−3 is proposed as a viable material for cladding layers in blue- and green-emitting laser diodes. Spectral reflectometry and ellipsometry are used to provide evidence of a reduced...

  • Communication
  • Open Access
4 Citations
5,633 Views
12 Pages

Research on Germanium Photodetector with Multi-Mode Waveguide Input

  • Longsheng Wu,
  • Dongsheng Lv,
  • Nengyang Zhao,
  • Ruxue Wang and
  • Aimin Wu

In this work, a vertical N-I-P germanium (Ge) photodetector (PD) with a multi-mode waveguide input is presented. The fabricated devices exhibit a low dark current of 10 nA at bias of −1 V, and a high responsivity of exceeding 0.75 A/W over the...

  • Review
  • Open Access
4 Citations
2,298 Views
28 Pages

27 June 2022

In this paper, we review the application of a recent formula for the lattice thermal conductivity to silicon and germanium, which are two of the most commonly used materials in electronic devices, and to graphene, one the most promising new materials...

  • Review
  • Open Access
170 Citations
16,630 Views
39 Pages

19 March 2014

The performance of strained silicon (Si) as the channel material for today’s metal-oxide-semiconductor field-effect transistors may be reaching a plateau. New channel materials with high carrier mobility are being investigated as alternatives and hav...

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