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The geochemistry of the fatty acids in the modern sediments in the Northern South Yellow Sea is still poorly studied, and studies on the geochemistry of the fatty acids in relatively long-core sediment samples are lacking. Thus, the fatty acids in the core sediments in the Northern South Yellow Sea were separated and identified to study their components and distribution characteristics, and the sources of organic matter and the early diagenetic evolution of the fatty acids in the sediments were discussed. The results show that saturated straight-chain fatty acids (methyl ester) have the highest content in the core sediments in the Northern South Yellow Sea, which account for 83.89% of the total fatty acids (methyl ester). nC_16:0 is dominant, accounting for 30.48% of the n-saturated fatty acids (methyl ester). Unsaturated fatty acids (methyl ester) account for 7.59% of the total fatty acids (methyl ester). Binary unsaturated fatty acids (methyl ester) can only be detected in some samples, which are low in content and dominated by C_18:2. Based on the components and distribution of the fatty acids (methyl ester) in the core sediments in the Northern South Yellow Sea, combined with the characteristics of other lipid biomarker compounds, the actual geological background, and previous research results, it is considered that the sources of organic matter in the core sediments are marine–terrestrial mixed materials, with terrestrial materials dominating. The fatty acids’ (methyl ester) CPI, the relative content of short-chain saturated fatty acids (methyl ester), and the unsaturated fatty acids (methyl ester) in the core sediments show non-obvious variation as the burial depth increases, reflecting that the fatty acids in the core sediments are strongly degraded at the early diagenetic stage, and this degradation is controlled by various complicated factors. Full article

There are many controversies over the material sources of the Late Paleozoic strata in the Lower Yangtze region, and there is a lack of consensus on the basin source–sink system, which hinders the reconstruction of Late Paleozoic paleogeography and exploration of energy and mineral resources in the area. This study aimed to clarify the sedimentary provenance and tectonic background of the Upper Permian Longtan Formation in the Chizhou area of southern Anhui Province. The key objectives were to: (i) analyze the geochemical characteristics of sandstones using major, trace, and rare earth elements; (ii) determine the tectonic setting of the sediment source region based on discrimination diagrams; and (iii) integrate geochemical, sedimentological, and paleocurrent data to reconstruct the source-to-sink system. The geochemical data suggest that the sandstone samples exhibit relatively high SiO₂, Fe₂O₃, MgO, and Na₂O content and relatively low TiO₂, Al₂O₃, and K₂O content, consistent with average values of post-Archean Australian shale (PAAS) and the upper continental crust (UCC). The chondrite-normalized rare earth element patterns resemble PAAS, with enrichment in light REEs and depletion in heavy REEs. Tectonic discrimination diagrams indicate a provenance from active continental margins and continental island arcs, with minor input from passive continental margins. Combined with regional tectonic context and paleocurrent measurements, the results suggest that the Longtan Formation sediments primarily originated from the Neoproterozoic Jiangnan orogenic belt and the Cathaysia Block, notably the Wuyi terrane. These research results not only provide new geological data for further clarifying the provenance of Late Paleozoic sedimentary basins in the Lower Yangtze region but also establish the foundation for constructing the Late Paleozoic tectonic paleogeographic pattern in South China. Full article

This paper presents a geomechanical characterization for unwelded volcanic bimrock materials. Bimrocks are geological materials consisting of blocks of rock of different sizes embedded in a finer matrix. Many volcanic deposits and outcrops can be classified as bimrocks, and some of them correspond to unwelded bimrocks, i.e., with the absence of strong bonds between blocks of rock and matrix. The geomechanical characterization proposed is oriented towards bimrocks slopes, their stability and landslide hazard occurrence. It consists of five steps which includes the material description, the volcanic deposit classification, the definition of block size range, the computation of the volumetric block percentage, the geotechnical characterization of the blocks of rock, and the geological and geotechnical analysis of the matrix that surrounds the blocks. The geomechanical characterization proposed is applied to four slopes at the Western Cordillera of Ecuador, where slopes instabilities are common. Results show that the geomechanical characterization sets a reliable framework for geotechnically describing bimrocks materials, explaining the actual stability state of the slopes. It also enables taking appropriate and optimum decisions in the design and management of volcanic slopes, thus contributing to a sustainable approach of landslide mitigation. Full article

The resistivity imaging system is specifically designed for the precise measurement of resistivity distributions within drilled columnar core samples. Its coaxial symmetric configuration enables the non-destructive characterization of electrical properties, with broad applications in oil and gas exploration, reservoir evaluation, and geological research. By integrating a ring return electrode and full-circumference electrode arrays, the system can acquire core-scale resistivity data in conductive media environments. The self-developed imaging software employs advanced processing algorithms—including depth correction, amplitude normalization, and image enhancement—to transform raw resistivity measurements into high-resolution surface imaging maps. Experimental results demonstrate that the system can resolve features such as cracks with a minimum width of 0.5 mm and pores with a minimum inner diameter of 0.4 mm in granite core, providing a novel technical approach for the fine-scale characterization of core materials. Full article

The cement sheath is critical for ensuring the long-term safety and operational efficiency of oil and gas wells. However, complex geological conditions and operational stresses during production can induce cement sheath deterioration and cracking, leading to reduced zonal isolation, diminished hydrocarbon recovery, and elevated operational expenditures. This study investigates the development of a novel microbial self-healing well cement slurry system, employing fly ash as microbial carriers and sustained-release microcapsules encapsulating calcium sources and nutrients. Systematic evaluations were conducted, encompassing microbial viability, cement slurry rheology, fluid loss control, anti-channeling capability, and the mechanical strength, permeability, and microstructural characteristics of set cement stones. Results demonstrated that fly ash outperformed blast furnace slag and nano-silica as a carrier, exhibiting superior microbial loading capacity and viability. Optimal performance was observed with additions of 3% microorganisms and 3% microcapsules to the cement slurry. Microscopic analysis further revealed effective calcium carbonate precipitation within and around micro-pores, indicating a self-healing mechanism. These findings highlight the significant potential of the proposed system to enhance cement sheath integrity through localized self-healing, offering valuable insights for the development of advanced, durable well-cementing materials tailored for challenging downhole environments. Full article

The aim of this study was to improve the efficiency of in situ uranium leaching by developing a specialized methodology for selecting rational parameters for the chemical treatment of production wells. This approach was designed to enhance the filtration properties of ores and extend the uninterrupted operation period of wells, considering the clay content of the productive horizon, the geological characteristics of the ore-bearing layer, and the composition of precipitation-forming materials. The mineralogical characteristics of ore and precipitate samples formed during the in situ leaching of uranium under various mining and geological conditions at a uranium deposit in the Syrdarya depression were identified using an X-ray diffraction analysis. It was established that ores of the Santonian stage are relatively homogeneous and consist mainly of quartz. During well operation, the precipitates formed are predominantly gypsum, which has little impact on the filtration properties of the ore. Ores of the Maastrichtian stage are less homogeneous and mainly composed of quartz and smectite, with minor amounts of potassium feldspar and kaolinite. The leaching of these ores results in the formation of gypsum with quartz impurities, which gradually reduces the filtration properties of the ore. Ores of the Campanian stage are heterogeneous, consisting mainly of quartz with varying proportions of clay minerals and gypsum. The leaching of these ores generates a variety of precipitates that significantly reduce the filtration properties of the productive horizon. Effective compositions and concentrations of decolmatant (clog removal) solutions were selected under laboratory conditions using a specially developed methodology and a TESCAN MIRA scanning electron microscope. Based on a scanning electron microscope analysis of the samples, the effectiveness of a decolmatizing solution based on hydrochloric and hydrofluoric acids (taking into account the concentration of the acids in the solution) was established for the destruction of precipitate formation during the in situ leaching of uranium. Geological blocks were ranked by their clay content to select rational parameters of decolmatant solutions for the efficient enhancement of ore filtration properties and the prevention of precipitation formation. Pilot-scale testing of the selected decolmatant parameters under various mining and geological conditions allowed the optimal chemical treatment parameters to be determined based on the clay content and the composition of precipitates in the productive horizon. An analysis of pilot well trials using the new approach showed an increase in the uninterrupted operational period of wells by 30%–40% under average mineral acid concentrations and by 25%–45% under maximum concentrations with surfactant additives in complex geological settings. As a result, an effective methodology for ranking geological blocks based on their ore clay content and precipitate composition was developed to determine the rational parameters of decolmatant solutions, enabling a maximized filtration performance and an extended well service life. This makes it possible to reduce the operating costs of extraction, control the geotechnological parameters of uranium well mining, and improve the efficiency of the in situ leaching of uranium under complex mining and geological conditions. Additionally, the approach increases the environmental and operational safety during uranium ore leaching intensification. Full article

Tin is an indispensable metal for contemporary society owing to its extensive application. China is a major tin manufacturer and consumer worldwide. Nonetheless, the crucial characteristics of its tin metabolism remain limited. Therefore, a dynamic material flow analysis (MFA) from 2001 to 2022 was performed in this study to trace China’s tin flows and stocks. Findings show that China became a net tin exporter from a life cycle perspective, and annual tin consumption embodied in various final products varied between 49.3 kilo tons (Kt) in 2001 and 161.5 Kt in 2022, with home appliances and electronics being the dominant consumption sectors. A total of 913.3 Kt of tin became in-use stocks. In addition, the imported tin embodied in various final products varied between 13.9 Kt in 2001 and 21.6 Kt in 2022, with machinery being the dominant consumption sector. The exported tin embodied in various final products varied between 12.0 Kt in 2001 and 76.3 Kt in 2022, with machinery being the dominant consumption sector. Finally, this study proposes some suggestions, in view of the Chinese reality, like enhancing tin recycling, promoting tin geological prospecting, optimizing the structure of the tin trade, and promoting regional cooperation, to improve the supply security of tin resources. Full article

Residential and agricultural buildings must prioritize environmental sustainability, employing locally sourced, bio/geologically sustainable materials, and reversible construction methods. Hence, adobe construction and earth-based building methods are experiencing a comeback. This article describes the hygrothermal performances of a real scale agricultural building prototype, in real field conditions, built and designed to be energy-efficient, environmentally friendly, and well-suited for the hot, dry climates typical of the Mediterranean region during summer. The building prototype is a small modular two room construction, one room based on wood (for control purpose) and the other one on raw earth. The experimental set up highlights the passive cooling and humidity regulation potential provided by raw earth and adobe brick technology in agricultural buildings used for fruit and vegetable storage. Such passive cooling alternatives in the Mediterranean climate could reduce the need for energy-intensive and environmentally impactful cold storage rooms. Full article

The great megalithic sites reveal an extended use of their monuments. In Late Prehistory, in Protohistory, and even in historical times, dolmens remained visible references on the landscape and were central for navigating it. The megaliths of Menga, Viera, and Romeral provide quality data to confirm their continued relevance. Our aim here is to understand whether menhirs also played that role, using the area of Tierras de Antequera, which is connected to the sea, as a case study. With that goal in mind, a research project has been initiated through intensive archaeological field surveying, combined with the collection of testimonies from oral tradition and other archaeological tools such as GIS, geophysical prospection, photogrammetry and RTI, for the detection of engravings and paintings on some of the located landmarks. We present in this paper the first geological analyses in the megalithic territory of Antequera to determine the raw material of the menhirs that are studied and the geological outcrops from which they come. Full article

Calcium–magnesium (Ca–Mg) carbonates are among the most widely distributed carbonates in the Earth’s surface environment, and their formation mechanisms are of great significance for revealing geological environmental changes and carbon sequestration processes. In this study, the gas diffusion method was employed with L-glutamic acid, L-glycine, and L-lysine as nucleation templates for carbonate minerals to systematically investigate their regulatory effects on the mineralization of Ca–Mg carbonates. The results demonstrated that L-glycine, with the shortest length, was more conducive to forming aragonite, whereas acidic L-glutamic acid, which contains more carboxyl groups, was more beneficial for the structural stability of aragonite. The morphology of the Ca-Mg carbonate minerals became more diverse and promoted the formation of spherical and massive mineral aggregates under the action of amino acids. Moreover, the amino acids significantly increased the MgCO₃ content in Mg calcite (L-glutamic acid: 10.86% > L-glycine: 7.91% > L-lysine: 6.63%). The acidic L-glutamic acid likely promotes the dehydration and incorporation of Mg²⁺ into the Mg calcite lattice through the preferential adsorption of Mg²⁺ via its side-chain carboxyl groups. This study shows how amino acid functional groups influence Ca–Mg carbonate mineralization and provides insights into biogenic Mg-rich mineral origins and advanced mineral material synthesis. Full article

Hydrotechnical structures reshape sandy coasts by altering hydrodynamics and sediment transport, yet their long-term effects on sediment texture remain underexplored, particularly in the Baltic Sea. This study investigates the spatial and temporal variations in sediment grain size near two ports (Šventoji and Klaipėda) on the sandy Baltic Sea coast, considering the influence of jetties, nourishment, and geological framework. A total of 246 surface sand samples were collected from beach and foredune zones between 1993 and 2018. These samples were analyzed in relation to shoreline changes, hydrodynamic data, and geological context. The results show that sediment texture is most affected within 1–2 km downdrift and up to 4–5 km updrift of port structures. Downdrift areas tend to contain coarser, poorly sorted sediments because of erosion and the exposure of deeper strata, while updrift zones accumulate finer, well-sorted sands via longshore transport. In the long term, the geological framework controls sediment characteristics. In the medium term, introduced material that differs in grain size from natural beach sediments may alter the texture of the sediment, either coarsening or refining it. The latter slowly returns to its natural texture. Short-term changes are driven by storm events. These findings highlight the importance of integrating structural interventions, nourishment practices, and geological understanding for sustainable coastal management. Full article

The alkali–silica reaction (ASR) is an important mechanism of concrete deterioration, whereby reactive silica in aggregate interacts with cement alkalis to form expanding gel, which compromises the structural integrity of the concrete. Although the Republic of Korea has historically been classified as a low-risk region for ASR due to its geological stability, documented examples of concrete damage since the late 1990s have necessitated a rigorous reassessment of local aggregates. This study evaluated the ASR potential of 84 aggregate samples sourced from diverse Korean geological regions using standardized protocols, including ASTM C 1260 for mortar bar expansion and ASTM C 289 for chemical reactivity, supplemented by soundness, acid drainage, and weathering index analyses. The results indicate expansion within the range of 0.1–0.2%, classified as potentially deleterious, for some rock types. In addition to ASR reactivity, isolated high anomalies (e.g., high soundness, acid producing, and weathering) suggest the existence of other durability risks. Consequently, while Korean aggregates predominantly have a low ASR reactivity, the adoption of various validated ASR tests as a routine test and the integration of supplementary cementitious materials are recommended to ensure long-term concrete durability, highlighting the need for sustained monitoring and further investigation into mitigation strategies. Full article

The growing consumption of oil and gas resources and the increasing difficulty of extraction have created major challenges for traditional manufacturing and maintenance, particularly in the timely supply of critical components, customized production, and complex structure fabrication. Additive manufacturing (AM) technology, with its high design freedom, precision, and rapid prototyping, provides new approaches to address these issues. However, systematic reviews of related efforts are scarce. This paper reviews the applications and progress of metal and non-metal AM technologies in oil and gas extraction and gathering engineering, focusing on the just-in-time (JIT) manufacturing of failed components, the manufacturing and repair of specialized equipment and tools for oil and gas extraction and gathering, and artificial core and reservoir geological modeling fabrication. AM applications in this field remain exploratory and face challenges with regard to their standards, supply chains, materials, and processes. Future research should emphasize developing materials and processes for extreme conditions, optimizing process parameters, establishing standards and traceability systems, and integrating AM with digital design and reverse engineering to support efficient, safe, and sustainable industry development. This work aims to provide a reference for advancing AM research and engineering applications in the oil and gas sector. Full article

With the growing impact of environmental challenges, the need for well-planned and effectively executed actions to support progress and sustainable social development has become increasingly evident. Geoparks play a vital role in this endeavor by fostering the development of products that celebrate local heritage and promote its conservation, utilizing the natural and cultural resources unique to each region in sustainable ways. Geoproducts, in particular, aim to enrich cultural identity and elevate the value of the landscape and geodiversity by integrating communities into innovative approaches and technologies, engaging them in commercialization, and ensuring sustainability alongside social inclusion. Within the framework of the Safi Geopark Project, this article delves into the concept of geoproducts, their definitions, and their potential to bolster local identity and social and economic development. Leveraging the abundant geological and cultural resources of Safi province, the study presents both tangible and intangible geoproducts that merge traditional craftsmanship with modern sustainability practices. Notable examples include ammonite-inspired ceramics, educational materials, and eco-friendly cosmetics, each carefully designed to reflect and celebrate the region’s geoheritage. This article underscores the crucial role of community involvement in the creation of geoproducts, highlighting their impact on conservation, education, and the promotion of sustainable tourism. By proposing actionable strategies, this study not only broadens the understanding of geoproducts within geoparks but also reinforces their importance as instruments for regional development, heritage conservation, and sustainable economic growth. Full article

This study presents a comprehensive methodology for the detection and characterization of fractures in geological samples using X-ray computed tomography (CT). By combining convolution-based image processing techniques with advanced neural network-based segmentation, the proposed approach achieves high precision in identifying complex fracture networks. The method was applied to a marly limestone sample from the Maiolica Formation, part of the Umbria–Marche stratigraphic succession (Northern Apennines, Italy), a geological context where fractures often vary in size and contrast and are frequently filled with minerals such as calcite or clays, making their detection challenging. A critical part of the work involved addressing multiple sources of uncertainty that can impact fracture identification and measurement. These included the inherent spatial resolution limit of the CT system (voxel size of 70.69 μm), low contrast between fractures and the surrounding matrix, artifacts introduced by the tomographic reconstruction process (specifically the Radon transform), and noise from both the imaging system and environmental factors. To mitigate these challenges, we employed a series of preprocessing steps such as Gaussian and median filtering to enhance image quality and reduce noise, scanning from multiple angles to improve data redundancy, and intensity normalization to compensate for shading artifacts. The neural network segmentation demonstrated superior capability in distinguishing fractures filled with various materials from the host rock, overcoming the limitations observed in traditional convolution-based methods. Overall, this integrated workflow significantly improves the reliability and accuracy of fracture quantification in CT data, providing a robust and reproducible framework for the analysis of discontinuities in heterogeneous and complex geological materials. Full article