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50 pages, 6488 KiB  
Article
A Bio-Inspired Adaptive Probability IVYPSO Algorithm with Adaptive Strategy for Backpropagation Neural Network Optimization in Predicting High-Performance Concrete Strength
by Kaifan Zhang, Xiangyu Li, Songsong Zhang and Shuo Zhang
Biomimetics 2025, 10(8), 515; https://doi.org/10.3390/biomimetics10080515 (registering DOI) - 6 Aug 2025
Abstract
Accurately predicting the compressive strength of high-performance concrete (HPC) is critical for ensuring structural integrity and promoting sustainable construction practices. However, HPC exhibits highly complex, nonlinear, and multi-factorial interactions among its constituents (such as cement, aggregates, admixtures, and curing conditions), which pose significant [...] Read more.
Accurately predicting the compressive strength of high-performance concrete (HPC) is critical for ensuring structural integrity and promoting sustainable construction practices. However, HPC exhibits highly complex, nonlinear, and multi-factorial interactions among its constituents (such as cement, aggregates, admixtures, and curing conditions), which pose significant challenges to conventional predictive models. Traditional approaches often fail to adequately capture these intricate relationships, resulting in limited prediction accuracy and poor generalization. Moreover, the high dimensionality and noisy nature of HPC mix data increase the risk of model overfitting and convergence to local optima during optimization. To address these challenges, this study proposes a novel bio-inspired hybrid optimization model, AP-IVYPSO-BP, which is specifically designed to handle the nonlinear and complex nature of HPC strength prediction. The model integrates the ivy algorithm (IVYA) with particle swarm optimization (PSO) and incorporates an adaptive probability strategy based on fitness improvement to dynamically balance global exploration and local exploitation. This design effectively mitigates common issues such as premature convergence, slow convergence speed, and weak robustness in traditional metaheuristic algorithms when applied to complex engineering data. The AP-IVYPSO is employed to optimize the weights and biases of a backpropagation neural network (BPNN), thereby enhancing its predictive accuracy and robustness. The model was trained and validated on a dataset comprising 1,030 HPC mix samples. Experimental results show that AP-IVYPSO-BP significantly outperforms traditional BPNN, PSO-BP, GA-BP, and IVY-BP models across multiple evaluation metrics. Specifically, it achieved an R2 of 0.9542, MAE of 3.0404, and RMSE of 3.7991 on the test set, demonstrating its high accuracy and reliability. These results confirm the potential of the proposed bio-inspired model in the prediction and optimization of concrete strength, offering practical value in civil engineering and materials design. Full article
26 pages, 3314 KiB  
Article
Antenna Model with Pattern Optimization Based on Genetic Algorithm for Satellite-Based SAR Mission
by Saray Sánchez-Sevilleja, Marcos García-Rodríguez, José Luis Masa-Campos and Juan Manuel Cuerda-Muñoz
Sensors 2025, 25(15), 4835; https://doi.org/10.3390/s25154835 (registering DOI) - 6 Aug 2025
Abstract
 Synthetic aperture radar (SAR) systems are of paramount importance to remote sensing applications, including Earth observation and environmental monitoring. Accurate calibration of these systems is imperative to ensuring the accuracy and reliability of the acquired data. A central component of the calibration process [...] Read more.
 Synthetic aperture radar (SAR) systems are of paramount importance to remote sensing applications, including Earth observation and environmental monitoring. Accurate calibration of these systems is imperative to ensuring the accuracy and reliability of the acquired data. A central component of the calibration process is the antenna model, which serves as a fundamental reference for characterizing the radiation pattern, gain, and overall performance of SAR systems. The present paper sets out to describe the implementation and validation of a phased-array antenna model for Synthetic Aperture Radar Systems (SARAS) in MATLAB R2024a. The antenna model was developed for utilization in the Spanish Earth observation missions PAZ and PRECURSOR-ECO. The antenna model incorporates a number of functions, which are divided into two primary modules: the first of these is the antenna pattern generation (APG) module, and the second is the antenna excitation generation (AEG) module. The present document focuses on the AEG, the function of which is to generate patterns for all required beams. These patterns are optimized and matched to specific calculated masks using an ad hoc genetic algorithm (GA). In consideration of the aforementioned factors, the AEG module generates a set of complex excitations corresponding to the required beam from different satellite operational beams, based on several radiometrically defined parameters.  Full article
(This article belongs to the Special Issue Recent Advances in Synthetic Aperture Radar (SAR) Remote Sensing)
15 pages, 1258 KiB  
Article
Biochar Affects Greenhouse Gas Emissions from Urban Forestry Waste
by Kumuduni Niroshika Palansooriya, Tamanna Mamun Novera, Dengge Qin, Zhengfeng An and Scott X. Chang
Land 2025, 14(8), 1605; https://doi.org/10.3390/land14081605 (registering DOI) - 6 Aug 2025
Abstract
Urban forests are vital to cities because they provide a range of ecosystem services, including carbon (C) sequestration, air purification, and urban cooling. However, urban forestry also generates significant amounts of organic waste, such as grass clippings, pruned tree branches, and fallen tree [...] Read more.
Urban forests are vital to cities because they provide a range of ecosystem services, including carbon (C) sequestration, air purification, and urban cooling. However, urban forestry also generates significant amounts of organic waste, such as grass clippings, pruned tree branches, and fallen tree leaves and woody debris that can contribute to greenhouse gas (GHG) emissions if not properly managed. In this study, we investigated the effect of wheat straw biochar (produced at 500 °C) on GHG emissions from two types of urban forestry waste: green waste (GW) and yard waste (YW), using a 100-day laboratory incubation experiment. Overall, GW released more CO2 than YW, but biochar addition reduced cumulative CO2 emissions by 9.8% in GW and by 17.6% in YW. However, biochar increased CH4 emissions from GW and reduced the CH4 sink strength of YW. Biochar also had contrasting effects on N2O emissions, increasing them by 94.3% in GW but decreasing them by 61.4% in YW. Consequently, the highest global warming potential was observed in biochar-amended GW (125.3 g CO2-eq kg−1). Our findings emphasize that the effect of biochar on GHG emissions varies with waste type and suggest that selecting appropriate biochar types is critical for mitigating GHG emissions from urban forestry waste. Full article
(This article belongs to the Special Issue Land Use Effects on Carbon Storage and Greenhouse Gas Emissions)
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19 pages, 790 KiB  
Article
How Does the Power Generation Mix Affect the Market Value of US Energy Companies?
by Silvia Bressan
J. Risk Financial Manag. 2025, 18(8), 437; https://doi.org/10.3390/jrfm18080437 (registering DOI) - 6 Aug 2025
Abstract
To remain competitive in the decarbonization process of the economy worldwide, energy companies must preserve their market value to attract new investors and remain resilient throughout the transition to net zero. This article examines the market value of US energy companies during the [...] Read more.
To remain competitive in the decarbonization process of the economy worldwide, energy companies must preserve their market value to attract new investors and remain resilient throughout the transition to net zero. This article examines the market value of US energy companies during the period 2012–2024 in relation to their power generation mix. Panel regression analyses reveal that Tobin’s q and price-to-book ratios increase significantly for solar and wind power, while they experience moderate increases for natural gas power. In contrast, Tobin’s q and price-to-book ratios decline for nuclear and coal power. Furthermore, accounting-based profitability, measured by the return on assets (ROA), does not show significant variation with any type of power generation. The findings suggest that market investors prefer solar, wind, and natural gas power generation, thereby attributing greater value (that is, demanding lower risk compensation) to green companies compared to traditional ones. These insights provide guidance to executives, investors, and policy makers on how the power generation mix can influence strategic decisions in the energy sector. Full article
(This article belongs to the Special Issue Linkage Between Energy and Financial Markets)
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43 pages, 3290 KiB  
Article
Hydroprocessed Ester and Fatty Acids to Jet: Are We Heading in the Right Direction for Sustainable Aviation Fuel Production?
by Mathieu Pominville-Racette, Ralph Overend, Inès Esma Achouri and Nicolas Abatzoglou
Energies 2025, 18(15), 4156; https://doi.org/10.3390/en18154156 (registering DOI) - 5 Aug 2025
Abstract
Hydrotreated ester and fatty acids to jet (HEFA-tJ) is presently the most developed and economically attractive pathway to produce sustainable aviation fuel (SAF). An ongoing systematic study of the critical variables of different pathways to SAF has revealed significantly lower greenhouse gas (GHG) [...] Read more.
Hydrotreated ester and fatty acids to jet (HEFA-tJ) is presently the most developed and economically attractive pathway to produce sustainable aviation fuel (SAF). An ongoing systematic study of the critical variables of different pathways to SAF has revealed significantly lower greenhouse gas (GHG) reduction potential for the HEFA-tJ pathway compared to competing markets using the same resources for road diesel production. Moderate yield variations between air and road pathways lead to several hundred thousand tons less GHG reduction per project, which is generally not evaluated thoroughly in standard environmental assessments. This work demonstrates that, although the HEFA-tJ market seems to have more attractive features than biodiesel/renewable diesel, considerable viability risks might manifest as HEFA-tJ fuel market integration rises. The need for more transparent data and effort in this regard, before envisaging making decisions regarding the volume of HEFA-tJ production, is emphasized. Overall, reducing the carbon intensity of road diesel appears to be less capital-intensive, less risky, and several times more efficient in reducing GHG emissions. Full article
(This article belongs to the Special Issue Sustainable Approaches to Energy and Environment Economics)
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13 pages, 4131 KiB  
Article
MBE Growth of High-Quality HgCdSe for Infrared Detector Applications
by Zekai Zhang, Wenwu Pan, Gilberto A. Umana Membreno, Shuo Ma, Lorenzo Faraone and Wen Lei
Materials 2025, 18(15), 3676; https://doi.org/10.3390/ma18153676 - 5 Aug 2025
Abstract
HgCdSe has recently been proposed as a potential alternative material to HgCdTe for fabricating high-performance infrared detectors. This work presents a study on the growth of high-crystalline-quality HgCdSe materials on GaSb (211)B substrates via molecular beam epitaxy and demonstration of the first prototype [...] Read more.
HgCdSe has recently been proposed as a potential alternative material to HgCdTe for fabricating high-performance infrared detectors. This work presents a study on the growth of high-crystalline-quality HgCdSe materials on GaSb (211)B substrates via molecular beam epitaxy and demonstration of the first prototype HgCdSe-based mid-wave infrared detectors. By optimizing the MBE growth parameters, and especially the thermal cleaning process of the GaSb substrate surface prior to epitaxial growth, high-quality HgCdSe material was achieved with a record XRD full width at half maximum of ~65 arcsec. At a temperature of 77 K, the mid-wave infrared HgCdSe n-type material demonstrated a minority carrier lifetime of ~1.19 µs, background electron concentration of ~2.2 × 1017 cm−3, and electron mobility of ~1.6 × 104 cm2/Vs. The fabricated mid-wave infrared HgCdSe photoconductor presented a cut-off wavelength of 4.2 µm, a peak responsivity of ~40 V/W, and a peak detectivity of ~1.2 × 109 cmHz1/2/W at 77 K. Due to the relatively high background electron concentration, the detector performance is lower than that of state-of-the-art low-doped HgCdTe counterparts. However, these preliminary results indicate the great potential of HgCdSe materials for achieving next-generation IR detectors on large-area substrates with features of lower cost and larger array format size. Full article
(This article belongs to the Section Optical and Photonic Materials)
19 pages, 3116 KiB  
Article
Few-Shot Intelligent Anti-Jamming Access with Fast Convergence: A GAN-Enhanced Deep Reinforcement Learning Approach
by Tianxiao Wang, Yingtao Niu and Zhanyang Zhou
Appl. Sci. 2025, 15(15), 8654; https://doi.org/10.3390/app15158654 (registering DOI) - 5 Aug 2025
Abstract
To address the small-sample training bottleneck and inadequate convergence efficiency of Deep Reinforcement Learning (DRL)-based communication anti-jamming methods in complex electromagnetic environments, this paper proposes a Generative Adversarial Network-enhanced Deep Q-Network (GA-DQN) anti-jamming method. The method constructs a Generative Adversarial Network (GAN) to [...] Read more.
To address the small-sample training bottleneck and inadequate convergence efficiency of Deep Reinforcement Learning (DRL)-based communication anti-jamming methods in complex electromagnetic environments, this paper proposes a Generative Adversarial Network-enhanced Deep Q-Network (GA-DQN) anti-jamming method. The method constructs a Generative Adversarial Network (GAN) to learn the time–frequency distribution characteristics of short-period jamming and to generate high-fidelity mixed samples. Furthermore, it screens qualified samples using the Pearson correlation coefficient to form a sample set, which is input into the DQN network model for pre-training to expand the experience replay buffer, effectively improving the convergence speed and decision accuracy of DQN. Our simulation results show that under periodic jamming, compared with the DQN algorithm, this algorithm significantly reduces the number of interference occurrences in the early communication stage and improves the convergence speed, to a certain extent. Under dynamic jamming and intelligent jamming, the algorithm significantly outperforms the DQN, Proximal Policy Optimization (PPO), and Q-learning (QL) algorithms. Full article
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19 pages, 3110 KiB  
Article
Integrated Environmental–Economic Assessment of Small-Scale Natural Gas Sweetening Processes
by Qing Wen, Xin Chen, Xingrui Peng, Yanhua Qiu, Kunyi Wu, Yu Lin, Ping Liang and Di Xu
Processes 2025, 13(8), 2473; https://doi.org/10.3390/pr13082473 - 5 Aug 2025
Abstract
Effective in situ H2S removal is essential for the utilization of small, remote natural gas wells, where centralized treatment is often unfeasible. This study presents an integrated environmental–economic assessment of two such processes, LO-CAT® and triazine-based absorption, using a scenario-based [...] Read more.
Effective in situ H2S removal is essential for the utilization of small, remote natural gas wells, where centralized treatment is often unfeasible. This study presents an integrated environmental–economic assessment of two such processes, LO-CAT® and triazine-based absorption, using a scenario-based framework. Environmental impacts were assessed via the Waste Reduction Algorithm (WAR), considering both Potential Environmental Impact (PEI) generation and output across eight categories, while economic performance was analyzed based on equipment, chemical, energy, environmental treatment, and labor costs. Results show that the triazine-based process offers superior environmental performance due to lower toxic emissions, whereas LO-CAT® demonstrates better economic viability at higher gas flow rates and H2S concentrations. An integrated assessment combining monetized environmental impacts with economic costs reveals that the triazine-based process becomes competitive only if environmental impacts are priced above specific thresholds. This study contributes a practical evaluation framework and scenario-based dataset that support sustainable process selection for decentralized sour gas treatment applications. Full article
(This article belongs to the Section Chemical Processes and Systems)
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22 pages, 1646 KiB  
Article
Stochastic Optimization Scheduling Method for Mine Electricity–Heat Energy Systems Considering Power-to-Gas and Conditional Value-at-Risk
by Chao Han, Yun Zhu, Xing Zhou and Xuejie Wang
Energies 2025, 18(15), 4146; https://doi.org/10.3390/en18154146 - 5 Aug 2025
Abstract
To fully accommodate renewable and derivative energy sources in mine energy systems under supply and demand uncertainties, this paper proposes an optimized electricity–heat scheduling method for mining areas that incorporates Power-to-Gas (P2G) technology and Conditional Value-at-Risk (CVaR). First, to address uncertainties on both [...] Read more.
To fully accommodate renewable and derivative energy sources in mine energy systems under supply and demand uncertainties, this paper proposes an optimized electricity–heat scheduling method for mining areas that incorporates Power-to-Gas (P2G) technology and Conditional Value-at-Risk (CVaR). First, to address uncertainties on both the supply and demand sides, a P2G unit is introduced, and a Latin hypercube sampling technique based on Cholesky decomposition is employed to generate wind–solar-load sample matrices that capture source–load correlations, which are subsequently used to construct representative scenarios. Second, a stochastic optimization scheduling model is developed for the mine electricity–heat energy system, aiming to minimize the total scheduling cost comprising day-ahead scheduling cost, expected reserve adjustment cost, and CVaR. Finally, a case study on a typical mine electricity–heat energy system is conducted to validate the effectiveness of the proposed method in terms of operational cost reduction and system reliability. The results demonstrate a 1.4% reduction in the total operating cost, achieving a balance between economic efficiency and system security. Full article
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33 pages, 6551 KiB  
Article
Optimization Study of the Electrical Microgrid for a Hybrid PV–Wind–Diesel–Storage System in an Island Environment
by Fahad Maoulida, Kassim Mohamed Aboudou, Rabah Djedjig and Mohammed El Ganaoui
Solar 2025, 5(3), 39; https://doi.org/10.3390/solar5030039 - 4 Aug 2025
Abstract
The Union of the Comoros, located in the Indian Ocean, faces persistent energy challenges due to its geographic isolation, heavy dependence on imported fossil fuels, and underdeveloped electricity infrastructure. This study investigates the techno-economic optimization of a hybrid microgrid designed to supply electricity [...] Read more.
The Union of the Comoros, located in the Indian Ocean, faces persistent energy challenges due to its geographic isolation, heavy dependence on imported fossil fuels, and underdeveloped electricity infrastructure. This study investigates the techno-economic optimization of a hybrid microgrid designed to supply electricity to a rural village in Grande Comore. The proposed system integrates photovoltaic (PV) panels, wind turbines, a diesel generator, and battery storage. Detailed modeling and simulation were conducted using HOMER Energy, accompanied by a sensitivity analysis on solar irradiance, wind speed, and diesel price. The results indicate that the optimal configuration consists solely of PV and battery storage, meeting 100% of the annual electricity demand with a competitive levelized cost of energy (LCOE) of 0.563 USD/kWh and zero greenhouse gas emissions. Solar PV contributes over 99% of the total energy production, while wind and diesel components remain unused under optimal conditions. Furthermore, the system generates a substantial energy surplus of 63.7%, which could be leveraged for community applications such as water pumping, public lighting, or future system expansion. This study highlights the technical viability, economic competitiveness, and environmental sustainability of 100% solar microgrids for non-interconnected island territories. The approach provides a practical and replicable decision-support framework for decentralized energy planning in remote and vulnerable regions. Full article
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17 pages, 1459 KiB  
Article
Assessing Controlled Traffic Farming as a Precision Agriculture Strategy for Minimising N2O Losses
by Bawatharani Raveendrakumaran, Miles Grafton, Paramsothy Jeyakumar, Peter Bishop and Clive Davies
Nitrogen 2025, 6(3), 63; https://doi.org/10.3390/nitrogen6030063 - 4 Aug 2025
Abstract
Intensive vegetable farming emits high nitrous oxide (N2O) due to traffic-induced compaction, highlighting the need for preventing nitrogen (N) losses through better traffic management. This study examined the effects of Controlled Traffic Farming (CTF) and Random Traffic Farming (RTF) on N [...] Read more.
Intensive vegetable farming emits high nitrous oxide (N2O) due to traffic-induced compaction, highlighting the need for preventing nitrogen (N) losses through better traffic management. This study examined the effects of Controlled Traffic Farming (CTF) and Random Traffic Farming (RTF) on N2O emissions using intact soil cores (diameter: 18.7 cm; depth: 25 cm) collected from a vegetable production system in Pukekohe, New Zealand. Soil cores from CTF beds, CTF tramlines, and RTF plots were analysed under fertilised (140 kg N/ha) and unfertilised conditions. N2O fluxes were monitored over 58 days using gas chambers. The fertilised RTF system significantly (p < 0.05) increased N2O emissions (5.4 kg N2O–N/ha) compared to the unfertilised RTF system (1.53 kg N2O–N/ha). The emission from fertilised RTF was 46% higher than the maximum N2O emissions (3.7 kg N2O–N/ha) reported under New Zealand pasture conditions. The fertilised CTF system showed a 31.6% reduction in N2O emissions compared to fertilised RTF and did not differ significantly from unfertilised CTF. In general, CTF has demonstrated some resilience against fertiliser-induced N2O emissions, indicating the need for further investigation into its role as a greenhouse gas mitigation strategy. Full article
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17 pages, 3816 KiB  
Article
Charging Station Siting and Capacity Determination Based on a Generalized Least-Cost Model of Traffic Distribution
by Mingzhao Ma, Feng Wang, Lirong Xiong, Yuhonghao Wang and Wenxin Li
Algorithms 2025, 18(8), 479; https://doi.org/10.3390/a18080479 - 4 Aug 2025
Viewed by 106
Abstract
With the popularization of electric vehicles and the continuous expansion of the electric vehicle market, the construction and management of charging facilities for electric vehicles have become important issues in research and practice. In some remote areas, the charging stations are idle due [...] Read more.
With the popularization of electric vehicles and the continuous expansion of the electric vehicle market, the construction and management of charging facilities for electric vehicles have become important issues in research and practice. In some remote areas, the charging stations are idle due to low traffic flow, resulting in a waste of resources. Areas with high traffic flow may have fewer charging stations, resulting in long queues and road congestion. The purpose of this study is to optimize the location of charging stations and the number of charging piles in the stations based on the distribution of traffic flow, and to construct a bi-level programming model by analyzing the distribution of traffic flow. The upper-level planning model is the user-balanced flow allocation model, which is solved to obtain the optimal traffic flow allocation of the road network, and the output of the upper-level planning model is used as the input of the lower-layer model. The lower-level planning model is a generalized minimum cost model with driving time, charging waiting time, charging time, and the cost of electricity consumed to reach the destination of the trip as objective functions. In this study, an empirical simulation is conducted on the road network of Hefei City, Anhui Province, utilizing three algorithms—GA, GWO, and PSO—for optimization and sensitivity analysis. The optimized results are compared with the existing charging station deployment scheme in the road network to demonstrate the effectiveness of the proposed methodology. Full article
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26 pages, 1085 KiB  
Article
Evaluating Sustainable Battery Recycling Technologies Using a Fuzzy Multi-Criteria Decision-Making Approach
by Chia-Nan Wang, Nhat-Luong Nhieu and Yen-Hui Wang
Batteries 2025, 11(8), 294; https://doi.org/10.3390/batteries11080294 - 4 Aug 2025
Viewed by 128
Abstract
The exponential growth of lithium-ion battery consumption has amplified the urgency of identifying sustainable and economically viable recycling solutions. This study proposes an integrated decision-making framework based on the T-Spherical Fuzzy Einstein Interaction Aggregator DEMATEL-CoCoSo approach to comprehensively evaluate and rank battery recycling [...] Read more.
The exponential growth of lithium-ion battery consumption has amplified the urgency of identifying sustainable and economically viable recycling solutions. This study proposes an integrated decision-making framework based on the T-Spherical Fuzzy Einstein Interaction Aggregator DEMATEL-CoCoSo approach to comprehensively evaluate and rank battery recycling technologies under uncertainty. Ten key evaluation criteria—encompassing environmental, economic, and technological dimensions—were identified through expert consultation and literature synthesis. The T-Spherical Fuzzy DEMATEL method was first applied to analyze the causal interdependencies among criteria and determine their relative weights, revealing that environmental drivers such as energy consumption, greenhouse gas emissions, and waste generation exert the most systemic influence. Subsequently, six recycling alternatives were assessed and ranked using the CoCoSo method enhanced by Einstein-based aggregation, which captured the complex interactions present in the experts’ evaluations and assessments. Results indicate that Direct Recycling is the most favorable option, followed by the Hydrometallurgical and Bioleaching methods, while Pyrometallurgical Recycling ranked lowest due to its high energy demands and environmental burden. The proposed hybrid model effectively handles linguistic uncertainty, expert variability, and interdependent evaluation structures, offering a robust decision-support tool for sustainable technology selection in the circular battery economy. The framework is adaptable to other domains requiring structured expert-based evaluations under fuzzy environments. Full article
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22 pages, 2179 KiB  
Article
Conversion of Oil Palm Kernel Shell Wastes into Active Biocarbons by N2 Pyrolysis and CO2 Activation
by Aik Chong Lua
Clean Technol. 2025, 7(3), 66; https://doi.org/10.3390/cleantechnol7030066 - 4 Aug 2025
Viewed by 149
Abstract
Oil palm kernel shell is an abundant agricultural waste generated by the palm oil industry. To achieve sustainable use of this waste, oil palm kernel shells were converted into valuable resources as active biocarbons. A two-stage preparation method involving N2 pyrolysis, followed [...] Read more.
Oil palm kernel shell is an abundant agricultural waste generated by the palm oil industry. To achieve sustainable use of this waste, oil palm kernel shells were converted into valuable resources as active biocarbons. A two-stage preparation method involving N2 pyrolysis, followed by CO2 activation, was used to produce the active biocarbon. The optimum pyrolysis conditions that produced the largest BET surface area of 519.1 m2/g were a temperature of 600 °C, a hold time of 2 h, a nitrogen flow rate of 150 cm3/min, and a heating rate of 10 °C/min. The optimum activation conditions to prepare the active biocarbon with the largest micropore surface area or the best micropore/BET surface area combination were a temperature of 950 °C, a CO2 flow rate of 300 cm3/min, a heating rate of 10 °C/min, and a hold time of 3 h, yielding BET and micropore surface areas of 1232.3 and 941.0 m2/g, respectively, and consisting of 76.36% of micropores for the experimental optimisation technique adopted here. This study underscores the importance of optimising both the pyrolysis and activation conditions to produce an active biocarbon with a maximum micropore surface area for gaseous adsorption applications, especially to capture CO2 greenhouse gas, to mitigate global warming and climate change. Such a comprehensive and detailed study on the conversion of oil palm kernel shell into active biocarbon is lacking in the open literature. The research results provide a practical blueprint on the process parameters and technical know-how for the industrial production of highly microporous active biocarbons prepared from oil palm kernel shells. Full article
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21 pages, 4289 KiB  
Article
H2 Transport in Sedimentary Basin
by Luisa Nicoletti, Juan Carlos Hidalgo, Dariusz Strąpoć and Isabelle Moretti
Geosciences 2025, 15(8), 298; https://doi.org/10.3390/geosciences15080298 - 3 Aug 2025
Viewed by 143
Abstract
Natural hydrogen is generated by fairly deep processes and/or in low-permeability rocks. In such contexts, fluids circulate mainly through the network of faults and fractures. However, hydrogen flows from these hydrogen-generating layers can reach sedimentary rocks with more typical permeability and porosity, allowing [...] Read more.
Natural hydrogen is generated by fairly deep processes and/or in low-permeability rocks. In such contexts, fluids circulate mainly through the network of faults and fractures. However, hydrogen flows from these hydrogen-generating layers can reach sedimentary rocks with more typical permeability and porosity, allowing H2 flows to spread out rather than be concentrated in fractures. In that case, three different H2 transport modes exist: advection (displacement of water carrying dissolved gas), diffusion, and free gas Darcy flow. Numerical models have been run to compare the efficiency of these different modes and the pathway they imply for the H2 in a sedimentary basin with active aquifers. The results show the key roles of these aquifers but also the competition between free gas flow and the dissolved gas displacement which can go in opposite directions. Even with a conservative hypothesis on the H2 charge, a gaseous phase exists at few kilometers deep as well as free gas accumulation. Gaseous phase displacement could be the faster and diffusion is neglectable. The modeling also allows us to predict where H2 is expected in the soil: in fault zones, eventually above accumulations, and, more likely, due to exsolution, above shallow aquifers. Full article
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