Search Results (1,977)

This review examines current research and development directions in thorium-based nuclear fuel cycles and reactor systems, including innovative and modular reactor concepts being investigated in several nuclear-producing countries. The analysis considers the feasibility of integrating thorium-containing fuels into both existing and emerging reactor technologies. Particular attention is paid to the potential use of thorium-based fuels in pressurized water reactors (PWRs) as transitional platforms that can enable gradual introduction in thorium without requiring immediate deployment of entirely new reactor architectures.This study synthesizes representative quantitative results reported in the recent literature, including neutronic performance metrics, conversion ratio estimates, and fuelbehavior characteristics of mixed Th–U oxide fuels under typical operating conditions. These results are evaluated together with broader system-level considerations, such as fuelcycle closure potential, materials performance, and technology readiness across different reactor classes.A comparative assessment of light water reactors (LWRs), heavy water reactors (HWRs), and molten salt reactors (MSRs) demonstrates that each platform offers distinct advantages and limitations for thorium deployment. While LWR systems provide the most realistic near-term pathway for partial thorium introduction within the existing nuclear infrastructure, HWR and MSR concepts offer more favorable conditions for efficient thorium utilization and potential Th–U fuelcycle closure. These reactor classes are currently being explored within national research and development programs focused on advanced and modular nuclear technologies.By integrating neutronic analysis, materials considerations, fuelcycle strategies, and techno-economic factors, this review provides a system-level perspective on the research and development of innovative thorium reactor concepts and outlines realistic pathways for their gradual implementation in evolving nuclear energy systems. Full article

The decarbonization of international shipping has accelerated interest in ammonia as a zero-carbon marine fuel. However, its acute toxicity poses safety challenges fundamentally different from those associated with LNG. This study presents a structured comparative regulatory analysis of the IGF Code and the IMO Interim Guidelines for Ships Using Ammonia as Fuel through a chapter-by-chapter review of key safety domains. The results show that, despite structural similarities, the two frameworks diverge significantly in their underlying safety logic: LNG regulation is primarily oriented toward flammability and explosion prevention, whereas ammonia regulation adopts a toxicity-driven safety architecture. This shift is reflected in ppm-level gas detection thresholds, ammonia release mitigation systems (ARMS), toxic area and Safe Haven concepts, broader secondary containment measures, and enhanced personnel protection requirements. These findings suggest that ammonia safety cannot be adequately addressed through incremental extensions of LNG-based rules alone. Instead, it requires a dedicated regulatory approach that explicitly incorporates toxic exposure management into ship design and operation. Full article

Wear remains a dominant cause of performance loss and premature failure in mechanical components, motivating the development of environmentally benign surface-engineering solutions. Among thermal spray systems, high-velocity oxy-fuel (HVOF)-sprayed WC-Co coatings are widely applied under severe wear conditions. The development of nanophase coatings offers the potential for enhanced mechanical performance. However, retaining the nanostructure and limiting decarburization during deposition remain key challenges. In this study, nanophase WC-12Co feedstocks with two particle size ranges, together with Al-modified nanophase powders, were used to deposit coatings under optimized HVOF spraying conditions (spray distance 200 mm, reduced O₂/fuel ratio, and high particle velocity) and were benchmarked against a conventional WC-12Co (12 wt.% Co) coating. The coatings were characterized in terms of microstructure and phase constitution (OM, SEM/EDS, XRD) as well as thickness, porosity (0.5–3.6%), adhesion strength (up to 65 MPa), and microhardness (~1040–1210 HV). Tribological behavior was assessed by ASTM G99 pin-on-disk testing and counterbody wear was quantified via geometric volume loss estimations. The use of larger nanophase particles enabled effective nanostructure retention with limited decarburization, whereas reducing particle size intensified decarburization, promoting increased W₂C formation, and markedly reduced coating cohesion, despite lower porosity and higher hardness. Aluminum additions enhanced coating microhardness and suppressed Co₃W₃C formation, indicating improved phase stability with minimal additional decarburization. Although coating wear remained negligible for all systems, Al-containing coatings exhibited increased friction (up to 35%) and significantly higher counterbody wear (up to sevenfold) compared to the Al-free nanophase coating, which was found to correlate with coating microhardness. Overall, the results demonstrate that optimizing nanophase WC-Co coatings requires balancing competing mechanisms between microstructural stability, cohesive integrity, and tribological response, highlighting the critical role of feedstock design in tailoring coating performance. Full article

This study develops an integrated vessel-level framework for assessing logistics performance and operational energy efficiency in container shipping. The novelty of the study lies in the development of a unified analytical approach that explicitly integrates logistics indicators with fuel consumption and emissions within a consistent system boundary, including auxiliary engine operation during both sea passages and port stays. The framework is applied to four medium-sized container vessels (6000–7500 TEU; 20-foot equivalent unit) under normalised operating conditions. The results show that higher capacity utilisation and economies of scale significantly improve both cost and energy performance, while emissions intensity varies by more than twofold across vessels. A deterministic sensitivity analysis is applied to evaluate the influence of key operational parameters. The analysis identifies service speed as the dominant driver, followed by vessel loading rate, while port-related parameters—such as auxiliary engine load and port productivity—have a lower yet still measurable influence, reducing emissions by up to 5% under improved conditions. The main contribution of the study is the development of a practical vessel-level benchmarking tool that captures logistics–energy interactions and supports operational decision-making under current regulatory frameworks, including EU ETS, FuelEU Maritime, and the IMO Carbon Intensity Indicator (CII). Full article

Biodiesel fuel produced through transesterification is mainly used in blends with conventional diesel fuel (D100). The analysis of the combustion process parameters for each specific biodiesel fuel represents the basis for a rational approach to the utilization of available motor fuel quantities. In this study, the differential and cumulative heat release laws during the combustion of D100 and blends of biodiesel fuel made from waste grape seed oil and D100 were analyzed. In addition, the engine efficiency and economy for the cases of using the aforementioned fuels were analyzed. The tests were conducted on a single-cylinder, air-cooled diesel engine with direct fuel injection. The engine testing was conducted for two engine loads; that for which the brake was a mean effective pressure of 4.2 bar, and for the full load, that for the brake was a mean effective pressure of 5.6 bar at engine speeds of 1635 rpm, 1937 rpm, and 2239 rpm. All experimental work was conducted for conventional diesel fuel D100 and for biodiesel diesel blends B7 and B14. The combustion rates of D100, a blend containing 7% of biodiesel by volume (B7), and a blend containing 14% of biodiesel by volume (B14) were examined. However, the higher combustion rate of the B14 blend, particularly during the combustion of the first 50% of the fuel mass per cycle, could have a positive impact on the fuel economy of the working cycle and the brake thermal efficiency (BTE). The maximum heat release rates for D100, B7, and B14 at full load and an engine speed of 2239 rpm are 115.65 J/deg, 148.01 J/deg, and 152.99 J/deg, respectively. At full load and engine speeds of 1635 rpm and 2239 rpm, the brake thermal efficiencies (BTEs) for D100, B7, and B14 were 0.301, 0.285, and 0.296 and 0.281, 0.273, and 0.277, respectively. Under other tests, the highest BTE was observed for the B14 blend. Therefore, from the perspective of brake thermal efficiency (BTE), the most favorable blend for application is B14. Full article

Marine biofouling is a major global concern affecting the marine industry, the environment, and public health. The accumulation of organisms on submerged surfaces causes significant economic losses, including increased fuel consumption, higher pollutant emissions, and accelerated corrosion. Antifouling (AF) coatings with biocides are widely used to prevent this problem. However, many conventional biocides have been banned due to toxicity, creating an urgent need for environmentally friendly alternatives. In previous studies, we synthesized a gallic acid derivative and three flavonoids that showed AF activity against the settlement of mussel larvae (Mytilus galloprovincialis) together with low ecotoxicity. In the present work, to further assess their potential in marine coatings and exploit the advantages of nanocarriers in protecting and prolonging bioactive effects, these compounds were loaded into halloysite nanotubes (HNTs) and incorporated into epoxy coatings. Coatings containing the same AF compounds in free form were also prepared for comparison. HNTs were characterized by scanning electron microscopy (SEM), and compound loading was quantified by thermogravimetric (TG) analysis. The resulting composites were analyzed by SEM and dynamic water contact angle measurements. Laboratory bioassays with M. galloprovincialis larvae showed that coatings containing HNT-loaded synthetic compounds generally reduced larval settlement more effectively than the corresponding coatings containing the same compounds directly dispersed in the epoxy matrix, with values below 20% after both 15 and 40 h of exposure for the best-performing formulation. These findings highlight the novelty of the proposed HNT-based delivery strategy for nature-inspired synthetic antifoulants and support its potential for the development of effective and environmentally safer AF coatings. Full article

Small long-lifetime pressurized water reactors (PWRs) impose higher requirements on the reactivity compensation capacity, power distribution control precision, and long-term burnup adaptability of burnable poisons due to their compact core volume and extended operational lifetime demands. Traditional experience-dependent design of burnable poison combinations struggles to balance multi-objective requirements and easily overlooks the compatibility of different burnable poison combinations, leading to issues such as uneven reactivity release, excessive fluctuations, or insufficient burnup depth in the designed schemes. To address these challenges, this study introduces the reference point-based non-dominated sorting genetic algorithm (NSGA-III) into the optimization design of burnable poison material combinations for small long-lifetime PWRs. Combined with deterministic methods, a multi-objective optimization model is established with core objectives, including controlling initial excess reactivity, reducing reactivity fluctuations, and improving burnup depth. The decision variables include the types of burnable poison materials, their combination ratios, the arrangement of poison-containing fuel plates, and the loading form of the burnable poisons. The calculation results show that the combination of Gd₂O₃ and B₄C exhibits the best comprehensive performance as burnable poisons; the combined application of Er₂O₃, Eu₂O₃, Sm₂O₃, ²³¹Pa, ²⁴¹Am, ²⁴⁰Pu, and ²³⁷Np requires further research in conjunction with core schemes; and Dy₂O₃ is not suitable as a burnable poison combination material. Full article

The sluggish kinetics of the hydrogen oxidation reaction (HOR) in alkaline media remain a primary bottleneck for anion exchange membrane fuel cells (AEMFCs), necessitating catalysts that synergistically optimize the adsorption of hydrogen (*H) and hydroxide (*OH) intermediates. Herein, we construct a well-defined heterointerface between Pd clusters and CeO₂ on nitrogen-doped carbon (Pd-CeO₂/NC) to electronically engineer the active sites. Spectroscopic studies and theoretical calculations collectively reveal that CeO₂ acts as an electron acceptor, drawing electrons from Pd via interfacial Pd-O-Ce bridges. This charge transfer induces a downshift of the Pd d-band center, which optimally tunes the adsorption strength of both *H and *OH at the interface, thereby breaking the scaling relationship that limits HOR activity. The resulting Pd-CeO₂/NC catalyst achieves an exceptional exchange current density of 3.66 mA cm⁻², surpassing that of commercial Pt/C by a factor of two and ranking among the best reported noble metal catalysts. Furthermore, it exhibits outstanding long-term stability and remarkable CO tolerance, retaining high activity in an atmosphere containing 1000 ppm CO. This work underscores the profound efficacy of metal–oxide heterointerface engineering in regulating electronic structures for multi-intermediate optimization, offering a viable design principle for advanced alkaline HOR electrocatalysts. Full article

Though the European Commission has repeatedly stated that the necessary energy transition in Europe should leave “no one behind”, this paper describes a building refurbishment case that has entailed economic hardships for the low-income families involved. The project is located in the area of P. D. Orcasitas in southern Madrid, led by a grassroots neighbours’ movement, comprising one hundred and seven housing blocks, containing more than 2000 dwellings. The main source of funding for the operation consists of subsidies granted by the Madrid City Council; however, Spanish legislation requires the state Agency of Tax Administration to classify these subsidies as capital gains derived from lucrative transfers. Based on the tax data of vulnerable beneficiaries, the conclusion is that the recipients have ended up returning part of the subsidies to the State through their Income Tax Return. In addition, the Spanish Social Security Institute requires the return of social benefits associated with non-contributory retirement pensions and the Minimum Living Income. Apart from tax accounting, regulations are revised to draw conclusions. Unlike most actuations of this kind, in this case the negative effects are obvious. Although intended to alleviate fuel poverty, the initiative has exacerbated vulnerability due to the impact of the imposed penalties on household income. In conclusion, unless preventive measures are implemented, the mandatory refurbishment of inefficient buildings may place an undue burden on vulnerable low-income occupants and hinder the effective implementation of energy-efficiency regulations. Full article

The insufficient octane ratings of commercial fuels limit the efficiency of spark-ignition (SI) engines and worsens emissions due to knock. One alternative approach to mitigate this phenomenon is the Octane-on-Demand (OOD) concept, which adjusts fuel properties onboard the vehicle. Although implementing this advanced technology can contribute to greenhouse-gas (GHG) emission reductions, few studies have examined its impact on combustion characteristics. Accordingly, the objective of this study was to conduct a comprehensive investigation combining fuel characterization and engine testing to evaluate the effectiveness of the OOD strategy in directly suppressing knock in an SI engine, an aspect not previously reported in the literature. The present study was divided into two parts. In the fuel study, optimal conditions for obtaining a candidate fuel—high-octane fractions (HOF)—from gasoline were determined based on chromatographic (GC–MS) analyses. During engine testing, commercial gasoline and blends containing HOF in several proportions were evaluated in a dual-fuel operation under knocking conditions. The maximum amplitude of pressure oscillations (MAPO) was used as the knock indicator. The results demonstrate that temporary fuel enrichment using only gasoline-derived fractions, without additional octane boosters, can effectively suppress knocking combustion. These findings highlight the influence of the OOD concept on the combustion process and provide guidance for optimizing fueling strategy design under knock-limited operation. The study contributes to the growing body of knowledge regarding OOD applications and underscores the need for comprehensive testing under real-world engine operating conditions. Full article

Reducing and managing emissions of mine waters and the minerals dissolved in them, and above all, using these wastes as resources, is an important element of sustainable development in regions undergoing a gradual phase-out of fossil fuel extraction. This article examines selected aspects of mine water management and the mineral substances contained therein, using the Polish hard coal mining industry as a case study, providing valuable insights for both Poland and other mining regions reducing raw material extraction regarding the sustainability of social water demand, mining sector restructuring, and Sustainable Development Goals (SDGs). In Poland, underground hard coal mining remains a significant source of mine water and mineral salt emissions. Mine waters, discharged into the catchments of major rivers (approximately 200 million m³ per year) along with their dissolved mineral compounds (approximately 1.5 million Mg per year), have repeatedly contributed to serious environmental disruptions, e.g., the phenomena of so-called “fish kill”. This study analyzes both the scale of emissions and the economic utilization of mineralized mine waters discharged to the surface by underground hard coal mining in Poland. Key processes and potential causes for the observed increase in environmental burdens are discussed. Furthermore, the paper presents a current statistical assessment of the trends and scale of emission changes, which can serve as a basis for environmental management decision-making amidst the decarbonization of the economy. Utilizing potential water resources and mineral compounds from mine waters for internal use or within circular economy applications can reduce environmental pressure, support compliance with sustainable development policies, and mitigate long-term impacts on post-mining regions. Full article

Accelerated industrial development demands the search for efficient remediation technologies. Microbial fuel cells (MFCs) have the capacity to remediate organic matter-rich effluent by utilizing bacteria as biocatalysts capable of oxidizing organic material while simultaneously producing electricity. In this paper, a novel electrode is prepared through the carbonization of a tailored photopolymer with iron nanoparticles and carbon black (C-iNPCB) and its performance tested as an anode using dual chamber MFCs for the remediation of paper recycling plant effluent. Its efficiency is compared to a graphite rod (GR) and a carbon black-coated 3D-printed structure (3D-CB). The paper effluent containing chemical oxygen demand 5.0 g/L was used as feedstock in the MFCs. The GR anode (0.91 A/m²; 0.32 W/m²) and 3D-CB anode (0.88 A/m²; 0.30 W/m²) both achieved 56% COD removal, while the C-iNPCB-anode (5.71 A/m²; 3.75 W/m²) was the best performing, with over 80% COD removal. The photopolymerized doped anode exhibited superior performance in terms of both organic matter oxidation and conductivity, indicating higher effectiveness of this type of electrode in MFC technology. Full article

Biofouling is an issue of global significance that impairs marine infrastructure, causes increased fuel consumption and greenhouse gas emissions, and threatens biodiversity. Since the year 2000, self-polishing copolymer (SPC) coatings and fouling release coatings (FRCs) dominate the fouling protection coatings market. SPC technology is based on the controlled release of biocides using a mixture of acrylic and natural binders as a delivery system. FRC technology is based on PDMS providing surface properties that resist attachment of fouling organisms. FRCs often contain surface modifying agents, such as free silicone oils, to tune the physicochemical properties of the surface. However, the long-term efficacy of these agents and their migration and distribution in PDMS-based coatings have not been well studied. In this study, we employed time-of-flight secondary ion mass spectrometry (ToF-SIMS) combined with multivariate analysis to examine the distribution of silicone oils as a function of exposure to artificial seawater (ASW). The results show that pure PDMS-based coatings allow uniform distribution of silicone oils with robust behavior upon ASW exposure. In contrast, epoxy–PDMS-based coatings displayed phase separation of the oils, which strongly altered their surface chemistry. Our findings suggest that the modification of mobile oils is critical to the performance of marine antifouling coatings. Furthermore, the presence of other ingredients of commercial coating formulations strongly affected the distribution of mobile oils. This study lays the foundation for future systematic research aimed at developing predictive models to optimize fouling protection coatings for the marine industry. Full article

Pyrolysis of refuse-derived fuel (RDF) is a promising waste-to-energy route, but its use in higher-value applications remains limited by tar carryover, benzene, toluene, ethylbenzene, and xylenes (BTEX), heteroatom-containing compounds, and pollutant accumulation in recirculated scrubber water. This study evaluated operating windows for RDF pyrolysis coupled with direct wet scrubbing and closed-loop water reuse, with the aim of identifying regimes suitable for different end-use tiers. A Taguchi L27 design of experiments (DOE), i.e., an orthogonal array comprising 27 experimental runs, was applied to evaluate the effects of pyrolysis temperature, residence time, scrubber liquid-to-gas ratio, and scrubber-water temperature, while sequential reuse of the same scrubber-water inventory was evaluated at 5, 10, and 15 cycles. Cleaned-gas pollutants were quantified by compound-resolved gas chromatography–mass spectrometry (GC–MS) after solid-phase adsorption (SPA) sampling, while phenolics and polycyclic aromatic hydrocarbons (PAHs) in scrubber water were determined by extraction followed by GC–MS. Feasibility within each end-use tier was defined as simultaneous satisfaction of tier-specific cleaned-gas thresholds (C_tar, C_BTEX, I_N, and I_S) and the corresponding water-loop hazard limit (I_tox), using literature-informed engineering screening criteria. The results showed that stronger scrubbing reduced gas-phase tar and BTEX burdens, whereas extended water reuse caused systematic accumulation of phenolics and PAHs and increased the composite water-loop hazard index. Boiler-grade operation remained feasible across a broad operating range, with 23 of the 27 tested conditions remaining robust, whereas internal combustion engine combined heat and power (ICE-CHP) feasibility was restricted to a narrow robust regime, and no robust microturbine-grade condition was identified. These findings show that operating windows for RDF pyrolysis must be defined jointly by gas cleanliness and water-loop management constraints. Full article

The aim of this study was to comprehensively characterize lavender pellets produced from post-distillation residues and evaluate their multifunctional valorization potential. Physicochemical properties, including moisture, ash, heating value, organic matter, total and organic carbon, macro- and micronutrients, potentially toxic heavy metals, polyphenols, microbiological safety, and nutritive composition, were assessed. The pellets demonstrated an energy content comparable to other agricultural residues, with a higher heating value of 18,900 kJ/kg and a lower heating value of 16,603 kJ/kg. High organic matter (87%) and a slightly acidic pH support soil moisture retention, while favorable macronutrient levels enhance their suitability as a soil amendment. Water-based extractions (infusion and decoction) achieved higher yields (15.60–21.66%) than ethanol (13.04%) and more effectively recovered bioactive polyphenols, particularly rosmarinic and chlorogenic acids. Low moisture and water activity ensured storage stability and minimal microbial growth, which was confirmed by microbiological safety tests. Nutritionally, pellets contained moderate protein (9.38%), high cellulose (33.38%), and low fat (2.18%), with total amino acids of 8.91 g/100 g and 36.7% essential amino acids, along with a favorable fatty acid profile rich in polyunsaturated fractions. Overall, these findings highlight lavender pellets as a sustainable resource for energy, soil improvement, bioactive compound recovery, and complementary animal feed within circular economy frameworks. However, future research should focus on investigating whether residual compounds remain in lavender residues that could exert antifeedant or phytotoxic effects. Additionally, the potential for the sequential valorization of lavender residues should be explored, initially through the extraction of bioactive phenols, followed by pellet production for use as fuel or soil amendments. This approach would enable multiple cascading uses and maximize their contribution to comprehensive circular economy strategies. Full article