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Search Results (1,982)

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Keywords = friction and wear mechanism

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18 pages, 2857 KB  
Article
Synergistic Tribofilm Growth in Ethylene Glycol: A Dual-Additive Approach for Superior Lubrication
by Xiangli Wen, Peng Gong, Ningyi Yuan, Yu Tian, Lvzhou Li and Jianning Ding
Materials 2026, 19(3), 493; https://doi.org/10.3390/ma19030493 - 26 Jan 2026
Abstract
This study provides an original insight into the synergistic mechanism through which TM-104 and Vanlube 672 facilitate the in situ formation of a nanoscale bilayer tribofilm in ethylene glycol-based hydraulic fluid. By optimizing the additive formulation to 0.5 wt.% TM-104 and 2.0 wt.% [...] Read more.
This study provides an original insight into the synergistic mechanism through which TM-104 and Vanlube 672 facilitate the in situ formation of a nanoscale bilayer tribofilm in ethylene glycol-based hydraulic fluid. By optimizing the additive formulation to 0.5 wt.% TM-104 and 2.0 wt.% Vanlube 672, a structurally graded tribofilm was autonomously assembled at the friction interface, comprising a 6 nm-thick PxOy-rich inner layer and a 140 nm-thick amorphous carbon outer layer. This engineered interlayer delivers exceptional tribological enhancements, with a 31% improvement in lubricity, a 71% increase in wear resistance, and a remarkable 577% enhancement in extreme-pressure load capacity. The first discovery was that there were differences in the mechanisms between these two layers: the inner PxOy layer establishes strong chemisorption bonds with the substrate, while the outer carbon layer facilitates energy dissipation through shear-induced graphitization. These findings establish a new paradigm for designing multi-functional lubricant additives and provide a scientific basis for developing high-performance fire-resistant hydraulic fluids operable under extreme conditions. Full article
19 pages, 2597 KB  
Article
Multiscale Synergistic Investigation on the Mechanical and Tribological Performances of Graphene-Reinforced PEEK/PTFE Composites
by Yan Wang, Kaiqi Dong, Henan Tang, Bin Yang and Shijie Wang
Polymers 2026, 18(3), 308; https://doi.org/10.3390/polym18030308 - 23 Jan 2026
Viewed by 95
Abstract
Polytetrafluoroethylene (PTFE) is a self-lubricating material but has poor wear resistance. The wear resistance of the composites was enhanced by the incorporation of polyetheretherketone (PEEK), whereas the friction-reducing performance was compromised, thus resulting in an inherent trade-off between wear resistance and lubricity. Graphene [...] Read more.
Polytetrafluoroethylene (PTFE) is a self-lubricating material but has poor wear resistance. The wear resistance of the composites was enhanced by the incorporation of polyetheretherketone (PEEK), whereas the friction-reducing performance was compromised, thus resulting in an inherent trade-off between wear resistance and lubricity. Graphene nanosheets (GNSs) with high strength and lubricity were introduced as a reinforcement for PEEK/PTFE composites. Composite specimens with varying GNS contents were fabricated and characterized for their mechanical and tribological properties and wear morphologies. Combined with molecular dynamics (MD) simulations, the micro-mechanisms were further elucidated. The optimal GNS content was determined to be 2 wt%, which improved the tensile strength by 10.58% and reduced the wear rate by 17.88% compared to PEEK/PTFE. It achieved the synchronous enhancement of mechanical strength and wear resistance while maintaining desirable friction-reducing performance. MD simulation results demonstrated that the strong interfacial interactions between GNSx and the polymer enabled GNSs to adsorb polymer chains and form a dense rigid network with reduced free volume (FV). The mechanical properties were enhanced by efficient load transfer and the suppression of interfacial delamination enabled by this unique structure; meanwhile, wear resistance was improved due to the mitigation of friction-induced molecular chain scission. Full article
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16 pages, 5622 KB  
Article
Tailoring the Microstructure and Properties of HiPIMS-Deposited DLC-Cr Nanocomposite Films via Chromium Doping
by Jicheng Ding, Wenjian Zhuang, Qingye Wang, Qi Wang, Haijuan Mei, Dongcai Zhao, Xingguang Liu and Jun Zheng
Nanomaterials 2026, 16(2), 150; https://doi.org/10.3390/nano16020150 - 22 Jan 2026
Viewed by 46
Abstract
Chromium-doped diamond-like carbon (DLC-Cr) nanocomposite films were successfully deposited using a high-power impulse magnetron sputtering (HiPIMS) system. The Cr content in the films was controlled by adjusting the Cr target powers. The influence of Cr content on the microstructure, mechanical properties, tribological performance, [...] Read more.
Chromium-doped diamond-like carbon (DLC-Cr) nanocomposite films were successfully deposited using a high-power impulse magnetron sputtering (HiPIMS) system. The Cr content in the films was controlled by adjusting the Cr target powers. The influence of Cr content on the microstructure, mechanical properties, tribological performance, and wettability of the films was systematically investigated. The results show that the Cr content and deposition rate of the films increased with increases in the target power. The surface topography of the films evolved from smooth to rough as the Cr target increased from 10 W to 70 W. At low Cr doping rates, the film mainly exhibited an amorphous structure, whereas the nanocomposite structure was formed at proper Cr doping rates. Raman and XPS analyses revealed that Cr incorporation altered the ID/IG ratio and promoted the formation of Cr-C bonds, leading to a more graphitic and nanocomposite-like structure. The nanoindentation results show that an optimal Cr content enhances both hardness and elastic modulus, while higher Cr concentrations lead to a decline in mechanical strength due to more graphitization and decreasing stress. Tribological tests exhibited a significant reduction in the friction coefficient (0.21) and wear rate (0.63 × 10−14 m3/N·m) at a moderate Cr level. Additionally, the surface wettability evolved toward enhanced hydrophilicity with increasing Cr power, as evidenced by reduced water contact angles and increased surface energy. These findings demonstrate that controlled Cr incorporation effectively tailors the structure, stress state, and surface chemistry of DLC films, offering a tunable pathway to achieving optimal mechanical performance and tribological stability for advanced engineering applications. Full article
(This article belongs to the Section Synthesis, Interfaces and Nanostructures)
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22 pages, 51561 KB  
Article
Effect of V Content on Microstructure and Properties of TiNbZrVx Medium-Entropy Alloy Coatings on TC4 Substrate by Laser Cladding
by Wen Zhang, Ying Wu, Chuan Yang, Yongsheng Zhao, Zhenhong Wang, Jia Yang, Wei Feng, Yang Deng, Junjie Zhang, Qingfeng Xian, Xingcheng Long, Zhirong Liang and Hui Chen
Coatings 2026, 16(1), 141; https://doi.org/10.3390/coatings16010141 - 22 Jan 2026
Viewed by 29
Abstract
In order to improve the wear resistance of titanium alloy and apply it to the high-speed train brake disc, TiNbZrVx (x = 0, 0.2, 0.4, 0.6, 0.8) refractory medium-entropy alloy coatings were prepared on Ti-6Al-4V (TC4) substrate. The effect of V content [...] Read more.
In order to improve the wear resistance of titanium alloy and apply it to the high-speed train brake disc, TiNbZrVx (x = 0, 0.2, 0.4, 0.6, 0.8) refractory medium-entropy alloy coatings were prepared on Ti-6Al-4V (TC4) substrate. The effect of V content on the microstructure, mechanical properties, and friction and wear properties of the coatings was studied. TiNbZrVx coatings achieved good metallurgical bonding with the substrate, forming BCC and B2 phases and AlZr3 intermetallic compound (IMC). From TiNbZr coating to TiNbZrV0.8 coating, V promotes element segregation and new phase formation, which decreased the average grain size from 85.055 μm to 56.515 μm, increased the average hardness from 265.5 HV to 343.4 HV, and reduced the room temperature (RT) wear rate by 97.8%. However, the ductility of the coatings decreased from 15.7% to 5.8% because the grain boundary precipitates changed the dislocation arrangement, and the tensile fracture mode changed from ductile fracture to brittle fracture. Abrasive wear was the main wear mode at RT, and adhesive wear and oxidation wear were the main wear modes at elevated temperature. The COF at elevated temperature was lower than that at RT, because a large number of friction pair components were transferred to the coating surface at high temperature and were repeatedly rolled to form a dense film, which played a certain lubricating role. Full article
(This article belongs to the Section Laser Coatings)
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14 pages, 9051 KB  
Article
The Effect of Laser Surface Hardening on the Microstructural Characteristics and Wear Resistance of 9CrSi Steel
by Zhuldyz Sagdoldina, Daryn Baizhan, Dastan Buitkenov, Gulim Tleubergenova, Aibek Alibekov and Sanzhar Bolatov
Materials 2026, 19(2), 423; https://doi.org/10.3390/ma19020423 - 21 Jan 2026
Viewed by 90
Abstract
This study presents a systematic investigation of laser surface hardening of 9CrSi tool steel with the aim of establishing the relationships between processing parameters, microstructural evolution, and resulting mechanical and tribological properties under the applied laser conditions. The influence of laser power, modulation [...] Read more.
This study presents a systematic investigation of laser surface hardening of 9CrSi tool steel with the aim of establishing the relationships between processing parameters, microstructural evolution, and resulting mechanical and tribological properties under the applied laser conditions. The influence of laser power, modulation frequency, and scanning speed on the hardened layer depth, microstructure, and surface properties was analyzed. Laser treatment produced a martensitic surface layer with varying fractions of retained austenite, while the transition zone consisted of martensite, granular pearlite, and carbide particles. X-ray diffraction identified the presence of α′-Fe, γ-Fe, and Fe3C phases, with peak broadening associated with increased lattice microstrain induced by rapid self-quenching. The surface microhardness increased from approximately 220 HV0.1 in the untreated state to 950–1000 HV0.1 after laser hardening, with hardened layer thicknesses ranging from about 500 to 750 µm depending on the processing regime. Instrumented indentation showed higher elastic modulus values for all hardened conditions. Tribological tests under dry sliding conditions revealed reduced coefficients of friction and more than an order-of-magnitude decrease in wear rate compared with untreated steel. The results provide a parameter–microstructure–performance map for laser-hardened 9CrSi steel, demonstrating how variations in laser processing conditions affect hardened layer characteristics and functional performance. Full article
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23 pages, 136328 KB  
Article
Mechanical Wear and Friction Behavior of 30CrMnSiNi2A Steel Rocket Sled Sliders Under High-Speed and Heavy-Load Conditions: A Finite Element Analysis
by Ye Hao, Naiming Lin, Lin Wu, Kai Yan, Weihua Wang, Yuan Yu, Qing Zhou, Zhiqi Liu, Qunfeng Zeng, Dongyang Li and Yucheng Wu
Metals 2026, 16(1), 122; https://doi.org/10.3390/met16010122 - 20 Jan 2026
Viewed by 106
Abstract
The rocket sled slider is a key connection component between the rocket sled and the track for support, guidance and load-bearing, ensuring the system’s safe and reliable operation. Wear of sliders under high—velocity and heavy—load conditions is crucial for equipment reliability. This study [...] Read more.
The rocket sled slider is a key connection component between the rocket sled and the track for support, guidance and load-bearing, ensuring the system’s safe and reliable operation. Wear of sliders under high—velocity and heavy—load conditions is crucial for equipment reliability. This study establishes a wear prediction model for sled rails using ANSYS, incorporating a dimensionless acceleration factor into the simulation. By analyzing dynamic characteristics of contact friction stress, wear volume, depth, and stress over time, the tribological characteristics of 30CrMnSiNi2A steel sliders were studied. The simulation results showed that during dry—friction sliding, slider wear is highly related to speed and load, increasing significantly as they increase. The slider’s contact surface has non-uniform stress distribution with stress concentration and gradient changes. Quantitative analysis has revealed that friction stress is positively correlated with load, and its sensitivity to speed changes is high at low speeds and relatively low at high speeds. Full article
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18 pages, 8088 KB  
Article
A Potentially Repairable Composite Coating for Significantly Enhancing Wear and Corrosion Resistance of Magnesium Alloy
by Yueyu Huang, Ruilin Zeng, Shequan Wang, Ninghua Long, Yingpeng Zhang, Qun Wang and Chidambaram Seshadri Ramachandran
Lubricants 2026, 14(1), 44; https://doi.org/10.3390/lubricants14010044 - 20 Jan 2026
Viewed by 210
Abstract
The AZ31 magnesium alloy is an attractive lightweight metallic material, but its low corrosion resistance and wear resistance significantly limit its widespread application in fields such as aerospace, the automotive industry, and mechanical engineering. Moreover, most coating systems currently cannot restore their original [...] Read more.
The AZ31 magnesium alloy is an attractive lightweight metallic material, but its low corrosion resistance and wear resistance significantly limit its widespread application in fields such as aerospace, the automotive industry, and mechanical engineering. Moreover, most coating systems currently cannot restore their original functions and dimensions after localized damage. Based on this, this study combined cold spray (CS), micro-arc oxidation (MAO), and magnetron sputtering (MS) to develop a high-performance and repairable composite modification strategy. First, a 5056 aluminum alloy coating was prepared on AZ31 via CS, followed by the growth of a hard alumina (Al2O3) coating via MAO and a diamond-like carbon (DLC) coating via MS on the 5056 aluminum alloy surface. The microstructure, phase composition, hardness, tribological properties, and electrochemical corrosion behavior of the coatings were evaluated using scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDS), X-ray diffraction (XRD), Vickers hardness testing, ball-on-disk dry sliding wear testing, and potentiodynamic polarization testing in a 3.5% sodium chloride solution. The CS 5056 aluminum alloy coating reduced the corrosion current density of AZ31 from 4.098 × 10−5 A/cm2 to 2.714 × 10−6 A/cm2. The MAO alumina coating increased the hardness of AZ31 from 68.60 HV0.05 to 1614.00 HV0.05 and decreased the wear rate from 1.703 × 106 μm3/(N·m) to 2.038 × 103 μm3/(N·m). The DLC coating further reduced the average coefficient of friction of the alumina coating from 0.48 to 0.27, decreased the wear rate to 6.979 × 102 μm3/(N·m), and lowered the corrosion current density from 3.020 × 10−6 A/cm2 to 8.860 × 10−9 A/cm2. This indicates that the three-phase composite coating achieves synergistic improvements in the corrosion and wear resistance of AZ31 through complementary advantages. Additionally, the thick CS aluminum alloy underlayer provides potential repairability, enabling the restoration of function and dimensions after damage without compromising the magnesium substrate. Overall, the proposed 5056Al/Al2O3/DLC composite coating strategy offers a reliable protective approach for AZ31 components and is expected to further expand their application fields. Full article
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18 pages, 3761 KB  
Article
Effect of Fiber Material on Tribological Performance of Filament-Winding Composite Materials in a Water-Lubricated Environment
by Yicong Yu, Zhijun Chen and Zhiwei Guo
Polymers 2026, 18(2), 269; https://doi.org/10.3390/polym18020269 - 19 Jan 2026
Viewed by 297
Abstract
Water-lubricated bearings are critical components in marine propulsion systems, necessitating materials with exceptional tribological properties to ensure reliability. Filament-winding technology is an effective molding method for enhancing the comprehensive properties of polymers, and the selection of fiber materials has a significant impact on [...] Read more.
Water-lubricated bearings are critical components in marine propulsion systems, necessitating materials with exceptional tribological properties to ensure reliability. Filament-winding technology is an effective molding method for enhancing the comprehensive properties of polymers, and the selection of fiber materials has a significant impact on the performance of polymers. In this study, three types of polyurethane (PU) matrix filament-winding composites were fabricated via filament-winding technology. Under water-lubricated conditions, a friction test (disk-to-disk) with a duration of 2 h was performed, followed by systematic observations of the resultant wear behavior. The results indicate that aramid fibers exhibited the superior reinforcing effect on the PU matrix, effectively suppressing wear while enhancing mechanical properties. Specifically, under the conditions of 0.5 MPa-250 r/min (0.314 m/s), the minimum friction coefficient of the aramid fiber-wound composite material was 0.093, which was 57.73% lower than that of pure polyurethane. Under the conditions of 0.7 MPa-50 r/min (0.0628 m/s), the wear mass of the sample was limited to only 1.5 mg, which was 12% lower than that of polyurethane. This research can provide a practical reference for the application of filament-wound composite materials in water-lubricated bearings. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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19 pages, 4052 KB  
Article
Microstructure and Wear Resistance of (Mg2Si + SiCp)/Al Composites
by Dekun Zhou, Xiaobo Liu and Miao Yang
Metals 2026, 16(1), 111; https://doi.org/10.3390/met16010111 - 18 Jan 2026
Viewed by 169
Abstract
The microstructure and wear behaviors of Mg2Si/Al composites with 0 wt.%, 5 wt.%, and 10 wt.% SiC particles were studied using XRD, OM observation, SEM observation, EDS analysis, an extraction experiment, a hardness test, and the dry sliding wear test. It [...] Read more.
The microstructure and wear behaviors of Mg2Si/Al composites with 0 wt.%, 5 wt.%, and 10 wt.% SiC particles were studied using XRD, OM observation, SEM observation, EDS analysis, an extraction experiment, a hardness test, and the dry sliding wear test. It is shown by the results that after the addition of 10 wt.% SiC particles, the population of primary Mg2Si particles increased, while the mean size of these particles reduced from 40 ± 10 μm (in the SiC-free composite) to 25 ± 8 μm. Both the matrix and the eutectic structure were refined. The tetrakaidecahedral morphologies of Mg2Si crystals were confirmed by the results of extraction tests. The wear test results with GCr15 steel as the friction pair show that the Mg2Si/Al composite with 10 wt.% SiC particles displayed more favorable wear resistance than the specimens with 0 wt.% and 5 wt.% SiC particle additions under both constant load and constant sliding velocity conditions. Under applied loads of 10 N, 20 N, and 30 N at a fixed sliding speed of 300 r/min, the wear rate of the Mg2Si-Al composites reinforced with 10 wt.% SiC particles was 36.01%, 48.29%, and 23.32% lower than that of the SiC-free composites, respectively. When the sliding speed was set to 300 r/min, 550 r/min, 750 r/min, and 1000 r/min under a constant applied load of 20 N, the wear rate of the 10 wt.% SiC-reinforced Mg2Si-Al composites was reduced by 40.37%, 40.87%, 26.20%, and 25.78%, respectively, compared with the SiC-free counterparts. The wear failure mechanisms of (Mg2Si + SiCP)/Al composites were mainly adhesive wear and abrasive wear, but the proportion of oxidation wear increased after the addition of the SiC particles. Full article
(This article belongs to the Special Issue Recent Advances in Forming Processes of Lightweight Metals)
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25 pages, 19691 KB  
Article
Effects of Post-Heat Treatment on Mechanical and Tribological Properties of 3D-Printed PLA and PEEK Structures
by Yunxiang Deng and Li Chang
Polymers 2026, 18(2), 253; https://doi.org/10.3390/polym18020253 - 16 Jan 2026
Viewed by 244
Abstract
In the present study, post-heat treatment was applied to improve the mechanical and tribological performance of 3D-printed polymer components. Two polymers, i.e., polylactic acid (PLA) and polyether ether ketone (PEEK), were used as base materials. Re-entrant structures were incorporated into printed specimens to [...] Read more.
In the present study, post-heat treatment was applied to improve the mechanical and tribological performance of 3D-printed polymer components. Two polymers, i.e., polylactic acid (PLA) and polyether ether ketone (PEEK), were used as base materials. Re-entrant structures were incorporated into printed specimens to mitigate friction-induced vibrations (FIV). The results showed that the heat-treatment process effectively enhanced the mechanical properties of both materials by increasing their elastic modulus and yield strength. Specifically, the tensile and compressive strengths of heat-treated PLA increased from 44.14 MPa to 47.66 MPa and from 68 MPa to 82 MPa, respectively. A similar trend was observed for heat-treated PEEK, with tensile strength increasing from 75.53 MPa to 84.91 MPa and compressive strength from 106 MPa to 123 MPa. Furthermore, the increased stiffness enabled the re-entrant structures to more effectively reduce FIV during the sliding process of specimens. However, heat treatment produced contrasting effects on the wear performance of the two polymers. The specific wear rate of the heat-treated PLA sample with the re-entrant structure increased from 2.36 × 10−5 mm3/(N · m) to 4.5 × 10−4 mm3/(N · m), while it decreased for the PEEK sample from 3.18 × 10−6 mm3/(N · m) to 6.2 × 10−7 mm3/(N · m). Microscopic observations revealed that this difference was due to the variations in the brittleness of the treated materials, which influenced wear-debris formation and the development of the transfer film on the steel counterface. These findings demonstrate that post-heat treatment is an effective method for tailoring and optimizing the mechanical behavior of printed polymers while also emphasizing the necessity of systematically evaluating its influence on the tribological performance of printed engineering parts subjected to different sliding conditions. Full article
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18 pages, 6562 KB  
Article
Optimal CeO2 Doping for Synergistically Enhanced Mechanical, Tribological, and Thermal Properties in Zirconia Ceramics
by Feifan Chen, Yongkang Liu, Zhenye Tang, Xianwen Zeng, Yuwei Ye and Hao Chen
Materials 2026, 19(2), 362; https://doi.org/10.3390/ma19020362 - 16 Jan 2026
Viewed by 148
Abstract
CeO2 doping is a well-established strategy for enhancing the properties of zirconia (ZrO2) ceramics, with the prior literature indicating an optimal doping range of around 10–15 wt.% for specific attributes. Building upon this foundation, this study provides a systematic investigation [...] Read more.
CeO2 doping is a well-established strategy for enhancing the properties of zirconia (ZrO2) ceramics, with the prior literature indicating an optimal doping range of around 10–15 wt.% for specific attributes. Building upon this foundation, this study provides a systematic investigation into the concurrent evolution of mechanical, tribological, and thermophysical properties across a broad compositional spectrum (0–20 wt.% CeO2). The primary novelty lies in the holistic correlation of these often separately examined properties, revealing their interdependent trade-offs governed by microstructural development. The 15Ce-ZrO2 composition, consistent with the established optimal range, achieved a synergistic balance: hardness increased by 27.6% to 310 HV1, the friction coefficient was minimized to 0.205, and the wear rate was reduced to 1.81 × 10−3 mm3/(N m). Thermally, it exhibited a 72.2% reduction in the thermal expansion coefficient magnitude at 1200 °C and a low thermal conductivity of 0.612 W/(m·K). The enhancement mechanisms are consistent with solid solution strengthening, grain refinement, and likely enhanced phonon scattering, potentially from point defects such as oxygen vacancies commonly associated with aliovalent doping in oxide ceramics, while performance degradation beyond 15 wt.% is linked to CeO2 agglomeration and duplex microstructure formation. This work provides a relatively comprehensive insight into the dataset and mechanism, which is conducive to the fine design of multifunctional ZrO2 bulk ceramics. It is not limited to determining the optimal doping level, but also aims to clarify the comprehensive performance map, providing reference significance for the development of advanced ceramic materials with synergistically optimized hardness, wear resistance, and thermal properties. Full article
(This article belongs to the Section Advanced and Functional Ceramics and Glasses)
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39 pages, 4627 KB  
Review
Friction Stir Processing: An Eco-Efficient Route to High-Performance Surface Architectures in MMCs
by Sachin Kumar Sharma, Saša Milojević, Lokesh Kumar Sharma, Sandra Gajević, Yogesh Sharma, Mohit Sharma, Stefan Čukić and Blaža Stojanović
Processes 2026, 14(2), 306; https://doi.org/10.3390/pr14020306 - 15 Jan 2026
Viewed by 193
Abstract
Friction Stir Processing (FSP) has emerged as an advanced solid-state surface engineering technique for tailoring high-performance surface architectures in metal matrix composites (MMCs). By combining localized thermo-mechanical deformation with controlled material flow, FSP enables grain refinement, homogeneous dispersion of reinforcement, and strong interfacial [...] Read more.
Friction Stir Processing (FSP) has emerged as an advanced solid-state surface engineering technique for tailoring high-performance surface architectures in metal matrix composites (MMCs). By combining localized thermo-mechanical deformation with controlled material flow, FSP enables grain refinement, homogeneous dispersion of reinforcement, and strong interfacial bonding without melting or altering bulk properties. This review critically examines the role of FSP in enhancing the mechanical, tribological, and corrosion performance of composites, with emphasis on process–structure–property relationships. Key strengthening mechanisms, including grain boundary strengthening, load transfer, particle pinning, and defect elimination, are systematically discussed, along with their implications for wear resistance, fatigue life, and durability. Special attention is given to corrosion and tribo-corrosion behavior, highlighting electrochemical mechanisms such as micro-galvanic interactions, passive film stability, and interfacial chemistry. Furthermore, the eco-efficiency, industrial viability, and sustainability advantages of FSP are evaluated in comparison with conventional surface modification techniques. The review concludes by identifying critical challenges and outlining future research directions for the scalable, multifunctional, and sustainable design of composite surfaces. Full article
(This article belongs to the Section Materials Processes)
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31 pages, 4459 KB  
Review
Prospects and Challenges for Achieving Superlubricity in Porous Framework Materials (MOFs/POFs): A Review
by Ruishen Wang, Xunyi Liu, Sifan Huo, Mingming Liu, Jiasen Zhang, Yuhong Liu, Yanhong Cheng and Caixia Zhang
Lubricants 2026, 14(1), 42; https://doi.org/10.3390/lubricants14010042 - 15 Jan 2026
Viewed by 268
Abstract
Metal–organic frameworks (MOFs) and porous organic frameworks (POFs) have been extensively explored in recent years as lubricant additives for various systems due to their structural designability, pore storage capacity, and tunable surface chemistry. These materials are utilized to construct low-friction, low-wear interfaces and [...] Read more.
Metal–organic frameworks (MOFs) and porous organic frameworks (POFs) have been extensively explored in recent years as lubricant additives for various systems due to their structural designability, pore storage capacity, and tunable surface chemistry. These materials are utilized to construct low-friction, low-wear interfaces and investigate the potential for superlubricity. This paper systematically reviews the tribological behavior and key mechanisms of MOFs/POFs in oil-based, water-based, and solid coating systems. In oil-based systems, MOFs/POFs primarily achieve friction reduction and wear resistance through third-body particles, layer slip, and synergistic friction-induced chemical/physical transfer films. However, limitations in achieving superlubricity stem from the multi-component heterogeneity of boundary films and the dynamic evolution of shear planes. In water-based systems, MOFs/POFs leverage hydrophilic functional groups to induce hydration layers, promote polymer thickening, and soften gels through interfacial anchoring. Under specific conditions, a few cases exhibit superlubricity with coefficients of friction entering the 10−3 range. In solid coating systems, two-dimensional MOFs/COFs with controllable orientation leverage interlayer weak interactions and incommensurate interfaces to reduce potential barriers, achieving structural superlubricity at the 10−3–10−4 level on the micro- and nano-scales. However, at the engineering scale, factors such as roughness, contamination, and discontinuities in the lubricating film still constrain performance, leading to amplified energy dissipation and degradation. Finally, this paper discusses key challenges in achieving superlubricity with MOFs/POFs and proposes future research directions, including the design of shear-plane structures. Full article
(This article belongs to the Special Issue Superlubricity Mechanisms and Applications)
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23 pages, 5255 KB  
Article
Analysis of Wear Behavior Between Tire Rubber and Silicone Rubber
by Juana Abenojar, Miguel Angel Martínez and Daniel García-Pozuelo
Appl. Sci. 2026, 16(2), 878; https://doi.org/10.3390/app16020878 - 14 Jan 2026
Viewed by 189
Abstract
Vulcanized NR-SBR is widely used in vehicle components; however, its irreversible crosslinking limits recyclability and contributes to the large number of tires discarded annually worldwide, and in this context, this work presents an experimental comparative assessment of the tribological behavior of conventional tire [...] Read more.
Vulcanized NR-SBR is widely used in vehicle components; however, its irreversible crosslinking limits recyclability and contributes to the large number of tires discarded annually worldwide, and in this context, this work presents an experimental comparative assessment of the tribological behavior of conventional tire rubber and silicone VMQ, motivated by a wheel concept based on a detachable tread aimed at improving durability and sustainability rather than proposing an immediate material substitution. Wear and friction behavior were investigated under abrasive and self-friction conditions using pin-on-disk testing with an abrasive counterpart representative of asphalt, supported by optical and scanning electron microscopy. The results show that NR-SBR undergoes severe abrasive and erosive wear, characterized by deep and irregular wear tracks, pronounced fluctuations in the dynamic friction coefficient, and strong sensitivity to load and sliding speed, particularly during the initial stages of track formation. In contrast, VMQ exhibits mild abrasive wear dominated by viscoelastic deformation, leading to shallow and stable wear tracks, lower friction coefficients, and significantly reduced material loss once the contact track is fully developed. These differences are attributed to the distinct mechanical responses of the elastomers, as the higher hardness and limited strain capacity of rubber promote micro-tearing and unstable material removal, while the high elasticity of silicone enables stress redistribution and stable contact conditions under abrasive loading. UV aging increases stiffness of rubber, resulting in reduced wear and friction, while silicone remains largely unaffected after 750 h due to the stability of its Si–O–Si backbone. Self-friction tests further indicate that smooth silicone sliding against rubber yields the lowest friction values, highlighting a favorable material pairing for detachable tread concepts. Factorial design analysis confirms material type as the dominant factor influencing both wear and friction. Overall, for the specific materials and operating conditions investigated, VMQ demonstrates higher durability, greater tribological stability, and improved aging resistance compared to NR-SBR, providing experimental evidence that supports its potential for long-life, more sustainable detachable tread applications. Full article
(This article belongs to the Section Materials Science and Engineering)
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25 pages, 4121 KB  
Review
Advances in the Tribological Research of Ceramic-on-Ceramic Artificial Joints
by Menglin Zhou, Zihan Lin, Xiaolu Jiang, Jianhua Jin, Qi Wan, Li Zhang and Zhaoxian Zheng
Lubricants 2026, 14(1), 36; https://doi.org/10.3390/lubricants14010036 - 14 Jan 2026
Viewed by 134
Abstract
Ceramic-on-ceramic (CoC) bearings are widely used in total hip arthroplasty due to their extremely low wear rate, excellent chemical stability, and good biocompatibility. They are considered one of the most reliable long-term friction bearing systems. Although frictional instability, lubrication regime transitions, and microstructural [...] Read more.
Ceramic-on-ceramic (CoC) bearings are widely used in total hip arthroplasty due to their extremely low wear rate, excellent chemical stability, and good biocompatibility. They are considered one of the most reliable long-term friction bearing systems. Although frictional instability, lubrication regime transitions, and microstructural damage mechanisms have been widely reported at the experimental and retrieval-analysis levels, current clinical evidence, limited by follow-up duration and event incidence, has not demonstrated a definitive negative impact on the clinical performance of fourth-generation ceramic components, including BIOLOX® delta. Data from national arthroplasty registries consistently demonstrate excellent survivorship and low complication rates for 4th-generation ceramics in both hard-on-soft and hard-on-hard configurations. The most reported causes for revision, such as infection, dislocation, aseptic loosening, and periprosthetic fracture, are not primarily associated with ceramic-related complications, such as ceramic fracture, excessive wear, squeaking, and revision, related to bearing failure; however, these mechanisms remain highly relevant for the design and evaluation of emerging ceramic materials and next-generation implant systems, where inadequate control may potentially impact long-term clinical performance. This review summarizes recent advances in the tribological research of CoC artificial joints, focusing on clinical tribological challenges, material composition and surface characteristics, lubrication mechanisms, wear and microdamage evolution, and third-body effects. Recent progress in ceramic toughening strategies, surface engineering, biomimetic lubrication simulation, and structural optimization is also discussed. Finally, future research directions are outlined to support the performance optimization and long-term reliability assessment of CoC artificial joint systems. Full article
(This article belongs to the Special Issue Tribology of Medical Devices)
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