Search Results (2,654)

Soil aggregates are critical determinants of soil erosion resistance and nutrient retention capacity, while freeze–thaw cycles (FTCs) induce the structural reorganization of soil aggregates, thereby altering soil stability and influencing soil organic carbon (SOC) sequestration. This study was located in the Minjia River Basin in the typical seasonal freeze–thaw areas of the Loess Plateau and aimed to quantify the effects of FTCs on soil aggregate stability and SOC content under different land use types. Farmland, grassland, and forestland with more than 20 years of usage in the region were selected, and a 0–20 cm soil layer was subjected to seven FTCs (−8 °C to 20 °C), followed by wet and dry sieving classification, focusing on soil aggregate distribution, aggregate stability, mean weight diameter (MWD), geometric mean diameter (GMD), aggregate particle fractal dimension (APD), and SOC content of the aggregate. The results showed that soil aggregates in all land use types were dominated by macroaggregates (>2 mm), with the proportion in forestland (61–63%) > grassland (54–58%) > farmland (38–51%). FTCs enhanced aggregate stability across all land use types, especially in farmland. Concurrently, FTCs reduced the SOC content in all aggregate size fractions, with reduction rates ranging from farmland (9.00–21%) to grassland (4–26%) to forestland (5–31%). Notably, FTCs significantly increased the contribution of 2–5 mm water-stable (WS) aggregates to SOC sequestration, with increment rates of 86% (farmland), 80% (grassland), and 86% (forestland). Furthermore, FTCs altered the correlation between SOC content and aggregate stability. Specifically, the positive correlations of SOC with MWD and GMD were strengthened in aggregates < 0.5 mm but weakened in aggregates >0.5 mm. These findings advance our understanding of the coupled mechanisms underlying soil erosion and carbon cycling across land uses under freeze–thaw, providing a theoretical basis for ecosystem restoration and optimized soil carbon management in cold regions. Full article

In the saline, cold, and arid regions of Western China, the adhesive performance at the carbon fiber-reinforced polymer (CFRP)–concrete interface critically affects the long-term reliability of CFRP-strengthened structures. Replacing the organic epoxy resin (EP) with inorganic magnesium phosphate cement (MPC) has been proposed as an alternative. However, comparative studies on the deterioration of MPC- and EP-bonded CFRP–concrete under sulfate freeze–thaw cycles are limited. This study employed double-shear tests to systematically compare the failure modes, ductility, and bond performance of the CFRP–concrete interface bonded with MPC and EP after 25, 50, and 75 sulfate freeze–thaw cycles. The results indicate that, as the number of cycles increased, MPC-bonded specimens exhibited progressive interfacial peeling, whereas EP-bonded specimens underwent abrupt brittle fracture. At 0, 25, 50, and 75 cycles, the peak strains of MPC specimens exceeded those of EP specimens by 9.28%, 10.13%, 5.99%, and 0.86%, respectively, indicating greater ductility. Bond performance declined markedly for both groups as cycles increased, with MPC specimens showing greater deterioration. After 75 cycles, compared with EP-bonded specimens, MPC-bonded specimens showed a 16.56% lower interfacial load capacity, a 21.53% reduction in peak bond stress, and a 6.03% shorter effective bond length. This systematic comparison of MPC- and EP-bonded CFRP–concrete under sulfate freeze–thaw exposure provides guidance for adhesive selection and strengthening practices in saline, cold, and arid regions. Full article

With the rapid development of infrastructure and the need to protect natural ecosystems, manufactured sand is used to replace river sand in concretes. To compare the deterioration patterns of concretes made with different sands, C50 specimens using basalt (C50X), tuff (C50N), and granite (C50H) manufactured sands and river sand (C50T) were prepared, then tested outdoors by full burial in a sulfate saline soil and indoors by accelerated freeze–thaw in a sulfate solution. The outdoor experiments indicate that C50X deteriorated the slowest, whereas the resistance to mass loss ranking was: C50X > C50H > C50N > C50T. In the indoor freeze–thaw experiments, C50X also performed best, retaining 51% relative dynamic modulus of elasticity (RDME) after 450 cycles. X-ray diffraction and scanning electron microscopy showed that C50T was weakened by abundant MgSO₄·7H₂O crystals, while C50X formed a denser matrix that limits salt-crystallization expansion. Moreover, a GM(1,1)-Markov model was developed to forecast long-term durability. For C50X, the model predicted an estimated service life of 68 months in the outdoor environment, at which point it is projected to reach the 5% mass loss failure threshold. Separately, it forecasted that the RDME would remain above 41% after 450 indoor freeze–thaw cycles. Full article

Pavement texture is a crucial factor influencing both skid resistance and durability. This study aims to investigate the impact of texture reconstruction on pavement performance, which holds significant scientific value for enhancing road safety and durability. The research focuses on the reconstruction of airport cement pavement textures through the design of seven solid–liquid, two-component coating formulations, comprising three types of coatings: emulsion coating (P), waterborne epoxy coating (E), and water-based coating (W). Laser texture scanning technology was employed to identify the texture characteristics, which, combined with the British pendulum test, enabled a comprehensive analysis of skid resistance. Additionally, the coating–concrete interfacial strength and frost resistance were evaluated through pull-out tests, flexural strength tests, and freeze–thaw cycle tests. The results demonstrated that, compared to uncoated concrete, the mean profile depth (MPD) of the P, E, and W coatings increased by 43.4%, 34.7%, and 21.6%, respectively. Furthermore, the peak band of the slope spectrum density (SSD) shifted from a range greater than 1 mm to approximately 0.5 mm following coating application. The British pendulum number (BPN) increased by 25%, 20%, and 15% for the P, E and W coatings, demonstrating a strong correlation with MPD (R² = 0.95). These results indicate that the coated surface texture exhibits superior properties, which explain the enhanced slip resistance from a textural perspective. Moreover, the interfacial strength between the coating and concrete initially increased and then decreased with increasing coating thickness. In comparison, the interfacial bonding strength of the E coating was significantly higher than that of the P and W coatings. Furthermore, compared to the P and W coatings, the flexural bond strength of the E coating increased by 7% and 74%, respectively. After undergoing the freeze–thaw cycle, the E coating exhibited the best freeze resistance, while the W coating exhibited the poorest performance. In summary, the P coating excelled in texture reconstruction, while the E coating provided superior bonding and freeze resistance. This paper presents a novel approach to the development of coating materials for use on airport pavements. Full article

In situ physical coal fracturing is one of the key technologies for deep coal resource extraction, among which the liquid nitrogen cyclic freeze–thaw (LNCFT) technique demonstrates remarkable fracturing effects and promising application potential in physical coal breaking. To determine economically viable mining and coalbed methane (CBM) extraction cycles, this study builds on previous research and conducts a series of experiments to investigate the effects of different cold condition temperatures and freeze–thaw cycles on the mesoscopic surface structure and macroscopic mechanical properties of deep, water-rich coal-rock samples. A statistical damage constitutive model for saturated coal-rock under coupled freeze–thaw and loading, incorporating a damage threshold, was established to more accurately describe the damage patterns and mechanisms. The results indicate that lower cold condition temperatures lead to greater mesoscopic crack propagation, lower uniaxial compressive strength, and significantly reduced freeze–thaw failure cycles. Under −45 °C, saturated coal-rock samples experienced macroscopic failure after only 23 freeze–thaw cycles, which is 9 and 15 cycles fewer than those under −30 °C and −15 °C, respectively. Furthermore, measurements of wave velocities in three directions before and after testing revealed that freeze–thaw cycles caused particularly pronounced damage in the direction perpendicular to the bedding planes. Additionally, the established coupled statistical damage constitutive model provides a more accurate and intuitive analysis of the entire process from damage to failure under different cold conditions, showing that as the temperature decreases and freeze–thaw cycles increase, the coal-rock’s brittleness diminishes while plastic deformation and ductile failure characteristics are enhanced. In summary, for coal and CBM extraction using the LNCFT technique, it is recommended to extract gas once after approximately 35 cycles of liquid nitrogen injection. This study provides a theoretical basis for the application of liquid nitrogen cyclic freeze–thaw technology in deep coal fracturing. Full article

Accurate prediction of bridge deterioration is essential for optimizing inspection schedules, prioritizing maintenance activities, and ensuring infrastructure safety. This study developed machine learning-based predictive models to estimate the deterioration states of bridge decks, superstructures, and substructures using a comprehensive dataset from the Colorado National Highway System spanning 2014 to 2024. Structural, operational, and environmental parameters including freeze–thaw cycles, precipitation, condensation risk, and extreme temperatures were incorporated to capture both design-driven and climate-driven deterioration mechanisms. Decision Tree, Random Forest, and Gradient Boosting classifiers were trained and evaluated using Balanced Accuracy, Matthews Correlation Coefficient, Cohen’s Kappa, and macro-averaged F1-scores, with class imbalance addressed via SMOTETomek resampling. The Gradient Boosting classifier achieved the highest predictive performance, with balanced accuracy exceeding 97% across all components. Feature importance analysis revealed that sufficiency rating, year of construction, and environmental stressors were among the most influential predictors. Incorporating environmental variables improved predictive accuracy by up to 4.5 percentage points, underscoring their critical role in deterioration modeling. These findings demonstrate that integrating environmental factors into machine learning frameworks enhances the reliability of deterioration forecasts and supports the development of climate-aware asset management strategies, enabling transportation agencies to proactively plan maintenance interventions and improve infrastructure resilience. Full article

Ultra-high-performance concrete (UHPC) has been widely utilised in strengthening and rehabilitating conventional normal concrete (NC) structures due to its exceptional mechanical properties and durability. However, in cold climates, the interfacial bond between UHPC and NC is susceptible to degradation under freeze–thaw cycles, potentially compromising the composite action and long-term performance of strengthened structures. This study systematically investigated the shear behaviour of a UHPC-NC interface with planted reinforcement subjected to various freeze–thaw conditions. The experiments were conducted considering different numbers of freeze–thaw cycles (0, 20, 40, 60, 80, and 100) and salt solution concentrations (0%, 3.5%, and 5%). Direct shear tests were performed to evaluate interfacial failure modes, mass loss, and shear strength degradation. Results identified three characteristic failure modes: adhesive debonding at the interface, mixed failure involving both the interface and the NC substrate, and crushing failure within the NC substrate. Specimens exposed to 3.5% salt solution experienced the most significant deterioration, exhibiting a 35% reduction in shear strength after 100 freeze–thaw cycles. Normally, lower salt concentrations were found to induce greater interfacial damage compared to higher concentrations. The study underscores the importance of increasing the embedment depth of the planted reinforcement to alleviate stress concentration and enhance interfacial durability in freeze–thaw environments. Full article

Little research is reported on the properties of Portland cement concrete (PCC) mixtures comprising plastic waste materials. Therefore, this novel study was initiated to evaluate the effects of plastic waste materials on different properties of PCC. Plastic boxes and containers made of polypropylene were cut, grinded, pulverized, and incorporated into PCC mixtures. Sand was partially replaced by plastic waste materials with 0%, 5%, 10%, 15%, and 20% volume ratios. Experiments were conducted using PCC cylinders and prisms to evaluate several unique properties of PCC containing plastic waste. Innovative interactions and contributions of several PCC properties including workability, air content, density, water absorption, mechanical properties, rapid chloride ion penetration, and freeze–thaw deterioration are investigated. The new experimental data indicated that the workability and density of PCC decreased with increasing plastic waste replacement levels. The maximum decreases in workability and density were 23% and 6.2% for the PCC with 20% plastic replacement, respectively. On the other hand, our research has shown that air content and water absorption of PCC increases with increasing plastic waste amount. The maximum increase in air content and water absorption were 78% and 29% for the PCC with 20% plastic waste. This study also shows that the mechanical properties of PCC (e.g., compressive and splitting strengths) after 7 and 28 days of moist curing decreased with increasing plastic waste content. Another new finding is that the rapid chloride permeability of PCC increased and the freeze–thaw durability of PCC decreased with an increase in plastic waste amount. One of the most critical discoveries of this experimental study is that plastic waste increases the durability of PCC, i.e., durability factor of PCC with 20% plastic waste was 9.3% compared to 28.5% for the control PCC without plastic waste materials. Full article

Coal gangue concrete in high, cold mines in western China is subject to freeze–thaw damage due to prolonged low temperatures and large temperature variations, leading to surface spalling, cracking, and degradation of mechanical performance. In this study, four coal gangue concrete mixtures with replacement ratios of 0%, 20%, 40%, and 60% were prepared using gangue from the Halagou Mine in the Shendong area. Freeze–thaw cycle tests were conducted to analyze the effects of the replacement rate and number of cycles on compressive strength, elastic modulus, and peak strain. The results show that both compressive strength and elastic modulus decrease with increasing freeze–thaw cycles, while the peak strain increases. After 80 cycles, the compressive strength of the M0, M20, and M40 groups decreased by 35.0%, 41.8%, and 51.1%, respectively, and their elastic modulus dropped by 49.2%, 86.2%, and 92.0%. The M60 group was too severely damaged to be tested. Based on the experimental data, a constitutive model for coal gangue concrete under freeze–thaw conditions was developed and validated using Abaqus finite element analysis, with simulation errors below 10%. Considering both mechanical performance and resource utilization, the optimal coal gangue replacement rate is determined to be 20%. Full article

Sperm cryopreservation is a key technique in assisted reproductive technologies (ART), livestock breeding, fertility preservation, and wildlife conservation. However, the freeze–thaw process induces significant oxidative stress through the production of reactive oxygen species (ROS) by mitochondria, which can lead to impaired sperm motility, membrane damage, DNA fragmentation, and reduced fertilization potential. MitoQ is a mitochondria-targeted antioxidant consisting of a ubiquinone moiety conjugated to triphenylphosphonium (TPP⁺). MitoQ selectively accumulates in the mitochondrial matrix, where it efficiently scavenges reactive oxygen species (ROS) at their point of origin. This targeted action helps preserve mitochondrial function, sustain ATP production, and inhibit apoptotic signaling. Extensive experimental evidence across diverse species, including bulls, rams, boars, humans, dogs, and goats, shows that MitoQ supplementation during cryopreservation enhances post-thaw sperm viability, motility, membrane integrity, and DNA stability. Optimal dosing between 50 and 150 nM achieves these benefits without cytotoxicity, although higher doses may paradoxically increase oxidative damage. Compared to conventional antioxidants, MitoQ offers superior mitochondrial protection and enhanced preservation of sperm bioenergetics. Future directions involve exploring synergistic combinations with other cryoprotectants, advanced delivery systems such as nanoparticles and hydrogels, and detailed mechanistic studies on long-term effects. Overall, MitoQ represents a promising adjunct for improving sperm cryopreservation outcomes across clinical, agricultural, and conservation settings. Full article

Replacing natural aggregates in cement-stabilized macadam (CSM) with waste rubber particles reduces mineral resource consumption, manages solid waste, and enhances the long-term performance of cementitious materials, addressing environmental challenges. An optimized gradation of rubber particles was proposed based on different combinations of particle sizes. Five rubber particle combinations with different gradations were incorporated into CSM to create a rubberized cement-stabilized macadam (RCSM). The strength of RCSM was verified through compressive and flexural tensile tests. The toughness of RCSM was evaluated using the flexural ultimate failure strain and flexural tensile resilient modulus. Crack resistance was evaluated through freeze–thaw, fatigue, and shrinkage tests. The results indicate that the compressive and flexural strengths of RCSM with 1.18–4.75 mm rubber particles are closest to those of CSM. The ultimate strain of CSM increased by up to 1.83 times with optimized rubber gradation, while its modulus decreased by more than half. Furthermore, RCSM with 1.18–4.75 mm rubber particles exhibited the best performance in fatigue life under high stress ratio, frost resistance, and shrinkage behavior. Comprehensive test results showed that rubber particles ranging from 1.18 to 2.36 mm were most effective in improving the road performance of RCSM. Full article

Silica fume (SF) is extensively utilized for enhancing concrete properties. This study examines the impact of SF dosage on concrete frost resistance. Specimens were produced by replacing cement with SF at 5%, 10%, 20%, and 30% ratios. Mechanical testing and microscopic characterization measured variations in mass loss, relative dynamic elastic modulus, flexural strength, hydration products, and pore structure. Digital image correlation tracked failure development during flexural tests. Results indicated that SF-modified concrete showed lower mass loss, better elastic modulus retention, and improved flexural strength maintenance compared to plain concrete after identical freeze–thaw (F-T) cycles. Additionally, SF-modified concrete demonstrated reduced crack widths and slower crack expansion during bending. The 10% SF mixture, after 300 cycles, achieved optimal results characterized by 2.83% mass loss, 88.1% relative dynamic modulus, and only a 17% flexural strength reduction. Microscopic studies confirm that SF addition increases calcium silicate hydrate formation, decreases calcium hydroxide levels, and refines pore structure with higher density. These modifications enhance frost resistance. A service-life prediction model using gray model approach methodology projected that 10% SF concrete would last 2.01 times longer than unmodified concrete under F-T exposure. Full article

To investigate the deterioration pattern of the rheological properties of high-viscosity high-elasticity asphalt (HVEA) under UV and salt freeze–thaw (SFT) cycle environments, two snowmelt salts were used for coupled aging tests, along with temperature sweep, bending beam rheological (BBR), and Fourier-transform infrared spectroscopy (FT-IR) tests. The results showed that both snowmelt salts could enhance the high-temperature rutting resistance of HVEA, in which the enhancement effect of NaCl was more significant. With the increase in salt concentration, the BBR stiffness of HVEA decreased and then increased, while the m-value showed the opposite trend, indicating that the addition of snowmelt salt impaired its low-temperature creep performance. Additionally, UV-SFT aging would exacerbate the degradation of low-temperature crack resistance. The temperature sensitivity of HVEA gradually decreased with the drop of viscosity temperature sensitivity (VTS) value; salt corrosion further significantly reduced its temperature sensitivity. UV-SFT aging would significantly weaken fatigue performance of HVEA, especially after 15 cycles. FT-IR test showed that UV-SFT resulted in the enhancement of S=O and C=C characteristic peaks, suggesting that the HVEA underwent oxidization and chemical aging, which increased the low-temperature brittleness. Full article

Three-dimensional-printed concrete (3DPC) is an additive manufacturing technology that forms 3D solids via layer-by-layer printing based on 3D model data, but it consumes large amounts of river sand (RS) and has poor frost resistance. To address these issues, this study used industrial waste electric arc furnace slag (EAFS) as an aggregate at 0–100% replacement ratios to test the workability, mechanical properties, frost resistance, and microstructures of 3DPC specimens. The results show that EAFS improves mortar flowability and extends the printing window, but full replacement increases slump and reduces constructability. The stress dispersion and dense packing effects of EAFS ensure excellent mechanical properties of specimens before and after freeze–thaw cycles. At an 80% EAFS replacement ratio, compressive and flexural strengths increase by 2.52%/13.8% and 10.6%/18.2%, respectively; after freeze–thaw cycles, the specimens exhibit the best frost resistance. The interfacial transition zone between EAFS and cement matrix is only 2 μm, with 1.8% lower porosity and 20.14% fewer harmful pores than the 100% RS specimen after freeze–thaw cycles. In conclusion, 80% EAFS replacement balances 3DPC performance and solid waste utilization, providing important references for EAFS’s safe application in 3DPC and its performance improvement mechanism. Full article

The soil freeze–thaw process is a dominant disturbance in the seasonally frozen ground and the active layer of permafrost, which plays a crucial role in the surface energy balance, water cycle, and carbon exchange and has a pronounced influence on vegetation phenology. This study proposes a novel density-based Freeze–Thaw Disturbance Index (FTDI) based on the identification of the freeze–thaw disturbance region (FTDR) over the Qinghai–Tibet Plateau (QTP). FTDI is defined as an areal density metric based on geomorphic disturbances, i.e., the proportion of FTDRs within a given region, with higher values indicating greater areal densities of disturbance. As a measure of landform clustering, FTDI complements existing freeze–thaw process indicators and provides a means to assess the geomorphic impacts of climate-driven freeze–thaw changes during permafrost degradation. The main conclusions are as follows: the FTDR results that are identified by the random forest model are reliable and highly consistent with ground observations; the FTDRs cover 8.85% of the total area of the QTP, and mainly in the central and eastern regions, characterized by prolonged freezing durations and the average annual ground temperature (MAGT) is close to 0 °C, making the soil in these regions highly susceptible to warming-induced disturbances. Most of the plateau exhibits low or negligible FTDI values. As a geomorphic indicator, FTDI reflects the impact of potential freeze–thaw dynamic phase changes on the surface. Higher FTDI values indicate a greater likelihood of surface thawing processes triggered by rising temperatures, which impact surface processes. Regions with relatively high FTDI values often contain substantial amounts of organic carbon, and may experience delayed vegetation green-up despite general warming trends. This study introduces the FTDI derived from the FTDR as a novel index, offering fresh insights into the study of freeze–thaw processes in the context of climate change. Full article