Search Results (1,125)

The co-disposal of municipal solid waste incineration fly ash (MSWI-FA) in cement kilns is an effective method for managing incineration by-products in China. However, the presence of heavy metals in MSWI-FA raises environmental concerns. This study analyzed the Cu, Zn, Cd, Pb, Cr, and Ni concentrations in MSWI-FA from 11 representative facilities across China and assessed the efficacy of a three-stage water washing process for Cl and heavy metal removal. The results revealed significant regional variations in heavy metal content that were strongly correlated with surface soil levels, with Zn, Pb, and Cu exhibiting the highest concentrations. Elemental correlations, such as Cu-Pb and Zn-Cd synergies and Cd-Ni antagonism, suggest common waste sources and temperature-dependent volatilization during incineration. The washing process (solid–liquid ratio = 1:10) achieved 97.1 ± 2.0% Cl removal, reducing residual Cl to 0.45 ± 0.32%, but demonstrated limited heavy metal elimination (10.28–19.38% efficiency), resulting in elevated concentrations (32.5–60.8% increase) due to 43.4 ± 9.2% mass loss. Notably, the washing effluents exceeded municipal wastewater discharge limits by up to 52-fold for Pb and 38-fold for Cd, underscoring the need for advanced effluent treatment. To mitigate environmental risks, the addition of washed MSWI-FA in cement kilns should be restricted to ≤0.5%, with Cd content prioritized in pre-disposal assessments. This study provides actionable insights for optimizing MSWI-FA co-processing while ensuring compliance with ecological safety standards. Full article

Full-section interval casting technology was adopted for the integral immersed tube of the Chebei Immersed Tunnel. Field tests (Chebei Immersed Tunnel) were conducted to establish the time-dependent development of the concrete shrinkage strain of the full-section casting segments. And laboratory experiments were then carried out to investigate the influence of factors such as the reinforcement ratio and stress, expansive agent content and composition, fly ash content, and curing temperature and humidity on the expansive effect of calcium–magnesium composite expansive agents. Field tests revealed that casting segments exhibit initial expansion followed by shrinkage, reaching a final strain of 348 με (microstrain). Laboratory investigations demonstrated that reinforcement (20–30 MPa stress) in post-casting belts effectively restrains segments without compromising the performance of calcium–magnesium composite expansive agents. The optimal 5:3:2 ratio of CaO, MgO 90s, and MgO 200s agents controlled shrinkage strain within 80 με by combining CaO’s rapid early expansion with MgO’s sustained effect. Field validation confirmed the mix’s effectiveness in preventing cracking, with key findings: (1) fly ash content and curing conditions significantly influence expansive behavior, and (2) shrinkage development can be precisely regulated through agent composition adjustments. Full article

The resource utilization potential and environmental impact of fly ash from municipal solid waste incinerators (MSWIs) have attracted wide attention. In this study, four MSWIs in Hangzhou, Zhejiang Province were selected to systematically evaluate the effects of different incinerator types and flue gas deacidification processes on fly ash’s oxide and heavy metal components and their temporal changes as well as conduct risk assessment. The results showed that the contents of MgO, Al₂O₃, SiO₂, and Fe₂O₃ in the grate furnace fly ash were significantly lower than those in the fluidized bed fly ash, but the compressive strength of its fly ash was high. Chemicals added during the flue gas deacidification process such as CaO and NaHCO₃ significantly affected the contents of CaO and Na₂O. In addition, heavy metals such as Cu, Mn, Cr, and Ni were mainly distributed in the fluidized bed fly ash, while heavy metals such as Pb and Cd were mainly collected in the grate furnace fly ash. The concentrations of various components in the fly ash fluctuated but were not significant under different time dimensions. Risk assessment indicated that heavy metals such as Cd, Pb, and Sb posed a high risk. This study is expected to provide theoretical support for the safe management and resource utilization of fly ash. Full article

This study evaluated the productivity, nutritional composition, amino acid profile, fatty acid profile and presence of Salmonella spp. of housefly larva meal reared on domestic animal manure. A study was conducted to produce larva on three types of manure in a controlled environment located at 3200 mASL. Adult flies used as brood stock were reared in advance to avoid contamination with pathogenic germs and were fed sugar syrup and pasteurized milk to promote oviposition. Data were analyzed by ANOVA, the Kruskal–Wallis test and descriptive statistics, using confidence intervals. The results indicate that the type of organic substrate had an effect on the time of development, weight, size and percentage mortality of larva, being higher in a mixture of swine manure and poultry manure. Regarding nutritional composition, it was determined that larva meals contain 56.5% crude protein, 13.07% fat, 12.03% carbohydrates, 10.93% ash and 6.77% crude fiber. The most abundant fatty acids are palmitic acid with 29.34%, palmitoleic acid with 21.65% and oleic acid with 26.53%. An adequate balance of amino acids was determined, highlighting among them the content of arginine and threonine within the essential amino acids. House fly larva meals contain an adequate balance of nutrients and can be used as an ingredient for animal feed formulation. However, their use in animals should be further evaluated in future studies to assess their viability, absorption, bioavailability, and potential allergic reactions. Full article

To address the practical limitations of conventional alkaline activators (e.g., handling hazards, cost) and promote the resource utilization of industrial solid wastes, this study developed a novel all-solid-waste activator system comprising soda residue (SR) and carbide slag (CS). The synergistic effects of SR-CS activators on the hydration behavior of blast furnace slag (GGBS)–fly ash (FA) cementitious composites were systematically investigated. Mechanical performance, phase evolution, and microstructural development were analyzed through compressive strength tests, XRD, FTIR, TG-DTG, and SEM-EDS. Results demonstrate that in the SR-CS activator system, which combines with desulfuriation gypsum as sulfate activator, increasing CS content elevates the normal consistency water demand due to the high-polarity, low-solubility Ca(OH)₂ in CS. The SR-CS activator accelerates the early hydration process of cementitious materials, shortening the paste setting time while achieving compressive strengths of 17 MPa at 7 days and 32.4 MPa at 28 days, respectively. Higher fly ash content reduced strength owing to increased unreacted particles and prolonged setting. Conversely, desulfurization gypsum exhibited a sulfate activation effect, with compressive strength peaking at 34.2 MPa with 4 wt% gypsum. Chloride immobilization by C-S-H gel was confirmed, effectively mitigating environmental risks associated with SR. This work establishes a sustainable pathway for developing low-carbon cementitious materials using multi-source solid wastes. Full article

This study investigates the emission characteristics and environmental impacts of pollutants from bagasse-fired biomass boilers through the integrated field monitoring of two sugarcane processing plants in Guangxi, China. Comprehensive analyses of flue gas components, including PM_2.5, NOx, CO, heavy metals, VOCs, HCl, and HF, revealed distinct physicochemical and emission profiles. Bagasse exhibited lower C, H, and S content but higher moisture (47~53%) and O (24~30%) levels compared to coal, reducing the calorific values (8.93~11.89 MJ/kg). Particulate matter removal efficiency exceeded 98% (water film dust collector) and 95% (bag filter), while NOx removal varied (10~56%) due to water solubility differences. Heavy metals (Cu, Cr, Ni, Pb) in fuel migrated to fly ash and flue gas, with Hg and Mn showing notable volatility. VOC speciation identified oxygenated compounds (OVOCs, 87%) as dominant in small boilers, while aromatics (60%) and alkenes (34%) prevailed in larger systems. Ozone formation potential (OFP: 3.34~4.39 mg/m³) and secondary organic aerosol formation potential (SOAFP: 0.33~1.9 mg/m³) highlighted aromatic hydrocarbons (e.g., benzene, xylene) as critical contributors to secondary pollution. Despite compliance with current emission standards (e.g., PM < 20 mg/m³), elevated CO (>1000 mg/m³) in large boilers indicated incomplete combustion. This work underscores the necessity of tailored control strategies for OVOCs, aromatics, and heavy metals, advocating for stricter fuel quality and clear emission standards to align biomass energy utilization with environmental sustainability goals. Full article

To reduce the cost of coal mine filling materials, a novel composite cementitious material was developed by utilizing coal-based solid waste materials, including fly ash, desulfurized gypsum, and carbide slag, along with cement and water as raw materials. Initially, a comprehensive analysis of the physical and chemical properties of each raw material was conducted. Subsequently, proportioning tests were systematically carried out using the single-variable method. During these tests, multiple crucial performance indicators were measured. Specifically, the fluidity and bleeding rate of the slurry were evaluated to assess its workability, while the compressive strength and chemically bound water content of the hardened sample were tested to determine its mechanical properties and hydration degree. Through in-depth analysis of the test results, the optimal formulation of the composite cementitious material was determined. In the basic group, the mass ratio of fly ash to desulfurized gypsum was set at 70:30. In the additional group, the carbide slag addition amount accounted for 20% of the total mass, the cement addition amount was 15%, and the water–cement ratio was fixed at 0.65. Under these optimal proportioning conditions, the composite cementitious material exhibited excellent performance: its fluidity ranged from 180 to 220 mm, the bleeding rate within 6 h was less than 5%, and the 28-day compressive strength reached 17.69 MPa. The newly developed composite cementitious material features good fluidity and high strength of the hardened sample, fully meeting the requirements for mine filling materials. Full article

To address the challenges of concrete construction in polar regions, this study investigates the feasibility of fabricating cement-based materials under severely low temperatures using electric-induced heating curing methods. Cement mortars incorporating fly ash (FA-CM), ground granulated blast furnace slag (GGBS-CM), and metakaolin (MK-CM) were cured at environmental temperatures of −20 °C, −40 °C, and −60 °C. The optimal carbon fiber (CF) contents were determined using the initial electric resistivity to ensure a consistent electric-induced heating curing process. The thermal profiles during curing were monitored, and mechanical strength development was systematically evaluated. Hydration characteristics were elucidated through thermogravimetric analysis (TG), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR) to identify phase compositions and reaction products. Results demonstrate that electric-induced heating effectively mitigates the adverse effect caused by the ultra-low temperature constraints, with distinct differences in the strength performance and hydration kinetics among supplementary cementitious materials. MK-CM exhibited superior early strength development with strength increasing rates above 10% compared to the Ref. specimen, which was attributed to the accelerated pozzolanic reactions. Microstructural analyses further verified the macroscopic strength test results that showed that electric-induced heating curing can effectively promote the performance development even under severely cold environments with a higher hydration degree and refined micro-pore structure. This work proposes a viable strategy for polar construction applications. Full article

Flotation was investigated to treat incineration fly ash with diesel, kerosene, TX-100, or SDS as a collector and methyl isobutyl carbinol (MIBC) or 2-Octyl alcohol as a frother. Fly ash was separated into light and residual materials. Comparison of yield, carbon and sulfur removal showed that kerosene and MIBC showed the best performance. The results revealed that flotation was a method that could simultaneously achieve the removal of organics and S-containing compounds. Specifically, approximately 7.63–9.45% of the total mass was collected as light material, which was enriched with organic carbon. Contents of organic carbon reached 14.35 wt%–14.56 wt% in the light materials from those of 2.74 wt%–3.52 wt% in the original fly ash. Elemental analysis further proved that sulfur was also accumulated in light material. Approximately 78.84–81.69% of the organic carbon and 80.47–82.66% of the sulfur were removed. Decarbonization was primarily achieved through the flotation of organic materials, while desulfurization resulted from both flotation and the dissolution of soluble salts. Furthermore, the contents of the chloride and heavy metals in the residual fly ash also decreased. Particle size analysis showed that flotation was effective in the removal of smaller particles, and those particles were also rich in heavy metals. Overall, by selecting the right collector and frother, flotation was also able to reduce the leaching toxicity of heavy metals. The residual fly ash was safe for further disposal. Organic carbon, sulfur and heavy metals were accumulated in the light materials, which accounted for less than 10% of the original mass. The portion of fly ash needing further treatment was therefore greatly reduced. Full article

This study investigates the influence of steel fiber content (0~3% by volume) on the workability and mechanical properties of ultra-high-performance concrete (UHPC) incorporating slag or fly ash. Although UHPC exhibits excellent strength and durability, its brittleness and high cost hinder broader applications. Steel fibers are known to improve mechanical performance and toughness, but their interaction with mineral admixtures remains underexplored. Flowability, compressive strength, flexural behavior, impact resistance, and microstructure were evaluated. Results show that increasing fiber content significantly reduces workability, with fly ash-based mixes showing better flowability than slag-based ones. Mechanical properties improved with higher fiber volume, and an optimal content of 2% achieved the best balance between workability and strength. Impact testing and stress–strain analysis revealed that steel fibers enhance energy absorption and toughness under dynamic loading. SEM observations at 3 days indicated initial bonding between the fibers and matrix, with minor microcracks, suggesting further strength development over time. This work offers a fresh understanding of the combined influence of steel fibers and mineral admixtures in UHPC and supports their effective application in durable and cost-efficient high-performance concrete design. Full article

The road construction sector urgently requires environmentally friendly, low-carbon, and high-performance base materials. Traditional materials exhibit issues of high energy consumption and carbon emissions, making it difficult for them to align with sustainable development requirements. While slag- and fly ash-based geopolymers demonstrate promising application potential in civil engineering, research on their application in road-stabilized soils remains insufficient. To address the high energy consumption and carbon emissions associated with conventional road base materials and to fill this research gap, this study investigated the utilization of industrial solid wastes through slag-based geopolymer and fly ash as stabilizers, systematically evaluating the pavement performance of two distinct soil types. Unconfined compressive strength tests and freeze–thaw cycling tests were conducted to elucidate the effects of stabilizer dosage, fly ash co-stabilization, and compaction degree on mechanical properties. The results demonstrated that the compressive strength of both stabilized soils increased significantly with higher slag-based geopolymer content, achieving peak values of 5.2 MPa (soil sample 1) and 4.5 MPa (soil sample 2), representing a 30% improvement over cement-stabilized soils with identical mix proportions. Fly ash co-stabilization exhibited more pronounced reinforcement effects on soil sample 2. At a 98% compaction degree, soil sample 1 maintained a stable 50% strength enhancement, whereas soil sample 2 displayed a dose-dependent exponential strength increase. Freeze–thaw resistance tests revealed the superior performance of soil sample 1, showing a loss of compressive strength (BDR) of 78% with 8% geopolymer stabilization alone, which improved to 90% after fly ash co-stabilization. For soil sample 2, the BDR increased from 64% to 80% through composite stabilization. This study confirms that slag/fly ash-based geopolymer-stabilized soils not only meet the strength requirements for heavy-traffic subbases and light-traffic base courses, but also demonstrates its great potential as a low-carbon and environmentally friendly material to replace traditional road base materials. Full article

This paper presents the results of testing the insulation performance of geopolymers based on fly ashes with the addition of waste broken glass. The waste glass was dried and ground to a maximum of 1 mm grain size. The proportions of broken glass in the total binder’s mass were 0%, 10%, 20%, and 30%. Sodium hydroxide and sodium silicate were the activators of the alkaline reaction. The obtained geopolymer materials were characterised by determining the basic physico-mechanical properties. The chemical composition, density, and thermal conductivity coefficient were determined. The mechanical performance, including compressive and flexural strength, was investigated after 28 days of curing. The morphological analysis was also carried out using microphotographs obtained from optical and scanning microscopes. A significant effect of the waste glass on the tested geopolymers’ mechanical performance was observed. Proportions of 10% and 20% broken glass in the binder led to more than a four-fold increase in the compressive strength and a two-fold increase in the flexural strength compared to the geopolymer without the waste glass. All tested geopolymers had excellent insulation ability compared to the reference mortar (more than 80% higher than cement mortar). However, the problem is potential alkali–silica reaction, which can occur when the waste glass content is high. Full article

Despite the availability of various materials for chimney applications, ongoing research seeks alternatives with improved thermal and chemical resistance. Geopolymers are a promising solution, exhibiting exceptional resistance to high temperatures, fire, and aggressive chemicals. This study investigates fly ash-based lightweight geopolymer concretes that incorporate expanded clay aggregate (E.C.A.), perlite (P), and foamed geopolymer aggregate (F.G.A.). The composites were designed to ensure a density below 1200 kg/m³, reducing overall weight while maintaining necessary performance. Aggregate content ranged from 60 to 75 wt.%. Physical (density, thickness, water absorption), mechanical (flexural and compressive strength), and thermal (conductivity, resistance) properties were evaluated. F.G.A. 60 achieved a 76.8% reduction in thermal conductivity (0.1708 vs. 0.7366 W/(m·K)) and a 140.4% increase in thermal resistance (0.1642 vs. 0.0683). The F.G.A./E.C.A./P 60 mixture showed the highest compressive strength (18.069 MPa), reaching 52.7% of the reference concrete’s strength, with a 32.3% lower density (1173.3 vs. 1735.0 kg/m³). Water absorption ranged from 4.9% (REF.) to 7.3% (F.G.A. 60). All samples, except F.G.A. 70 and F.G.A. 75, endured heating up to 800 °C. The F.G.A./E.C.A./P 60 composite demonstrated well-balanced performance: low thermal conductivity (0.2052 W/(m·K)), thermal resistance up to 1000 °C, flexural strength of 4.386 MPa, and compressive strength of 18.069 MPa. The results confirm that well-designed geopolymer lightweight concretes are suitable for chimney and flue pipe linings operating between 500 and 1000 °C and exposed to acidic condensates and aggressive chemicals. This study marks the initial phase of a broader project on geopolymer-based prefabricated chimney systems. Full article

Conventional controlled low-strength material (CLSM) is a self-consolidating cementitious material with high flowability and low strength, traditionally composed of cement, sand, and water. This study explores the sustainable utilization of off-specification fly ash (OSFA) and bottom ash (BA), classified as industrial by-products with potential environmental hazards, to develop eco-friendly geopolymer CLSM as an alternative to conventional CLSM. Sodium hydroxide (NaOH) was used as an alkali activator to stabilize and solidify both two-part (liquid NaOH) and one-part (solid NaOH pellets) geopolymer CLSM mixtures. These mixtures were evaluated based on flowability (ASTM D6103-17) and compressive strength (<300 psi per ACI Committee 229 guidelines for excavatability). A cost analysis was also conducted. The results demonstrated that incorporating OSFA as a cement replacement increased water demand by 15% to meet flowability requirements, while BA substitution for sand led to segregation challenges requiring mixture adjustments. For two-part mixtures, higher carbon content in OSFA necessitated an increased water-to-fly ash ratio. All self-consolidating mixtures exhibited 1-day compressive strengths ranging from 5 psi (0.03 MPa) to 87 psi (0.6 MPa). One-part mixtures showed a 1% to 34% reduction in 7-day compressive strength compared to two-part mixtures, improving excavatability. Increasing the BA-to-OSFA ratio from 1:1 to 3:1 reduced water demand due to lower surface area but increased the NaOH/OSFA ratio. This study highlights the potential of geopolymer CLSM to reduce costs by up to 94% at current NaOH prices (USD 6 per cubic yard) while repurposing hazardous industrial by-products, offering a cost-efficient, sustainable, and environmentally responsible solution for CLSM production. Full article

The concrete industry increasingly seeks sustainable alternatives to conventional materials to reduce the environmental impact while maintaining structural performance. This study evaluates the use of locally sourced rhyolite as a coarse aggregate combined with recycled supplementary cementitious materials (SCMs) to address the sustainability and durability. Due to its high silica content, rhyolite is prone to the alkali–silica reaction (ASR), which may affect concrete durability. Concrete mixtures incorporating rhyolite with silica fume (SF), Class F fly ash (FA), and slag cement (SC) were tested for compressive strength, porosity, density, absorption, mortar bar expansion, electrical resistivity, and rapid chloride permeability. All rhyolite-based mixtures—regardless of SCM incorporation—achieved higher 90-day compressive strengths than the conventional control mixture, with 10% SF reaching the highest value. Additionally, each recycled SCM effectively reduced ASR-induced expansion, with 20% FA showing the most significant reduction and superior durability, including the greatest decrease in chloride permeability and the highest electrical resistivity, indicating enhanced corrosion resistance. These results confirm that rhyolite aggregates, when combined with SCMs, can improve durability and reduce ASR. Therefore, rhyolite shows potential for use in structural concrete under standard exposure conditions. This strategy supports circular economy goals by incorporating regional and recycled materials to develop concrete with improved durability characteristics. Full article