Search Results (46)

This paper develops a novel entropy-based framework to quantify tail risk and detect speculative bubbles in financial markets. By integrating extreme value theory with information theory, I introduce the Tail-Weighted Entropy (TWE) measure, which captures how information scales with extremeness in asset price distributions. I derive explicit bounds for TWE under heavy-tailed models and establish its connection to tail index parameters, revealing a phase transition in entropy decay rates during bubble formation. Empirically, I demonstrate that TWE-based signals detect crises in equities, commodities, and cryptocurrencies days earlier than traditional variance-ratio tests, with Bitcoin’s 2021 collapse identified weeks prior to the peak. The results show that entropy decay—not volatility explosions—serves as the primary precursor to systemic risk, offering policymakers a robust tool for preemptive crisis management. Full article

Atmospheric responses to earthquakes or volcanic eruptions have become an interesting topic and can potentially contribute to future forecasting of these events. Extensive anomalies of the total electron content (TEC) are most often linked with geomagnetic storms or Earth-dependent phenomena, like earthquakes, volcanic eruptions, or nuclear explosions. This study extends rarely discussed, but very frequent, interactions between tectonic plate boundaries and the ionosphere. Our investigations focus on the very frequent occurrence of TEC enhancements not exclusively linked with individual seismic phenomena but located over tectonic plate boundaries. The objective of this study is to provide a review of the global spatiotemporal distribution of TEC anomalies, facilitating the discussion of their potential relations with tectonic activity. We apply a Kriging-based UPC-IonSAT quarter-of-an-hour time resolution rapid global ionospheric map (UQRG) from the Polytechnic University of Catalonia (UPC) IonSAT group for the detection of relative vertical TEC (VTEC) changes. Our study describes global relative and normalized VTEC variations, which have spatial and temporal behaviours strongly indicating their relationship both with geomagnetic changes and the tectonic plate system. The variations in geomagnetic fields, including the storms, disturb the ionosphere and amplify TEC variations persisting for several hours over tectonic plate boundaries, mostly over the diverging ones. The seismic origin of the selected parts of these TEC enhancements and depletions and their link with tectonic plate edges are suspected from their duration, shape, and location. The changes in TEC originating from both sources can be observed separately or together, and therefore, there is an open question about the directions of the energy transfers. However, the importance of geomagnetic field lines seems to be probable, due to the frequent common occurrence of both types of TEC anomalies. This research also proves that permanent observation of global lithosphere–atmosphere–ionosphere coupling (LAIC) is also important in time periods without strong earthquake or volcanic events. The occurrence of TEC variations over diverging tectonic plate boundaries, sometimes combined with travelling anomalies of geomagnetic origin, can add to the studies on earthquake precursors and forecasting. Full article

Nitrogen-rich heterocycles constitute a family of high energy density materials (HEDMs) that have been developing intensively in recent years. A representative of this class is 1,2,4,5-tetrazine, a six-membered aromatic compound containing four nitrogen atoms in the ring. Many energetic compounds with this scaffold exhibit thermal stability, high density, and insensitivity to various stimuli, including friction, impact, and electrostatic discharge. This review presents methods for constructing 1,2,4,5-tetrazine precursors from acyclic reagents and describes their chemical modifications, leading to new energetic compounds with potential applications in the industry as explosives, propellants, or pyrotechnics. Synthetic procedures and reaction conditions are discussed, along with the detonation parameters of new nitrogen-rich tetrazine-based products, which allow estimation of their application potential. Full article

The results of a comprehensive investigation into the structure and properties of nanodiamond soot (NDS), obtained from the detonation of various explosive precursors (trinitrotoluene, a trinitrotoluene/hexogen mixture, and tetryl), are presented. The colloidal behavior of the NDS particles in different liquid media was studied. The results of the scanning electron microscopy, dynamic light scattering, zeta potential measurements, and laser diffraction analysis suggested a similarity in the morphology of the NDS particle aggregates and agglomerates. The phase composition of the NDS nanoparticles was studied using X-ray diffraction, Raman spectroscopy, electron diffraction, transmission electron microscopy, atomic force microscopy, and scanning tunneling microscopy. The NDS particles were found to comprise both diamond and graphite phases. The ratio of diamond to graphite phase content varied depending on the NDS explosive precursor, while the graphite phase content had a significant impact on the electrical conductivity of NDS. The study of the mechanical and tribological characteristics of polymer nanocomposites, modified with the selected NDS particles, indicated that NDS of various types can serve as a viable set of model nanofillers. Full article

Preparing copper-based azide by in situ reaction is well-suited for MEMS processing technology and holds promising prospects in the field of MEMS micro-initiators. This study involved the preparation of porous copper with particle sizes of approximately 30 nm, 60 nm and 100 nm through powder sintering. These were used as precursors for a gas–solid in situ azide reaction to produce copper-based azide with varying morphologies and compositions. Copper-based azide micro-initiators were designed, and their output performance was evaluated using CL-20 and HNS-IV explosives. Analytical results revealed that the product from the reaction of the 100 nm precursor exhibited a lumpy and uneven structure with a conversion rate of 90.36%. The product from the 60 nm precursor reaction had a dense surface with a conversion rate of 94.56%, while the 30 nm precursor resulted in a needle-like form with a conversion rate of 92.82%. Detonation experiments demonstrated that the copper-based azide micro-initiators prepared with 100 nm of a porous copper precursor exhibited unstable output performance, requiring a 1.6 mg charge to successfully detonate CL-20 explosives. On the other hand, copper-based azide micro-initiators prepared from 60 nm and 30 nm of porous copper precursors exhibited stable output performance. A charge of 0.8 mg was adequate for reliably and consistently detonating CL-20 and HNS-IV explosives. The reduced particle size of the precursor enhanced the output performance of the copper-based azide micro-initiators, providing increased energy redundancy during detonation and improving overall usage reliability. Full article

Raman spectroscopy is a type of inelastic scattering that provides rich information about a substance based on the coupling of the energy levels of their vibrational and rotational modes with an incident light. It has been applied extensively in many fields. As there is an increasing need for the remote detection of chemicals in planetary exploration and anti-terrorism, it is urgent to develop a compact, easily transportable, and fully automated remote Raman detection system for trace detection and identification of information, with high-level confidence about the target’s composition and conformation in real-time and for real field scenarios. Here, we present an unmanned vehicle-based remote Raman system, which includes a 266 nm air-cooling passive Q-switched nanosecond pulsed laser of high-repetition frequency, a gated ICMOS, and an unmanned vehicle. This system provides good spectral signals from remote distances ranging from 3 m to 10 m for simulating realistic scenarios, such as aluminum plate, woodblock, paperboard, black cloth, and leaves, and even for detected amounts as low as 0.1 mg. Furthermore, a convolutional neural network (CNN)-based algorithm is implemented and packaged into the recognition software to achieve faster and more accurate detection and identification. This prototype offers a proof-of-concept for an unmanned vehicle with accurate remote substance detection in real-time, which can be helpful for remote detection and identification of hazardous gas, explosives, their precursors, and so forth. Full article

Among the many commonly encountered hazards, improvised explosive devices (IEDs) remain the primary threat to military and civilian personnel due to the ease of their production and the widespread availability of their raw materials and precursors. Identifying traces of potential precursors is the first step in developing appropriate control measures. An interesting approach is to identify the precursors that are released around the site as they are handled and transformed into the final IEDs. CO₂ laser photoacoustic spectroscopy can offer the spectral characterization of a number of explosives-related compounds without sample preparation. Benzene, toluene, acetone, and ethylene glycol absorption spectra were determined in the IR region between 9.2 and 10.8 µm. Each substance emitted a unique photoacoustic response corresponding to its chemical composition that could be further used to identify the explosive material. Full article

The formation behavior of coated reactive explosively formed projectiles (EFP) is studied by the combination of experiments and simulations. The results show that the coated EFP can be obtained by explosively crushing the double-layer liners, and the simulation agrees with the experiment well. Then, the interaction process between the two liners is discussed in detail, and the formation and coating mechanism are revealed. It can be found that there are three phases in the formation process, including the impact, closing and stretching phases. During the impact phase, the velocities of two liners rise in turns with the kinetic energy exchange. In the closing phase, the copper liner is collapsed forward to the axis and completely coats the reactive liner. It is mentioned that the edge of the copper liner begins to form a metal precursor penetrator in this stage. During the stretching phase, the coated reactive EFP is further stretched and fractured, resulting in the separation of the metal precursor penetrator and the following coated reactive projectile. Further studies show both the edge thickness and the curvature radius of the copper liner have significant influences on formation behaviors. By decreasing the edge thickness or the curvature radius, the difficulty of closing decreases, but the tip velocity and the length of precursor penetrator increases. As the thickness and diameter of the reactive liner decrease, the coating velocity increases slightly, but the total length of coated reactive EFP tends to decrease. Full article

Aggregation-induced quenching (ACQ) is a hard problem in fluorescence material, leading to a poor utilization rate of fluorophores. In this work, 1,3,6,8-tetrakis(4-formylphenyl)pyrene (TFPPy) was synthesized and used as a precursor to build two kinds of fluorescence polymer. The TFFPy molecule with D2h symmetry can easily form polymers with C3 symmetry amines through the Schiff base reaction, making the resulting polymer a 3D amorphous material. Thus, ACQ of fluorophore can be reduced to minimum, making the most usage of the fluorescence of pyrene core. Fluorescence titration and DFT calculation can clearly prove this conclusion. The resulting CPs showed a highly sensitivity to picric acid, down to 3.43 ppm in solution, implying its potential in explosive detection. Full article

Ni(CO)₄, Cr(CO)₆, Co(CO)₃NO are some of the most common precursors used for focused electron beam induced deposition. Some of the compounds, even though extensively used have high requirements when it comes to handling being, explosives, highly flammable and with high toxicity levels, as is the case of Ni(CO)₄. We are employing simulations to determine values hard to determine experimentally, and compare them with DFT calculations and experimental data where available. The use of Quantemol-N cross section simulations for dissociative electron attachment (DEA) at low electron energy in the range of 0–20 eV, gives valuable information on the fragmentation of the molecules, based on their bond dissociation energies, electron affinities and incident electron energies. The values obtained for the cross sections are 0.12 × 10⁻¹⁸ cm² for Ni(CO)₄, 4.5 × 10⁻¹⁶ cm² for Co(CO)₃NO DEA cross-sections and 4.3 × 10⁻¹⁵ cm² for Cr(CO)₆. Full article

The development of carbon dots (CDs), either using green or chemical precursors, has inevitably led to their wide range application, from bioimaging to optoelectronic devices. The reported precursors and properties of these CDs have opened new opportunities for the future development of high-quality CDs and applications. Green precursors were classified into fruits, vegetables, flowers, leaves, seeds, stem, crop residues, fungi/bacteria species, and waste products, while the chemical precursors were classified into acid reagents and non-acid reagents. This paper quickly reviews ten years of the synthesis of CDs using green and chemical precursors. The application of CDs as sensing materials in optical sensor techniques for environmental monitoring, including the detection of heavy metal ions, phenol, pesticides, and nitroaromatic explosives, was also discussed in this review. This profound review will offer knowledge for the upcoming community of researchers interested in synthesizing high-quality CDs for various applications. Full article

In order to explore the mechanism of haze formation, the meteorological effect and chemical reaction process of the explosive growth (EG) of PM_2.5 were studied. In this study, the level of PM_2.5, water-soluble inorganic ions, carbonaceous aerosols, gaseous precursors, and meteorological factors were analyzed in Shanghai in 2018. The EG event is defined by a net increase of PM_2.5 mass concentration greater than or equal to 100 μg m⁻³ within 3, 6, or 9 h. The results showed that the annual average PM_2.5 concentration in Shanghai in 2018 was 43.2 μg m⁻³, and secondary inorganic aerosols and organic matter (OM) accounted for 55.8% and 20.1% of PM_2.5, respectively. The increase and decrease in the contributions of sulfate, nitrate, ammonium (SNA), and elemental carbon (EC) to PM_2.5 from clean days to EG, respectively, indicated a strong, secondary transformation during EG. Three EG episodes (Ep) were studied in detail, and the PM_2.5 concentration in Ep3 was highest (135.7 μg m⁻³), followed by Ep2 (129.6 μg m⁻³), and Ep1 (82.3 μg m⁻³). The EG was driven by stagnant conditions and chemical reactions (heterogeneous and gas-phase oxidation reactions). This study improves our understanding of the mechanism of haze pollution and provides a scientific basis for air pollution control in Shanghai. Full article

High-energy ball milling (HEBM) of powders is a complex process involving mixing, morphology changes, generation and evolution of defects of the crystalline lattice, and formation of new phases. This review is dedicated to the memory of our colleague, Prof. Michail A. Korchagin (1946–2021), and aims to highlight his works on the synthesis of materials by self-propagating high-temperature synthesis (SHS) and thermal explosion (TE) in HEBM mixtures as important contributions to the development of powder technology. We review results obtained by our group, including those obtained in collaboration with other researchers. We show the applicability of the HEBM mixtures for the synthesis of powder products and the fabrication of bulk materials and coatings. HEBM influences the parameters of synthesis as well as the structure, phase composition, phase distribution (in composites), and grain size of the products. The microstructural features of the products of synthesis conducted using the HEBM precursors are dramatically different from those of the products formed from non-milled mixtures. HEBM powders are also suitable as feedstock materials for depositing coatings by thermal spraying. The emerging applications of HEBM powders and future research directions in this area are discussed. Full article

Scholars from around the world have been attempting to simplify and cheapen the synthetic method for the promising high-energy compound CL-20 for decades. The lack of understanding of the formation mechanisms of hexaazaisowurtzitane derivatives―CL-20 precursors―is a barrier to solving the said problems. Here, we report the results from an in-depth study into the acid-catalyzed condensation between benzamide and glyoxal in a molar ratio of 2:1 in polar protic and aprotic solvents. Sixteen compounds were isolated and identified, of which eight were synthesized for the first time. A geminal diol, N,N’-(2,2-dihydroxyethane-1,1-diyl)dibenzamide, was synthesized. Two isomers of 1,2-bis(benzoylamino)-1,2-ethanediol were isolated and identified. N,N’-(1-oxoethane-1,2-diyl)dibenzamide and 2-oxo-2-[(phenylcarbonyl)amino]ethyl benzoate were produced that were likely formed due to the 1,2-hydride shift. N-polysubstituted 1,4-dioxane-2,3,5,6-tetramine was synthesized for the first time, whose structure may be of interest as a scaffold for new explosives. DMSO, THF and HCOOH were found to be able to engage in a reaction with benzamide, or condensation products thereof, and glyoxal under acid-catalyzed conditions. Full article

In this paper, we discuss the hypothesis on the volcanic origin of the precursor sediments for a thick (0.6 m) clay bed, hosted by the sequence of lithothamnium limestones of the Pińczów Formation. Combined X-ray powder diffraction, imaging methods (optical and electron microscopy), and chemical analysis were used to document the volcanic markers, which were preserved in the rock studied. The results obtained show that the clay bed discussed is bentonite in origin. This bentonite, which can be called Drugnia Rządowa bentonite, is composed almost entirely of montmorillonite with little admixtures of quartz and biotite. A small amount of calcite is present, but only in the top of the bed. Despite that, the bentonite contains nothing but clay material—it is a model example of entirely altered pyroclastic rock, which retains texture originally developed in volcanic glass fragments and reveals the preserved original features of the precursor fallout pyroclastic deposits (rhyolitic in character). The thick bentonite beds, discovered for the first time within the Badenian lithothamnium limestones of the Pińczów Formation, can be considered as a record of a violent, explosive volcanic event related to the closure of the Outer Carpathian basin and the development of the Carpathian Foredeep. Full article