Search Results (277)

CO₂ transport is a crucial part of CCUS. Nonetheless, due to the physical property differences between CO₂ and natural gas and oil, CO₂ pipeline transport is distinct from natural gas and oil transport. Gaseous CO₂ transportation has become the preferred scheme for transporting impurity-containing CO₂ tail gas in purification plants due to its advantages of simple technology, low cost, and high safety, which are well suited to the scenarios of low transportation volume and short distance in purification plants. The research on its physical property and state parameters is precisely aimed at optimizing the process design of gaseous transportation so as to further improve transportation efficiency and safety. Therefore, it has important engineering practical significance. Firstly, this paper collected and analyzed the research cases of CO₂ transport both domestically and internationally, revealing that phase state and physical property testing of CO₂ gas containing impurities is the basic condition for studying CO₂ transport. Subsequently, the exhaust gas captured by the purification plant was captured after hydrodesulfurization treatment, and the characteristics of the exhaust gas components were obtained by comparing before and after treatment. By preparing fluid samples with varied CO₂ content and conducting the flash evaporation test and PV relationship test, the compression factor and density of natural gas under different temperatures and pressures were obtained. It is concluded that under the same pressure in general, the higher the CO₂ content, the smaller the compression factor. Except for pure CO_2, the higher the CO₂ content, the higher the density under constant pressure, which is related to the content of C₂ and heavier hydrocarbon components. At the same temperature, the higher the CO₂ content, the higher the viscosity under the same pressure; the lower the pressure, the slower the viscosity growth slows down. The higher the CO₂ content at the same temperature, the higher the specific heat at constant pressure. With the decrease in temperature, the CO₂ content reaching the highest specific heat at the identical pressure gradually decreases. Finally, BWRS, PR, and SRK equations of state were utilized to calculate the compression factor and density of the gas mixture with a molar composition of 50% CO₂ and the gas mixture with a molar composition of 100% CO₂. Compared with the experimental results, the most suitable equation of state is selected as the PR equation, which refers to the parameter setting of critical nodes of CO₂ gas transport. Full article

Current treatment methods for desulfurization wastewater in the ship exhaust gas cleaning (EGC) system face several problems, including process complexity, unstable performance, large spatial requirements, and high energy consumption. This study investigates rotating dynamic filtration (RDF) as an efficient treatment approach through experimental testing, theoretical analysis, and pilot-scale validation. Flux increases with temperature and pressure but decreases with feed concentration, remaining unaffected by circulation flow. For a small membrane (152 mm), flux consistently increases with rotational speed across all pressures. For a large membrane (374 mm), flux increases with rotational speed at 300 kPa but firstly increases and then decreases at 100 kPa. Filtrate turbidity in all experiments complies with regulatory standards. Due to the unique hydrodynamic characteristics of RDF, back pressure reduces the effective transmembrane pressure, whereas shear force mitigates concentration polarization and cake layer formation. Separation performance is governed by the balance between these two forces. The specific energy consumption of RDF is only 10–30% that of cross-flow filtration (CFF). Under optimized pilot-scale conditions, the wastewater was concentrated 30-fold, with filtrate turbidity consistently below 2 NTU, outperforming CFF. Moreover, continuous operation proves more suitable for marine environments. Full article

The increasing levels of ozone pollution have become a significant environmental issue in urban areas worldwide. Previous studies have confirmed that the urban ozone pollution in China is mainly controlled by volatile organic compounds (VOCs) rather than nitrogen oxides. Therefore, a study on the emission characteristics and source analysis of VOCs is important for controlling urban ozone pollution. In this study, hourly concentrations of 57 VOC species in four groups were obtained in April 2022, a period of high ozone pollution in Kunming, China. The ozone formation potential analysis showed that the accumulated reactive VOCs significantly contributed to the subsequent ozone formation, particularly aromatics (44.16%) and alkanes (32.46%). In addition, the ozone production rate in Kunming is mainly controlled by VOCs based on the results of the empirical kinetic modeling approach (K_NOx/K_VOCs = 0.25). The hybrid single-particle Lagrangian integrated trajectory model and polar coordinate diagram showed high VOC and ozone concentrations from the southwest outside the province (50.28%) and the south in local areas (12.78%). Six factors were obtained from the positive matrix factorization model: vehicle exhaust (31.80%), liquefied petroleum gas usage (24.16%), the petrochemical industry (17.81%), fuel evaporation (11.79%), coal burning (7.47%), and solvent usage (6.97%). These findings underscore that reducing anthropogenic VOC emissions and strengthening controls on the related sources could provide a scientifically robust strategy for mitigating ozone pollution in Kunming. Full article

Researchers have tended to blend isopropanol (IPA) with other fuels in diesel engines to reduce emissions and improve performance. However, low-reactivity controlled compression ignition via port injection at a low cetane number results in a well-mixed charge of low-reactivity fuel, air, and recirculated exhaust gas (EGR). This study’s novel approach combines critical elements, such as the mass fraction of port-injected IPA, EGR ratio, and charge temperature, to improve combustion characteristics and lessen emissions from a diesel engine. The results demonstrated that the injection of IPA and the installation of EGR at the inlet reduced NO_x, smoke, and PM_2.5. On the contrary, HC and CO increased with the port-injection of IPA and EGR. Preheating air at the inlet can suppress the emissions of HC and CO. Under 1500 rpm and 60% load, when compared to diesel at the same EGR ratio and charge temperature, the maximum smoke decrease rate (26%) and PM_2.5 decrease rate (21%) occur at 35% IPA, 45 °C, and 10% EGR, while the maximum NO_x decrease rate (24%) occurs at 35% IPA, 60 °C, and 20% EGR. These findings support the novelty of the research. Conversely, it modestly increased CO and HC emissions. However, port-injecting IPA increased thermal efficiency by up to 24% at 60 °C, 1500 rpm, and 60% load with EGR. Full article

At present, there is a lack of in-depth knowledge of the effects of heavy metal-related industries (HMIs) in China on the environment. Hunan Province, as a representative gathering place of HMIs, is among the regions in China that are the most severely polluted with heavy metals. This paper selected Hunan Province as the study area to analyze the development trend, characteristics of pollution emissions, and environmental impacts of seven HMIs based on emission permit information data from Hunan Province. The results of this study show that (1) from 2000 to 2022, the number of heavy metal-related enterprises in Hunan Province increased overall. Among the seven industries, the chemical product manufacturing industry (CPMI) had the largest number of enterprises, whereas the nonferrous metal smelting and rolling industry (NSRI) had the highest gross industrial product (27.6%). (2) HMIs in Hunan Province had significant emissions of cadmium (Cd), arsenic (As), and hydargyrum (Hg) from exhaust gas and wastewater. Heavy metal-related exhaust gas and wastewater outlets from the NSRI constituted 43.9% and 35.3%, respectively, of all outlets of the corresponding type. The proportions of exhaust gas outlets involving Cd, Hg, and As from the NSRI to total exhaust gas outlets were 44.27%, 60.54%, and 34.23%, respectively. The proportions of wastewater outlets involving Cd, Hg, and As from the NSRI to total wastewater outlets were 61.13%, 57.89%, and 75.30%, respectively. (3) The average distances of heavy metal-related enterprises from arable land, rivers, and flooded areas in Hunan Province were 256 m, 1763 m, and 3352 m, respectively. Counties with high environmental risk (H-L type) were situated mainly in eastern Hunan. Among them, Chenzhou had the most heavy metal-related wastewater outlets (22.7%), and Hengyang had the most heavy metal-related exhaust gas outlets (23.1%). The results provide a scientific basis for the prevention and control of heavy metal pollution and an enhancement in environmental sustainability in typical Chinese areas where HMIs are concentrated. Full article

To address severe ammonia gas and dust pollution coupled with resource waste in exhaust gases from urea prilling towers, a production process for gasified biochar-based slow-release fertilizer is proposed to achieve resource recovery of exhaust pollutants. Through phosphoric acid impregnation modification applied to gasified biochar, its ammonia gas adsorption capacity was significantly enhanced, with saturated adsorption capacity increasing from 0.61 mg/g (unmodified) to 32 mg/g. Coupled with the tower-top bag filter, the modified biochar combines with ammonia gas and urea dust in exhaust gases, subsequently forming biochar-based slow-release fertilizer through dehydration and granulation processes. Material balance analysis demonstrates that a single 400,000-ton/year urea prilling tower achieves a daily fertilizer production capacity of 55 tons, with 18% active ingredient content. The nitrogen content can be upgraded to national standards through urea supplementation. Economic analysis demonstrates a total capital investment of USD1.2 million, with an annual net profit of USD0.88 million and a static payback period of 1.36 years. This process not only achieves ammonia gas emission reduction but also converts waste biochar into high-value fertilizer. It displays dual advantages of environmental benefits and economic feasibility and provides an innovative solution for resource utilization of the exhaust gases from the urea prilling process. Full article

Highly over-mature marine shales are distributed worldwide with substantial resource potential, yet their pore structure characteristics and controlling mechanisms remain poorly understood, hindering accurate shale gas resource prediction and efficient development. This study focuses on the Cambrian Niutitang Formation shales in the Upper Yangtze region of South China. To decipher the multiscale pore network architecture and its genetic constraints, we employ scanning electron microscopy (SEM) pore extraction and fluid intrusion methods (CO₂ and N₂ adsorption, and high-pressure mercury intrusion porosimetry) to systematically characterize pore structures in these reservoirs. The results demonstrate that the shales exhibit high TOC contents (average 4.78%) and high thermal maturity (average Ro 3.64%). Three dominant pore types were identified: organic pores, intragranular pores, and intergranular pores. Organic pores are sparsely developed with diameters predominantly below 50 nm, displaying honeycomb, slit-like, or linear morphologies. Intragranular pores are primarily feldspar dissolution voids, while intergranular pores exhibit triangular or polygonal shapes with larger particle sizes. CO₂ adsorption isotherms (Type I) and low-temperature N₂ adsorption curves (H3-H4 hysteresis) indicate wedge-shaped and slit-like pores, with pore size distributions concentrated in the 0.5–50 nm range, showing strong heterogeneity. Pore structure shows weak correlations with TOC and quartz content but a strong correlation with feldspar abundance. This pattern arises from hydrocarbon generation exhaustion and graphitization-enhanced organic pore collapse under high compaction stress, which reduces pore preservation capacity. The aulacogen tectonic setting engenders proximal sediment provenance regimes that preferentially preserve labile minerals such as feldspars. This geological configuration establishes optimal diagenetic conditions for the subsequent development of meso- and macro-scale of dissolution pores. Our findings demonstrate that feldspar-rich shales, formed in a proximal depositional system with well-developed inorganic pores, serve as favorable reservoirs for the exploration of highly over-mature marine shale gas. Full article

With conventional fuels dwindling and emissions rising, there is a necessity to develop and assess innovative substitute fuel for compression ignition (CI) engines. This study investigates the potential of magnesium oxide (MgO) nanoparticles as a sustainable additive to enhance the performance and reduce emissions of used cooking oil (UCO) biodiesel–diesel blends in CI engines. MgO nanoparticles were biosynthesized using Citrus aurantium peel extract, offering an environmentally friendly production method. A single-cylinder CI engine was used to test the performance of diesel fuel (B0), a 20% biodiesel blend (B20), and B20 blends with 30 ppm (B20M30) and 60 ppm (B20M60) MgO nanoparticles. Engine performance parameters (brake thermal efficiency (BTE), brake-specific fuel consumption (BSFC), and exhaust gas temperature (EGT)) and emission characteristics (CO, NO_x, unburnt hydrocarbons (HCs), and smoke opacity) were measured. The B20M60 blend showed a 2.38% reduction in BSFC and a 3.38% increase in BTE compared to B20, with significant reductions in unburnt HC, CO, and smoke opacity. However, NO_x emissions increased by 6.57%. The green synthesis method enhances sustainability, offering a promising pathway for cleaner and more efficient CI engine operation using UCO biodiesel, demonstrating the effectiveness of MgO nanoparticles. Full article

Exhaust emissions from ships are significant threats to the environment and human health, necessitating effective control measures and treatment technologies. In response to the increasing stringency of emission regulations set by the International Maritime Organization (IMO) and national governments, the shipping industry must adopt advanced techniques to mitigate these emissions. The study focuses on the current status of exhaust pollution prevention and control on the Lijiang River and describes the latest progress in ship emission management. It summarizes the sources and hazards of nitrogen oxides (NO_X), sulfur oxides (SO_X), and particulate matter (PM) emitted from ships. The study introduces and compares several exhaust treatment key technologies for desulfurization, denitrification, and integrated desulfurization and denitrification to emphasize their principles, processes, and characteristics. It also demonstrates the future prospects for controlling exhaust gas pollution on inland ships and advocates for the development of integrated technologies that are efficient, space-saving, and cost-effective. The research aims to provide a valuable reference for inland ship exhaust pollution prevention and control. Full article

Enhancing the safety of pulverizing systems is crucial for ensuring safe operation in the power industry. In this study, the exhaust air transfer system of a 330 MW power unit was investigated through numerical simulations. The internal flow field, the temperature distribution, and the CO concentration in the primary airbox under five exhaust air transfer conditions were analyzed. Furthermore, the effects of varying hot air velocity and temperature on the low-velocity region and combustible gas accumulation were examined to determine optimal safety conditions. The results indicate that, among the five conditions, the 100% B exhaust air transfer leads to the largest low-velocity region, the highest average CO mass fraction, and the greatest deflagration risk, whereas the 75% A exhaust air transfer condition ensures higher safety. Increasing the hot air velocity from 1 m/s to 10 m/s improves flow characteristics and reduces volatile matter accumulation, with lower velocities associated with higher CO concentrations. In contrast, raising the hot air temperature from 560 K to 610 K has a smaller effect on the flow characteristics, although higher temperatures correspond to slightly increased CO levels. In practical operation, maintaining an A/B exhaust air ratio of 75%A/25%B or keeping the hot air velocity above 5 m/s and the hot air temperature below 580 K is most beneficial for the safe operation of the pulverizing system. Full article

The global shipping industry facilitates the movement of approximately 80% of goods across the world but accounts for nearly 3% of total greenhouse gas (GHG) emissions every year, and other pollutants. One challenge in reducing shipping emissions is understanding and quantifying emission characteristics. A detailed method for calculating shipping emissions should be applied when preparing exhaust gas inventory. This research focused on quantifying CO₂, NO_x, and SO_x emissions from tankers, containers, bulk carriers, and general cargo in the Republic of Korea using spatio-temporal analysis and maritime big data. Using the bottom-up approach, this study calculates vessel emissions from the ship engines while considering the fuel type and operation mode. It leveraged the Geographic Information System (GIS) to generate spatial distribution maps of vessel exhausts. The research revealed variability in emissions according to ship types, sizes, and operational modes. CO₂ emissions were dominant, totaling 10.5 million tons, NO_x 179,355.2 tons, and SO_x 32,505.1 tons. Tankers accounted for about 43.3%, containers 33.1%, bulk carriers 17.3%, and general cargo 6.3%. Further, emissions in hoteling and cruising were more significant than during maneuvering and reduced speed zones (RSZs). This study contributes to emission databases, providing a basis for the establishment of targeted emission control policies. Full article

Currently, there is a need for dynamic space missions based on small satellites. These missions can be supported by propulsion systems with thrust-vectoring capabilities. This capability can be realized based on electrodeless plasma thrusters (EPTs). EPTs stand out for their versatility, offering adjustable thrust characteristics and fewer components, making them ideal for small satellites. However, their efficiency remains below optimal levels, largely due to complexities in plasma acceleration. This research aims to better understand dominant acceleration mechanisms in EPTs by studying ion energy distribution function changes based on exhaust orifice diameter and power variations. The total power supplied to the thruster varies in the range of 24 to 40 W, and the exhaust diameter varies in the range from 6.5 to 10.5 mm. It was found that the ion velocity does not change as a function of the diameter of the exit aperture. This indicates the insignificance of the mechanism of the gas-dynamic acceleration of plasma in EPTs with a small form factor and supports recent views that the main contribution to the acceleration of particles in EPT is made by electromagnetic effects. The findings could help refine EPT designs, enhancing their overall effectiveness and reliability for future space missions. Full article

The growth of global trade has fueled a booming shipping industry, but high pollutant emissions from low-speed marine diesel engines have become a global concern. In this study, it is hypothesized that the combustion efficiency of biodiesel B10 in low-speed two-stroke diesel engines can be improved and pollutant emissions can be reduced by optimizing the exhaust gas recirculation (EGR) rate and injection time. This study systematically analyzed the effects of EGR rate (5%, 10%, and 20%) and injection time (0 °CA to 6 °CA delay) on combustion and emission characteristics using numerical simulation combined with experimental validation. The results showed that the in-cylinder combustion temperature and NOx emission decreased significantly with the increase in EGR rate, but the soot emission increased. Specifically, NOx emissions decreased by 35.13%, 59.95%, and 85.21% at EGR rates of 5%, 10%, and 15%, respectively, while soot emissions increased by 12.25%, 26.75%, and 58.18%, respectively. Delaying the injection time decreases the in-cylinder pressure and temperature peaks, decreasing NOx emissions but increasing soot emissions. Delaying the injection time from 2 °CA to 4 °CA and 6 °CA decreased NOx emission by 16.01% and 25.44%, while increasing soot emission by 4.98% and 11.64%, respectively. By combining numerical simulation and experimental validation, this study provides theoretical support for the combustion optimization of a low-speed two-stroke diesel engine when using biodiesel, and is of great significance for the green development of the shipping industry. Full article

Despite its higher density, viscosity, and lower calorific value, biodiesel has been explored as an alternative energy source to diesel fuel. This study investigated biodiesel produced from croton macrostachyus (CMS) seed, a non-edible feedstock. The research aimed to experimentally analyze cylinder pressure, heat release rate, and ignition delay, as well as engine performance and emission characteristics, at a constant speed of 2700 rpm under varying loads (0–80%) using diesel, B10, B15, B20, and B25 blended fuels. Among the tested blends, B25 exhibited superior performance, achieving the highest peak cylinder pressure (CP) of 58.21 bar and a maximum heat release rate (HRR) of 543.9 J/CA at 80% engine load. Conversely, B20 at 60% engine load, followed by B25 and pure diesel at 80% engine load, demonstrated the shortest ignition delay (ID) and the most advanced start of combustion (SoC). Compared to the biodiesel blends, pure diesel showed: a 5.5–14% increase in brake thermal efficiency (BTE), a 17–26% decrease in brake-specific fuel consumption (BSFC), and a 7–12% reduction in exhaust gas temperature (EGT). Regarding emissions, carbon monoxide (CO) and hydrocarbon (HC) emissions were lower for pure diesel, while carbon dioxide (CO₂) and nitrogen oxide (NOx) emissions were higher for biodiesel blends, attributed to their inherent oxygen content. In conclusion, CMS biodiesel displays promising characteristics, suggesting its potential suitability for use in internal combustion engines. Full article

Serpentine exhaust systems, known for their infrared and radar stealth capabilities, are becoming standard in flying wing aircraft. However, their design is constrained by the fuselage layout, causing potential offsets between the engine and nozzle exit axes. Developing a universal, high-performance serpentine nozzle design that accommodates various vertical and spanwise offsets (ΔZ, ΔY) presents a significant challenge. A series of ‘Preferred Nozzles’ and ‘Modest Nozzles’ were designed and numerically evaluated to assess the impact of these offsets on flow characteristics. Results show that the ‘Modest Nozzle’ exhibits a complex wave system and significant local losses in the constant-area extension section when subjected to ΔZ > 0.10D₀ (D₀ is the nozzle inlet diameter) or ΔY > 1.0D₀, leading to a rapid thrust coefficient decrease. Vertical offsets significantly affect the Preferred Nozzle’s aerodynamic performance. When ΔZ = −0.50D₀, a large vertical offset in the first ‘S’ section creates a recirculation zone, causing significant losses and reducing the thrust coefficient to around 0.96. When ΔZ ≥ −0.25D₀, gas flow and wall shear stress distributions transition smoothly. When ΔZ ≥ 0.10D₀, as the spanwise offset increases, the thrust coefficient experiences only a 0.17% loss and remains above 0.97. Full article