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23 pages, 6682 KiB  
Article
Study on Live Temperature Rise and Electrical Characteristics of Composite Insulators with Internal Conductive Defects
by Jianghai Geng, Zhongfeng He, Yuming Zhang, Hao Zhang, Zheng Zhong and Ping Wang
Coatings 2025, 15(8), 945; https://doi.org/10.3390/coatings15080945 - 13 Aug 2025
Viewed by 211
Abstract
Internal conductive defects in composite insulators severely degrade their insulation performance and are considered concealed defects, posing a significant threat to the safe and stable operation of the power grid. Focusing on this issue, this study develops an electro-thermal multi-physical field simulation model [...] Read more.
Internal conductive defects in composite insulators severely degrade their insulation performance and are considered concealed defects, posing a significant threat to the safe and stable operation of the power grid. Focusing on this issue, this study develops an electro-thermal multi-physical field simulation model and uses finite element analysis to investigate the electric field distribution and temperature rise characteristics. Composite insulator specimens with varying defect lengths were fabricated using the electrical erosion test. Charged tests were then conducted on these defective specimens, as well as on field-decommissioned specimens. The impact of internal conductive defects on the infrared, ultraviolet, and electric field distribution characteristics of composite insulators during operation was analyzed. The results indicate that the surface electric field of composite insulators with internal conductive defects becomes highly concentrated along the defect path, with a significant increase in electric field strength at the defect’s end. The maximum field strength migrates toward the grounded end as the defect length increases. Conductive defects lead to partial discharge and abnormal temperature rise at the defect’s end and the bending points of the composite insulator. The temperature rise predominantly manifests as “bar-form temperature rise,” with temperature rise regions correlating well with discharge areas. Conductive defects accelerate the decay-like degradation process of composite insulators through a positive feedback loop formed by the coupling of electric field distortion, Joule heating, material degradation, and discharge activity. This study identifies the key characteristics of electrical and temperature rise changes in insulators with conductive defects, reveals the deterioration evolution process and degradation mechanisms of insulators, and provides effective criteria for on-site diagnosis of conductive defects. Full article
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16 pages, 3635 KiB  
Article
Properties and Diffusion Plugging Mechanism of Modified Sodium Bentonite
by Sen Hu, Bo Tian, Kaimin Niu, Haowu Wang and Zhihao Li
Coatings 2025, 15(8), 941; https://doi.org/10.3390/coatings15080941 - 12 Aug 2025
Viewed by 190
Abstract
With rising global temperatures, roads in the permafrost regions of the Qinghai–Tibet Plateau are exhibiting issues such as subsidence, water accumulation alongside the roads and in their foundations, and ongoing permafrost degradation. Among these issues, water accumulation has emerged as a prominent challenge [...] Read more.
With rising global temperatures, roads in the permafrost regions of the Qinghai–Tibet Plateau are exhibiting issues such as subsidence, water accumulation alongside the roads and in their foundations, and ongoing permafrost degradation. Among these issues, water accumulation has emerged as a prominent challenge in road management. In this study, sodium-based-bentonite-modified cementitious waterproof grouting materials were prepared and utilized as functional barrier layers. The rheological properties, mechanical strength, flowability, and setting time of the materials were tested under different sodium bentonite dosages. The feasibility of the application of these materials was evaluated, accounting for the evolution of pressure, flow rate, and diffusion distance of permafrost subgrades over different time scales when the materials were applied as functional barrier layers. The results indicate that, when used as a functional barrier layer, the modified cement-based grouting material exhibits a fluidity that meets the upper limit of grouting requirements, with a controllable setting time. Both compressive strength and apparent viscosity rise with the addition of sodium-based bentonite (Na-bentonite). Notably, an appropriate viscosity range of 0.35–0.50 Pa·s was found to effectively resist groundwater erosion while satisfying the critical performance requirements for grouting applications, demonstrating excellent applicability. In the field grouting test, the effects of grouting pressure and flow rate over different time scales on soil cracking, spreading distance, and the crack-filling process were further analyzed. Based on these findings, a technical solution using a new type of subgrade treatment material (functional barrier layer) was proposed, providing a reference for related theoretical research and engineering practice. Full article
(This article belongs to the Section Environmental Aspects in Colloid and Interface Science)
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16 pages, 10759 KiB  
Article
Hydrodynamic and Climatic Effects on an Amazon Beach Under Unplanned Occupation: A Case Study
by Remo Luan Marinho da Costa Pereira, Luci Cajueiro Carneiro Pereira and Cesar Mosso
Coasts 2025, 5(3), 29; https://doi.org/10.3390/coasts5030029 - 8 Aug 2025
Viewed by 180
Abstract
This study aimed to evaluate how tidal modulation influences breaking waves on a macrotidal beach along the Amazonian coast under varying climatic conditions. The study utilized medium-term data (2006–2018) from national and international institutions and short-term data (2012–2014) from in situ measurements at [...] Read more.
This study aimed to evaluate how tidal modulation influences breaking waves on a macrotidal beach along the Amazonian coast under varying climatic conditions. The study utilized medium-term data (2006–2018) from national and international institutions and short-term data (2012–2014) from in situ measurements at Ajuruteua Beach. Offshore winds and waves, predominantly from the northeast, were influenced by severe storms associated with La Niña and El Niño events. During these periods, wave heights exceeded 5 m, with wave periods ranging from 12 to 20 s. Tidal fluctuations (typically 5.0–6.0 m) modulated nearshore wave heights and periods, with variations determined by offshore conditions and climatic influences. Wave heights decreased from 2–5 m offshore to 1–2 m nearshore. At low tide, sandbanks dissipated wave energy, resulting in significantly smaller breaking waves (0.1–0.5 m) compared with high tide (1–1.8 m). The northern part of Ajuruteua Beach experienced a progressive retreat, with a total area loss of 0.15 km2 and a shoreline retreat of 0.360 km between 2007 and 2021. The combination of high hydrodynamic energy and unregulated development led to the destruction of 43 buildings between 2007 and 2013 and an additional 44 houses between 2013 and 2021 within the intertidal zone. Moreover, the absence of coastal management strategies has exacerbated erosion, underscoring the urgent need for planning and regulatory frameworks. Based on the findings of this study, it is recommended that land use be regulated and both short- and long-term physical processes be systematically integrated into future coastal protection planning. Full article
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15 pages, 1835 KiB  
Article
Stress Development in Droplet Impact Analysis of Rain Erosion Damage on Wind Turbine Blades: A Review of Liquid-to-Solid Contact Conditions
by Quentin Laplace Oddo, Quaiyum M. Ansari, Fernando Sánchez, Leon Mishnaevsky and Trevor M. Young
Appl. Sci. 2025, 15(15), 8682; https://doi.org/10.3390/app15158682 - 6 Aug 2025
Viewed by 406
Abstract
The wind energy sector is experiencing substantial growth, with global wind turbine capacity increasing and projected to expand further in the coming years. However, rain erosion on the leading edges of turbine blades remains a significant challenge, affecting both aerodynamic efficiency and structural [...] Read more.
The wind energy sector is experiencing substantial growth, with global wind turbine capacity increasing and projected to expand further in the coming years. However, rain erosion on the leading edges of turbine blades remains a significant challenge, affecting both aerodynamic efficiency and structural longevity. The associated degradation reduces annual energy production and leads to high maintenance costs due to frequent inspections and repairs. To address this issue, researchers have developed numerical models to predict blade erosion caused by water droplet impacts. This study presents a finite element analysis model in Abaqus to simulate the interaction between a single water droplet and wind turbine blade material. The novelty of this model lies in evaluating the influence of several parameters on von Mises and S33 peak stresses in the leading-edge protection, such as friction coefficient, type of contact, impact velocity, and droplet diameter. The findings provide insights into optimising LEP numerical models to simulate rain erosion as closely as possible to real-world scenarios. Full article
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14 pages, 1015 KiB  
Article
Integrating Dimensional Analysis and Machine Learning for Predictive Maintenance of Francis Turbines in Sediment-Laden Flow
by Álvaro Ospina, Ever Herrera Ríos, Jaime Jaramillo, Camilo A. Franco, Esteban A. Taborda and Farid B. Cortes
Energies 2025, 18(15), 4023; https://doi.org/10.3390/en18154023 - 29 Jul 2025
Viewed by 327
Abstract
The efficiency decline of Francis turbines, a key component of hydroelectric power generation, presents a multifaceted challenge influenced by interconnected factors such as water quality, incidence angle, erosion, and runner wear. This paper is structured into two main sections to address these issues. [...] Read more.
The efficiency decline of Francis turbines, a key component of hydroelectric power generation, presents a multifaceted challenge influenced by interconnected factors such as water quality, incidence angle, erosion, and runner wear. This paper is structured into two main sections to address these issues. The first section applies the Buckingham π theorem to establish a dimensional analysis (DA) framework, providing insights into the relationships among the operational variables and their impact on turbine wear and efficiency loss. Dimensional analysis offers a theoretical basis for understanding the relationships among operational variables and efficiency within the scope of this study. This understanding, in turn, informs the selection and interpretation of features for machine learning (ML) models aimed at the predictive maintenance of the target variable and important features for the next stage. The second section analyzes an extensive dataset collected from a Francis turbine in Colombia, a country that is heavily reliant on hydroelectric power. The dataset consisted of 60,501 samples recorded over 15 days, offering a robust basis for assessing turbine behavior under real-world operating conditions. An exploratory data analysis (EDA) was conducted by integrating linear regression and a time-series analysis to investigate efficiency dynamics. Key variables, including power output, water flow rate, and operational time, were extracted and analyzed to identify patterns and correlations affecting turbine performance. This study seeks to develop a comprehensive understanding of the factors driving Francis turbine efficiency loss and to propose strategies for mitigating wear-induced performance degradation. The synergy lies in DA’s ability to reduce dimensionality and identify meaningful features, which enhances the ML models’ interpretability, while ML leverages these features to model non-linear and time-dependent patterns that DA alone cannot address. This integrated approach results in a linear regression model with a performance (R2-Test = 0.994) and a time series using ARIMA with a performance (R2-Test = 0.999) that allows for the identification of better generalization, demonstrating the power of combining physical principles with advanced data analysis. The preliminary findings provide valuable insights into the dynamic interplay of operational parameters, contributing to the optimization of turbine operation, efficiency enhancement, and lifespan extension. Ultimately, this study supports the sustainability and economic viability of hydroelectric power generation by advancing tools for predictive maintenance and performance optimization. Full article
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30 pages, 92065 KiB  
Article
A Picking Point Localization Method for Table Grapes Based on PGSS-YOLOv11s and Morphological Strategies
by Jin Lu, Zhongji Cao, Jin Wang, Zhao Wang, Jia Zhao and Minjie Zhang
Agriculture 2025, 15(15), 1622; https://doi.org/10.3390/agriculture15151622 - 26 Jul 2025
Viewed by 345
Abstract
During the automated picking of table grapes, the automatic recognition and segmentation of grape pedicels, along with the positioning of picking points, are vital components for all the following operations of the harvesting robot. In the actual scene of a grape plantation, however, [...] Read more.
During the automated picking of table grapes, the automatic recognition and segmentation of grape pedicels, along with the positioning of picking points, are vital components for all the following operations of the harvesting robot. In the actual scene of a grape plantation, however, it is extremely difficult to accurately and efficiently identify and segment grape pedicels and then reliably locate the picking points. This is attributable to the low distinguishability between grape pedicels and the surrounding environment such as branches, as well as the impacts of other conditions like weather, lighting, and occlusion, which are coupled with the requirements for model deployment on edge devices with limited computing resources. To address these issues, this study proposes a novel picking point localization method for table grapes based on an instance segmentation network called Progressive Global-Local Structure-Sensitive Segmentation (PGSS-YOLOv11s) and a simple combination strategy of morphological operators. More specifically, the network PGSS-YOLOv11s is composed of an original backbone of the YOLOv11s-seg, a spatial feature aggregation module (SFAM), an adaptive feature fusion module (AFFM), and a detail-enhanced convolutional shared detection head (DE-SCSH). And the PGSS-YOLOv11s have been trained with a new grape segmentation dataset called Grape-⊥, which includes 4455 grape pixel-level instances with the annotation of ⊥-shaped regions. After the PGSS-YOLOv11s segments the ⊥-shaped regions of grapes, some morphological operations such as erosion, dilation, and skeletonization are combined to effectively extract grape pedicels and locate picking points. Finally, several experiments have been conducted to confirm the validity, effectiveness, and superiority of the proposed method. Compared with the other state-of-the-art models, the main metrics F1 score and mask mAP@0.5 of the PGSS-YOLOv11s reached 94.6% and 95.2% on the Grape-⊥ dataset, as well as 85.4% and 90.0% on the Winegrape dataset. Multi-scenario tests indicated that the success rate of positioning the picking points reached up to 89.44%. In orchards, real-time tests on the edge device demonstrated the practical performance of our method. Nevertheless, for grapes with short pedicels or occluded pedicels, the designed morphological algorithm exhibited the loss of picking point calculations. In future work, we will enrich the grape dataset by collecting images under different lighting conditions, from various shooting angles, and including more grape varieties to improve the method’s generalization performance. Full article
(This article belongs to the Section Artificial Intelligence and Digital Agriculture)
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20 pages, 7090 KiB  
Article
The Influence of Hard Protection Structures on Shoreline Evolution in Riohacha, Colombia
by Marta Fernández-Hernández, Luis Iglesias, Jairo Escobar, José Joaquín Ortega, Jhonny Isaac Pérez-Montiel, Carlos Paredes and Ricardo Castedo
Appl. Sci. 2025, 15(14), 8119; https://doi.org/10.3390/app15148119 - 21 Jul 2025
Viewed by 713
Abstract
Over the past 50 years, coastal erosion has become an increasingly critical issue worldwide, and Colombia’s Caribbean coast is no exception. In urban areas, this challenge is further complicated by hard protection structures, which, while often implemented as immediate solutions, can disrupt sediment [...] Read more.
Over the past 50 years, coastal erosion has become an increasingly critical issue worldwide, and Colombia’s Caribbean coast is no exception. In urban areas, this challenge is further complicated by hard protection structures, which, while often implemented as immediate solutions, can disrupt sediment transport and trigger unintended long-term consequences. This study examines shoreline changes in Riohacha, the capital of La Guajira Department, over a 35-year period (1987–2022), focusing on the impacts of coastal protection structures—specifically, the construction of seven groins and a seawall between 2006 and 2009—on coastal dynamics. Using twelve images (photographs and satellite) and the Digital Shoreline Analysis System (DSAS), the evolution of both beaches and cliffs has been analyzed. The results reveal a dramatic shift in shoreline behavior: erosion rates of approximately 0.5 m/year prior to the interventions transitioned to accretion rates of up to 11 m/year within the groin field, where rapid infill occurred. However, this sediment retention has exacerbated erosion in downstream cliff areas, with retreat rates reaching 1.8 ± 0.2 m/year. To anticipate future coastal evolution, predictive models were applied through 2045, providing insights into potential risks for infrastructure and urban development. These findings highlight the need for a strategic, long-term approach to coastal management that considers both the benefits and unintended consequences of engineering interventions. Full article
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15 pages, 4363 KiB  
Article
Effect of Soft Rock Material Addition on Surface Charge Properties and Internal Force of Aeolian Sandy Soil Particles in the Maowusu Desert
by Zhe Liu, Yang Zhang, Yingying Sun, Yuliang Zhang, Na Wang, Feinan Hu, Yuhu Luo and Tingting Meng
Resources 2025, 14(7), 116; https://doi.org/10.3390/resources14070116 - 21 Jul 2025
Viewed by 377
Abstract
The Maowusu Desert is still suffering from serious ecological and environmental security issues such as wind erosion and desertification, influenced by both natural and human factors. The amendment of aeolian sandy soil with soft rock material presents an effective erosion control strategy, leveraging [...] Read more.
The Maowusu Desert is still suffering from serious ecological and environmental security issues such as wind erosion and desertification, influenced by both natural and human factors. The amendment of aeolian sandy soil with soft rock material presents an effective erosion control strategy, leveraging the complementary structural and compositional properties of both materials to enhance soil stability and rehabilitate degraded environments. However, there are few studies that investigate the effect of soil surface electrochemical properties and particle interaction forces on the structural stability of compound soils with soft rock and sandy soil. This decade-long field study quantified the electrochemical properties and interparticle forces and their synergistic effects on structural stability across five soft rock-to-aeolian sandy soil blend volume ratios (0:1, 1:5, 1:2, 1:1, 1:0) within the 0–30 cm soil profile. The results showed that the soil organic matter (SOM), specific surface area (SSA), and cation exchange capacity (CEC) significantly increased with the incorporation of soft rock material. For five different proportions, with the addition of soft rock and the extension of planting years, the content of SOM increased from 5.65 g·kg−1 to 11.36 g·kg−1, the CEC varied from 4.68 cmol kg−1 to 17.91 cmol kg−1, while the σ0 importantly decreased from 1.8 to 0.47 c m−2 (p < 0.05). For the interaction force at 2.4 nm between soil particles, the absolute value of van der Waals attractive force increased from 0.10 atm to 0.38 atm, and the net force decreased from 0.09 atm to −0.30 atm after the incorporation ratios of soft rock from 0:1 to 1:1. There was a significant negative correlation between the resultant net force between the particles of compound soil and the SSA and CEC. These results indicate that the addition of soft rock material positively improves the surface electrochemical properties and internal forces between aeolian sandy soil particles, further enhancing its structural stability. This study establishes a foundational theoretical framework for advancing our mechanistic understanding of aeolian sand stabilization and ecosystem rehabilitation in the Mu Us Desert. Full article
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18 pages, 1777 KiB  
Review
Biochar in Agriculture: A Review on Sources, Production, and Composites Related to Soil Fertility, Crop Productivity, and Environmental Sustainability
by Md. Muzammal Hoque, Biplob Kumar Saha, Antonio Scopa and Marios Drosos
C 2025, 11(3), 50; https://doi.org/10.3390/c11030050 - 11 Jul 2025
Viewed by 1235
Abstract
Due to soil nutrient depletion and rising food demand from an increasing global population, it is essential to find sustainable ways to boost crop yields, improve soil health, and address the environmental issues induced by agriculture. The most appropriate approach is to consider [...] Read more.
Due to soil nutrient depletion and rising food demand from an increasing global population, it is essential to find sustainable ways to boost crop yields, improve soil health, and address the environmental issues induced by agriculture. The most appropriate approach is to consider sustainable amendments, such as biochar and its derivatives, which are vital constituents of soil health due to their affordability, low reactivity, large surface area, and reduced carbon footprint. In this context, biochar and its derivatives in farming systems focus on improving soil structure, nutrient holding capacity, microbial activities, and the perpetuation of soil fertility. Despite its benefits, biochar, if it is used in high concentration, can sometimes become highly toxic, causing soil erosion due to reducing surface area, increasing pH levels, and altering soil properties. This review highlights the production methods and sources of feedstocks, emphasizing their important contribution to the soil’s physicochemical and biological properties. Furthermore, it critically evaluates the environmental applications and their impacts, providing data built upon the literature on contaminant removal from soil, economic factors, heavy metal immobilization, carbon sequestration, and climate resilience. This review emphasizes the main challenges and future prospects for biochar use in comparison to modified biochar (MB) to propose the best practices for sustainable farming systems. Full article
(This article belongs to the Special Issue Carbons for Health and Environmental Protection (2nd Edition))
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12 pages, 232 KiB  
Review
Hypodiploidy: A Poor Prognostic Cytogenetic Marker in B-CLL
by Andrew Ruggero and Carlos A. Tirado
DNA 2025, 5(3), 32; https://doi.org/10.3390/dna5030032 - 1 Jul 2025
Viewed by 395
Abstract
In B-cell chronic lymphocytic leukemia (B-CLL), hypodiploidy is a rare but aggressive subtype of the disease with a very bad prognosis. Hypodiploidy, in contrast to normal B-CLL chromosomal aberrations, is marked by widespread genomic instability, which promotes treatment resistance and quick illness development. [...] Read more.
In B-cell chronic lymphocytic leukemia (B-CLL), hypodiploidy is a rare but aggressive subtype of the disease with a very bad prognosis. Hypodiploidy, in contrast to normal B-CLL chromosomal aberrations, is marked by widespread genomic instability, which promotes treatment resistance and quick illness development. Its persistence after treatment implies that chromosomal loss gives cancerous clones a selection edge, which is made worse by telomere malfunction and epigenetic changes. Since thorough genetic profiling has a major impact on patient outcomes, advanced diagnostic methods are crucial for early detection. Treatment approaches must advance beyond accepted practices because of its resistance to traditional medicines. Hematopoietic stem cell transplantation (HSCT) and chimeric antigen receptor (CAR) T-cell therapy are two potential new therapeutic modalities. Relapse and treatment-related morbidity continue to be limiting concerns, despite the noteworthy improvements in outcomes in high-risk CLL patients receiving HSCT. Although more research is required, CAR T-cell treatment is effective in treating recurrent B-ALL and may also be used to treat B-CLL with hypodiploidy. Novel approaches are essential for enhancing patient outcomes and redefining therapeutic success when hypodiploidy challenges established treatment paradigms. Hypodiploidy is an uncommon yet aggressive form of B-CLL that has a very bad prognosis. Hypodiploidy represents significant chromosomal loss and structural imbalance, which contributes to a disordered genomic environment, in contrast to more prevalent cytogenetic changes. This instability promotes resistance to certain new drugs as well as chemoimmunotherapy and speeds up clonal evolution. Its persistence after treatment implies that hypodiploid clones have benefits in survival, which are probably strengthened by chromosomal segregation issues and damaged DNA repair pathways. Malignant progression and treatment failure are further exacerbated by telomere erosion and epigenetic dysregulation. The need for more sensitive molecular diagnostics is highlighted by the fact that standard karyotyping frequently overlooks hypodiploid clones, particularly those concealed by endoreduplication, despite the fact that these complications make early and correct diagnosis crucial. Hypodiploidy requires a move toward individualized treatment because of their link to high-risk genetic traits and resistance to conventional regimens. Although treatments like hematopoietic stem cell transplantation and CAR T-cells show promise, long-term management is still elusive. To improve long-term results and avoid early relapse, addressing this cytogenetic population necessitates combining high-resolution genomic technologies with changing therapy approaches. Full article
20 pages, 17149 KiB  
Article
Assessment of Trail Erosion Under the Impact of Tourist Traffic in the Bucegi Mountains, Romanian Carpathians
by Mihai Radu Jula and Mircea Voiculescu
Environments 2025, 12(7), 223; https://doi.org/10.3390/environments12070223 - 28 Jun 2025
Viewed by 866
Abstract
Trail erosion is a global issue, particularly in mountainous regions, that is largely driven by increased tourist flows and uncontrolled trampling. Our study was conducted in the Bucegi Mountains, Southern Carpathians, Romania, along three of the most frequented hiking trails, each with varying [...] Read more.
Trail erosion is a global issue, particularly in mountainous regions, that is largely driven by increased tourist flows and uncontrolled trampling. Our study was conducted in the Bucegi Mountains, Southern Carpathians, Romania, along three of the most frequented hiking trails, each with varying levels of difficulty. Two of these trails cross both the forest and alpine zones, and the other crosses only the alpine zone: Jepii Mici, connecting the Bușteni resort (960 m a.s.l.) to Babele Chalet (2200 m a.s.l.); Jepii Mari, linking Bușteni resort to the National Sports Complex Piatra Arsă (1960 m a.s.l.); and the trail between Babele Chalet and Omu Peak (2505 m a.s.l.). Our analysis focused on morphometric parameters, the volume of displaced soil, and associated geohazards, serving as indicators for assessing the degradation state of hiking trails and their suitability for mountain biking and tourist traffic. The findings reveal a high degree of trail degradation, highlighted by increased trail width, the development of parallel trail sections due to dispersed tourist traffic, areas with abrupt gradient changes, and sections severely affected by erosion, resulting in significant volumes of displaced soil. These factors hinder effective tourist traffic, including hiking and mountain biking, and degrade the mountainous landscape. Conversely, the results can be useful for both monitoring annual trail erosion rates and facilitating tourist access, tailored to individual and group interests, as well as the physical readiness of each tourist, to offer a more pleasurable and sustainable experience. Full article
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19 pages, 11860 KiB  
Article
Improved Properties of Ceramic Shells by Optimizing the Surface Composition from Lanthanide-Based Composites
by Minghui Li, Jianbo Yu, Xia Li, Zhigang Yang, Zhongming Ren and Xiaoxin Zhang
Coatings 2025, 15(7), 746; https://doi.org/10.3390/coatings15070746 - 23 Jun 2025
Viewed by 439
Abstract
The precision casting of nickel-based single-crystal superalloys imposes stringent requirements on the high-temperature stability and chemical inertness of ceramic shell face coats. To address the issue of traditional EC95 shells (95% Al2O3–5% SiO2) being prone to react [...] Read more.
The precision casting of nickel-based single-crystal superalloys imposes stringent requirements on the high-temperature stability and chemical inertness of ceramic shell face coats. To address the issue of traditional EC95 shells (95% Al2O3–5% SiO2) being prone to react with the alloy melt at elevated temperatures, thereby inducing casting defects, this study proposes a lanthanide oxide-based ceramic face coat material. Three distinct powders—LaAlO3 (LA), LaAlO3/La2Si2O7 (LAS), and LaAl11O18/La2Si2O7/Al2O3 (LA11S)—are successfully prepared through solid-phase sintering of the La2O3-Al2O3-SiO2 ternary system. Their slurry properties, shell sintering processes, and high-temperature performance are systematically investigated. The results demonstrate that optimal slurry coating effectiveness is achieved when LA powder is processed with a liquid-to-powder ratio of 3:1 and a particle size of 300 mesh. While LA shells show no cracking at 1300 °C, their face coats fail above 1400 °C due to the formation of a La2Si2O7 phase. In contrast, LAS and LA11S shells suppress cracking through the La2Si2O7 and LaAl11O18 phases, respectively, exhibiting exceptionally high-temperature stability at 1400 °C and 1500 °C. All three shells meet the high-temperature strength requirements for CMSX-4 single-crystal alloy casting. Interfacial reaction analysis and Gibbs free energy calculations reveal that Al2O3-forming reactions occur between the novel shells and alloy melt, accompanied by minor dissolution erosion without other chemical side reactions. This work provides a high-performance face coat material solution for investment casting of nickel-based superalloys. Full article
(This article belongs to the Special Issue Advances in Ceramic Materials and Coatings)
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34 pages, 2086 KiB  
Review
Local Scour Around Marine Structures: A Comprehensive Review of Influencing Factors, Prediction Methods, and Future Directions
by Bingchuan Duan, Duoyin Wang, Chenxi Qin and Lunliang Duan
Buildings 2025, 15(12), 2125; https://doi.org/10.3390/buildings15122125 - 19 Jun 2025
Viewed by 851
Abstract
Local scour is a phenomenon of sediment erosion and transport caused by the dynamic interaction between water flow and seabed sediment, posing a serious threat to the safety of marine engineering structures such as cross-sea bridges and offshore wind turbines. To improve scour [...] Read more.
Local scour is a phenomenon of sediment erosion and transport caused by the dynamic interaction between water flow and seabed sediment, posing a serious threat to the safety of marine engineering structures such as cross-sea bridges and offshore wind turbines. To improve scour prediction and prevention capabilities, this review systematically analyzes the influence mechanisms of factors such as hydrodynamic conditions, sediment characteristics, and structural geometry, and discusses scour protection measures. Based on this, a comprehensive evaluation of the applicability of different prediction methods, including traditional empirical formulas, numerical simulations, probabilistic prediction models, and machine learning (ML) methods, was conducted. The study focuses on analyzing the limitations of existing methods: empirical formulas lack adaptability under complex field conditions, numerical simulation still faces challenges in validating real marine environments, and data-driven models suffer from “black box” issues and insufficient generalization capabilities. Based on the current research progress, this review presents prospects for future development, emphasizing the need to deepen the study of scouring mechanisms in complex real marine environments, develop efficient numerical models for engineering applications, and explore intelligent prediction methods that integrate data-driven approaches with physical mechanisms. This aims to provide more reliable theoretical support for the safe design, risk prevention, and scouring mitigation measures in marine engineering. Full article
(This article belongs to the Section Building Structures)
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15 pages, 2052 KiB  
Article
Assessment of Potential Environmental Risks Posed by Soils of a Deactivated Coal Mining Area in Northern Portugal—Impact of Arsenic and Antimony
by Marcus Monteiro, Patrícia Santos, Jorge Espinha Marques, Deolinda Flores, Manuel Azenha and José A. Ribeiro
Pollutants 2025, 5(2), 15; https://doi.org/10.3390/pollutants5020015 - 18 Jun 2025
Viewed by 1029
Abstract
Active and abandoned mining sites are significant sources of heavy metals and metalloid pollution, leading to serious environmental issues. This study assessed the environmental risks posed by potentially toxic elements (PTEs), specifically arsenic (As) and antimony (Sb), in the Technosols (mining residues) of [...] Read more.
Active and abandoned mining sites are significant sources of heavy metals and metalloid pollution, leading to serious environmental issues. This study assessed the environmental risks posed by potentially toxic elements (PTEs), specifically arsenic (As) and antimony (Sb), in the Technosols (mining residues) of the former Pejão coal mine complex in Northern Portugal, a site impacted by forest wildfires in October 2017 that triggered underground combustion within the waste heaps. Our methodology involved determining the “pseudo-total” concentrations of As and Sb in the collected heap samples using microwave digestion with aqua regia (ISO 12914), followed by analysis using hydride generation-atomic absorption spectroscopy (HG-AAS). The concentrations of As an Sb ranging from 31.0 to 68.6 mg kg−1 and 4.8 to 8.3 mg kg−1, respectively, were found to be above the European background values reported in project FOREGS (11.6 mg kg−1 for As and 1.04 mg kg−1 for Sb) and Portuguese Environment Agency (APA) reference values for agricultural soils (11 mg kg−1 for As and 7.5 mg kg−1 for Sb), indicating significant enrichment of these PTEs. Based on average Igeo values, As contamination overall was classified as “unpolluted to moderately polluted” while Sb contamination was classified as “moderately polluted” in the waste pile samples and “unpolluted to moderately polluted” in the downhill soil samples. However, total PTE content alone is insufficient for a comprehensive environmental risk assessment. Therefore, further studies on As and Sb fractionation and speciation were conducted using the Shiowatana sequential extraction procedure (SEP). The results showed that As and Sb levels in the more mobile fractions were not significant. This suggests that the enrichment in the burned (BCW) and unburned (UCW) coal waste areas of the mine is likely due to the stockpiling of lithic fragments, primarily coals hosting arsenian pyrites and stibnite which largely traps these elements within its crystalline structure. The observed enrichment in downhill soils (DS) is attributed to mechanical weathering, rock fragment erosion, and transport processes. Given the strong association of these elements with solid phases, the risk of leaching into surface waters and aquifers is considered low. This work underscores the importance of a holistic approach to environmental risk assessment at former mining sites, contributing to the development of sustainable remediation strategies for long-term environmental protection. Full article
(This article belongs to the Section Soil Pollution)
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18 pages, 733 KiB  
Review
Dredge Sediment as an Opportunity: A Comprehensive and Updated Review of Beneficial Uses in Marine, River, and Lagoon Eco-Systems
by Chiara Fratini, Serena Anselmi and Monia Renzi
Environments 2025, 12(6), 200; https://doi.org/10.3390/environments12060200 - 12 Jun 2025
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Abstract
Dredging is essential for the maintenance of ports, waterways, lakes, and lagoons to ensure their operability and economic value. Over the last few decades, scientists have focused on the significant environmental challenges associated with dredging, including habitat destruction, loss of biodiversity, sediment suspension, [...] Read more.
Dredging is essential for the maintenance of ports, waterways, lakes, and lagoons to ensure their operability and economic value. Over the last few decades, scientists have focused on the significant environmental challenges associated with dredging, including habitat destruction, loss of biodiversity, sediment suspension, and contamination with heavy metals and organic pollutants. The huge loss of sediment in coastal areas and the associated erosion processes are now forcing stakeholders to look ahead and turn potential problems into an opportunity to develop new sediment management strategies, beyond environmental protection, toward ecosystem restoration and coastal resilience. Moreover, the European and Italian strategies, such as the European Green Deal (EGD) and the Italian Ecological Transition Plan (PTE), highlight the need to reuse dredge sediment in circular economy strategies, transforming them into valuable resources for construction, agriculture, and environmental restoration projects. European legislation on dredging is fundamental to the issue of management and priorities of dredged materials, but the implementation rules are deferred to individual member states. In Italy, the Ministerial Decree 173/2016 covers the main aspects of dredge activities and dredge sediment management. Moreover, it encourages the remediation and reuse of the dredge sediment. This study starts with a comprehensive analysis of the innovative remediation techniques that minimize impacts and promote sustainable, beneficial sediment management. Different remediation methods, such as electrochemical treatments, chemical stabilization, emerging nanotechnologies, bioremediation, and phytoremediation, will be evaluated for their effectiveness in reducing pollution. Finally, we highlight new perspectives, integrated strategies, and multidisciplinary approaches that combine various technological innovations, including artificial intelligence, to enhance sediment reuse with the aim of promoting economic growth and environmental protection. Full article
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