Search Results (73)

Integrated optical waveguide amplifiers, with their compact footprint, low power consumption, and scalability, are the basis for optical communications. The realization of high gain in such integrated devices is made more challenging by the tight optical constraints. In this work, we present efficient amplification in an erbium–ytterbium-based hybrid slot waveguide consisting of a silicon nitride waveguide and a thin-film active layer/electron-beam resist. The electron-beam resist as the upper cladding layer not only possesses the role of protecting the waveguide but also has tighter optical confinement in the vertical cross-section direction. On this basis, an accurate and comprehensive dynamic model of an erbium–ytterbium co-doped amplifier is realized by introducing quenched ions. A modal gain of above 20 dB is achieved at the signal wavelength of 1530 nm in a 1.4 cm long hybrid slot waveguide, with fractions of quenched ions f_q = 30%. In addition, the proposed hybrid waveguide amplifiers exhibit higher modal gain than conventional air-clad amplifiers under the same conditions. Endowing silicon nitride photonic integrated circuits with efficient amplification enriches the integration of various active functionalities on silicon. Full article

Objective: This in vitro study evaluated the effectiveness of three laser systems—diode, CO₂, and Er:YAG—for debonding composite attachments used in aligner orthodontic therapy. Materials and Methods: Fifty extracted human premolars with composite attachments were divided into five groups (n = 10): control, RT (rotary tools), diode laser (980 nm, irradiance was 4811 W/cm²), CO₂ laser (10.6 µm, irradiance 1531 W/cm²), and Er:YAG laser (2940 nm, irradiance 471.7 W/cm²). Shear bond strength (SBS) testing measured debonding forces. Enamel surface changes were evaluated using micro-CT, optical profilometry, and stereomicroscopy. The Adhesive Remnant Index (ARI) assessed residual bonding material. Results: Laser treatment increased enamel roughness (p < 0.05). Er:YAG laser caused the highest roughness (Sa = 2.03 µm) and up to 0.17 mm enamel loss but left minimal adhesive remnants and no fractures. Diode laser preserved surface smoothness with moderate bond weakening. CO₂ laser had intermediate effects. RT showed the highest SBS but resulted in greater enamel alteration. SBS was significantly reduced in the laser groups, lowest for Er:YAG (81.7 ± 45.5 MPa vs. control 196.2 ± 75.3 MPa). ARI indicated better adhesive removal in the laser-treated groups, with Er:YAG showing the highest percentage of clean enamel surfaces (67% vs. 25%). Conclusions: Er:YAG demonstrated the best balance between effective debonding and enamel preservation. Diode and CO₂ lasers also offer viable alternatives to rotary tools. Further clinical studies are recommended. Full article

A tetraerbium cluster containing soft-base dianionic 4,8-difluorobenzo [1,2-d:5,4-d′]bisthiazole-2,6-dithiol (H₂L) ligands, μ-OH, and coordinated 1,2-dimethoxyethane (DME) of the general formula {Er₄(μ-L)₄(μ-OH)₄(DME)₄} (1) was synthesized using a one-pot method. X-ray analysis revealed that 1 is an asymmetrical tetramer in which there are four μ₂-bridging bisthiazole ligands and four μ₂-bridging hydroxide anions per four erbium ions. The molecule of 1 has inherent chirality, and the geometry of intramolecular F…F short contacts implies the formation of a classical halogen bond. Upon excitation by a 375 nm diode laser, compound 1 shows the moderate metal-centered emission of Er³⁺ ions that peaked at 1530 nm. Full article

Random lasers (RLs) based on glasses and glass-ceramics doped with rare-earth ions (REI) deserve great attention because of their specific physical properties such as large thermal stability, possibility to operate at high intensities, optical wavelength tunability, and prospects to operate Fiber-RLs, among other characteristics of interest for photonic applications. In this article, we present a brief review of experiments with RLs based on tellurite and germanate glasses and glass-ceramics doped with neodymium (Nd³⁺), erbium (Er³⁺), and ytterbium (Yb³⁺) ions. The glass samples were fabricated using the melt-quenching technique followed by controlled crystallization to achieve the glass-ceramics. Afterwards, the samples were crushed to obtain the powder samples for the RLs experiments. The experiments demonstrated RLs emissions at various wavelengths, with feedback mechanisms due to light scattering at grain/air and crystalline/glass interfaces. The phenomenon of replica symmetry breaking was verified through statistical analysis of the RLs intensity fluctuations, indicating a photonic phase-transition (corresponding to the RL threshold) analogous to the paramagnetic-to-spin glass transition in magnetic materials. The various results reported here highlight the potential of glasses and glass-ceramics for the development of RLs with improved performance in terms of reduction of laser threshold and large lifetime of the active media in comparison with organic materials. Full article

This study focused on the nature of rare earth metal complex compounds that can form during the carbonate–alkaline processing of industrial waste materials, such as phosphogypsum and red mud, at 70–100 °C and 1–10 atm. Experimental findings revealed that the dissolution of synthetic carbonates of rare earth elements (REEs) in a concentrated carbonate-ion medium (3 mol/L) leads to the formation of ion-associates of varying strengths. Light (lanthanum, praseodymium, and neodymium) and medium (samarium) REE groups exhibited a tendency to form loose ion-associates, whereas heavy REEs (terbium, dysprosium, holmium, erbium, thulium, lutetium, and yttrium) formed close ion-associates. To confirm the existence of these ion-associates, the specific conductivity of solutions was measured after dissolving thulium (III) and samarium (III) carbonates at phase ratios ranging from 1:2000 g/mL to 1:40 g/mL in a potassium carbonate medium. The decay of ion-associates, leading to the precipitation of rare earth metal (III) carbonates, was tested in an ammonium carbonate medium. Thermal decomposition of ammonium carbonate at 70–75 °C during 1–4 h was accompanied by full rare earth carbonates’ sedimentation and its in-the-way separation into groups because of the varied strength of ion-associates. The results of this study provide a basis for developing processes to separate rare earth metals into groups during their carbonate–alkaline extraction into solution. Full article

This work presents a comparative study of five rare earth compounds—Erbium nitrate pentahydrate lll (Er), Neodymium nitrate pentahydrate (Nd), Samarium III Nitrate Hexahydrate (Sm), Yterbium III Chloride Hexahydrate (Yb) and Praseodymium nitrate hexahydrate lll (Pr)—protecting API 5L X70 steel from corrosion in saline medium that uses electrochemical impedance spectroscopy (EIS) and polarization curves (CPs) at different concentrations and in static mode. The results show that Erbium is the best corrosion inhibitor, containing 50 ppm and reaching an inhibition efficiency of about 89%, and similar result was shown by Sm with an IE~87.9%, while the other rare earths (Nd, Yb and Pr) showed a decrease in corrosion protection at the same concentration, since they were below an IE~80%. On the other hand, with the Langmuir model it was possible to describe that the adsorption process of the three rare earths follows a combined physisorption–chemisorption process to protect the metal’s surface. The observed adsorption free energy, ΔG°ads, reaches −38.7 kJ/mol for Er, −34.4 kJ/mol for Nd, and −33.6 kJ/mol for Pr; whereas Sm and Yb have adsorption free energies of −33.9 and −35.0 kJ/mol, respectively. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) further confirmed the formation of a protective film. Their characterization using density functional theory showed the transference of charge from the iron cluster towards the rare earth metal compounds. The adsorption process produced a slightly polarized region of interaction with the metal surface. Also, it was found that the adsorption of the rare earths affected the magnetic properties of the surface of the iron cluster. Quantum chemical descriptors, such as Pearson’s HSAB (Hard and Soft Acids and Bases) descriptors, were useful in predicting the behavior of the flow of electrons between the metal surface and the interacting rare earth ions. Full article

This study employs advanced structural characterization techniques, including anomalous small-angle X-ray scattering (ASAXS), small-angle X-ray scattering (SAXS), and X-ray photoelectron spectroscopy (XPS), to investigate erbium (Er³⁺)-doped silica-based glass-ceramic thin films synthesized via the sol–gel method. This research examines the SiO₂-TiO₂ and SiO₂-TiO₂-PO_2.5 systems, focusing on the formation, dispersion, and structural integration of Er³⁺-containing nanocrystals within the amorphous matrix under different thermal treatments. Synchrotron radiation tuned to the L_III absorption edge of erbium enabled ASAXS measurements, providing element-specific details about the localization of Er³⁺ ions. The findings confirm their migration into crystalline phases, such as erbium phosphate (EPO) and erbium titanate (ETO). SAXS and Guinier analysis quantified nanocrystal sizes, revealing trends influenced by their composition and heat treatment. Complementary XPS analysis of the Er 5p core-level states provided detailed information on the chemical and electronic environment of the Er³⁺ ions, confirming their stabilization within the crystalline structure. Transmission electron microscopy (TEM) highlighted the nanoscale morphology, verifying the aggregation of Er³⁺ ions into well-defined nanocrystals. The results offer a deeper understanding of their size, distribution, and interaction with the surrounding matrix. Full article

This systematic study was conducted on the separation of yttrium (Y) and erbium (Er) from a chloride medium using a mixed extractant system composed of [N1444][P507] and TRPO (trialkylphosphine oxide) in kerosene. This investigation focused on the effects of various extractants, extraction systems, the initial acidity of the aqueous phase, and the phase contact time on the extraction efficiencies of Y and Er. This study showed that using the combination of [N1444][P507] and TRPO notably increased the extraction performance and enhanced the separation factor between Y and Er, outperforming the individual use of P507 or [N1444][P507] under identical conditions. The extraction efficiencies for Y and Er reached 88.4% and 93.3%, respectively, with a separation factor (Er/Y) of 1.84, highlighting the system’s effectiveness in selectively isolating rare earth elements. Optimal stripping conditions were obtained using 0.1 mol/L of HCl, resulting in a successful recovery of 93.1% of Y³⁺ and 78.9% of Er³⁺ from the organic phase. The extraction mechanism involved both ion exchange and ion association. The enthalpy changes (ΔH) associated with the extraction of Y³⁺ (−2.5 kJ·mol⁻¹) and Er³⁺ (4.6 KJ·mol⁻¹) demonstrate that the extraction processes are exothermic, reflecting the thermodynamic differences between the two ions. Full article

The ASE (Amplified Spontaneous Emission) light source, based on erbium-doped fiber (EDF), is a broadband light source with advantages such as high power, excellent temperature stability, and low coherent light generation. It is widely used in the field of fiber optic sensing. However, traditional ASE sources suffer from temperature sensitivity and low efficiency, which can compromise the accuracy and stability of the output light’s average wavelength. This study focuses on optimizing the erbium-doped fiber (EDF) to improve the temperature stability and efficiency of the ASE light source. Through simulations, we found that the appropriate doping concentration and length of the EDF are key factors in enhancing the stability and efficiency of the ASE source. Inorganic metal chloride vapor-phase doping combined with an improved chemical vapor deposition process was used to fabricate the erbium-doped fiber, ensuring low background loss, minimal OH⁻ absorption, and uniform distribution of the erbium ions in the core of the fiber. The optimized EDFs were integrated into the ASE source, achieving a power conversion efficiency of 53.6% and a temperature stability of 0.118 ppm/°C within the temperature range of −50 °C to 70 °C. This study offers a practical approach for improving the performance of ASE light sources and advancing the development of high-precision fiber optic sensing technologies. Full article

In this work, we present an experimental approach for monitoring the temperature of submicrometric, real-time operating electrical circuits using luminescence thermometry. For this purpose, we utilized lanthanide-doped up-converting nanocrystals as nanoscale temperature probes, which, combined with a highly sensitive confocal photoluminescence microscope, enabled temperature monitoring with spatial resolution limited only by the diffraction of light. To validate our concept, we constructed a simple model of an electrical microcircuit based on a single silver nanowire with a diameter of approximately 100 nm and a length of about 50 µm, whose temperature increase was induced by electric current flow. By driving electric current only along one half of the nanowire, we created a dual-function microstructure, where one section is a resistive heater, while the other operates as a radiator. Such a combination realistically reflects the electronic circuit and its thermal behavior. We demonstrated that nanocrystals distributed around this circuit allow for remote temperature readout and enable precise monitoring of the thermal energy propagation and heat dissipation processes, which are crucial for designing and developing highly integrated electronic on-chip devices. Full article

A transparent Er³⁺,Yb³⁺:GdMgB₅O₁₀ single crystal with dimensions up to 24 × 15 × 12 mm was grown successfully by the high-temperature solution growth on dipped seeds technique from K₂Mo₃O₁₀-based solvent. The grown crystal was characterized using PXRD, DSC and ATR techniques. Differential scanning calorimetry measurements and SEM analysis of the heat-treated solids revealed Er,Yb:GdMgB₅O₁₀ to be an incongruent melting compound with an onset point of 1087 °C. The absorption edge of the Er,Yb:GMBO sample is located in the region of 245 nm, which approximates a value of 4.8 eV. Absorption and emission spectra, and luminescence kinetics, were studied. The energy transfer efficiency from ytterbium to erbium ions was determined. The laser operation in continuous-wave mode was realized and output characteristics were measured. The maximal output power of 0.15 W with a slope efficiency of 11% was obtained at 1568 nm. Full article

Upconversion nanoparticles (UCNPs) and carbon quantum dots (CQDs) have emerged as promising candidates for enhancing both the stability and efficiency of perovskite solar cells (PSCs). Their rising prominence is attributed to their dual capabilities: they effectively passivate the surfaces of perovskite-sensitive materials while simultaneously serving as efficient spectrum converters for sunlight. In this work, we synthesized UCNPs doped with erbium ions as down/upconverting ions for ultraviolet (UV) and near-infrared (NIR) light harvesting. Various percentages of the synthesized UCNPs were integrated into the mesoporous layers of PSCs. The best photovoltaic performance was achieved by a PSC device with 30% UCNPs doped in the mesoporous layer, with PCE = 16.22% and a fill factor (FF) of 74%. In addition, the champion PSCs doped with 30% UCNPs were then passivated with carbon quantum dots at different spin coating speeds to improve their photovoltaic performance. When compared to the pristine PSCs, a fabricated PSC device with 30% UCNPs passivated with CQDs at a spin coating speed of 3000 rpm showed improved power conversion efficiency (PCE), from 16.65% to 18.15%; a higher photocurrent, from 20.44 mA/cm² to 22.25 mA/cm²; and a superior fill factor (FF) of 76%. Furthermore, the PSCs integrated with UCNPs and CQDs showed better stability than the pristine devices. These findings clear the way for the development of effective PSCs for use in renewable energy applications. Full article

This paper reports for the first time on a new layered magnetic heterometallic erbium telluride EuErCuTe₃. Single crystals of the compound were obtained from the elements at 1120 K using CsI as a flux. The crystal structure of EuErCuTe₃ was solved in the space group Cmcm (a = 4.3086(3) Å, b = 14.3093(9) Å, and c = 11.1957(7) Å) with the KZrCuS₃ structure type. In the orthorhombic structure of erbium telluride, distorted octahedra ([ErTe₆]⁹⁻) form two-dimensional layers (${}_{\infty }{}^2\left\{{\left[\mathrm{E}\mathrm{r}{\left(\mathrm{T}\mathrm{e}1\right)}_{2/2}^e{\left(\mathrm{T}\mathrm{e}2\right)}_{4/2}^k\right]}^{-}\right\})$, while distorted tetrahedra ([CuTe₄]⁷⁻) form one-dimensionally connected substructures (${}_{\infty }{}^1\left\{{\left[\mathrm{C}\mathrm{u}{\left(\mathrm{T}\mathrm{e}1\right)}_{2/2}^e{\left(\mathrm{T}\mathrm{e}2\right)}_{2/1}^t\right]}^{5-}\right\}$) along the [100] direction. The distorted octahedra and tetrahedra form parallel two-dimensional layers (${}_{\infty }{}^2\left\{{\left[\mathrm{C}\mathrm{u}\mathrm{E}\mathrm{r}{\mathrm{T}\mathrm{e}}_3\right]}^{2-}\right\})$ between which Eu²⁺ ions are located in a trigonal-prismatic coordination environment (${\left[{\mathrm{E}\mathrm{u}\mathrm{T}\mathrm{e}}_6\right]}^{10-})$. The trigonal prisms are connected by faces, forming chains (${}_{\infty }{}^1\left\{{\left[{\mathrm{E}\mathrm{u}\left(\mathrm{T}\mathrm{e}1\right)}_{2/2}{\left(\mathrm{T}\mathrm{e}2\right)}_{4/2}\right]}^{2-}\right\}$) along the [100] direction. Regularities in the variations in structural parameters were established in the series of erbium chalcogenides (EuErCuCh₃ with Ch = S, Se, and Te) and tellurides (EuLnCuTe₃ with Ln = Gd, Er, and Lu). Ab-initio calculations of the crystal structure, phonon spectrum, and elastic properties of the compound EuErCuTe₃ were performed. The types and wavenumbers of fundamental modes were determined, and the involvement of ions in the IR and Raman modes was assessed. The experimental Raman spectra were interpreted. The telluride EuErCuTe₃ at temperatures below 4.2 K was ferrimagnetic, as were the sulfide and selenide derivatives (EuErCuCh₃ with Ch = S and Se). Its experimental magnetic characteristics were close to the calculated ones. The decrease in the magnetic phase transition temperature in the series of the erbium chalcogenides was discovered. Full article

A reaction in anhydrous toluene between the formally unsaturated fragment [Ln(hfac)₃] (Ln³⁺ = Eu³⁺, Gd³⁺ and Er³⁺; Hhfac = hexafluoroacetylacetone) and [Al(qNO)₃] (HqNO = 8-hydroxyquinoline N-oxide), here prepared for the first time from [Al(O^tBu)₃] and HqNO, affords the dinuclear heterometallic compounds [Ln(hfac)₃Al(qNO)₃] (Ln³⁺ = Eu³⁺, Gd³⁺ and Er³⁺) in high yields. The molecular structures of these new compounds revealed a dinuclear species with three phenolic oxygen atoms bridging the two metal atoms. While the europium and gadolinium complexes show the coordination number (CN) 9 for the lanthanide centre, in the complex featuring the smaller erbium ion, only two oxygens bridge the two metal atoms for a resulting CN of 8. The reaction of [Eu(hfac)₃] with [Alq₃] (Hq = 8-hydroxyquinoline) in the same conditions yields a heterometallic product of composition [Eu(hfac)₃Alq₃]. A recrystallization attempt from hot heptane in air produced single crystals of two different morphologies and compositions: [Eu₂(hfac)₆Al₂q₄(OH)₂] and [Eu₂(hfac)₆(µ-Hq)₂]. The latter compound can be directly prepared from [Eu(hfac)₃] and Hq at room temperature. Quantum mechanical calculations confirm (i) the higher stability of [Eu(hfac)₃Al(qNO)₃] vs. the corresponding [Eu(hfac)₃Alq₃] and (ii) the preference of the Er complexes for the CN 8, justifying the different behaviour in terms of the Lewis acidity of the metal centre. Full article