Search Results (105,465)

The scope of actual pro-environmental initiatives, programs, interventions, and campaigns is limited. Therefore, spillover effects from these activities to other domains of economy, the private sphere, and society are crucial to achieve a transformation of society towards sustainability. Starting from the known literature and using Google Scholar as a platform for searching additional studies, this explorative, traditional narrative review analyses behavioural spillover effects, where either one behaviour influences the likelihood of another behaviour, or an intervention shows an impact on an environmentally significant behaviour, which it did not primarily address. In the scientific literature, spillover is classified by direction (environmentally positive versus negative), involved behaviours (similar or cross-behavioural), timing (short or long term), context (e.g., work to private life), and social scope (personal, interpersonal, intra- and inter-organisational, intergroup, or international). Positive spillover can result from cognitive dissonance reduction, consistent self-perception, pro-environmental values, norms, self-identity, action-based learning, and habit formation. Negative spillover emerges through rebound effects, moral licensing, and psychological reactance. Stronger spillover is observed between similar behaviours, while cross-domain spillover is generally weaker. According to previous research, a facilitated participatory approach with strong pro-environmental orientation appears recommendable for practitioners to foster the value change required for effective and sustained positive spillover. Full article

Iodoacetic acid (IAA), a highly cytotoxic disinfection byproduct commonly detected in drinking water, poses a potential risk to female reproductive health. The direct molecular mechanisms underlying its effects on the reproductive system epithelium remain unclear. This study demonstrates that IAA induces glycational stress in primary porcine uterine (UECs) and oviduct epithelial cells (OECs), representing an early event contributing to extensive cellular toxicity. IAA exposure inhibited Glyceraldehyde-3-Phosphate Dehydrogenase (GAPDH) enzymatic activity and promoted the accumulation of advanced glycation end products (AGEs) Nε-(carboxymethyl)lysine (CML), triggering mitochondrial dysfunction, redox imbalance, calcium dyshomeostasis, and endoplasmic reticulum stress. These disturbances activated a dysregulated signaling network involving the p38 MAPK, AKT, and NF-κB pathways, ultimately causing G1/S cell cycle arrest and apoptosis. Notably, pretreatment with the AGE inhibitor pyridoxamine reduced CML accumulation, restored mitochondrial function, and alleviated apoptotic cell death. These findings identify glycational stress as a key initiating mechanism for IAA-induced reproductive epithelial toxicity, providing mechanistic insight into the potential health risks of environmental disinfection byproducts. Full article

Light availability is a key environmental factor regulating nitrogen assimilation, carbon metabolism, and nutritional quality in leafy vegetables grown in controlled environments. However, how practical lighting regimes used in plant factories with artificial lighting (PFALs) influence the coordination between nitrogen assimilation and central carbon metabolism across different lettuce cultivar types remains insufficiently understood. This study investigated how moderate differences in photosynthetic photon flux density (PPFD) influence nitrogen metabolism and metabolic coordination in hydroponically cultivated lettuce. Two cultivars representing contrasting morphological types, iceberg lettuce (‘Celebration’) and leaf lettuce (‘Sunny’), were grown under LED light intensities of 150 and 200 µmol·m⁻²·s⁻¹. Nitrate, nitrite, and ammonium concentrations were measured together with the activities of nitrate reductase (NRA) and nitrite reductase (NiRA), as well as ascorbic acid content. Metabolomic profiling was additionally performed to characterize broader metabolic responses. Higher light intensity enhanced nitrate reduction capacity in both cultivars, but the resulting patterns of nitrogen accumulation were strongly genotype-dependent. The leaf lettuce cultivar ‘Sunny’ exhibited increased NRA and reduced nitrate accumulation under higher light intensity, whereas the iceberg lettuce cultivar ‘Celebration’ accumulated more nitrate under the same conditions. Ammonium responses further suggested differences in downstream nitrogen assimilation processes. Elevated light intensity also increased ascorbic acid levels in both cultivars. Metabolomic analysis revealed contrasting cultivar-specific shifts in central carbon metabolism, particularly involving soluble sugars and tricarboxylic acid cycle intermediates, indicating differential coordination between carbon metabolism and nitrogen utilization. Overall, these findings demonstrate that moderate changes in light intensity within the practical PFAL cultivation range can significantly influence the integration of carbon and nitrogen metabolism in lettuce. Importantly, cultivar-specific physiological traits determine how these metabolic responses translate into nitrate accumulation and nutritional quality in controlled-environment production systems. Full article

The increasing prevalence of cancer in Thailand over the past decade has resulted in a substantial rise in the use of anticancer drugs, which are eventually discharged into municipal wastewater through hospital and domestic effluents. The inability of conventional wastewater treatment systems to completely remove these pharmaceuticals has been widely reported. The continuous release of these emerging anticancer agents into aquatic environments reduces water quality and threatens biodiversity. Even at trace levels, these compounds may act as persistent pollutants capable of impairing ecosystem. This study investigated the occurrence and concentration levels of three widely used chemotherapeutic agents including cyclophosphamide (COP), doxorubicin (DOX), and vincristine (VIN) in Bangkok’s municipal wastewater to evaluate their potential environmental risks. Thirty-two influent and effluent wastewater samples were collected from eight large-scale wastewater treatment plants (WWTPs) from October 2024 to January 2025. Samples were processed using solid-phase extraction (SPE) and analyzed by liquid chromatography–triple quadrupole mass spectrometry (LC–MS/MS). The analytical method demonstrated high precision and reproducibility, with relative standard deviations (%RSD) below the 20% acceptance limit for all compounds. Method accuracy ranged from 81.84% to 107.21%. Results showed the presence of only COP in almost influent and effluent at levels ranging from 0.26 to 2.06 µg/L. In contrast, DOX and VIN levels remained consistently below the limits of quantitation (LOQ) in all WWTP samples. This study establishes the first baseline for COP, DOX, and VIN contamination in Bangkok’s municipal wastewater. Notably, the residue of COP in wastewater suggests that current wastewater treatment facilities in Thailand are insufficient for its removal, posing a potential long-term risk to local aquatic ecosystems. Full article

This paper evaluates the efficiency of modernization of the regional railway line Prievidza–Jelšovce in Slovakia using cost–benefit analysis (CBA), reflecting increased investment costs and the potential electrification of the line. The assessment is based on a detailed analysis of transport demand and infrastructure conditions, where daily railway passenger volumes range between 2300 and 3700 passengers, while individual car transport exceeds 10,000 passengers per day in most sections. Two alternative modernization variants were evaluated. The results show that the project generates socio-economic benefits, particularly through travel time savings amounting to approximately €42.3 million and reductions in operating costs and externalities. Significant environmental benefits were identified, especially in the case of the more advanced variant, with reductions in air pollution reaching €56.3 million and greenhouse gas emissions reaching €42.2 million. Despite these benefits, the economic evaluation indicates negative net economic outcomes for both variants. The total economic investment costs (excluding VAT and adjusted for economic appraisal) reach €543.4 million for the EIA variant and €511.9 million for the proposed variant, resulting in net economic values of −€186.2 million and −€70.8 million, respectively. The results therefore suggest that neither variant achieves full economic efficiency under the given assumptions, although the proposed variant performs significantly better. The findings highlight the strong sensitivity of project efficiency to investment costs and the scope of modernization. The study confirms the necessity of regularly updating CBA analyses in transport projects, as changes in input parameters can substantially influence investment decision-making. Full article

Coastal port ecosystems serve as critical interfaces between marine environments and anthropogenic activities, yet zooplankton community dynamics in these transitional zones remain poorly understood. This study investigated seasonal variations in zooplankton assemblages and their environmental drivers in the coastal waters surrounding Lanshan Port, northern Yellow Sea, through quarterly field surveys spanning spring to winter. A total of 33 zooplankton species and 16 planktonic larval categories were identified, with Hydromedusa, Copepoda, and planktonic larvae comprising the three dominant groups. Marked seasonal disparities were observed in species richness (spring: 21 species and 11 larvae categories; winter: 8 species and 3 larvae categories), biomass (autumn: 333.7 mg/m³; winter: 34.0 mg/m³), and abundance (spring: 185.3 ind/m³; winter: 25.7 ind/m³). Notably, Aidanosagitta crassa maintained perennial dominance across all seasons. Principal component analysis of dominant zooplankton taxa across seasons indicated that the first two principal components explained 70.05% and 15.97% of the total variance in zooplankton community structure, respectively, with distinct seasonal clustering of sampling sites along PC1 reflecting pronounced seasonal succession in community composition. Redundancy analysis revealed seasonal-specific correlations between dominant taxa and nutrients: nitrate concentration was negatively correlated with the relative abundance of Sergestidae in both spring and summer, whereas ammonium concentration was negatively correlated with Hydromedusa; by contrast, the abundances of Chaetognatha and Tunicata exhibited a significant positive correlation with nitrate. We also found water temperature only drove communities in autumn, while salinity had little effect. These findings elucidate the mechanisms structuring zooplankton communities in temperate coastal port ecosystems and underscore the necessity of seasonally resolved monitoring frameworks for effective marine environmental management. Full article

Heavy metal contamination of foods remains a persistent global challenge for food safety and public health, driven by industrialization, mining activities, intensive agriculture, and ongoing environmental degradation. This scoping review synthesizes peer-reviewed literature on the occurrence of priority toxic metals—arsenic, cadmium, lead, mercury, and nickel—in food matrices, with emphasis on contamination pathways, analytical detection strategies, and documented human health effects. The reviewed studies reveal widespread accumulation of heavy metals in staple foods, including cereals, vegetables, seafood, and processed products, with concentrations frequently approaching or exceeding international regulatory limits, particularly in regions exposed to strong anthropogenic pressure. Conventional laboratory-based techniques, such as atomic absorption spectrometry and inductively coupled plasma methods, remain the reference standards for quantitative determination and regulatory compliance; however, their application to large-scale or continuous monitoring is often constrained by cost, infrastructure, and operational complexity. Consequently, increasing attention has been directed toward emerging detection approaches, including portable X-Ray fluorescence, Raman/SERS spectroscopy, electrochemical biosensors, electronic tongues, and in situ magnetic measurements, as complementary tools for rapid screening and field-based surveillance. Among these, environmental magnetism and in situ magnetic techniques stand out as non-destructive, low-cost proxies capable of identifying metal-associated particulate contamination linked to food production systems. Chronic dietary exposure to heavy metals is consistently associated with neurotoxicity, nephrotoxicity, carcinogenicity, and oxidative stress, underscoring the need for integrated, multi-tiered monitoring frameworks to support early detection, risk assessment, and prevention. Full article

Wear remains a dominant cause of performance loss and premature failure in mechanical components, motivating the development of environmentally benign surface-engineering solutions. Among thermal spray systems, high-velocity oxy-fuel (HVOF)-sprayed WC-Co coatings are widely applied under severe wear conditions. The development of nanophase coatings offers the potential for enhanced mechanical performance. However, retaining the nanostructure and limiting decarburization during deposition remain key challenges. In this study, nanophase WC-12Co feedstocks with two particle size ranges, together with Al-modified nanophase powders, were used to deposit coatings under optimized HVOF spraying conditions (spray distance 200 mm, reduced O₂/fuel ratio, and high particle velocity) and were benchmarked against a conventional WC-12Co (12 wt.% Co) coating. The coatings were characterized in terms of microstructure and phase constitution (OM, SEM/EDS, XRD) as well as thickness, porosity (0.5–3.6%), adhesion strength (up to 65 MPa), and microhardness (~1040–1210 HV). Tribological behavior was assessed by ASTM G99 pin-on-disk testing and counterbody wear was quantified via geometric volume loss estimations. The use of larger nanophase particles enabled effective nanostructure retention with limited decarburization, whereas reducing particle size intensified decarburization, promoting increased W₂C formation, and markedly reduced coating cohesion, despite lower porosity and higher hardness. Aluminum additions enhanced coating microhardness and suppressed Co₃W₃C formation, indicating improved phase stability with minimal additional decarburization. Although coating wear remained negligible for all systems, Al-containing coatings exhibited increased friction (up to 35%) and significantly higher counterbody wear (up to sevenfold) compared to the Al-free nanophase coating, which was found to correlate with coating microhardness. Overall, the results demonstrate that optimizing nanophase WC-Co coatings requires balancing competing mechanisms between microstructural stability, cohesive integrity, and tribological response, highlighting the critical role of feedstock design in tailoring coating performance. Full article

As cleaner production gains prominence in wooden product manufacturing, green evaluation of process schemes during early design is crucial. However, dust concentration, a key environmental indicator in wood product manufacturing, is often evaluated in a subjective and fragmented manner, which greatly hinders the selection of green process schemes in early design. To address this gap, an adaptability evaluation model for green process schemes was proposed based on process knowledge graphs (PKG) and fuzzy Bayesian network (FBN), with the objective of minimizing dust concentration. First, a PKG for wooden products was constructed based on the requirement-function-structure-characteristic-process-equipment (RFSCPE) ontology using patents and process manuals. Second, candidate process schemes were generated via the PKG, and dust-related causal relationships encoded in the PKG were mapped onto a Bayesian network structure. Third, conditional probabilities were obtained by combining probabilistic hesitant fuzzy sets and experimental dust data. The FBN was then updated to perform probabilistic reasoning on dust concentration. Finally, a case study on a wooden toy car validated the proposed approach, and sensitivity analysis identified the key dust-influencing factors, thereby providing quantitative support for greener process decisions. Full article

The development of metro-led urban underground public spaces (UUPSs) provides urban residents with extensive pedestrian-friendly activity areas sheltered from rain, snow, strong winds, and other extreme weather conditions. Although an increasing number of people are engaging in daily commercial and leisure activities within UUPSs, problems such as inconvenient transfer, poor visibility, and a lack of natural light, which indicate poor environmental quality, have led to an uneven distribution of user behavior, thereby reducing the efficiency of space utilization. Our aim in this study was to predict UUPS utilization rates by investigating the relationship between UUPS environmental attributes and user behavior characteristics and preferences. Six typical UUPSs in Wuhan were selected as case studies. User behavior data were collected using panoramic camera recordings, on-site observations, and space syntax methods, while spatial environmental factors were quantified. The correlation between various factors and multi-dimensional user behavior characteristics was discussed, and a Random Forest model was established to predict behavioral preferences. Our results indicate that accessibility and visibility are fundamental factors influencing user behavior characteristics, while the impact of landscape elements is relatively low. Regarding behavioral preference prediction, UUPS environmental features achieved the highest prediction accuracy for leisure behaviors, whereas the predictive performance for sports activities was lower. In this study, we reveal the influence of UUPS environmental factors on user behavior characteristics and predict preference patterns of different behaviors for space types. Focusing on the behavioral needs of space users, we provide a reference for the subsequent human-centered design of UUPSs. Full article

Sunset Yellow is a water-soluble synthetic dye resistant to degradation and stable under various conditions, posing an environmental challenge. In the present study pure chitosan hydrogel (PCH) films were synthesized, followed by the assessment of sorption capacity and recyclability compared to chitosan-based films doped with niobium oxide (CHN) or activated carbon (CHC). The aim was to promote the application of sorption methods for Sunset Yellow dye using these films as a treatment option for the pollutant, with the analysis of the effectiveness of the method and its behavior using adsorption kinetic models and thermodynamic analysis. Equilibrium was reached at 240 min for all films tested, with the adsorbed amounts ranging from 18.58 to 18.79 mg g⁻¹ at 30 °C, when the highest kinetic rate constants were observed. The pseudo-first-order kinetic model best described the experimental data, with the lowest Bayesian information criterion, Akaike information criterion, and mean absolute error values. Thermodynamic analysis indicated a spontaneous, exothermic process, with interactions ranging from electrostatic interactions in CHC and PCH to physisorption in CHN. Recycling tests showed 80% efficiency after the third cycle for all three films. These findings highlight the potential of chitosan-based films as an efficient option for removing Sunset Yellow dye from water, thus improving water quality and enhancing wastewater treatment. Full article

Drought in Angola is a recurrent and cyclical natural phenomenon that poses significant environmental, economic, and social challenges, affecting water resources, agriculture, ecosystems, livestock, and vulnerable communities. This study investigates the temporal evolution and spatial behavior of drought in the provinces of Cunene, Huila, and Namibe over the period 1980–2024. Drought conditions were assessed using the Standardized Precipitation Index (SPI) and the Standard Precipitation–Evapotranspiration Index (SPEI) at multiple time scales. Trends were evaluated using the Modified Mann–Kendall test and Sen’s slope estimator, while drought intensity was analyzed using run theory. The results reveal a clear intensification of drought conditions in the last decade, characterized by an increase in frequency and intensity, particularly after 2010. Extreme drought events were identified in the early 1980s, the mid-1990s, and more recently in 2019 and 2021. Despite some regional variability, the three provinces exhibit consistent temporal patterns, with drought events generally occurring simultaneously over the study period. These findings highlight the increasing pressure on water and environmental systems and underscore the need for improved drought monitoring and forecasting approaches to support more effective adaptation and decision-making. Full article

Gene family expansion and contraction are key processes underlying functional innovation and genome evolution in plants, yet their roles in the horticultural plant white clover (Trifolium repens) remain poorly understood. In this study, we systematically investigated the association between lineage-specific whole-genome duplication (WGD) and short interspersed nuclear elements (SINEs) with gene family dynamics and stress-responsive transcription. Our results indicate that white clover underwent a lineage-specific WGD, which is associated with increased gene family expansion. SINE copy number was strongly correlated with the proportion of significantly expanded genes (r = 0.637, p = 0.0259, n = 12), but not with the proportion of significantly contracted genes. This result suggests a potential association between SINE insertions and gene family expansion. GO enrichment analyses indicated that expanded gene families are predominantly involved in metabolic processes, environmental stress responses, defense mechanisms, and floral organ development, whereas contracted gene families were mainly enriched in core housekeeping functions, such as ubiquitin-dependent protein catabolism and mitochondrial organization. Transcriptome analyses further showed that genes within expanded families were broadly upregulated under drought, cadmium, and cold stress, while generally upregulated in floral tissues compared with other organs. Collectively, these findings reveal the relationships among WGD, SINE elements, and gene family dynamics in environmental adaptation and flower development, providing a molecular framework for understanding adaptive regulation associated with gene family expansion. Full article

The detection and monitoring of asbestos–cement roofing remain a critical public health and environmental challenge, especially in urban and suburban areas where asbestos-containing materials are still widespread due to their extensive use in the 20th century. Although hyperspectral and high-resolution multispectral remote sensing have proven effective for mapping asbestos–cement roofs, many existing approaches rely on proprietary software, limiting transparency, reproducibility, and large-scale adoption. This study presents a fully reproducible, cost-free Python-based workflow for the detection and temporal monitoring of asbestos–cement roofing using high-resolution multispectral WorldView-3 imagery. The workflow integrates atmospheric correction (using the Py6S radiative transfer model), spatial preprocessing, supervised pixel-based classification, postprocessing, and building-level aggregation within an open framework. A Maximum Likelihood Classifier is applied to VNIR and SWIR data using empirically defined roof typologies to enhance class separability. Pixel-level results are aggregated to the building scale through adaptive thresholding enabling the translation of spectral classifications into meaningful building-level information. Tested over the city of Mantua (Italy), the approach achieved reliable classification performance and enabled multi-temporal comparison to identify changes potentially due to roof remediation. Evaluation metrics (precision, recall, and F1-score) highlight the importance of carefully choosing the building-level threshold. By relying exclusively on open-source tools, the workflow enhances transparency, reproducibility, and scalability for long-term monitoring. Full article

Piezo-enhanced photocatalysis is progressively considered an eco-friendly technology for contaminant removal, harvesting not only solar energy but also mechanical vibrations found in nature. Multiferroic materials present a coupled effect of various properties and can potentially increase the applicability of this process. In this study, Cr- doped bismuth ferrite thin film was deposited on SrTiO₃ substrate by HiPIMS, and its photo-, piezo-, and piezo-photocatalytic efficiencies in Rhodamine B (RhB) degradation were analyzed. The highest removal percentage was found under the simultaneous exposure of visible light and mechanical vibrations, reaching 86.2% after 180 min. The calculated efficiencies for photo- and piezocatalysis were 12.2% and 83.7%, respectively. The rate constant (k) for piezo-photocatalysis was 16.1 times higher than that found during photocatalytic experiments. To assess the contribution of each reactive species to the decomposition process, different reagents were added to the Rhodamine B contaminated solution. The results revealed that when p-benzoquinone was used, the degradation efficiency declined significantly from 86.2% to 37.6%, suggesting that superoxide radicals (O₂^•−) play a key role in decomposing RhB molecules. The structural, chemical, optical, and ferroelectric changes caused by the catalytic processes were analyzed and linked to the proposed degradation mechanisms. The poor photocatalytic efficiency was linked to an improper band structure and an improper polarization orientation of the ferroelectric domains in the as-deposited film. The degradation mechanisms in piezo-photocatalysis were driven partly by the band bending caused by mechanical vibrations and partly by the reorientation of the induced polarization of the domains in the unstrained film. Full article