Search Results (282)

At present, there is a lack of in-depth knowledge of the effects of heavy metal-related industries (HMIs) in China on the environment. Hunan Province, as a representative gathering place of HMIs, is among the regions in China that are the most severely polluted with heavy metals. This paper selected Hunan Province as the study area to analyze the development trend, characteristics of pollution emissions, and environmental impacts of seven HMIs based on emission permit information data from Hunan Province. The results of this study show that (1) from 2000 to 2022, the number of heavy metal-related enterprises in Hunan Province increased overall. Among the seven industries, the chemical product manufacturing industry (CPMI) had the largest number of enterprises, whereas the nonferrous metal smelting and rolling industry (NSRI) had the highest gross industrial product (27.6%). (2) HMIs in Hunan Province had significant emissions of cadmium (Cd), arsenic (As), and hydargyrum (Hg) from exhaust gas and wastewater. Heavy metal-related exhaust gas and wastewater outlets from the NSRI constituted 43.9% and 35.3%, respectively, of all outlets of the corresponding type. The proportions of exhaust gas outlets involving Cd, Hg, and As from the NSRI to total exhaust gas outlets were 44.27%, 60.54%, and 34.23%, respectively. The proportions of wastewater outlets involving Cd, Hg, and As from the NSRI to total wastewater outlets were 61.13%, 57.89%, and 75.30%, respectively. (3) The average distances of heavy metal-related enterprises from arable land, rivers, and flooded areas in Hunan Province were 256 m, 1763 m, and 3352 m, respectively. Counties with high environmental risk (H-L type) were situated mainly in eastern Hunan. Among them, Chenzhou had the most heavy metal-related wastewater outlets (22.7%), and Hengyang had the most heavy metal-related exhaust gas outlets (23.1%). The results provide a scientific basis for the prevention and control of heavy metal pollution and an enhancement in environmental sustainability in typical Chinese areas where HMIs are concentrated. Full article

The risk of developing symptomatic knee osteoarthritis (KOA) during a lifetime, i.e., pain, aching, or stiffness in a joint associated with radiographic KOA, was estimated in 2008 to be around 40% in men and 47% in women. The clinical and scientific communities lack an efficient diagnostic method to effectively monitor, evaluate, and predict the evolution of KOA before and during the therapeutic protocol. In this review, we summarize the main methods that are used or seem promising for the diagnosis of osteoarthritis, with a specific focus on non- or low-invasive methods. As standard diagnostic tools, arthroscopy, magnetic resonance imaging (MRI), and X-ray radiography provide spatial and direct visualization of the joint. However, discrepancies between findings and patient feelings often occur, indicating a lack of correlation between current imaging methods and clinical symptoms. Alternative strategies are in development, including the analysis of biochemical markers or acoustic emission recordings. These methods have undergone deep development and propose, with non- or minimally invasive procedures, to obtain data on tissue condition. However, they present some drawbacks, such as possible interference or the lack of direct visualization of the tissue. Other original methods show strong potential in the field of KOA monitoring, such as electrical bioimpedance or near-infrared spectrometry. These methods could permit us to obtain cheap, portable, and non-invasive data on joint tissue health, while they still need strong implementation to be validated. Also, the use of Artificial Intelligence (AI) in the diagnosis seems essential to effectively develop and validate predictive models for KOA evolution, provided that a large and robust database is available. This would offer a powerful tool for researchers and clinicians to improve therapeutic strategies while permitting an anticipated adaptation of the clinical protocols, moving toward reliable and personalized medicine. Full article

Micro gas turbines serve small-scale generation where swift response and low emissions are highly valued, and they are commonly fuelled by natural gas. True to their ‘micro’ designation, their size is indeed compact; however, a noteworthy portion of the enclosure is devoted to power electronics components. This article considers whether these components can be made even smaller by substituting their conventional silicon switches with switches fashioned from silicon carbide. The wider bandgap of silicon carbide permits stronger electric fields and reliable operation at higher temperatures, which together promise lower switching losses, less heat, and simpler cooling arrangements. This study rests on a simple volumetric model. Two data sets feed the model. First come the manufacturer specifications for a pair of converter modules (one silicon, the other silicon carbide) with identical operation ratings. Second are the operating data and dimensions of a commercial 100 kW micro gas turbine. The model splits the converter into two parts: the semiconductor package and its cooling hardware. It then applies scaling factors that capture the higher density of silicon carbide and its lower switching losses. Lower switching losses reduce generated heat, so heatsinks, fans, or coolant channels can be slimmer. Together these effects shrink the cooling section and, therefore, the entire converter. The findings show that a micro gas turbine inverter built with silicon carbide occupies about one fifth less space and delivers more than a quarter higher power density than its silicon counterpart. Full article

New conjugated carbazolyl-substituted azulenes, such as 1,2,3-tris(carbazolyl)azulene and 1,2,3,6-tetrakis(carbazolyl)azulene, were synthesized via cross-coupling reactions in high yields. The resulting compounds exhibit a significant ability to absorb and emit light in the visible region, in the range of 400 to 600 nanometers. Studies have shown that azulene with carbazolyl substituents at positions 1, 2, 3, and 6 possesses unique photophysical properties, manifested as intense emission in the blue photoluminescence region (λ_PL at 444 and 490 nm), which is not observed in the original azulene. This feature arises due to the donor properties of carbazolyl substituents, which have a strong effect on the electronic structure of azulene, creating the conditions for a permitted HOMO-LUMO electronic transition. Full article

We report new medium-resolution spectroscopy covering the wavelength range from 0.6 to 2.4 $\mathsf{\mu }$m, as well as multi-epoch, multi-wavelength photometry, of the Class I high-mass embedded young stellar object Mol 12 (IRAS 05373+2349). It is embedded ($A_V\simeq 12$) in the centre of a dense core at a distance of 1.59 kpc from the Sun and has a total luminosity of $1.74\times {10}^3{L}_{\odot }$. The spectra show a large number of permitted atomic emission lines, mostly for Fe, H, C, N, and Ca, that originate in the inner zones of a very active protoplanetary disc and no photospheric absorption lines. Conspicuously, the He I line at 1.0830 $\mathsf{\mu }$m displays a complex P-Cygni profile. Also, the first overtone CO emission band-heads at 2.3 $\mathsf{\mu }$m are seen in emission. From the strengths of the principal emission lines, we determined the accretion rate and luminosity to be $\dot{M}\sim {10}^{-5}{M}_{\odot }$ y⁻¹ and $L_{\mathrm{acc}}\sim {10}^3{L}_{\odot }$, respectively. Decade-long light curves show a series of irregular brightness dips of more than four magnitudes in r, becoming shallower as the wavelength increases and disappearing at $\lambda >3\mathsf{\mu }$m. The colour–magnitude diagrams suggest the occurrence of a series of eclipses caused by the passage of small dust cloudlets in front of the star, producing more than 10 magnitudes of extra extinction. Full article

Cement production is a major contributor to CO₂ emissions, while construction and demolition waste (CDW) presents growing environmental challenges. The new European standard UNE-EN 197-6 permits the use of recycled concrete fines as partial clinker replacements, providing a regulatory framework for integrating CDW into cementitious systems. This study investigates two CDW-derived fillers, FHH (recycled concrete filler) and FHC (recycled ceramic–concrete mixed filler), as partial substitutes for ordinary Portland cement (OPC). The materials were characterized using XRD, XRF, FTIR, and particle size analysis. Cement pastes and mortars with 10%, 20%, and 30% volume replacements were evaluated for hydration behavior, mechanical performance, and durability. At lower replacement levels, FHC promoted ettringite formation and microstructural refinement, while FHH favored carbonate hydrate development; both fillers also exhibited durability comparable to the control. At higher levels, they maintained satisfactory compressive strength. This study offers critical insights into the integration of CDW-derived fillers into cementitious systems, revealing their potential to significantly reduce clinker consumption while maintaining high mechanical and durability standards. Full article

Ice accumulation poses a significant hazard to aviation safety, particularly in cold weather conditions, as it can compromise aerodynamic performance, increase structural weight, and diminish lift, occasionally resulting in severe stall incidents. At present, such risks are managed through the use of energy-demanding active ice protection systems (IPSs), which operate either by inhibiting ice formation (anti-icing) or by removing existing ice (de-icing). Nonetheless, in the context of future sustainable aviation, there is a pressing need to develop IPSs with lower energy requirements. A promising approach involves hybrid IPSs that integrate conventional active systems with passive superhydrophobic or icephobic surface treatments, which are capable of preventing, delaying, or minimizing ice buildup. These systems offer the potential to substantially decrease the energy consumption and consequently the CO₂ emissions. Furthermore, in accordance with FAA regulations, active IPSs are not permitted to operate during takeoff and initial flight stages to prevent any reduction in engine thrust. These two reasons emphasize the critical importance of developing efficient coatings that, on the one hand, promote the mobility of water droplets, hereby preventing ice formation, as achieved by superhydrophobic surfaces, and on the other hand, facilitate ice detachment, as required for icephobic performance. In this context, the primary objective of the present work is to emphasize the icephobic properties of two superhydrophobic coatings. To achieve this, an extensive characterization is first conducted, including wettability, Surface Free Energy (SFE), and surface roughness, to confirm their superhydrophobic nature. This is followed by an assessment of their icephobic performance, specifically in terms of ice adhesion strength, with comparisons made against a commercial aeronautical coating. The results revealed a significant reduction in both the wettability and SFE of the developed coatings compared to the reference, along with a marked decrease in ice adhesion strength, thereby demonstrating their icephobic properties. Future activities will focus on the combination of coatings with active IPS in order to assess the energy efficiency under extensive icing conditions where both superhydrophobic and icephobic properties are required. Full article

The prohibition zone policy restricts certain activities in specific areas to protect the environment, while the emission permit policy allows companies to trade emissions permits as a market-based approach to regulation. Can the two policies jointly promote the carbon emission reduction of the pig breeding industry (PBI)? Based on the panel data of 31 provinces and cities in China from 2010 to 2020, this paper adopts propensity score matching and multi-period difference-in-differences (PSM-DID) models to study the impact of the dual policy of the prohibition zone and emission permit on the carbon emissions of the PBI. Our theoretical and empirical findings suggest that the dual policy significantly reduces carbon emissions in the PBI. A mediating analysis reveals that industrial structure and government penalties regulate the impact of the dual policy. Further analysis shows that the prohibition zone policy and the emission permit policy play a synergistic role in the impact on the carbon emissions of the PBI. Regional heterogeneity is also explored, indicating that the carbon emission reduction effect is more significant in western China. Policy implementers should fully consider various policies, regional differences, and regulatory factors, formulating complementary policy combinations to jointly promote the green new quality productivity of the PBI. Full article

This study aimed to assess the pollution levels, sources, ecological risk, and human health risks of metal(loid)s in water, sediment, and muscle tissue of Prochilodus lineatus and Pimelodus maculatus from rivers in the state of Mato Grosso do Sul, Brazil. The metal(loid)s content in river sediment, water, and fish tissue were determined by inductively coupled plasma optical emission spectrometry. Sediment pollution assessment was carried out by geo-accumulation index, contamination factor, enrichment factor, and pollution load index. There were significant differences in concentration values for Al, As, Cd, Co, Cr, Cu, Mo, Ni, Pb, and Hg. There was greater tendency for the elements Cu, Ni, Cu, N, Co, As, Hg, Al, and Co in the waters of the Anhanduí River in 2020 and Cr and Pb in 2021. The concentrations of As, Cd, Co, Cr, and Hg in the waters of the Anhanduí River are above the permitted limit values for heavy metal ions in drinking water established by the WHO. The concentrations of heavy metals in the sediments of rivers are above the limit set by Conama/Brazil and other countries. The sediments were very highly contaminated by Cd and Mo, and with moderate contamination of Pb. All sediments of rivers showed a decline in site quality, which indicates that it is polluted. Sediments were classified with severe enrichment by Cd and Mo. The content of Al was the highest in P. lineatus and P. maculatus in relation to other elements analyzed. There was also the presence of elements such as Cr, Cu, Cd, Hg, Ni, As, Pb, Mo, and Co in the tissues of the fish species. Therefore, the contamination of these rivers is a concern due to human consumption of fish, since there is a carcinogenic risk related mainly to As and Cd. Full article

Climate risk is the negative effect of climate change on several aspects of the environment, business, and society. There are two categories of climate risks: physical risks include direct impacts due to extreme events and chronic changes due to climate modifications that have become commonplace; the transition risk arises from the economic and regulatory adjustments required to shift toward reducing greenhouse gas emissions and the transition to renewable energy. The problem, in financial terms, is the correct assessment and quantification of transition risk, as it is not univocal in the literature. This research aims to provide a literature review on transition risk that permits filling this gap and identifying the proxies used for its representation and evaluation. Moreover, the analysis considers the critical aspect of the connection between transition and credit risk, as firms exposed to high transition risks may face challenges in maintaining creditworthiness. Results highlight the most commonly used proxies, including carbon pricing, CO₂ or GHG emissions, and metrics from various databases. However, the findings emphasize the importance of integrating these indicators with broader factors, such as a company’s negative environmental impacts (e.g., waste production and water usage) and delays in technological adaptation from a forward-looking perspective. Full article

Background/Objectives: Determining whether 3,4-dihydroxy-6-[¹⁸F]fluoro-L-phenylalanine positron emission tomography/computed tomography ([¹⁸F]F-DOPA PET/CT) data indicate brain metastasis progression (MP) or brain radionecrosis (RN) is challenging. The aim of this study was to present a method usable in the clinical setting without dedicated software that relies on less than five minutes of SiPM PET/CT data collected immediately after [¹⁸F]F-DOPA injection. Methods: We prospectively enrolled 15 patients with 19 lesions. Each acquisition was conducted in list mode (LM) for 25 min using a four-ring SiPM PET/CT system. We reconstructed three volumes from the LM file: acquisition duration of 120 s (V120), 270 s (V270), and 10 min for the standard clinical volume (Vclin). We measured each lesion’s maximum voxel activity (LS_max) and the corresponding mean activity with its standard deviation (CL_mean, CL_sd). We then calculated the LS_max/CL_mean ratio and the coefficient of variation (COV), defined as 100 × (CL_sd/CL_mean). Results: Lesions were classified as RN (n = 7) and MP (n = 12). For all volumes, LS_max/CL_mean differed significantly. The COV parameter exhibited significant differences in all comparisons except for V120 vs. V270. The best diagnostic performances were observed for V120 and V270, with an accuracy of 94.7%. The AUC values were 97.6% in both cases. Conclusions: A simple, static [¹⁸F]F-DOPA PET/CT acquisition, starting 1.5 min after injection and lasting less than five minutes, permitted reaching excellent diagnostic performance (100% sensitivity, 91.7% specificity, and 97.6% AUC) in discriminating between RN and MP. Full article

In response to climate change caused by shipping, the maritime emission trading system (METS) is used to reduce ship carbon emissions, and the METS also imposes additional costs on shipping carriers through emission permit trading. This paper focuses on the deployment of liquefied natural gas-powered (LNG-powered) ships for shipping alliances to comply with the METS. From the perspective of a liner alliance, we investigate how to determine the deployment of LNG-powered ships and how ship emissions will be affected. To investigate these problems, we propose an LNG-powered fleet deployment problem, which integrates slot co-chartering and emission permit trading, to determine the fleet deployment of LNG-powered and oil-powered ships, ship speeds and container shipment. To formulate our proposed problem, we develop a mixed-integer linear programming model, which can be solved effectively by CPLEX. Numerical experiments are provided to assess the effectiveness of our proposed model. Full article

The operational energy efficiency of new buildings in the EU should be at the level of ultra-low or near-zero energy buildings. It is therefore relatively difficult to achieve further energy savings. However, the pre-operational phase—raw material sourcing, manufacturing, transportation, and construction—offers significant energy savings and greenhouse gas reduction opportunities, referred to as embodied energy and equivalent CO₂ emissions. Unlike operational energy, no standard or legislative criteria have yet been established for embodied energy. Setting maximum embodied energy values converted to the unit of heated building area, accounting for building shape factor, and differentiating between high-mass and lightweight constructions are proposed. This study illustrates assessing environmental indicators based on building shape, highlighting the necessity of relative assessments over absolute values to favour energy efficiency. It also emphasizes that precise criteria should derive from authentic data collected during the energy certification and building permitting processes. Integrating assessments of embodied energy and operational energy demand facilitates a comprehensive evaluation of buildings’ environmental performance. Full article

This study investigates the impacts of climate change on precipitation and snowpack in the interior western United States (IWUS) using two sets of convection-permitting Weather Research and Forecasting model simulations. One simulation represents the ~1990 climate, and another represents an ~2050 climate using a pseudo-global warming approach. Climate perturbations for the future climate are given by the CMIP5 ensemble-mean global climate models under the high-end emission scenario. The study analyzes the projected changes in spatial patterns of seasonal precipitation and snowpack, with particular emphasis on the effects of elevation on orographic precipitation and snowpack changes in four key mountain ranges: the Montana Rockies, Greater Yellowstone area, Wasatch Range, and Colorado Rockies. The IWUS simulations reveal an increase in annual precipitation across the majority of the IWUS in this warmer climate, driven by more frequent heavy to extreme precipitation events. Winter precipitation is projected to increase across the domain, while summer precipitation is expected to decrease, particularly in the High Plains. Snow-to-precipitation ratios and snow water equivalent are expected to decrease, especially at lower elevations, while snowpack melt is projected to occur earlier by up to 26 days in the ~2050 climate, highlighting significant impacts on regional water resources and hydrological management. Full article

This study addresses the task of ecologically assessing the consequences of natural fires. Statistical data are presented on the carbon dioxide emissions in millions of tons and analytical data on the locations of peat fires, as well as modern methods of detection and control of peat and forest fires, divided into groups. An analysis of the works of leading Russian and international scientists and research organizations engaged in the search for methods of peat fire forecasting is also presented. Our aim was to develop a more effective method of preventing peat soil ignition by changing its physical and moisture characteristics. To that end, peat samples were selected in the Tver region. The laboratory equipment and the methodology of our experimental studies are described in detail, in which we simulated the natural climatic conditions in the center of the Russian Federation. This study provides a mathematical description of the process of spontaneous ignition, which occurs according to the following steps: a heat flow heats the surface to the ignition temperature, creating a self-heating zone; eventually, a wave of ignition (smoldering) capable of self-propagation is formed. We experimentally determined the spontaneous thermal ignition conditions in our experimental studies of the fire hazards of selected peat samples, where the test material was loaded in a cylindrical container made of brass net with a 0.8 mm mesh, of the dimensions 30 × 30 mm. Thermocouple elements were placed inside the container, fixing the temperature of the surface and the center of the sample, where the smoldering or ignition zone of the test material formed. We analyzed the results of our experimental studies on peat samples’ self-heating chemical reaction, leading us to draw conclusions about the possibility of fires on peat soil depending on its physical and chemical characteristics. We also offer recommendations that will improve peat soils’ fire safety, permitting agricultural crop production without a peat fire risk. Full article