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26 pages, 9773 KiB  
Review
A Narrative Review of the Clinical Applications of Echocardiography in Right Heart Failure
by North J. Noelck, Heather A. Perry, Phyllis L. Talley and D. Elizabeth Le
J. Clin. Med. 2025, 14(15), 5505; https://doi.org/10.3390/jcm14155505 - 5 Aug 2025
Abstract
Background/Objectives: Historically, echocardiographic imaging of the right heart has been challenging because its abnormal geometry is not conducive to reproducible anatomical and functional assessment. With the development of advanced echocardiographic techniques, it is now possible to complete an integrated assessment of the right [...] Read more.
Background/Objectives: Historically, echocardiographic imaging of the right heart has been challenging because its abnormal geometry is not conducive to reproducible anatomical and functional assessment. With the development of advanced echocardiographic techniques, it is now possible to complete an integrated assessment of the right heart that has fewer assumptions, resulting in increased accuracy and precision. Echocardiography continues to be the first-line imaging modality for diagnostic analysis and the management of acute and chronic right heart failure because of its portability, versatility, and affordability compared to cardiac computed tomography, magnetic resonance imaging, nuclear scintigraphy, and positron emission tomography. Virtually all echocardiographic parameters have been well-validated and have demonstrated prognostic significance. The goal of this narrative review of the echocardiographic parameters of the right heart chambers and hemodynamic alterations associated with right ventricular dysfunction is to present information that must be acquired during each examination to deliver a comprehensive assessment of the right heart and to discuss their clinical significance in right heart failure. Methods: Using a literature search in the PubMed database from 1985 to 2025 and the Cochrane database, which included but was not limited to terminology that are descriptive of right heart anatomy and function, disease states involving acute and chronic right heart failure and pulmonary hypertension, and the application of conventional and advanced echocardiographic modalities that strive to elucidate the pathophysiology of right heart failure, we reviewed randomized control trials, observational retrospective and prospective cohort studies, societal guidelines, and systematic review articles. Conclusions: In addition to the conventional 2-dimensional echocardiography and color, spectral, and tissue Doppler measurements, a contemporary echocardiographic assessment of a patient with suspected or proven right heart failure must include 3-dimensional echocardiographic-derived measurements, speckle-tracking echocardiography strain analysis, and hemodynamics parameters to not only characterize the right heart anatomy but to also determine the underlying pathophysiology of right heart failure. Complete and point-of-care echocardiography is available in virtually all clinical settings for routine care, but this imaging tool is particularly indispensable in the emergency department, intensive care units, and operating room, where it can provide an immediate assessment of right ventricular function and associated hemodynamic changes to assist with real-time management decisions. Full article
(This article belongs to the Special Issue Cardiac Imaging in the Diagnosis and Management of Heart Failure)
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24 pages, 9190 KiB  
Article
Modeling the Historical and Future Potential Global Distribution of the Pepper Weevil Anthonomus eugenii Using the Ensemble Approach
by Kaitong Xiao, Lei Ling, Ruixiong Deng, Beibei Huang, Qiang Wu, Yu Cao, Hang Ning and Hui Chen
Insects 2025, 16(8), 803; https://doi.org/10.3390/insects16080803 (registering DOI) - 3 Aug 2025
Viewed by 42
Abstract
The pepper weevil Anthonomus eugenii is a devastating pest native to Central America that can cause severe damage to over 35 pepper varieties. Global trade in peppers has significantly increased the risk of its spread and expansion. Moreover, future climate change may add [...] Read more.
The pepper weevil Anthonomus eugenii is a devastating pest native to Central America that can cause severe damage to over 35 pepper varieties. Global trade in peppers has significantly increased the risk of its spread and expansion. Moreover, future climate change may add more uncertainty to its distribution, resulting in considerable ecological and economic damage globally. Therefore, we employed an ensemble model combining Random Forests and CLIMEX to predict the potential global distribution of A. eugenii in historical and future climate scenarios. The results indicated that the maximum temperature of the warmest month is an important variable affecting global A. eugenii distribution. Under the historical climate scenario, the potential global distribution of A. eugenii is concentrated in the Midwestern and Southern United States, Central America, the La Plata Plain, parts of the Brazilian Plateau, the Mediterranean and Black Sea coasts, sub-Saharan Africa, Northern and Southern China, Southern India, Indochina Peninsula, and coastal area in Eastern Australia. Under future climate scenarios, suitable areas in the Northern Hemisphere, including North America, Europe, and China, are projected to expand toward higher latitudes. In China, the number of highly suitable areas is expected to increase significantly, mainly in the south and north. Contrastingly, suitable areas in Central America, northern South America, the Brazilian Plateau, India, and the Indochina Peninsula will become less suitable. The total land area suitable for A. eugenii under historical and future low- and high-emission climate scenarios accounted for 73.12, 66.82, and 75.97% of the global land area (except for Antarctica), respectively. The high-suitability areas identified by both models decreased by 19.05 and 35.02% under low- and high-emission scenarios, respectively. Building on these findings, we inferred the future expansion trends of A. eugenii globally. Furthermore, we provide early warning of A. eugenii invasion and a scientific basis for its spread and outbreak, facilitating the development of effective quarantine and control measures. Full article
(This article belongs to the Section Insect Ecology, Diversity and Conservation)
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20 pages, 6694 KiB  
Article
Spatiotemporal Assessment of Benzene Exposure Characteristics in a Petrochemical Industrial Area Using Mobile-Extraction Differential Optical Absorption Spectroscopy (Me-DOAS)
by Dong keun Lee, Jung-min Park, Jong-hee Jang, Joon-sig Jung, Min-kyeong Kim, Jaeseok Heo and Duckshin Park
Toxics 2025, 13(8), 655; https://doi.org/10.3390/toxics13080655 - 31 Jul 2025
Viewed by 213
Abstract
Petrochemical complexes are spatially expansive and host diverse emission sources, making accurate monitoring of volatile organic compounds (VOCs) challenging using conventional two-dimensional methods. This study introduces Mobile-extraction Differential Optical Absorption Spectroscopy (Me-DOAS), a real-time, three-dimensional remote sensing technique for assessing benzene emissions in [...] Read more.
Petrochemical complexes are spatially expansive and host diverse emission sources, making accurate monitoring of volatile organic compounds (VOCs) challenging using conventional two-dimensional methods. This study introduces Mobile-extraction Differential Optical Absorption Spectroscopy (Me-DOAS), a real-time, three-dimensional remote sensing technique for assessing benzene emissions in the Ulsan petrochemical complex, South Korea. A vehicle-mounted Me-DOAS system conducted monthly measurements throughout 2024, capturing data during four daily intervals to evaluate diurnal variation. Routes included perimeter loops and grid-based transects within core industrial zones. The highest benzene concentrations were observed in February (mean: 64.28 ± 194.69 µg/m3; geometric mean: 5.13 µg/m3), with exceedances of the national annual standard (5 µg/m3) in several months. Notably, nighttime and early morning sessions showed elevated levels, suggesting contributions from nocturnal operations and meteorological conditions such as atmospheric inversion. A total of 179 exceedances (≥30 µg/m3) were identified, predominantly in zones with benzene-handling activities. Correlation analysis revealed a significant relationship between high concentrations and specific emission sources. These results demonstrate the utility of Me-DOAS in capturing spatiotemporal emission dynamics and support its application in exposure risk assessment and industrial emission control. The findings provide a robust framework for targeted management strategies and call for integration with source apportionment and dispersion modeling tools. Full article
(This article belongs to the Section Air Pollution and Health)
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17 pages, 458 KiB  
Article
Effects of Chestnut Tannin Extract on Enteric Methane Emissions, Blood Metabolites and Lactation Performance in Mid-Lactation Cows
by Radiša Prodanović, Dušan Bošnjaković, Ana Djordjevic, Predrag Simeunović, Sveta Arsić, Aleksandra Mitrović, Ljubomir Jovanović, Ivan Vujanac, Danijela Kirovski and Sreten Nedić
Animals 2025, 15(15), 2238; https://doi.org/10.3390/ani15152238 - 30 Jul 2025
Viewed by 119
Abstract
Dietary tannin supplementation represents a potential strategy to modulate rumen fermentation and enhance lactation performance in dairy cows, though responses remain inconsistent. A 21-day feeding trial was conducted to evaluate the effect of chestnut tannin (CNT) extract on the enteric methane emissions (EME), [...] Read more.
Dietary tannin supplementation represents a potential strategy to modulate rumen fermentation and enhance lactation performance in dairy cows, though responses remain inconsistent. A 21-day feeding trial was conducted to evaluate the effect of chestnut tannin (CNT) extract on the enteric methane emissions (EME), blood metabolites, and milk production traits in mid-lactation dairy cows. Thirty-six Holstein cows were allocated to three homogeneous treatment groups: control (CNT0, 0 g/d CNT), CNT40 (40 g/d CNT), and CNT80 (80 g/d CNT). Measurements of EME, dry matter intake (DMI), milk yield (MY), and blood and milk parameters were carried out pre- and post-21-day supplementation period. Compared with the no-additive group, the CNT extract reduced methane production, methane yield, and methane intensity in CNT40 and CNT80 (p < 0.001). CNT40 and CNT80 cows exhibited lower blood urea nitrogen (p = 0.019 and p = 0.002) and elevated serum insulin (p = 0.003 and p < 0.001) and growth hormone concentrations (p = 0.046 and p = 0.034), coinciding with reduced aspartate aminotransferase (p = 0.016 and p = 0.045), and lactate dehydrogenase (p = 0.011 and p = 0.008) activities compared to control. However, CNT80 had higher circulating NEFA and BHBA than CNT0 (p = 0.003 and p = 0.004) and CNT40 (p = 0.035 and p = 0.019). The blood glucose, albumin, and total bilirubin concentrations were not affected. MY and fat- and protein-corrected milk (FPCM), MY/DMI, and FPCM/DMI were higher in both CNT40 (p = 0.004, p = 0.003, p = 0.014, p = 0.010) and CNT80 (p = 0.002, p = 0.003, p = 0.008, p = 0.013) cows compared with controls. Feeding CNT80 resulted in higher protein content (p = 0.015) but lower fat percentage in milk (p = 0.004) compared to CNT0. Milk urea nitrogen and somatic cell counts were significantly lower in both CNT40 (p < 0.001, p = 0.009) and CNT80 (p < 0.001 for both) compared to CNT0, while milk lactose did not differ between treatments. These findings demonstrate that chestnut tannin extract effectively mitigates EME while enhancing lactation performance in mid-lactation dairy cows. Full article
(This article belongs to the Special Issue Advances in Nutrition and Feeding Strategies for Dairy Cows)
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19 pages, 3546 KiB  
Article
Loss and Early Recovery of Biomass and Soil Organic Carbon in Restored Mangroves After Paspalum vaginatum Invasion in West Africa
by Julio César Chávez Barrera, Juan Fernando Gallardo Lancho, Robert Puschendorf and Claudia Maricusa Agraz Hernández
Resources 2025, 14(8), 122; https://doi.org/10.3390/resources14080122 - 29 Jul 2025
Viewed by 246
Abstract
Invasive plant species pose an increasing threat to mangroves globally. This study assessed the impact of Paspalum vaginatum invasion on carbon loss and early recovery following four years of restoration in a mangrove forest with Rhizophora racemosa in Benin. Organic carbon was quantified [...] Read more.
Invasive plant species pose an increasing threat to mangroves globally. This study assessed the impact of Paspalum vaginatum invasion on carbon loss and early recovery following four years of restoration in a mangrove forest with Rhizophora racemosa in Benin. Organic carbon was quantified in the total biomass, including both aboveground and belowground components, as well as in the soil to a depth of −50 cm. In addition, soil gas fluxes of CO2, CH4, and N2O were measured. Three sites were evaluated: a conserved mangrove, a site degraded by P. vaginatum, and the same site post-restoration via hydrological rehabilitation and reforestation. Invasion significantly reduced carbon storage, especially in soil, due to lower biomass, incorporation of low C/N ratio organic residues, and compaction. Restoration recovered 7.8% of the total biomass carbon compared to the conserved mangrove site, although soil organic carbon did not rise significantly in the short term. However, improvements in deep soil C/N ratios (15–30 and 30–50 cm) suggest enhanced soil organic matter recalcitrance linked to R. racemosa reforestation. Soil CO2 emissions dropped by 60% at the restored site, underscoring restoration’s potential to mitigate early carbon loss. These results highlight the need to control invasive species and suggest that restoration can generate additional social benefits. Full article
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33 pages, 16026 KiB  
Article
Spatiotemporal Analysis of BTEX and PM Using Me-DOAS and GIS in Busan’s Industrial Complexes
by Min-Kyeong Kim, Jaeseok Heo, Joonsig Jung, Dong Keun Lee, Jonghee Jang and Duckshin Park
Toxics 2025, 13(8), 638; https://doi.org/10.3390/toxics13080638 - 29 Jul 2025
Viewed by 232
Abstract
Rapid industrialization and urbanization have progressed in Korea, yet public attention to hazardous pollutants emitted from industrial complexes remains limited. With the increasing coexistence of industrial and residential areas, there is a growing need for real-time monitoring and management plans that account for [...] Read more.
Rapid industrialization and urbanization have progressed in Korea, yet public attention to hazardous pollutants emitted from industrial complexes remains limited. With the increasing coexistence of industrial and residential areas, there is a growing need for real-time monitoring and management plans that account for the rapid dispersion of hazardous air pollutants (HAPs). In this study, we conducted spatiotemporal data collection and analysis for the first time in Korea using real-time measurements obtained through mobile extractive differential optical absorption spectroscopy (Me-DOAS) mounted on a solar occultation flux (SOF) vehicle. The measurements were conducted in the Saha Sinpyeong–Janglim Industrial Complex in Busan, which comprises the Sasang Industrial Complex and the Sinpyeong–Janglim Industrial Complex. BTEX compounds were selected as target volatile organic compounds (VOCs), and real-time measurements of both BTEX and fine particulate matter (PM) were conducted simultaneously. Correlation analysis revealed a strong relationship between PM10 and PM2.5 (r = 0.848–0.894), indicating shared sources. In Sasang, BTEX levels were associated with traffic and localized facilities, while in Saha Sinpyeong–Janglim, the concentrations were more influenced by industrial zoning and wind patterns. Notably, inter-compound correlations such as benzene–m-xylene and p-xylene–toluene suggested possible co-emission sources. This study proposes a GIS-based, three-dimensional air quality management approach that integrates variables such as traffic volume, wind direction, and speed through real-time measurements. The findings are expected to inform effective pollution control strategies and future environmental management plans for industrial complexes. Full article
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19 pages, 11455 KiB  
Article
Characterizing Tracer Flux Ratio Methods for Methane Emission Quantification Using Small Unmanned Aerial System
by Ezekiel Alaba, Bryan Rainwater, Ethan Emerson, Ezra Levin, Michael Moy, Ryan Brouwer and Daniel Zimmerle
Methane 2025, 4(3), 18; https://doi.org/10.3390/methane4030018 - 29 Jul 2025
Viewed by 159
Abstract
Accurate methane emission estimates are essential for climate policy, yet current field methods often struggle with spatial constraints and source complexity. Ground-based mobile approaches frequently miss key plume features, introducing bias and uncertainty in emission rate estimates. This study addresses these limitations by [...] Read more.
Accurate methane emission estimates are essential for climate policy, yet current field methods often struggle with spatial constraints and source complexity. Ground-based mobile approaches frequently miss key plume features, introducing bias and uncertainty in emission rate estimates. This study addresses these limitations by using small unmanned aerial systems equipped with precision gas sensors to measure methane alongside co-released tracers. We tested whether arc-shaped flight paths and alternative ratio estimation methods could improve the accuracy of tracer-based emission quantification under real-world constraints. Controlled releases using ethane and nitrous oxide tracers showed that (1) arc flights provided stronger plume capture and higher correlation between methane and tracer concentrations than traditional flight paths; (2) the cumulative sum method yielded the lowest relative error (as low as 3.3%) under ideal mixing conditions; and (3) the arc flight pattern yielded the lowest relative error and uncertainty across all experimental configurations, demonstrating its robustness for quantifying methane emissions from downwind plume measurements. These findings demonstrate a practical and scalable approach to reducing uncertainty in methane quantification. The method is well-suited for challenging environments and lays the groundwork for future applications at the facility scale. Full article
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20 pages, 6713 KiB  
Article
Influence of Nanosilica and PVA Fibers on the Mechanical and Deformation Behavior of Engineered Cementitious Composites
by Mohammed A. Albadrani
Polymers 2025, 17(15), 2067; https://doi.org/10.3390/polym17152067 - 29 Jul 2025
Viewed by 232
Abstract
This paper evaluates the synergistic effect of polyvinyl alcohol (PVA) fibers and nanosilica (nS) on the mechanical behavior and deformation properties of engineered cementitious composites (ECCs). ECCs have gained a reputation for high ductility, crack control, and strain-hardening behavior. Nevertheless, the next step [...] Read more.
This paper evaluates the synergistic effect of polyvinyl alcohol (PVA) fibers and nanosilica (nS) on the mechanical behavior and deformation properties of engineered cementitious composites (ECCs). ECCs have gained a reputation for high ductility, crack control, and strain-hardening behavior. Nevertheless, the next step is to improve their performance even more through nano-modification and fine-tuning of fiber dosage—one of the major research directions. In the experiment, six types of ECC mixtures were made by maintaining constant PVA fiber content (0.5, 1.0, 1.5, and 2.0%), while the nanosilica contents were varied (0, 1, 2, 3, and 5%). Stress–strain tests carried out in the form of compression, together with unrestrained shrinkage measurement, were conducted to test strength, strain capacity, and resistance to deformation, which was highest at 80 MPa, recorded in the concrete with 2% nS and 0.5% PVA. On the other hand, the mixture of 1.5% PVA and 3% nS had the highest strain result of 2750 µm/m, which indicates higher ductility. This is seen to be influenced by refined microstructures, improved fiber dispersion, and better fiber–matrix interfacial bonding through nS. In addition to these mechanical modifications, the use of nanosilica, obtained from industrial byproducts, provided the possibility to partially replace Portland cement, resulting in a decrease in the amount of CO2 emissions. In addition, the enhanced crack resistance implies higher durability and reduced long-term maintenance. Such results demonstrate that optimized ECC compositions, including nS and PVA, offer high performance in terms of strength and flexibility as well as contribute to the sustainability goals—features that will define future eco-efficient infrastructure. Full article
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19 pages, 1537 KiB  
Review
Milk Fatty Acids as Potential Biomarkers of Enteric Methane Emissions in Dairy Cattle: A Review
by Emily C. Youngmark and Jana Kraft
Animals 2025, 15(15), 2212; https://doi.org/10.3390/ani15152212 - 28 Jul 2025
Viewed by 335
Abstract
Measuring methane (CH4) emissions from dairy systems is crucial for advancing sustainable agricultural practices aimed at mitigating climate change. However, current CH4 measurement techniques are primarily designed for controlled research settings and are not readily scalable to diverse production environments. [...] Read more.
Measuring methane (CH4) emissions from dairy systems is crucial for advancing sustainable agricultural practices aimed at mitigating climate change. However, current CH4 measurement techniques are primarily designed for controlled research settings and are not readily scalable to diverse production environments. Thus, there is a need to develop accessible, production-level methods for estimating CH4 emissions. This review examines the relationship between enteric CH4 emissions and milk fatty acid (FA) composition, highlights key FA groups with potential as biomarkers for indirect CH4 estimation, and outlines critical factors of predictive model development. Several milk FAs exhibit strong and consistent correlations to CH4 emissions, supporting their utility as predictive biomarkers. Saturated and branched-chain FAs are generally positively associated with CH4 emissions, while unsaturated FAs, including linolenic acid, conjugated linoleic acids, and odd-chain FAs, are typically negatively associated. Variability in the strength and direction of correlations across studies is often attributable to differences in diet or lactation stage. Similarly, differences in experimental design, data processing, and model development contribute to much of the variation observed in predictive equations across studies. Future research should aim to (1) identify milk FAs that consistently correlate with CH4 emissions regardless of diet, (2) develop robust and standardized prediction models, and (3) prioritize the external validation of prediction models across herds and production systems. Full article
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19 pages, 13565 KiB  
Article
Estimation of Ultrahigh Resolution PM2.5 in Urban Areas by Using 30 m Landsat-8 and Sentinel-2 AOD Retrievals
by Hao Lin, Siwei Li, Jiqiang Niu, Jie Yang, Qingxin Wang, Wenqiao Li and Shengpeng Liu
Remote Sens. 2025, 17(15), 2609; https://doi.org/10.3390/rs17152609 - 27 Jul 2025
Viewed by 245
Abstract
Ultrahigh resolution fine particulate matter (PM2.5) mass concentration remote sensing products are crucial for atmospheric environmental monitoring, pollution source verification, health exposure risk assessment, and other fine-scale applications in urban environments. This study developed an ultrahigh resolution retrieval algorithm to estimate [...] Read more.
Ultrahigh resolution fine particulate matter (PM2.5) mass concentration remote sensing products are crucial for atmospheric environmental monitoring, pollution source verification, health exposure risk assessment, and other fine-scale applications in urban environments. This study developed an ultrahigh resolution retrieval algorithm to estimate 30 m resolution PM2.5 mass concentrations over urban areas from Landsat-8 and Sentinel-2A/B satellite measurements. The algorithm utilized aerosol optical depth (AOD) products retrieved from the Landsat-8 OLI and Sentinel-2 MSI measurements from 2017 to 2020, combined with multi-source auxiliary data to establish a PM2.5-AOD relationship model across China. The results showed an overall high coefficient of determination (R2) of 0.82 and 0.76 for the model training accuracy based on samples and stations, respectively. The model prediction accuracy in Beijing and Wuhan reached R2 values of 0.86 and 0.85. Applications in both cities demonstrated that ultrahigh resolution PM2.5 has significant advantages in resolving fine-scale spatial patterns of urban air pollution and pinpointing pollution hotspots. Furthermore, an analysis of point source pollution at a typical heavy pollution emission enterprise confirmed that ultrahigh spatial resolution PM2.5 can accurately identify the diffusion trend of point source pollution, providing fundamental data support for refined monitoring of urban air pollution and air pollution prevention and control. Full article
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17 pages, 3579 KiB  
Article
Source Apportionment of PM2.5 in a Chinese Megacity During Special Periods: Unveiling Impacts of COVID-19 and Spring Festival
by Kejin Tang, Xing Peng, Yuqi Liu, Sizhe Liu, Shihai Tang, Jiang Wu, Shaoxia Wang, Tingting Xie and Tingting Yao
Atmosphere 2025, 16(8), 908; https://doi.org/10.3390/atmos16080908 - 26 Jul 2025
Viewed by 229
Abstract
Long-term source apportionment of PM2.5 during high-pollution periods is essential for achieving sustained reductions in both PM2.5 levels and their health impacts. This study conducted PM2.5 sampling in Shenzhen from January to March over the years 2021–2024 to investigate the [...] Read more.
Long-term source apportionment of PM2.5 during high-pollution periods is essential for achieving sustained reductions in both PM2.5 levels and their health impacts. This study conducted PM2.5 sampling in Shenzhen from January to March over the years 2021–2024 to investigate the long-term impact of coronavirus disease 2019 and the short-term impact of the Spring Festival on PM2.5 levels. The measured average PM2.5 concentration during the research period was 22.5 μg/m3, with organic matter (OM) being the dominant component. Vehicle emissions, secondary sulfate, secondary nitrate, and secondary organic aerosol were identified by receptor model as the primary sources of PM2.5 during the observational periods. The pandemic led to a decrease of between 30% and 50% in the contributions of most anthropogenic sources in 2022 compared to 2021, followed by a rebound. PM2.5 levels in January–March 2024 dropped by 1.4 μg/m3 compared to 2021, mainly due to reduced vehicle emissions, secondary sulfate, fugitive dust, biomass burning, and industrial emissions, reflecting Shenzhen’s and nearby cities’ effective control measures. However, secondary nitrate and fireworks-related emissions rose significantly. During the Spring Festival, PM2.5 concentrations were 23% lower than before the festival, but the contributions of fireworks burning exhibited a marked increase in both 2023 and 2024. Specifically, during intense peak events, fireworks burning triggered sharp, short-term spikes in characteristic metal concentrations, accounting for over 50% of PM2.5 on those peak days. In the future, strict control over vehicle emissions and enhanced management of fireworks burning during special periods like the Spring Festival are necessary to reduce PM2.5 concentration and improve air quality. Full article
(This article belongs to the Special Issue New Insights in Air Quality Assessment: Forecasting and Monitoring)
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20 pages, 6095 KiB  
Article
Effect of Pre-Curing Time and Residual Water–Cement Ratio on CO2 Curing of Recycled Concrete
by Qiyi Lai, Cheng Wang, Yu Liu, Xuejin Ying, Zixin He, Jianjun Zhao and Xiao Zhao
Sustainability 2025, 17(15), 6769; https://doi.org/10.3390/su17156769 - 25 Jul 2025
Viewed by 385
Abstract
Using recycled concrete (RC) created from building debris to capture, utilize, and sequester CO2 is a green and sustainable development strategy. Before CO2 curing, pretreatment can provide a suitable environment for the carbonation reaction of the RC, accelerate the carbonation rate [...] Read more.
Using recycled concrete (RC) created from building debris to capture, utilize, and sequester CO2 is a green and sustainable development strategy. Before CO2 curing, pretreatment can provide a suitable environment for the carbonation reaction of the RC, accelerate the carbonation rate of the RC, and enhance its performance. The effects of the pre-curing time and residual water–cement ratio (Re) on the carbon sequestration rate, carbon sequestration, carbonation depth, and mechanical strength of RC were investigated and validated through X-ray diffraction (XRD) and scanning electron microscopy (SEM). The study demonstrated optimal carbon sequestration properties at a pre-curing time of 5 days. The corresponding carbon sequestration rate, unit carbon sequestration, carbonation depth, and compressive strength were 23.17%, 19.88 g/kg, 15.79 mm, and 28.7 MPa, respectively. Optimal carbon sequestration performance occurred at a Re of 0.26. The measured values were 20.15% (carbon sequestration rate), 17.38 g/kg (unit carbon sequestration), 12.55 mm (carbonation depth), and 31.1 MPa (compressive strength). According to the XRD and SEM results, the effects of pre-curing time and Re were mainly seen in the conversion rate of CaCO3 and a denser microstructure. This implies that improving the CO2 curing effect by controlling the pre-curing time and Re can both alleviate the pressure of greenhouse gas emissions and increase the utilization efficiency of RC. Full article
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18 pages, 1695 KiB  
Review
Temperature Monitoring in Metal Additive Manufacturing in the Era of Industry 4.0
by Aleksandar Mitrašinović, Teodora Đurđević, Jasmina Nešković and Milinko Radosavljević
Technologies 2025, 13(8), 317; https://doi.org/10.3390/technologies13080317 - 23 Jul 2025
Viewed by 240
Abstract
The field of metal additive manufacturing has witnessed significant growth in recent years, with technology offering the ability to produce complex geometries that are challenging to manufacture using the traditional methods. In situ monitoring and control of the manufacturing process are crucial for [...] Read more.
The field of metal additive manufacturing has witnessed significant growth in recent years, with technology offering the ability to produce complex geometries that are challenging to manufacture using the traditional methods. In situ monitoring and control of the manufacturing process are crucial for increasing the production capacity and improving the quality of manufactured parts. This article provides a comparative analysis of computational, indirect, and direct methods for in situ temperature monitoring during additive manufacturing of metal alloy components. Furthermore, it discusses the current status, recent improvements, and perspectives for in situ temperature measurements. The basic principles of thermal imaging, two-color pyrometry, and millimeter-wave radiometry are explored, highlighting their limitations for addressing challenges related to material emissivity and rapid changes in building material composition. Overcoming the challenges related to the inaccessibility of the chamber where the parts are formed, direct temperature measurements would allow for the integration of collected information into big data systems. Within the framework of Industry 4.0, this approach offers a viable alternative to the conventional metal shaping processes, improving the production capacity and part quality. This research aims to contribute to ongoing advancements in metal additive manufacturing and its potential to completely replace traditional metal casting practices in the Industry 4.0 era. Full article
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21 pages, 3372 KiB  
Article
Advanced Research on Biological Properties—A Study on the Activity of the Apis mellifera Antioxidant System and the Crystallographic and Spectroscopic Properties of 7-Diethylamino-4-hydroxycoumarin
by Klaudia Rząd, Iwona Budziak-Wieczorek, Aneta Strachecka, Patrycja Staniszewska, Adam Staniszewski, Anna Gryboś, Alicja Matwijczuk, Bożena Gładyszewska, Karolina Starzak, Anna A. Hoser, Maurycy E. Nowak, Małgorzata Figiel, Sylwia Okoń and Arkadiusz Paweł Matwijczuk
Int. J. Mol. Sci. 2025, 26(14), 7015; https://doi.org/10.3390/ijms26147015 - 21 Jul 2025
Viewed by 440
Abstract
The search for substances that increase the immunity of bees is becoming a necessity in the era of various environmental threats and the declining immunocompetence of these insects. Therefore, we tested the biological and physicochemical properties of 7-diethylamino-4-hydroxycoumarin (7DOC). In a cage test, [...] Read more.
The search for substances that increase the immunity of bees is becoming a necessity in the era of various environmental threats and the declining immunocompetence of these insects. Therefore, we tested the biological and physicochemical properties of 7-diethylamino-4-hydroxycoumarin (7DOC). In a cage test, two groups of bees were created: a control group fed with sugar syrup and an experimental group fed with sugar syrup with the addition of 7DOC. In each group, the longevity of the bees was determined and the protein concentrations and antioxidant activities in the bees’ hemolymph were determined. The bees fed with 7DOC lived 2.7 times longer than those in the control group. The protein concentrations and activities of SOD, CAT, GPx and GST, as well as the TAC levels, were significantly higher in the hemolymph of the supplemented workers. To confirm these potent biological properties of 7DOC, the UV-Vis spectra, emission and excitation of fluorescence, synchronous spectra and finally the fluorescence lifetimes of this compound were measured using the time-correlated single photon counting method, in various environments differing in polarity and in the environment applied in bee research. This compound was shown to be sensitive to changes in solvent polarity. The spectroscopic assays were complemented with crystallographic tests of the obtained monocrystals of the aforementioned compounds, which attested to the aggregation effects observed in the spectra measurements for the selected coumarin. The research results confirm that this compound has the potential to be implemented in apiary management, which will be our application goal, but further research into apiary conditions is required. Full article
(This article belongs to the Section Bioactives and Nutraceuticals)
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18 pages, 1443 KiB  
Article
Global CO2 Emission Reduction Disparities After and Before COVID-19
by Resham Thapa-Parajuli, Rupesh Neupane, Maya Timsina, Bibek Pokharel, Deepa Poudel, Milan Maharjan, Saman Prakash KC and Suprit Shrestha
Sustainability 2025, 17(14), 6602; https://doi.org/10.3390/su17146602 - 19 Jul 2025
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Abstract
The relationship between economic progress and environmental quality remains a central focus in global sustainability discourse. This study examines the link between per capita economic growth and CO2 emissions across 128 countries from 1996 to 2022, controlling for energy consumption, trade volume, [...] Read more.
The relationship between economic progress and environmental quality remains a central focus in global sustainability discourse. This study examines the link between per capita economic growth and CO2 emissions across 128 countries from 1996 to 2022, controlling for energy consumption, trade volume, and foreign direct investment (FDI) inflows. It also evaluates the role of governance quality—measured by regulatory quality and its volatility—while considering the globalization index as a confounding factor influencing CO2 emissions. We test the Environmental Kuznets Curve (EKC) hypothesis, which suggests that emissions initially rise with income but decline after reaching a certain economic threshold. Our findings confirm the global presence of the EKC. The analysis further shows that trade openness, governance, and globalization significantly influence FDI inflows, with FDI, in turn, reinforcing institutional quality through improved governance and globalization indicators. However, in countries with weaker governance and regulatory frameworks, FDI tends to promote pollution-intensive industrial growth, lending support to aspects of the Pollution Haven Hypothesis (PHH). We find a significant departure in EKC explained by post-COVID governance and globalization compromises, which induced the environment towards the PHH phenomenon. These results highlight the need for context-specific policy measures that align economic development with environmental constraints. Full article
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