Search Results (2,471)

Given the climate change observed in the past few decades, sustainable development and the use of renewable energy sources are urgent. In this scenario, hydrogen production through electrolyzers is a promising renewable source and energy vector because of its ultralow greenhouse emissions and high energy content. Hydrogen can be used in a variety of applications, from transportation to electricity generation, contributing to the diversification of the energy matrix. In this context, this paper presents an autonomous isolated DC microgrid system for generating and storing electrical energy to be exclusively used for feeding an electrolyzer hydrogen production plant, which has been retrofitted for green hydrogen production. Experimental verification was performed at Itaipu Parquetec, which consists of an alkaline electrolysis unit directly integrated with a battery energy storage system and renewable sources (e.g., photovoltaic and wind) by using an isolated DC microgrid concept based on DC/DC and AC/DC converters. Experimental results revealed that the new electrolyzer DC microgrid increases the system’s overall efficiency in comparison to the legacy thyristor-based power supply system by 26%, and it autonomously controls the energy supply to the electrolyzer under optimized conditions with an extremely low output current ripple. Another advantage of the proposed DC microgrid is its ability to properly manage the startup and shutdown process of the electrolyzer plant under power generation outages. This paper is the result of activities carried out under the R&D project of ANEEL program No. PD-10381-0221/2021, entitled “Multiport DC-DC Converter and IoT System for Intelligent Energy Management”, which was conducted in partnership with CTG-Brazil. Full article

The European Commission, through the REPowerEU plan and the “Fit for 55” package, aims to reduce fossil fuel dependence and greenhouse gas emissions by promoting electric and fuel cell hybrid electric vehicles (EV-FCHEVs). The transition to this mobility model requires energy systems that are able to provide both electricity and hydrogen while reducing the reliance of residential buildings on the national grid. This study analyses a poly-generative (PG) system composed of a Solid Oxide Fuel Cell (SOFC) fed by biomethane, a Photovoltaic (PV) system, and a Proton Exchange Membrane Electrolyser (PEME), with electric vehicles used as dynamic storage units. The assessment is based on simulation tools developed for the main components and applied to four representative seasonal days in Rende (Italy), considering different daily travel ranges of a 30-vehicle fleet. Results show that the PG system provides about 27 kW of electricity, 14.6 kW of heat, and 3.11 kg of hydrogen in winter, spring, and autumn, and about 26 kW, 14 kW, and 3.11 kg in summer; it fully covers the building’s electrical demand in summer and hot water demand in all seasons. The integration of EV batteries reduces grid dependence, improves renewable self-consumption, and allows for the continuous and efficient operation of both the SOFC and PEME, demonstrating the potential of the proposed system to support the green transition. Full article

This study explored the optimization of green hydrogen production via seawater electrolysis powered by a hybrid photovoltaic (PV)-wind system in KwaZulu-Natal, South Africa. A Box–Behnken Design (BBD), adapted from Response Surface Methodology (RSM), was utilized to address the synergistic effect of key operational factors on the integration of renewable energy for green hydrogen production and its economic viability. Addressing critical gaps in renewable energy integration, the research evaluated the feasibility of direct seawater electrolysis and hybrid renewable systems, alongside their techno-economic viability, to support South Africa’s transition from a coal-dependent energy system. Key variables, including electrolyzer efficiency, wind and PV capacity, and financial parameters, were analyzed to optimize performance metrics such as the Levelized Cost of Hydrogen (LCOH), Net Present Cost (NPC), and annual hydrogen production. At 95% confidence level with regression coefficient (R² > 0.99) and statistical significance (p < 0.05), optimal conditions of electricity efficiency of 95%, a wind-turbine capacity of 4960 kW, a capital investment of $40,001, operational costs of $40,000 per year, a project lifetime of 29 years, a nominal discount rate of 8.9%, and a generic PV capacity of 29 kW resulted in a predictive LCOH of 0.124$/kg H₂ with a yearly production of 355,071 kg. Within the scope of this study, with the goal of minimizing the cost of production, the lowest LCOH observed can be attributed to the architecture of the power ratios (Wind/PV cells) at high energy efficiency (95%) without the cost of desalination of the seawater, energy storage and transportation. Electrolyzer efficiency emerged as the most influential factor, while financial parameters significantly affected the cost-related responses. The findings underscore the technical and economic viability of hybrid renewable-powered seawater electrolysis as a sustainable pathway for South Africa’s transition away from coal-based energy systems. Full article

The development of hydrogen refueling infrastructure plays a strategic role in enabling the decarbonization of the transport sector, especially along major freight and passenger corridors such as the Trans-European Transport Network (TEN-T). Despite the growing interest in hydrogen mobility, existing methodologies for the optimal location of hydrogen refueling stations (HRS) remain fragmented and often overlook operational dynamics. Following a review of the existing literature on HRS location models and approaches, this study highlights key methodological gaps that hinder effective infrastructure planning. In response, a two-stage framework is proposed, combining a flow-based location model with a stochastic queueing approach to determine both the optimal placement of HRS and the number of dispensers required at each site. The method is applied to a real segment of the TEN-T network in Northern Italy. The results demonstrate the flexibility of the model in accommodating different hydrogen vehicle penetration scenarios and its utility as a decision-support tool for public authorities and infrastructure planners. Full article

Hydrogen is increasingly recognized as a clean energy vector and storage medium, yet its viability and strategic role in the Western Balkans remain underexplored. This study provides the first comprehensive techno-economic, environmental, and strategic evaluation of hydrogen production pathways in Albania. Results show clear trade-offs across options. The levelized cost of hydrogen (LCOH) is estimated at 8.76 €/kg H₂ for grid-connected, 7.75 €/kg H₂ for solar, and 7.66 €/kg H₂ for wind electrolysis—values above EU averages and reliant on lower electricity costs and efficiency gains. In contrast, fossil-based hydrogen via steam methane reforming (SMR) is cheaper at 3.45 €/kg H₂, rising to 4.74 €/kg H₂ with carbon capture and storage (CCS). Environmentally, Life Cycle Assessment (LCA) results show much lower Global Warming Potential (<1 kg CO₂-eq/kg H₂) for renewables compared with ~10.39 kg CO₂-eq/kg H₂ for SMR, reduced to 3.19 kg CO₂-eq/kg H₂ with CCS. However, grid electrolysis dominated by hydropower entails high water-scarcity impacts, highlighting resource trade-offs. Strategically, Albania’s growing solar and wind projects (electricity prices of 24.89–44.88 €/MWh), coupled with existing gas infrastructure and EU integration, provide strong potential. While regulatory gaps and limited expertise remain challenges, competition from solar-plus-storage, regional rivals, and dependence on external financing pose additional risks. In the near term, a transitional phase using SMR + CCS could leverage Albania’s gas assets to scale hydrogen production while renewables mature. Overall, Albania’s hydrogen future hinges on targeted investments, supportive policies, and capacity building aligned with EU Green Deal objectives, with solar-powered electrolysis offering the potential to deliver environmentally sustainable green hydrogen at costs below 5.7 €/kg H₂. Full article

Methane pyrolysis produces hydrogen (H₂) with solid carbon black as a co-product, eliminating direct CO₂ emissions and enabling a low-carbon supply when combined with renewable or low-carbon heat sources. In this study, we propose a hybrid geothermal pyrolysis configuration in which an enhanced geothermal system (EGS) provides base-load preheating and isothermal holding, while either electrical or solar–thermal input supplies the final temperature rise to the catalytic set-point. The work addresses four main objectives: (i) integrating field-scale geothermal operating envelopes to define heat-integration targets and duty splits; (ii) assessing scalability through high-pressure reactor design, thermal management, and carbon separation strategies that preserve co-product value; (iii) developing a techno-economic analysis (TEA) framework that lists CAPEX and OPEX, incorporates carbon pricing and credits, and evaluates dual-product economics for hydrogen and carbon black; and (iv) reorganizing state-of-the-art advances chronologically, linking molten media demonstrations, catalyst development, and integration studies. The process synthesis shows that allocating geothermal heat to the largest heat-capacity streams (feed, recycle, and melt/salt hold) reduces electric top-up demand and stabilizes reactor operation, thereby mitigating coking, sintering, and broad particle size distributions. High-pressure operation improves the hydrogen yield and equipment compactness, but it also requires corrosion-resistant materials and careful thermal-stress management. The TEA indicates that the levelized cost of hydrogen is primarily influenced by two factors: (a) electric duty and the carbon intensity of power, and (b) the achievable price and specifications of the carbon co-product. Secondary drivers include the methane price, geothermal capacity factor, and overall conversion and selectivity. Overall, geothermal-assisted methane pyrolysis emerges as a practical pathway to turquoise hydrogen, if the carbon quality is maintained and heat integration is optimized. The study offers design principles and reporting guidelines intended to accelerate pilot-scale deployment. Full article

The ongoing energy transition and decarbonization efforts have prompted the development of Hybrid Renewable Energy Systems (HRES) capable of integrating multiple generation and storage technologies to enhance energy autonomy. Among the available options, hydrogen has emerged as a versatile energy carrier, yet most studies have focused either on stationary applications or on mobility, seldom addressing their integration withing a single framework. In particular, the potential of Metal Hydride (MH) tanks remains largely underexplored in the context of sector coupling, where the same storage unit can simultaneously sustain household demand and provide in-house refueling for light-duty fuel-cell vehicles. This study presents the design and analysis of a residential-scale HRES that combines photovoltaic generation, a PEM electrolyzer, a lithium-ion battery and MH storage intended for direct integration with a fuel-cell electric microcar. A fully dynamic numerical model was developed to evaluate system interactions and quantify the conditions under which low-pressure MH tanks can be effectively integrated into HRES, with particular attention to thermal management and seasonal variability. Two simulation campaigns were carried out to provide both component-level and system-level insights. The first focused on thermal management during hydrogen absorption in the MH tank, comparing passive and active cooling strategies. Forced convection reduced absorption time by 44% compared to natural convection, while avoiding the additional energy demand associated with thermostatic baths. The second campaign assessed seasonal operation: even under winter irradiance conditions, the system ensured continuous household supply and enabled full recharge of two MH tanks every six days, in line with the hydrogen requirements of the light vehicle daily commuting profile. Battery support further reduced grid reliance, achieving a Grid Dependency Factor as low as 28.8% and enhancing system autonomy during cold periods. Full article

The development of high-speed computers and electronic memories, high-frequency communication networks, electroluminescent and photovoltaic devices, flexible displays, and more requires new materials with unique properties, such as a low dielectric constant, an adjustable refractive index, high hardness, thermal resistance, and processability. SiOC coatings possess a number of desirable properties required by modern technologies, including good heat and UV resistance, transparency, high electrical insulation, flexibility, and solubility in commonly used organic solvents. Chemical vapor deposition (CVD) is a very useful and convenient method to produce this type of layer. In this article we present the results of studies on SiOC coatings obtained from tetramethylcyclotetrasiloxane in a remote hydrogen plasma CVD process. The elemental composition (XPS, EDS) and chemical structure (FTIR and NMR spectroscopy-¹³C, ²⁹Si) of the obtained coatings were investigated. Photoluminescence analyses and ellipsometric and thermogravimetric measurements were also performed. The surface morphology was characterized using AFM and SEM. The obtained results allowed us to propose a mechanism for the initiation and growth of the SiOC layer. Full article

South Korea faces high levels of air pollution and is currently not on track to meet its transport sector 2030 and 2050 greenhouse gas emission reduction targets primarily due to infrastructural limitations. This study examines the potential health benefits of a more rapid green transition of South Korea’s transport sector from 2026 to 2050 in terms of avoided premature deaths and years of life lost due to reduced ambient PM_2.5 exposure. The research conducts a scenario analysis comparing the business-as-usual trajectory of the transport sector with two alternative scenarios. In the first alternative scenario, South Korea’s transport sector achieves its 2030 NDC in 2035 and carbon neutrality in 2050 with a reliance on CCUS for emission capture. The second alternative scenario entails stronger climate action in which the transport sector meets the 2030 NDC target in 2030 and the 2050 carbon neutrality transport sector target through a complete green transition to electric vehicles and hydrogen vehicles. The first alternative scenario results in an average of 80 avoided premature deaths (775 avoided years of life lost) and 53 MTCO₂e avoided emissions per year from 2026 to 2050. The second more rapid green transition scenario of South Korea’s transport sector achieves an average of 96 avoided premature deaths (925 avoided years of life lost) and 66 MTCO₂e avoided emissions per year. This research supports a more rapid green transition of South Korea’s transport sector for both health and climate gains. Full article

This review synthesizes recent research on alternative fuels for piston-engine aircraft and related propulsion technologies. Biofuels show substantial promise but face technological, economic, and regulatory barriers to widespread adoption. Among liquid options, biodiesel offers a high cetane number and strong lubricity yet suffers from poor low-temperature flow and reduced combustion efficiency. Alcohol fuels (bioethanol, biomethanol) provide high octane numbers suited to high-compression engines but are limited by hygroscopicity and phase-separation risks. Higher-alcohols (biobutanol, biopropanol) combine favorable heating values with stable combustion and emerge as particularly promising candidates. Biokerosene closely matches conventional aviation kerosene and can function as a drop-in fuel with minimal engine modifications. Emissions outcomes are mixed across studies: certain biofuels reduce NO_x or CO, while others elevate CO₂ and HC, underscoring the need to optimize combustion and advance second- to fourth-generation biofuel production pathways. Beyond biofuels, hydrogen engines and hybrid-electric systems offer compelling routes to lower emissions and improved efficiency, though they require new infrastructure, certification frameworks, and cost reductions. Demonstrated test flights with biofuels, synthetic fuels, and hydrogen confirm technical feasibility. Overall, no single option fully replaces aviation gasoline today; instead, a combined trajectory—biofuels alongside hydrogen and hybrid-electric propulsion—defines a pragmatic medium- to long-term pathway for decarbonizing general aviation. Full article

The decarbonization of hard-to-defossilize sectors, such as international maritime transport, requires innovative, and at times disruptive, energy solutions that combine efficiency, scalability, and climate benefits. Therefore, power-to-liquid (PtL) routes have stood out for their potential to use low-emission electricity for the production of synthetic fuels, via electrolytic hydrogen and CO₂ capture. However, the high energy demand inherent to these routes poses significant challenges to large-scale implementation. Moreover, PtL routes are usually at most neutral in terms of CO₂ emissions. This study evaluates, from a thermo-energetic perspective, the optimization potential of an e-methanol synthesis route through integration with a biomass oxy-fuel combustion process, making use of electrolytic oxygen as the oxidizing agent and the captured CO₂ as the carbon source. From the standpoint of a first-law thermodynamic analysis, mass and energy balances were developed considering the full oxygen supply for oxy-fuel combustion to be met through alkaline electrolysis, thus eliminating the energy penalty associated with conventional oxygen production via air separation units. The balance closure was based on a small-scale plant with a capacity of around 100 kta of methanol. In this integrated configuration, additional CO₂ surpluses beyond methanol synthesis demand can be directed to geological storage, which, when combined with bioenergy with carbon capture and storage (BECCS) strategies, may lead to net negative CO₂ emissions. The results demonstrate that electrolytic oxygen valorization is a promising pathway to enhance the efficiency and climate performance of PtL processes. Full article

In this work, diamond/Si heterojunctions were fabricated by synthesizing a diamond layer directly on a monocrystalline n-type Si substrate. The diamond layers were characterized using micro-Raman spectroscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD). The current–voltage (I–V) characteristics of the heterojunctions were measured at room temperature. The heterojunctions exhibited rectifying behavior, confirming their diode-like nature. Based on thermionic emission theory, key electrical parameters of the heterojunction diodes—including the ideality factor (n) and carrier mobility (μ)—were estimated from the I–V characteristics. The I–V curves revealed large ideality factors ranging from 1.5 to 6.5, indicating the presence of deep trap states with densities between 2 × 10¹⁵ and 8 × 10¹⁶ eV⁻¹·cm⁻³. These variations were attributed to differences in the structural quality of the diamond layers and the effects of surface hydrogen termination. Full article

Aviation is under increasing pressure to reduce carbon emissions in conventional transports and support the growth of low-altitude operations such as long-endurance eVTOLs. Hybrid-electric propulsion addresses these challenges by integrating the high specific energy of fuels or hydrogen with the controllability and efficiency of electrified powertrains. At present, the field of hybrid-electric aircraft is developing rapidly. To systematically study hybrid-electric propulsion control in aviation, this review focuses on practical aspects of system development, including propulsion architectures, system- and component-level modeling approaches, and energy management strategies. Key technologies in the future are examined, with emphasis on aircraft power-demand prediction, multi-timescale control, and thermal integrated energy management. This review aims to serve as a reference for configuration design, modeling and control simulation, as well as energy management strategy design of hybrid-electric propulsion systems. Building on this reference role, the review presents a coherent guidance scheme from architectures through modeling to energy-management control, with a practical roadmap toward flight-ready deployment. Full article

Hydrogen bonding, a prevalent molecular interaction in nature, is crucial in biological and chemical processes. The emergence of single-molecule techniques has enhanced our microscopic understanding of hydrogen bonding. However, it is still challenging to track the dynamic behaviour of hydrogen bonding in solution, particularly under physiological conditions where interactions are significantly weakened. Here, we present a nanoscale-confined, functionalised quantum mechanical tunnelling (QMT) probe that enables continuous monitoring of electrical fingerprints of single-molecule hydrogen bonding interactions for over tens of minutes in diverse solvents, including polar physiological solutions, which reveal reproducible multi-level conductance distributions. Moreover, the functionalised QMT probes have successfully discriminated between L(+)- and D(−)-tartaric acid enantiomers by resolving the conductance difference. This work uncovers dynamic single-molecule hydrogen bonding processes within confined nanoscale spaces under physiological conditions, establishing a new paradigm for probing molecular hydrogen-bonding networks in supramolecular chemistry and biology. Full article

Over the past decade, two-dimensional materials have become a research hotspot in chemistry, physics, materials science, and electrical and optical engineering due to their excellent properties. Graphene is one of the earliest discovered 2D materials. The absence of a bandgap in pure graphene limits its application in digital electronics where switching behavior is essential. In the present study, researchers have proposed a variety of methods for tuning the graphene bandgap. Machine learning methodologies have demonstrated the capability to enhance the efficiency of materials research by automating the recording of characteristic parameters from the discovery and preparation of 2D materials, property calculations, and simulations, as well as by facilitating the extraction and summarization of governing principles. In this work, we use first principle calculations to build a dataset of graphene band gaps under various conditions, including the application of a perpendicular external electric field, nitrogen doping, and hydrogen atom adsorption. Support Vector Machine (SVM), Random Forest (RF), and Multi-Layer Perceptron (MLP) Regression were utilized to successfully predict the graphene bandgap, and the accuracy of the models was verified using first principles. Finally, the advantages and limitations of the three models were compared. Full article