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Keywords = dry connections

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16 pages, 1176 KiB  
Article
Evaluating the Use of Rice Husk Ash for Soil Stabilisation to Enhance Sustainable Rural Transport Systems in Low-Income Countries
by Ada Farai Shaba, Esdras Ngezahayo, Goodson Masheka and Kajila Samuel Sakuhuka
Sustainability 2025, 17(15), 7022; https://doi.org/10.3390/su17157022 - 2 Aug 2025
Viewed by 248
Abstract
Rural roads are critical for connecting isolated communities to essential services such as education and health and administrative services, as well as production and market opportunities in low-income countries. More than 70% of movements of people and goods in Sub-Saharan Africa are heavily [...] Read more.
Rural roads are critical for connecting isolated communities to essential services such as education and health and administrative services, as well as production and market opportunities in low-income countries. More than 70% of movements of people and goods in Sub-Saharan Africa are heavily reliant on rural transport systems, using both motorised but mainly alternative means of transport. However, rural roads often suffer from poor construction due to the use of low-strength, in situ soils and limited financial resources, leading to premature failures and subsequent traffic disruptions with significant economic losses. This study investigates the use of rice husk ash (RHA), a waste byproduct from rice production, as a sustainable supplement to Ordinary Portland Cement (OPC) for soil stabilisation in order to increase durability and sustainability of rural roads, hence limit recurrent maintenance needs and associated transport costs and challenges. To conduct this study, soil samples collected from Mulungushi, Zambia, were treated with combinations of 6–10% OPC and 10–15% RHA by weight. Laboratory tests measured maximum dry density (MDD), optimum moisture content (OMC), and California Bearing Ratio (CBR) values; the main parameters assessed to ensure the quality of road construction soils. Results showed that while the MDD did not change significantly and varied between 1505 kg/m3 and 1519 kg/m3, the OMC increased hugely from 19.6% to as high as 26.2% after treatment with RHA. The CBR value improved significantly, with the 8% OPC + 10% RHA mixture achieving the highest resistance to deformation. These results suggest that RHA can enhance the durability and sustainability of rural roads and hence improve transport systems and subsequently improve socioeconomic factors in rural areas. Full article
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18 pages, 4489 KiB  
Article
Influence of Regional PM2.5 Sources on Air Quality: A Network-Based Spatiotemporal Analysis in Northern Thailand
by Khuanchanok Chaichana, Supanut Chaidee, Sayan Panma, Nattakorn Sukantamala, Neda Peyrone and Anchalee Khemphet
Mathematics 2025, 13(15), 2468; https://doi.org/10.3390/math13152468 - 31 Jul 2025
Viewed by 233
Abstract
Northern Thailand frequently suffers from severe PM2.5 air pollution, especially during the dry season, due to agricultural burning, local emissions, and transboundary haze. Understanding how pollution moves across regions and identifying source–receptor relationships are critical for effective air quality management. This study investigated [...] Read more.
Northern Thailand frequently suffers from severe PM2.5 air pollution, especially during the dry season, due to agricultural burning, local emissions, and transboundary haze. Understanding how pollution moves across regions and identifying source–receptor relationships are critical for effective air quality management. This study investigated the spatial and temporal dynamics of PM2.5 in northern Thailand. Specifically, it explored how pollution at one monitoring station influenced concentrations at others and revealed the seasonal structure of PM2.5 transmission using network-based analysis. We developed a Python-based framework to analyze daily PM2.5 data from 2022 to 2023, selecting nine representative stations across eight provinces based on spatial clustering and shape-based criteria. Delaunay triangulation was used to define spatial connections among stations, capturing the region’s irregular geography. Cross-correlation and Granger causality were applied to identify time-lagged relationships between stations for each season. Trophic coherence analysis was used to evaluate the hierarchical structure and seasonal stability of the resulting networks. The analysis revealed seasonal patterns of PM2.5 transmission, with certain stations, particularly in Chiang Mai and Lampang, consistently acting as source nodes. Provinces such as Phayao and Phrae were frequently identified as receptors, especially during the winter and rainy seasons. Trophic coherence varied by season, with the winter network showing the highest coherence, indicating a more hierarchical but less stable structure. The rainy season exhibited the lowest coherence, reflecting greater structural stability. PM2.5 spreads through structured, seasonal pathways in northern Thailand. Network patterns vary significantly across seasons, highlighting the need for adaptive air quality strategies. This framework can help identify influential monitoring stations for early warning and support more targeted, season-specific air quality management strategies in northern Thailand. Full article
(This article belongs to the Special Issue Application of Mathematical Theory in Data Science)
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18 pages, 3316 KiB  
Article
Impact of Farm Biogas Plant Auxiliary Equipment on Electrical Power Quality
by Zbigniew Skibko, Andrzej Borusiewicz, Jacek Filipkowski, Łukasz Pisarek and Maciej Kuboń
Energies 2025, 18(14), 3849; https://doi.org/10.3390/en18143849 - 19 Jul 2025
Viewed by 224
Abstract
Devices that meet the needs of agricultural biogas plants represent a significant share of the energy balance of the source. The digester mixer is a crucial component installed in the fermentation chamber. Energy consumption during mixing depends on the regime and intensity, as [...] Read more.
Devices that meet the needs of agricultural biogas plants represent a significant share of the energy balance of the source. The digester mixer is a crucial component installed in the fermentation chamber. Energy consumption during mixing depends on the regime and intensity, as well as the rheological properties of the carrier liquid, the dry matter content, and the dimensions of the fibers. Bioreactor operators often oversize mixers and extend mixing duration to avoid disruptions in biogas production. This paper analyzed the influence of digester mixer operations on selected electrical power quality parameters. For this purpose, two agricultural biogas plants with a capacity of 40 kW, connected to the low-voltage grid, were studied (one located approximately 120 m from the transformer station and the second 430 m away). As shown by the correlations presented in the article, the connection point of the biogas plant significantly impacted the magnitude of the influence of mixer operations on the analyzed voltage parameters. In the second biogas plant, switching on the mixers (in the absence of generation) caused the grid voltage to drop to the lower value permitted by regulations. (Switching on the mixers caused a change in voltage by about 30 V.) The most disturbances were introduced into the grid when the power generated by the biogas plant was equal to the power consumed by its internal equipment. (THDI then reached as high as 63.2%, while in other cases, it did not exceed 17%.) Furthermore, the operation of the mixers alone resulted in a reduction of approximately 1 MWh of energy exported to the power grid per month. Full article
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20 pages, 6439 KiB  
Article
Spatiotemporal Patterns of Hongshan Culture Settlements in Relation to Middle Holocene Climatic Fluctuation in the Horqin Dune Field, Northeast China
by Wenping Xue, Heling Jin, Wen Shang and Jing Zhang
Atmosphere 2025, 16(7), 865; https://doi.org/10.3390/atmos16070865 - 16 Jul 2025
Viewed by 252
Abstract
Given the increasing challenges posed by frequent extreme climatic events, understanding the climate–human connection between the climate system and the transitions of ancient civilizations is crucial for addressing future climatic challenges, especially when examining the relationship between the abrupt events of the Holocene [...] Read more.
Given the increasing challenges posed by frequent extreme climatic events, understanding the climate–human connection between the climate system and the transitions of ancient civilizations is crucial for addressing future climatic challenges, especially when examining the relationship between the abrupt events of the Holocene and the Neolithic culture development. Compared with the globally recognized “4.2 ka collapse” of ancient cultures, the initial start time and the cultural significance of the 5.5 ka climatic fluctuation are more complex and ambiguous. The Hongshan culture (6.5–5.0 ka) is characterized by a complicated society evident in its grand public architecture and elaborate high-status tombs. However, the driving mechanisms behind cultural changes remain complex and subject to ongoing debate. This paper delves into the role of climatic change in Hongshan cultural shifts, presenting an integrated dataset that combines climatic proxy records with archaeological data from the Hongshan culture period. Based on synthesized aeolian, fluvial-lacustrine, loess, and stalagmite deposits, the study indicates a relatively cold and dry climatic fluctuation occurred during ~6.0–5.5 ka, which is widespread in the Horqin dune field and adjacent areas. Combining spatial analysis with ArcGis 10.8 on archaeological sites, we propose that the climatic fluctuation between ~6.0–5.5 ka likely triggered the migration of the Hongshan settlements and adjustment of survival strategies. Full article
(This article belongs to the Special Issue Desert Climate and Environmental Change: From Past to Present)
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19 pages, 1145 KiB  
Article
Speed Prediction Models for Tangent Segments Between Horizontal Curves Using Floating Car Data
by Giulia Del Serrone and Giuseppe Cantisani
Vehicles 2025, 7(3), 68; https://doi.org/10.3390/vehicles7030068 - 5 Jul 2025
Viewed by 525
Abstract
The integration of connected autonomous vehicles (CAVs), advanced driver assistance systems (ADAS), and conventional vehicles necessitates the development of robust methodologies to enhance traffic efficiency and ensure safety across heterogeneous traffic streams. A comprehensive understanding of vehicle interactions and operating speed variability is [...] Read more.
The integration of connected autonomous vehicles (CAVs), advanced driver assistance systems (ADAS), and conventional vehicles necessitates the development of robust methodologies to enhance traffic efficiency and ensure safety across heterogeneous traffic streams. A comprehensive understanding of vehicle interactions and operating speed variability is essential to support informed decision-making in traffic management and infrastructure design. This study presents operating speed models aimed at estimating the 85th percentile speed (V85) on straight road segments, utilizing floating car data (FCD) for both calibration and validation purposes. The dataset encompasses approximately 2000 km of the Italian road network, characterized by diverse geometric features. Speed observations were analyzed under three traffic conditions: general traffic, free-flow, and free-flow with dry pavement. Results indicate that free-flow conditions improve the model’s explanatory power, while dry pavement conditions introduce greater speed variability. Initial models based exclusively on geometric parameters exhibited limited predictive accuracy. However, the inclusion of posted speed limits significantly enhanced model performance. The most influential predictors identified were the V85 on the preceding curve and the length of the straight segment. These findings provide empirical evidence to inform road safety evaluations and geometric design practices, offering insights into driver behavior in mixed-traffic environments. The proposed model supports the development of data-driven strategies for the seamless integration of automated and non-automated vehicles. Full article
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28 pages, 7736 KiB  
Article
Structural Analysis and Redrawing of a Sailing Catamaran with a Numerical and Experimental Approach
by Giovanni Maria Grasso, Marco Bonfanti, Fabio Lo Savio, Damiano Alizzio and Ferdinando Chiacchio
J. Mar. Sci. Eng. 2025, 13(7), 1270; https://doi.org/10.3390/jmse13071270 - 29 Jun 2025
Viewed by 288
Abstract
This study investigates the structural behavior of a sailing catamaran subjected to wind, wave, and self-weight loads, with the ultimate goal of improving the structural design through redrawing techniques. A digital model was developed using Creo software 6 and analyzed through Finite Element [...] Read more.
This study investigates the structural behavior of a sailing catamaran subjected to wind, wave, and self-weight loads, with the ultimate goal of improving the structural design through redrawing techniques. A digital model was developed using Creo software 6 and analyzed through Finite Element Analysis (FEA), complemented by experimental deformation tests conducted under dry conditions and controlled loading. These tests provided a reliable dataset for calibrating and validating the numerical model. The analysis focused on the structural responses of key components—such as bulkheads, hulls, and beam-to-hull connections—under both isolated as well as combined load scenarios. Most structural elements demonstrated low deformation, confirming the robustness of the design; however, stress concentrations were observed at the connecting plates, highlighting areas for improvement. The vessel’s overall stiffness, though advantageous for structural integrity, was identified as a constraint in weight redrawing efforts. Consequently, targeted structural modifications were proposed and implemented, resulting in reduced material usage, construction time, and overall costs. The study concludes by proposing the integration of advanced composite materials to further enhance performance and efficiency, thereby laying the groundwork for future integration with digital and structural health monitoring systems. Full article
(This article belongs to the Section Marine Environmental Science)
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12 pages, 2513 KiB  
Article
Study on Height Measurement for Polyethylene Terephthalate (PET) Materials Based on Residual Networks
by Chongwei Liao, Weixin Zhang, Yujie Peng and Changjun Liu
Sensors 2025, 25(13), 4030; https://doi.org/10.3390/s25134030 - 28 Jun 2025
Viewed by 302
Abstract
In industrial production, high-power microwaves are commonly used for heating and drying processes; however, their application in measurement is relatively limited. This paper presents a power measurement system to enhance the use of microwave measurements in industry and improve the efficiency of microwave [...] Read more.
In industrial production, high-power microwaves are commonly used for heating and drying processes; however, their application in measurement is relatively limited. This paper presents a power measurement system to enhance the use of microwave measurements in industry and improve the efficiency of microwave drying for PET particles. Operating at 2.45 GHz, the system integrates four-port power measurements based on the multilayer perceptron (MLP). By introducing residual connectivity, the residual network is determined to detect the height of PET particles. Experimental results show that this system can perform rapid measurements without needing a vector network analyzer (VNA), significantly improving the efficiency of microwave energy utilization in the early drying stages. Furthermore, the system offers practical and cost-efficient predictions for low-loss particulate materials. This power measurement strategy holds promising application potential in future industrial production. Full article
(This article belongs to the Section Electronic Sensors)
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34 pages, 8503 KiB  
Article
Hydrogeochemical Characterization and Determination of Arsenic Sources in the Groundwater of the Alluvial Plain of the Lower Sakarya River Basin, Turkey
by Nisa Talay and İrfan Yolcubal
Water 2025, 17(13), 1931; https://doi.org/10.3390/w17131931 - 27 Jun 2025
Viewed by 462
Abstract
Arsenic (As) contamination in groundwater represents a major global public health threat, particularly in alluvial aquifer systems where redox-sensitive geochemical processes facilitate the mobilization of naturally occurring trace elements. This study investigates groundwater quality, particularly focusing on the origin of arsenic contamination in [...] Read more.
Arsenic (As) contamination in groundwater represents a major global public health threat, particularly in alluvial aquifer systems where redox-sensitive geochemical processes facilitate the mobilization of naturally occurring trace elements. This study investigates groundwater quality, particularly focusing on the origin of arsenic contamination in shallow and deep alluvial aquifers of the Lower Sakarya River Basin, which are crucial for drinking, domestic, and agricultural uses. Groundwater samples were collected from 34 wells—7 tapping the shallow aquifer (<60 m) and 27 tapping the deep aquifer (>60 m)—during wet and dry seasons for the hydrogeochemical characterization of groundwater. Environmental isotope analysis (δ18O, δ2H, 3H) was conducted to characterize origin and groundwater residence times, and the possible hydraulic connection between shallow and deep alluvial aquifers. Mineralogical and geochemical characterization of the sediment core samples were carried out using X-ray diffraction and acid digestion analyses to identify mineralogical sources of As and other metals. Pearson correlation coefficient analyses were also applied to the results of the chemical analyses to determine the origin of metal enrichments observed in the groundwater, as well as related geochemical processes. The results reveal that 33–41% of deep groundwater samples contain arsenic concentrations exceeding the WHO and Turkish drinking water standard of 10 µg/L, with maximum values reaching 373 µg/L. Manganese concentrations exceeded the 50 µg/L limit in up to 44% of deep aquifer samples, reaching 1230 µg/L. On the other hand, iron concentrations were consistently low, remaining below the detection limit in nearly all samples. The co-occurrence of As and Mn above their maximum contaminant levels was observed in 30–33% of the wells, exhibiting extremely low sulfate concentrations (0.2–2 mg/L), notably low dissolved oxygen concentration (1.45–3.3 mg/L) alongside high bicarbonate concentrations (450–1429 mg/L), indicating localized varying reducing conditions in the deep alluvial aquifer. The correlations between molybdenum and As (rdry = 0.46, rwet = 0.64) also indicate reducing conditions, where Mo typically mobilizes with As. Arsenic concentrations also showed significant correlations with bicarbonate (HCO3) (rdry = 0.66, rwet = 0.80), indicating that alkaline or reducing conditions are promoting arsenic mobilization from aquifer materials. All these correlations between elements indicate that coexistence of As with Mn above their MCLs in deep alluvial aquifer groundwater result from reductive dissolution of Mn/Fe(?) oxides, which are primary arsenic hosts, thereby releasing arsenic into groundwater under reducing conditions. In contrast, the shallow aquifer system—although affected by elevated nitrate, sulfate, and chloride levels from agricultural and domestic sources—exhibited consistently low arsenic concentrations below the maximum contaminant level. Seasonal redox fluctuations in the shallow zone influence manganese concentrations, but the aquifer’s more dynamic recharge regime and oxic conditions suppress widespread As mobilization. Mineralogical analysis identified that serpentinite, schist, and other ophiolitic/metamorphic detritus transported by river processes into basin sediments were identified as the main natural sources of arsenic and manganese in groundwater of deep alluvium aquifer. Full article
(This article belongs to the Section Hydrogeology)
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24 pages, 3837 KiB  
Article
The Alleviating Effect of Brassinosteroids on Cadmium Stress in Potato Plants: Insights from StDWF4 Gene Overexpression
by Xiangyan Zhou, Rong Miao, Jiaqi Luo, Wenhui Tang, Kexin Liu, Caijuan Li and Dan Zhang
Agronomy 2025, 15(7), 1503; https://doi.org/10.3390/agronomy15071503 - 20 Jun 2025
Viewed by 484
Abstract
The potato is the fourth largest cultivated crop worldwide. Soil cadmium (Cd) pollution poses a significant threat to crop growth. Brassinosteroids (BRs) play a significant part in enhancing plant resistance against abiotic stresses. The DWF4 (dwarf4) gene is one of the rate-limiting enzyme [...] Read more.
The potato is the fourth largest cultivated crop worldwide. Soil cadmium (Cd) pollution poses a significant threat to crop growth. Brassinosteroids (BRs) play a significant part in enhancing plant resistance against abiotic stresses. The DWF4 (dwarf4) gene is one of the rate-limiting enzyme genes involved in the synthesis of BRs. This study employed seedlings of transgenic potatoes overexpressing the StDWF4 gene (OE) and wild-type (WT) potatoes to clarify their alleviating effect on Cd stresses. The differences in phenotype, ultrastructure, physiological indicators, and plant hormone levels of Cd2+-treated potatoes were analyzed. The molecular mechanism of potatoes’ response to Cd2+ stress was revealed by transcriptomics. Results showed that the dry weight, fresh weight, plant height, root length, and stem diameter of OE potatoes under Cd stress were significantly higher than those of WT potatoes. Ultrastructural analysis revealed that the mitochondria, cell walls, and cell membranes of WT were more fragile than those of OE under Cd stress. The Cd2+ concentration in OE was always lower than that in WT, and both concentrations increased gradually as the duration of Cd2+ treatment was prolonged. The 24-epibrassionlide (EBL) content in OE was higher than that in WT. RNA-seq analysis manifested that the gene expression levels of OE and WT plants changed significantly under Cd2+ treatment. The differentially expressed genes (DEGs) were primarily connected to the moderation of the metabolic pathways, biosynthesis of secondary metabolites, phenylpropanoid biosynthesis, and plant hormone signal transduction. These findings indicated that overexpression of the StDWF4 gene in potatoes enhanced their alleviating effect on Cd stresses. Full article
(This article belongs to the Section Plant-Crop Biology and Biochemistry)
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16 pages, 1995 KiB  
Article
Numerical and Experimental Multi-Approach Models for a Stone Pinnacle Reinforcement
by Miquel Llorens, Miquel Àngel Chamorro, Irieix Costa, Joan Fontàs and Ester Gifra
Buildings 2025, 15(13), 2148; https://doi.org/10.3390/buildings15132148 - 20 Jun 2025
Viewed by 294
Abstract
The church of Saint Felix in Girona (Spain) is crowned by an octagonal bell tower with a stone pinnacle at each corner. It was built using dry-joint stone masonry, a technique that involves laying stones in a precise pattern to create a solid [...] Read more.
The church of Saint Felix in Girona (Spain) is crowned by an octagonal bell tower with a stone pinnacle at each corner. It was built using dry-joint stone masonry, a technique that involves laying stones in a precise pattern to create a solid and durable structure. In order to strengthen the connection between the stone blocks of the pinnacles, a wooden bar was placed through a central hole carved in the stone structure. Today, the inner structure has completely disappeared. During maintenance and repair work, it was decided to restore the functionality of the disappeared reinforcement by installing a titanium bar in its place. Due to the uncertainty associated with the pinnacle’s behaviour and the lack of both, a proper numerical model of the monument, and an extensive characterization of the materials, a strategy based on multiple approaches was designed. The proposed strategy was based on combining numerical and experimental models, the final objective being to determine the length and mechanical properties of the metallic inclusion, considering the effects of gravity, wind, and seismic forces. A scale model of the pinnacle was evaluated in laboratory conditions. The results were used to calibrate a numerical model representing the scale specimen. After calibration, the results were extrapolated to a full-scale numerical model. The experimental and numerical results showed that the pinnacles needed to be reinforced along their entire height. The tensile stresses cause by wind and seismic forces at different levels, could not be compensated without the contribution of the titanium bar inserted into the pinnacle. Full article
(This article belongs to the Special Issue Mechanics of Masonry Towers)
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20 pages, 569 KiB  
Review
Multimodal Approaches in the Management of Temporomandibular Disorders: A Narrative Review
by Izabela Dąbkowska, Lena Sobiech, Agata Czępińska, Adam Bęben, Karolina Turżańska and Piotr Gawda
J. Clin. Med. 2025, 14(12), 4326; https://doi.org/10.3390/jcm14124326 - 17 Jun 2025
Viewed by 983
Abstract
Background/Objectives: Temporomandibular disorders (TMDs) are the most common cause of non-dental pain in the orofacial region. Due to the complex and multifactorial nature of TMD, a multidisciplinary approach is often required. The objective of this narrative review is to evaluate the effectiveness of [...] Read more.
Background/Objectives: Temporomandibular disorders (TMDs) are the most common cause of non-dental pain in the orofacial region. Due to the complex and multifactorial nature of TMD, a multidisciplinary approach is often required. The objective of this narrative review is to evaluate the effectiveness of multimodal therapies in the management of TMD. Methods: A literature search was performed using a combination of keywords: “TMD”, “TMJ”, “disorders”, “manual therapy”, “physical therapy”, “dry needling”, “botulinum toxin”, “Botox”, “splint”, and “psychotherapy”. The search was conducted in the PubMed, Google Scholar, and Scopus databases, focusing on studies involving human subjects. Results: The included studies reported that the use of multimodal approaches—such as physiotherapy, botulinum toxin injections, occlusal splints, and/or psychotherapy—led to symptom improvement or complete resolution in patients with TMD. Conclusions: Temporomandibular disorders are complex conditions with a multifactorial etiology involving both somatic and psychological components. Given the wide range of symptoms and the functional connections of the temporomandibular joint with the nervous, muscular, and skeletal systems—including the cervical spine—effective treatment of TMD requires a multidisciplinary strategy. Full article
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36 pages, 12446 KiB  
Article
Investigation of Diffusion Induced Fiber–Matrix Interface Damages in Adhesively Bonded Polymer Composites
by Dudu Mertgenç Yoldaş
Polymers 2025, 17(12), 1672; https://doi.org/10.3390/polym17121672 - 17 Jun 2025
Viewed by 460
Abstract
Composite materials have the advantages of high strength and low weight, and are therefore used in many areas. However, in humid and marine environments, mechanical properties may deteriorate due to moisture diffusion, especially in glass fiber reinforced polymers (GFRP) and carbon fiber reinforced [...] Read more.
Composite materials have the advantages of high strength and low weight, and are therefore used in many areas. However, in humid and marine environments, mechanical properties may deteriorate due to moisture diffusion, especially in glass fiber reinforced polymers (GFRP) and carbon fiber reinforced polymers (CFRP). This study investigated the damage formation and changes in mechanical properties of single-layer adhesive-bonded GFRP and CFRP connections under the effect of sea water. In the experiment, 0/90 orientation, twill-woven GFRP (7 ply) and CFRP (8 ply) plates were produced as prepreg using the hand lay-up method in accordance with ASTM D5868-01 standard. CNC Router was used to cut 36 samples were cut from the plates produced for the experiments. The samples were kept in sea water taken from the Aegean Sea, at 3.3–3.7% salinity and 23.5 °C temperature, for 1, 2, 3, 6, and 15 months. Moisture absorption was monitored by periodic weighings; then, the connections were subjected to three-point bending tests according to the ASTM D790 standard. The damages were analyzed microscopically with SEM (ZEISS GEMINI SEM 560). As a result of 15 months of seawater storage, moisture absorption reached 4.83% in GFRP and 0.96% in CFRP. According to the three-point bending tests, the Young modulus of GFRP connections decreased by 25.23% compared to dry samples; this decrease was 11.13% in CFRP. Moisture diffusion and retention behavior were analyzed according to Fick’s laws, and the moisture transfer mechanism of single-lap adhesively bonded composites under the effect of seawater was evaluated. Full article
(This article belongs to the Special Issue Multifunctional Polymer Composite Materials, 2nd Edition)
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12 pages, 1701 KiB  
Article
Effects of Hydration on the Mechanical Properties of Salt-Doped Poly(methyl methacrylate)
by Asae Ito, Naoki Uchida, Yusuke Hiejima and Koh-hei Nitta
Molecules 2025, 30(12), 2568; https://doi.org/10.3390/molecules30122568 - 12 Jun 2025
Viewed by 345
Abstract
The mechanical performance of poly(methyl methacrylate) (PMMA) is highly sensitive to moisture absorption, which induces plasticization and softening. In this study, we investigated the ductilization mechanism of PMMA by incorporating various metal salts with different cations (Li+ and Mg2+) and [...] Read more.
The mechanical performance of poly(methyl methacrylate) (PMMA) is highly sensitive to moisture absorption, which induces plasticization and softening. In this study, we investigated the ductilization mechanism of PMMA by incorporating various metal salts with different cations (Li+ and Mg2+) and controlling water absorption through hygroscopic interactions. A nonequilibrium constitutive model is introduced, in which localized water domains around salt-rich regions gradually diffuse into the PMMA matrix during tensile deformation. The stress–strain behavior is described by combining rigid (dry) and soft (hydrated) matrix components, connected through an internal kinetic variable governed by the strain-dependent diffusion rate. The model successfully reproduces experimental tensile data and captures the transition from brittle to ductile behavior as a function of the moisture content. Notably, Mg salts exhibit stronger water binding and slower moisture redistribution than Li salts, resulting in distinct mechanical responses. These findings provide a mechanistic framework for tailoring the ductility of hygroscopic polymer systems via ion–water–polymer interactions. Full article
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26 pages, 8645 KiB  
Article
Effect of the Gel Drying Method on Properties of Semicrystalline Aerogels Prepared with Different Network Morphologies
by Glenn A. Spiering, Garrett F. Godshall and Robert B. Moore
Gels 2025, 11(6), 447; https://doi.org/10.3390/gels11060447 - 10 Jun 2025
Viewed by 709
Abstract
The purpose of this study was to investigate the effect of different drying methods on the structure and properties of semicrystalline polymer aerogels. Aerogels, consisting of either globular or strut-like morphologies, were prepared from poly(ether ether ketone) (PEEK) or poly(phenylene sulfide) (PPS) and [...] Read more.
The purpose of this study was to investigate the effect of different drying methods on the structure and properties of semicrystalline polymer aerogels. Aerogels, consisting of either globular or strut-like morphologies, were prepared from poly(ether ether ketone) (PEEK) or poly(phenylene sulfide) (PPS) and dried using vacuum drying, freeze-drying, or supercritical CO2 extraction. Vacuum drying was found to result in aerogels with a higher shrinkage, smaller mesopores (with pore widths of 2–50 nm), and smaller surface areas compared to the use of supercritical extraction as the drying method. Freeze-dried aerogels tended to have properties between those of vacuum-dried aerogels and aerogels prepared with supercritical extraction. High network connectivity was found to lead to improved gel modulus, which increased the ability of aerogels to resist network deformation due to stresses induced during drying. The PEEK and PPS aerogel networks consisting of highly connected strut-like features were considerably stiffer than those composed of globular features, and thus shrank less under the forces induced by vacuum drying or freeze-drying. The aerogels prepared from PPS were found to have larger mesopores and smaller surface areas than the aerogels prepared from PEEK. The larger mesopores of the PPS aerogels induced lower capillary stresses on the aerogel network, and thus shrank less. This work demonstrates that preparing PEEK and PPS gels with strut-like features can allow aerogel processing with simpler evaporative drying methods rather than the more complex supercritical drying method. Full article
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5 pages, 2407 KiB  
Communication
Agricultural Irrigation Canals Threaten Wild Terrestrial Vertebrates in Northern Chile
by Pablo Espinoza-Carbullanca and Sebastián Muñoz-Leal
Wild 2025, 2(2), 22; https://doi.org/10.3390/wild2020022 - 9 Jun 2025
Viewed by 407
Abstract
Irrigation canals are essential for agriculture in semi-arid regions like northern Chile, yet their ecological impacts on wildlife remain underexplored. Here, we assessed the effects of a 900 m transect of a dry, polyethylene-covered irrigation canal in the Coquimbo region on local terrestrial [...] Read more.
Irrigation canals are essential for agriculture in semi-arid regions like northern Chile, yet their ecological impacts on wildlife remain underexplored. Here, we assessed the effects of a 900 m transect of a dry, polyethylene-covered irrigation canal in the Coquimbo region on local terrestrial fauna. A total of 121 reptiles, marsupials, and rodents were found in the canal, with 82.64% mortality. Our evidence suggests that the animals drowned when the water flux stopped or perished because of the extreme heat irradiated by the polyethylene geomembrane once the canal became empty. We highlight that these canals act as lethal pitfall traps for terrestrial vertebrates, as seen in other countries. Given the ecological impact that these waterways impose on local fauna, the implementation of mitigation strategies such as physical barriers, escape aids, and connectivity structures to reduce mortality is urgent in the region. Full article
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