Search Results (42)

The release of phosphorus (P) from littoral wetland sediments drives eutrophication, with iron (Fe) and sulfur (S) cycles playing key regulatory roles. This study investigated the Tongyang River corridor wetland (Lake Chaohu) in China to elucidate P–Fe–S coupling mechanisms. High-resolution two-dimensional (2D) Diffusive Gradients in Thin-Films (DGT), P-fractionation, and microbial sequencing were employed during wet and dry periods. Results indicated significant total phosphorus (TP) spatial heterogeneity and seasonal available phosphorus (AP) variation. A robust spatial co-variance between DGT-Fe and DGT-P (r > 0.95) reinforces the iron-redox paradigm. However, 2D mapping revealed discretized sub-millimeter “hotspots,” demonstrating that iron (oxyhydr)oxide reductive dissolution is governed by micro-scale niches rather than uniform processes. Microbial analysis further identified summer diversity and Chloroflexi enrichment as primary biological drivers of P mobilization. Specifically, hydrological fluctuations dictate the iron-redox cycle, with wet-period microbial activation serving as the engine for internal P release. These findings suggest that regulating sediment redox conditions across hydrological stages is essential for mitigating wetland eutrophication. Full article

To investigate the effect of high-arsenic (As) soil on the absorption of As by highland barley, 135 pairs of soil–crop samples were collected in the main producing areas of highland barley in the middle reaches of the Yarlung Zangbo River. Eight soil variables, including pH, redox potential (Eh), soil organic matter (SOM), total arsenic (T-As), total iron (T-Fe), total manganese (T-Mn), chemically extractable As (KH₂PO₄-As), and bioavailable As determined by diffusive gradients in thin films (DGT-As), were measured, along with As concentrations in barley grains (HB-As). Machine learning approaches were employed to construct predictive models for HB-As accumulation, and feature influence mechanisms were interpreted using SHapley Additive exPlanations (SHAP) and Partial Dependence Plot (PDP) analyses. The results showed that: (1) among models constructed using the full feature set, the random forest (RF) model exhibited the best predictive performance for HB-As, with R² values of 0.756 and 0.651 for the training and testing datasets, respectively; (2) SHAP analysis indicated that DGT-As had the greatest contribution to the model (30.5%), followed by T-As and T-Fe/Mn; and (3) significant interaction effects among soil variables jointly influenced HB-As accumulation. This study provides scientific support for agricultural product safety, soil security, and sustainable land use in plateau agroecosystems. Full article

The expanding use of rare earth elements (REEs) in high-tech industrials has increased their environmental release, raising concerns about their ecological risks. This study employed the Diffusive Gradients in Thin Films (DGT) technique to assess REE bioavailability, spatial distribution, and ecological risks of REEs in sediments of the Yitong River, a historically polluted urban river in Changchun, China. Sediment characteristics (organic matter, pH, salinity), nutrient dynamics (N, P), and metal concentrations (Fe, Mn, As, etc.) were analyzed alongside REEs to evaluate their interactions and environmental drivers. Results revealed that REE concentrations (0.453–1.687 μg L⁻¹) were dominated by light REEs (50.1%), with levels an order of magnitude lower than heavily industrialized regions. Ecological risk quotients (RQ) for individual REEs were below thresholds (RQ < 1), indicating negligible immediate risks, though spatial trends suggested urban runoff influences. Probabilistic risk assessment integrating DGT data and species sensitivity distributions (SSD) estimated a low combined toxic probability (2.26%) for REEs and nutrients. Microbial community analysis revealed correlations between specific bacterial (e.g., Clostridium, Dechloromonas) and fungal genera (e.g., Pseudeurotium) with metals and REEs, highlighting microbial sensitivity to pollutant shifts. This study provides a multidimensional framework linking REE bioavailability, sediment geochemistry, and microbial ecology, offering insights for managing REE contamination in urban riverine systems. Full article

Phosphorus (P) release from reservoir sediments critically influences water quality and ecosystem stability. This study analyzed surface sediments from four representative zones to investigate phosphorus fraction distribution, key influencing factors, and implications for water quality. Results showed that total phosphorus (TP) content in sediments from main and tributary inflow zones was significantly higher than in open-water and transition zones. Inorganic phosphorus (IP) was the dominant form, with iron-bound phosphorus (Fe-P) accounting for 33.2–42.0% of IP. A strong correlation existed between P release and the Fe/P molar ratio; notably, when the ratio approached 10, phosphorus desorption increased significantly, indicating a shift from sink to source. Sediments with grain sizes <0.01 mm had the highest P release rates, suggesting particle size, Fe content, and hydrodynamics jointly regulate P mobilization. Using the Diffusive Gradients in Thin Films (DGT) technique, phosphorus release in inflow zones exceeded 1 g/m² in all hydrological periods, contributing substantially to internal loading. Sediment-derived P primarily influenced bottom water, while surface water was more affected by external inputs. These findings highlight the spatial heterogeneity of P release and underscore the need for zone-specific management strategies in reservoir systems. Full article

South Dongting Lake is an essential aquatic ecosystem that receives substantial water inflows from the Xiangjiang and Zishui Rivers. However, it is significantly impacted by human activities, including mining, smelting, and farming. These activities have led to serious contamination of the lake’s sediments with heavy metals (HMs). This study investigated the distribution, mobility, and influencing factors of HMs at the sediment–water interface. To this end, sediment samples were analyzed from three key regions (Xiangjiang River estuary, Zishui River estuary, and northeastern South Dongting Lake) using traditional sampling methods and Diffusive Gradients in Thin Films (DGT) technology. Analysis of fifteen HMs (Pb, Bi, Ni, As, Se, Cd, Sb, Mn, Zn, V, Cr, Cu, Tl, Co, and Fe) revealed significant spatial heterogeneity. The results showed that Cr, Cu, Pb, Bi, Ni, As, Se, Cd, Sb, Mn, Zn, and Fe exhibited high variability (CV > 0.20), whereas V, Tl, and Co demonstrated stable concentrations (CV < 0.20). Concentrations were found to exceed background values of the upper continental crust of eastern China (UCC), Yangtze River sediments (YZ), and Dongting Lake sediments (DT), particularly at the Xiangjiang estuary (XE) and in the northeastern regions. Speciation analysis revealed that V, Cr, Cu, Ni, and As were predominantly found in the residual fraction (F4), while Pb and Co were concentrated in the oxidizable fraction (F3), Mn and Zn appeared primarily in the exchangeable fractions (F1 and F2), and Cd was notably dominant in the exchangeable fraction (F1), suggesting a high potential for mobility. Additionally, DGT results confirmed a significant potential for the release of Pb, Zn, and Cd. Contamination assessment using the Pollution Load Index (PLI) and Geoaccumulation Index (Igeo) identified Pb, Bi, Ni, As, Se, Cd, and Sb as major pollutants. Among these, Bi and Cd were found to pose the highest risks. Furthermore, the Risk Assessment Code (RAC) and the Potential Ecological Risk Index (PERI) highlighted Cd as the primary ecological risk contributor, especially in the XE. The study identified sediment grain size, pH, electrical conductivity, and nutrient levels as the primary influencing factors. The PMF modeling revealed HM sources as mixed smelting/natural inputs, agricultural activities, natural weathering, and mining/smelting operations, suggesting that remediation should prioritize Cd control in the XE with emphasis on external inputs. Full article

In this work, photothermal beam deflection spectrometry (BDS), combined with a passive sampling technique of diffusive gradients in thin film (DGT), is optimized to improve the method’s sensitivity. The limit of detection (LOD) is then reduced by a factor of 2 (to the value of 20 nM). The functionality of the technique is compared for Chelex-100 (Ch-100) and suspended particulate reagent–iminodiacetate resin (SPR-IDA), used as binding resins in passive samplers. The absorption capacity of SPR-IDA resin is found to be less than 1 μM and far below that one of Chelex-100 resin (around 6 μM). The BDS technique is applied for determination of iron redox species concentration in sediment porewater. It is found that Fe in sediment porewater occurs both in Fe²⁺ (0.073 μM) and Fe³⁺ (0.095 μM) forms. The validation of the presented method reveals that the BDS technique ensures good repeatability, reproducibility, and reliability. Full article

Elevated levels of cadmium (Cd) and lead (Pb) in the edible parts of rice (Oryza sativa L.) grown in agricultural soils may enter the human body through the food chain, posing significant health risks. In this study, rice and paired rhizosphere soil samples were collected from 194 locations in Jiangsu Province, China, with 60 samples selected for diffusive gradients in thin films (DGT) extraction analysis. The findings indicate that total soil concentrations of Cd and Pb are inadequate for assessing cadmium bioavailability, implying that current soil quality standards may not accurately reflect the bioaccessible fractions of these metals. Both DGT and soil solution measurements effectively predicted crop Cd levels, with the effective concentration (C_E) derived from the DGT-induced soil flux (DIFS) model showing the strongest correlation with rice Cd content. Pearson correlation analysis and a random forest (RF) model further identified critical factors influencing rice uptake of Cd and Pb, including soil iron (Fe) content, cation exchange capacity (CEC), pH, and the levels of zinc (Zn) and selenium (Se), which antagonize Cd uptake. Full article

The transformations of iron (Fe), phosphorus (P), and sulfide (S) have been previously investigated in many areas, but quantifying the effects of the seasons on nutrient transformations and bacterial community distributions is a major issue that requires urgent attention in areas with serious anthropogenic disturbance. The authors used the diffusive gradients in thin films (DGTs) technique and 16S rRNA gene sequencing to determine the spatial heterogeneity in the nutrient distribution and bacterial community structure in the overlying water and sediment in the Pearl River Delta (PRD). Sampling campaigns were conducted in summer and winter. The results show that the nutrient salts exhibited greater differences in time than in space and there were higher water pollution levels in winter than in summer. During summer, the abundant non-point source pollution from the rainfall input provided a rich substrate for the bacteria in the water, leading to a strong competitiveness of the PAOs and nitrifying bacteria. Meanwhile, a high temperature was favorable for the exchange of elements at the SWI, with a greater release of P, Fe, and N, while, with the low temperatures and high DO and nutrient salts seen in winter, the SOB and denitrifying bacteria were active, which correctly indicated the high concentration of SO₄²⁻ and NH₄⁺-N in the water. The microbial diversity and abundance were also affected by the season, with a higher richness and diversity of the microbial communities in summer than in winter, and the high salinity and nutrient salt concentration had a significant inhibitory effect on the microorganisms. A Mantel test revealed that the spatiotemporal distribution patterns of the dominant bacteria were closely related to the TOC and DO levels and played an important role in the P, Fe, S, and N cycle. These observations are important for understanding the nutrient salt transformation and diffusion in the Pearl River Delta. Full article

Urban areas are expanding rapidly and experience diverse and complex contamination of their surface waters. Addressing these issues requires different tools to describe exposures and predict toxicological risk to exposed biota. We surveyed 21 stormwater management ponds in Brampton, Ontario using three types of sampling methods deployed concurrently: time-integrated water sampling, biofilms cultured on artificial substrates, and organic-diffusive gradients in thin films (o-DGT) passive samplers. Our objective was to compare pesticide occurrences and concentrations to inform monitoring in stormwater ponds, which reflect pesticide pollution in urban areas. We detected 82 pesticides across the three sampling matrices, with most detections occurring in o-DGT samplers. The in situ accumulation of pesticides in o-DGTs during deployment and the high analytical sensitivity achieved establishes o-DGTs as excellent tools for capturing the mixtures of pesticides present. Water and biofilm sampling demonstrated that pesticide concentrations available for uptake are relatively low, with most below toxicological thresholds. Yet our results demonstrate that urban areas are subject to a wide range of pesticides, including herbicides, insecticides, and fungicides, and underscores the urgency of research to quantify the risks of chronic exposure to this chemical mixture. Full article

The bioavailability of heavy metals in soil is a crucial factor in determining their potential uptake by plants and their subsequent entry into the food chain. Various methods, including traditional chemical extractants and the diffusive gradients in thin films (DGT) technique, are employed to assess this bioavailability. The bioavailability of heavy metals, particularly cadmium (Cd) and lead (Pb), is also influenced by soil texture and their concentrations in the soil solution. The primary objectives of this experiment were to compare and correlate the assessment of the Cd and Pb bioavailability using the DGT technique and traditional extractants across two soil textural classes: sandy clay loam (SCL) and clay loam (CL) at two contamination levels: aged contaminated (NC) and artificially contaminated (AC). The specific objectives included assessing the bioavailability of Cd and Pb at different growth stages of the wheat plant and correlating the DGT-based bioassessments of Cd and Pb with their concentrations in various plant parts at different growth stages. This study also compared the effectiveness of the DGT method and traditional extraction techniques in assessing the bioavailable fractions of Cd and Pb in soil. The regression analysis demonstrated strong positive correlations between the DGT method and various extraction methods. The results showed that the wheat plants grown in the AC soils exhibited lower root, shoot, and grain weights compared to those grown in the NC soils, indicating that metal contamination negatively impacts plant performance. The concentrations of Cd and Pb in the wheat tissues varied across different growth stages, with the highest levels observed during the grain filling (S3) and maturity (S4) stages. It is concluded that the in situ assessment of Cd and Pb though DGT was strongly and positively correlated with the Cd and Pb concentration in wheat plant parts at the maturity stage. A correlation and regression analysis of the DGT assessment and traditional extractants showed that the DGT method provides a reliable tool for assessing the bioavailability of Cd and Pb in soils and helped in developing sustainable soil management strategies to ensure the safety of agricultural products for human consumption. Full article

The occurrence of β-blocker drugs in aquatic environments worldwide has caused increasing attention to their threat to human health in recent years. It is essential to monitor these widely prescribed pharmaceuticals in natural waters and sediments, helping us investigate their potential risk to humans and ecosystems. In this study, a passive sampling technique, diffusive gradients in thin-films (DGT), was systematically developed for eight frequently detected β-blockers. The effective capacities of target compounds were large enough for the devices to deploy for several weeks. The uptake of all compounds was linearly correlated with deployment times during the 7-day laboratory experiment and agreed well with the theoretical line, except for several compounds (e.g., ATL) due to their relatively slow uptake rate. The performance of most compounds was independent of varying pH values and organic matter contents; only a few compounds were affected, while the application in high-salinity environments needs to be conducted with caution. Field deployments of DGT to detect β-blockers in situ in rivers and sediments proved that DGT is an effective tool to monitor β-blocker drugs and their fate in the natural aquatic environment, while DGT probes can provide information for us to investigate the biogeochemical processes occurred in sediment, especially at the sediment–water interface. This novel approach will help us understand the behaviour of β-blocker drugs in the aquatic environment, assess their risks, finally protect human health and maintain the sustainable development of the ecosystem. Full article

Ferrihydrite is usually used as a remedy for arsenic (As)-contaminated soil due to its strong affinity and large specific surface area. However, its noncrystalline phase makes it unstable in long-term applications in the soil. In this study, a soil incubation experiment was designed using the diffusive gradient in thin film (DGT) technique and spectral techniques to investigate the fate of As-bearing ferrihydrite [As(V)-Fh] after long-term incubation at different soil water holding capacities (SWHCs). After As(V)-Fh (0.05 and 0.005 As/Fe molar ratio) was incubated in soil for 360 days, both DGT-derived labile As and Fe were released at 70% SWHC and 120% SWHC into the soil (at a vertical depth of 12 cm). The concentrations of DGT-As and DGT-Fe increased with incubation time and were greater at 120% SWHC. The results of X-ray diffraction (XRD) and scanning electron microscopy (SEM) showed that As(V)-Fh gradually transformed into hematite and goethite after 360 days of incubation. Goethite was mainly found in the 120% SWHC treatment after 180 days. Hematite and goethite formation rates were greater in the 120% SWHC treatment and in the bottom soil layer. Mechanistic analysis based on X-ray photoelectron spectroscopy (XPS) revealed that the variation in soil pH and the formation of Fe(II) (under flooded water conditions) are the two key factors promoting the formation of hematite (dehydrogenation and dehydration) and goethite (As(V)-Fh dissociation and reorganization). The As release mainly occurred due to the loss of adsorption sites. Thus, it is recommended that ferrihydrite be applied in paddy–dry rotations or dry-field patterns to effectively avoid the loss of As(V)-Fh in long-term-saturated soil. Full article

In this study, we examined for the first time the spatio-temporal distribution of trace metal (TM) contaminants (Zn, Cd, Pb, Cu, Ni and Co) in the seawater column of Pula Bay. The bay has been known for decades as one of the most industrialized regions on the Croatian side of the Adriatic. Water samples were collected at 20 sites (at two depths) in four different seasons. The main physico-chemical parameters and DOC were measured along the TMs. The spatial distribution clearly showed that areas with industrial and nautical activities are sources of Zn, Pb and Cu, while no increase was observed for Cd, Ni and Co. Compared to the reference area outside the bay, the increase in dissolved concentrations ranged from a factor of 1.1 for Ni and Co to 8.5 for Pb. A clear difference in TM concentrations was observed between seasons, with concentrations being higher in warmer periods than in colder periods. The potential bioavailability/toxicity of TMs was examined using a passive sampling technique: diffusive gradients in thin films (DGT). In addition, a single-factor pollution index based on the available EQSs was used for both the dissolved TMs and DGT to assess the potential risk to the environment. Full article

Polycyclic aromatic hydrocarbon (PAH) derivatives are widely present in the environment, and some are more hazardous than their parent PAHs. However, compared to PAHs, PAH derivatives are less studied due to challenges in monitoring as a result of their low concentrations in environmental matrixes. Here, we developed a new passive sampler based on diffusive gradients in thin films (DGT) to monitor PAH derivatives and PAHs in waters. In the laboratory study, the XAD18-DGT device exhibited high adsorption rates and was demonstrated to be suitable for deployment in environmental waters on the timescale of months. The diffusion coefficients, D, were 5.30 × 10⁻⁶ cm² s⁻¹, 4.51 × 10⁻⁶ cm² s⁻¹, 4.03 × 10⁻⁶ cm² s⁻¹ and 3.34 × 10⁻⁶ cm² s⁻¹ for 9-fluorenone (9-FL), 1-chloroanthraquinone (1-CLAQ), 9-nitroanthracene (9-NA) and phenanthrene (Phe), respectively, at 25 °C. The DGT device’s performance was independent of pH, ionic strength, deployment time and storage time, indicating it can be widely used in natural waters. In the field study, the target pollutant concentrations measured by the DGT are in good accordance with those determined via grab sampling. Then, the DGT devices were utilized to quantify PAH derivatives and PAHs in several rivers in Hefei, China. This work demonstrates the feasibility of using the DGT technique to detect trace PAH derivatives and PAHs in waters. Full article

To evaluate the level of contamination and predict the potential toxicity risk, selected metal concentrations (Cd, Pb, Cr, Mn, Co, Ni, Cu, Zn, and As) were determined in 40 surface sediment samples from the stratified karstic Krka River estuary (Croatia). In addition, diffusive gradients in thin films (DGT) probes were deployed in situ to understand the mobilization mechanisms and bioavailability of metals in the sediment. The results show significant spatial differences between the upper and lower estuary, with the latter being more affected by anthropogenic pollution. The pollution assessment using the enrichment factor (EF), the geoaccumulation index (Igeo), and the pollution load index (PLI) showed a strong enrichment of metals in the lower part of the estuary, especially of Mn, Cu, Zn, Pb, and As. The statistical analysis (PCA) revealed the former ferromanganese factory and the port as major sources of pollution in the area. Nickel, Co, and Cr, although slightly elevated, may be attributed to the natural origin. The metal mobility in the estuarine sediment was primarily governed by early diagenetic processes (aerobic organic matter mineralization, Fe and Mn oxyhydroxide reduction), which caused the release of metals from the sediment into the pore water and subsequently into the overlying water column. Full article