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Search Results (372)

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Keywords = dielectric modulation

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12 pages, 5607 KiB  
Article
Tunable Dual-Mode Resonant Excitation of Dumbbell-Shaped Structures in the Mid-Infrared Band
by Tao Jiang, Yafei Li, Zhuangzhuang Xu, Xike Qian, Rui Shi, Xiufei Li, Meng Wang and Ze Li
Nanomaterials 2025, 15(15), 1181; https://doi.org/10.3390/nano15151181 - 31 Jul 2025
Abstract
Metasurfaces have drawn extensive research attention for their unique optical properties and vast application potential. Among the various resonant modes induced in metasurfaces, BIC and electric anapole modes stand out as particularly interesting due to their distinctive physical characteristics. In this work, we [...] Read more.
Metasurfaces have drawn extensive research attention for their unique optical properties and vast application potential. Among the various resonant modes induced in metasurfaces, BIC and electric anapole modes stand out as particularly interesting due to their distinctive physical characteristics. In this work, we designed and investigated novel dimeric dumbbell-shaped metasurfaces incorporating two independently tunable asymmetric parameters. This structural innovation enables the simultaneous excitation of both electric anapole and QBIC modes under normally incident MIR illumination. More importantly, by adjusting these two asymmetric parameters, one can independently tune the resonance peaks of the two modes, thereby overcoming the performance limits of conventional single-peak modulation. This metasurface design demonstrates outstanding performance for dielectric environment-sensing applications. We conducted a comprehensive investigation of the sensing sensitivity for dumbbell-shaped metasurfaces of various geometries. Our simulation results show that the circular-shaped configuration achieved high sensitivity, reaching 20,930 GHz/RIU. This work offers a novel design paradigm for multi-mode control and functionalization of metasurface structures. Full article
(This article belongs to the Section Theory and Simulation of Nanostructures)
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27 pages, 4829 KiB  
Article
Quantitative Analysis of Ginger Maturity and Pulsed Electric Field Thresholds: Effects on Microstructure and Juice’s Nutritional Profile
by Zhong Han, Pan He, Yu-Huan Geng, Muhammad Faisal Manzoor, Xin-An Zeng, Suqlain Hassan and Muhammad Talha Afraz
Foods 2025, 14(15), 2637; https://doi.org/10.3390/foods14152637 - 28 Jul 2025
Viewed by 280
Abstract
This study used fresh (young) and old (mature) ginger tissues as model systems to investigate how plant maturity modulates the response to pulsed electric field (PEF), a non-thermal processing technology. Specifically, the influence of tissue maturity on dielectric behavior and its downstream effect [...] Read more.
This study used fresh (young) and old (mature) ginger tissues as model systems to investigate how plant maturity modulates the response to pulsed electric field (PEF), a non-thermal processing technology. Specifically, the influence of tissue maturity on dielectric behavior and its downstream effect on juice yield and bioactive compound extraction was systematically evaluated. At 2.5 kV/cm, old ginger exhibited a pronounced dielectric breakdown effect due to enhanced electrolyte content and cell wall lignification, resulting in a higher degree of cell disintegration (0.65) compared with fresh ginger (0.44). This translated into a significantly improved juice yield of 90.85% for old ginger, surpassing the 84.16% limit observed in fresh ginger. HPLC analysis revealed that the extraction efficiency of 6-gingerol and 6-shogaol increased from 1739.16 to 2233.60 µg/g and 310.31 to 339.63 µg/g, respectively, in old ginger after PEF treatment, while fresh ginger showed increases from 1257.88 to 1824.05 µg/g and 166.43 to 213.52 µg/g, respectively. Total phenolic content (TPC) and total flavonoid content (TFC) also increased in both tissues, with OG-2.5 reaching 789.57 µg GAE/mL and 336.49 µg RE/mL, compared with 738.19 µg GAE/mL and 329.62 µg RE/mL in FG-2.5. Antioxidant capacity, as measured by ABTS•+ and DPPH inhibition, improved more markedly in OG-2.5 (37.8% and 18.7%, respectively) than in FG-2.5. Moreover, volatile compound concentrations increased by 177.9% in OG-2.5 and 137.0% in FG-2.5 compared with their respective controls, indicating differential aroma intensification and compound transformation. Structural characterization by SEM and FT-IR further corroborated enhanced cellular disruption and biochemical release in mature tissue. Collectively, these results reveal a maturity-dependent mechanism of electro-permeabilization in plant tissues, offering new insights into optimizing non-thermal processing for functional food production. Full article
(This article belongs to the Section Food Engineering and Technology)
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13 pages, 7300 KiB  
Article
Strain and Layer Modulations of Optical Absorbance and Complex Photoconductivity of Two-Dimensional InSe: A Study Based on GW0+BSE Calculations
by Chuanghua Yang, Yuan Jiang, Wendeng Huang and Feng Pan
Crystals 2025, 15(7), 666; https://doi.org/10.3390/cryst15070666 - 21 Jul 2025
Viewed by 233
Abstract
Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and [...] Read more.
Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and the Bethe–Salpeter equation, we calculated the quasiparticle electronic structure, optical absorbance, and complex photoconductivity of 2D InSe from a single layer (1L) to three layers (3L). The calculation results show that the energy difference between the direct and indirect band gaps in 1L, 2L, and 3L InSe is so small that strain can readily tune its electronic structure. The 2D optical absorbance results calculated taking into account exciton effects show that light absorption increases rapidly near the band gap. Strain modulation of 1L InSe shows that it transforms from an indirect bandgap semiconductor to a direct bandgap semiconductor in the biaxial compressive strain range of −1.66 to −3.60%. The biaxial compressive strain causes a slight blueshift in the energy positions of the first and second absorption peaks in monolayer InSe while inducing a measurable redshift in the energy positions of the third and fourth absorption peaks. Full article
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10 pages, 1632 KiB  
Article
An Ultra-Narrowband Graphene-Perfect Absorber Based on Bound States in the Continuum of All-Dielectric Metasurfaces
by Qi Zhang, Xiao Zhang, Zhihong Zhu and Chucai Guo
Nanomaterials 2025, 15(14), 1124; https://doi.org/10.3390/nano15141124 - 19 Jul 2025
Viewed by 296
Abstract
Enhancing light absorption in two-dimensional (2D) materials, particularly few-layer structures, is critical for advancing optoelectronic devices such as light sources, photodetectors, and sensors. However, conventional absorption enhancement strategies often suffer from unstable resonant wavelengths and low-quality factors (Q-factors) due to the inherent weak [...] Read more.
Enhancing light absorption in two-dimensional (2D) materials, particularly few-layer structures, is critical for advancing optoelectronic devices such as light sources, photodetectors, and sensors. However, conventional absorption enhancement strategies often suffer from unstable resonant wavelengths and low-quality factors (Q-factors) due to the inherent weak light–matter interactions in 2D materials. To address these limitations, we propose an all-dielectric metasurface graphene-perfect absorber based on toroidal dipole bound state in the continuum (TD-BIC) with an ultra-narrow bandwidth and stable resonant wavelength. The proposed structure achieves tunable absorption linewidths spanning three orders of magnitude (6 nm to 0.0076 nm) through critical coupling modulation. Furthermore, the operational wavelength can be flexibly extended to any near-infrared region by adjusting the grating width. This work establishes a novel paradigm for enhancing the absorption of 2D materials in photonic device applications. Full article
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28 pages, 8047 KiB  
Article
Hybrid Dielectric Barrier Discharge Reactor: Production of Reactive Oxygen–Nitrogen Species in Humid Air
by Dariusz Korzec, Florian Freund, Christian Bäuml, Patrik Penzkofer, Oliver Beier, Andreas Pfuch, Klaus Vogelsang, Frank Froehlich and Stefan Nettesheim
Plasma 2025, 8(3), 27; https://doi.org/10.3390/plasma8030027 - 6 Jul 2025
Viewed by 579
Abstract
Reactive oxygen–nitrogen species (RONS) production in a Peltier-cooled hybrid dielectric barrier discharge (HDBD) reactor operated with humid air is characterized. Fourier-transform infrared spectroscopy (FTIR) is used to determine the RONS in the HDBD-produced gases. The presence of molecules O3, NO2 [...] Read more.
Reactive oxygen–nitrogen species (RONS) production in a Peltier-cooled hybrid dielectric barrier discharge (HDBD) reactor operated with humid air is characterized. Fourier-transform infrared spectroscopy (FTIR) is used to determine the RONS in the HDBD-produced gases. The presence of molecules O3, NO2, N2O, N2O5, and HNO3 is evaluated. The influence of HDBD reactor operation parameters on the FTIR result is discussed. The strongest influence of Peltier cooling on RONS chemistry is reached at conditions related to a high specific energy input (SEI): high voltage and duty cycle of plasma width modulation (PWM), and low gas flow. Both PWM and Peltier cooling can achieve a change in the chemistry from oxygen-based to nitrogen-based. N2O5 and HNO3 are detected at a low humidity of 7% in the reactor input air but not at humidity exceeding 90%. In addition to the FTIR analysis, the plasma-activated water (PAW) is investigated. PAW is produced by bubbling the HDBD plasma gas through 12.5 mL of distilled water in a closed-loop circulation at a high SEI. Despite the absence of N2O5 and HNO3 in the gas phase, the acidity of the PAW is increased. The pH value decreases on average by 0.12 per minute. Full article
(This article belongs to the Special Issue Processes in Atmospheric-Pressure Plasmas—2nd Edition)
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15 pages, 2854 KiB  
Article
Development of a Hydrogen-Sensing Antenna Operating in the Microwave Region for Applications in Safety-Critical Systems
by Antonio Jefferson Mangueira Sales, Stephen Rathinaraj Benjamin, João Paulo Costa do Nascimento, Felipe Felix do Carmo, Juscelino Chaves Sales, Roterdan Fernandes Abreu, Francisco Enilton Alves Nogueira, Paulo Maria de Oliveira Silva, Marcelo Antonio Santos da Silva, José Adauto da Cruz, Enio Pontes de Deus and Antonio Sergio Bezerra Sombra
Chemosensors 2025, 13(7), 233; https://doi.org/10.3390/chemosensors13070233 - 25 Jun 2025
Viewed by 580
Abstract
Hydrogen is gaining prominence as a clean energy vector, yet its extreme flammability demands robust detection solutions for industrial safety. In this study, we present the development and experimental validation of a microwave hydrogen gas sensor based on a patch-type microstrip antenna with [...] Read more.
Hydrogen is gaining prominence as a clean energy vector, yet its extreme flammability demands robust detection solutions for industrial safety. In this study, we present the development and experimental validation of a microwave hydrogen gas sensor based on a patch-type microstrip antenna with a silver sensing element. The device operates at 5.99 GHz and was tested under controlled environmental conditions (humidity: 20 ± 0.4%, temperature: 27 ± 0.2 °C). Hydrogen exposure induces measurable shifts in the antenna’s resonant frequency due to dielectric modulation of the silver layer. The sensor exhibited a linear sensitivity of 3 kHz/ppm in the 310–600 ppm concentration range, with a residual standard deviation of 31.1 kHz and a calculated limit of detection (LOD) of approximately 31 ppm. The reflection coefficient remained below −10 dB throughout, confirming that the antenna maintains functional RF performance during sensing. These results demonstrate the sensor’s dual functionality for gas detection and communication, offering a compact and scalable platform for hydrogen safety monitoring. Full article
(This article belongs to the Special Issue Novel Materials for Gas Sensing)
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12 pages, 2278 KiB  
Communication
An All-Optical Plasmon Modulator with a High Extinction Ratio Based on the Resonance of a Silver Block
by Jimi Fang, Sisi Yang, Xuefang Hu, Changgui Lu and Mengjia Lu
Photonics 2025, 12(7), 646; https://doi.org/10.3390/photonics12070646 - 25 Jun 2025
Viewed by 289
Abstract
Conventional all-optical modulators based on surface plasmon polaritons (SPPs) primarily utilize the nonlinear effect of a given material for modulation. Their performance is heavily dependent on the optical properties of the dielectric materials used and requires high pumping power. However, manipulating SPPs by [...] Read more.
Conventional all-optical modulators based on surface plasmon polaritons (SPPs) primarily utilize the nonlinear effect of a given material for modulation. Their performance is heavily dependent on the optical properties of the dielectric materials used and requires high pumping power. However, manipulating SPPs by controlling electron concentrations offers a material-independent approach suitable for all-optical modulators. In this paper, we propose a hybrid gold–ITO–silver block structure integrated within a Mach–Zehnder interferometer configuration to address this problem. The gold–ITO interface effectively localizes propagating SPPs. The pump light excites localized surface plasmons (LSPs) in the silver block, generating surface electric fields that modulate the electron concentration in the adjacent ITO layer. The extinction ratio is 50.8 dB when the electron concentration changes by 3.3 × 1020 cm−3, indicating that this structure is an all-optical modulator with a high extinction ratio. This approach shows significant promise for reducing pump power and enhancing the performance of all-optical modulators. Full article
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23 pages, 2905 KiB  
Article
Fluxgate Magnetometers Based on New Physical Principles
by Ivan V. Bryakin, Igor V. Bochkarev, Vadim R. Khramshin, Vadim R. Gasiyarov and Ivan N. Erdakov
Sensors 2025, 25(13), 3893; https://doi.org/10.3390/s25133893 - 22 Jun 2025
Viewed by 996
Abstract
This article considers a fluxgate magnetometer (FM) that operates based on a new physical principle. The authors analyze how the alternating electric charge potential of a cylindrical metal electrode impacts the structure of a cylindrical permanent magnet made of composite-conducting ferrite. They demonstrate [...] Read more.
This article considers a fluxgate magnetometer (FM) that operates based on a new physical principle. The authors analyze how the alternating electric charge potential of a cylindrical metal electrode impacts the structure of a cylindrical permanent magnet made of composite-conducting ferrite. They demonstrate that this impact and permanent magnet structure initiate the emergence of polarons with oscillating magnetism. This causes significant changes in the entropy of indirect exchange and the related sublattice magnetism fluctuations that ultimately result in the generation of circularly polarized spin waves at the spin wave resonance frequency that are channeled and evolve in dielectric ferrite waveguides of the FM. It is demonstrated that these moving spin waves have an electrodynamic impact on the measuring FM coils on the macro-level and perform parametric modulation of the magnetic permeability of the waveguide material. This results in the respective variations of the changeable magnetic field, which is also registered by the measuring FM coils. The authors considered a generalized flow of the physical processes in the FM to obtain a detailed representation of the operating functions of the FM. The presented experimental results for the proposed FM in the field meter mode confirm its operating parameters (±40 μT—measurement range, 0.5 nT—detection threshold). The usage of a cylindrical metal electrode as a source of exciting electrical change instead of a conventional multiturn excitation coil can significantly reduce temperature drift, simplify production technology, and reduce the unit weight and size. Full article
(This article belongs to the Section Physical Sensors)
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16 pages, 3499 KiB  
Article
Physical and Electrical Properties of Silicon Nitride Thin Films with Different Nitrogen–Oxygen Ratios
by Wen-Jie Chen, Yang-Chao Liu, Zhen-Yu Wang, Lin Gu, Yi Shen and Hong-Ping Ma
Nanomaterials 2025, 15(13), 958; https://doi.org/10.3390/nano15130958 - 20 Jun 2025
Viewed by 488
Abstract
Silicon oxynitride (SiOxNy, hereafter denoted as SiON) thin films represent an intermediate phase between silicon dioxide (SiO2) and silicon nitride (Si3N4). Through systematic compositional ratio adjustments, the refractive index can be precisely tuned [...] Read more.
Silicon oxynitride (SiOxNy, hereafter denoted as SiON) thin films represent an intermediate phase between silicon dioxide (SiO2) and silicon nitride (Si3N4). Through systematic compositional ratio adjustments, the refractive index can be precisely tuned across a wide range from 1.45 to 2.3. However, the underlying mechanism governing the influence of elemental composition on film structural quality remains insufficiently understood. To address this knowledge gap, we systematically investigate the effects of key industrial plasma-enhanced chemical vapor deposition (PECVD) parameters—including precursor gas selection and flow rate ratios—on SiON film properties. Our experimental measurements reveal that stoichiometric SiOxNy (x = y) achieves a minimum surface roughness of 0.18 nm. As oxygen content decreases and nitrogen content increases, progressive replacement of Si-O bonds by Si-N bonds correlates with increased structural defect density within the film matrix. Capacitance–voltage (C-V) characterization demonstrates a corresponding enhancement in device capacitance following these compositional modifications. Recent studies confirm that controlled modulation of film stoichiometry enables precise tailoring of dielectric properties and capacitive behavior, as demonstrated in SiON-based power electronics, thereby advancing applications in related fields. Full article
(This article belongs to the Section 2D and Carbon Nanomaterials)
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19 pages, 3119 KiB  
Article
Gate-Controlled Three-Terminal ZnO Nanoparticle Optoelectronic Synaptic Devices for In-Sensor Neuromorphic Memory Applications
by Dabin Jeon, Seung Hun Lee and Sung-Nam Lee
Nanomaterials 2025, 15(12), 908; https://doi.org/10.3390/nano15120908 - 11 Jun 2025
Cited by 1 | Viewed by 365
Abstract
This study reports a gate-tunable three-terminal optoelectronic synaptic device based on an Al/ZnO nanoparticles (NPs)/SiO2/Si structure for neuromorphic in-sensor memory applications. The ZnO NP film, fabricated via spin coating, exhibited strong UV-induced excitatory post-synaptic current (EPSC) responses that were modulated by [...] Read more.
This study reports a gate-tunable three-terminal optoelectronic synaptic device based on an Al/ZnO nanoparticles (NPs)/SiO2/Si structure for neuromorphic in-sensor memory applications. The ZnO NP film, fabricated via spin coating, exhibited strong UV-induced excitatory post-synaptic current (EPSC) responses that were modulated by gate voltage through charge injection across the SiO2 dielectric rather than by conventional field effect. Optical stimulation enabled short-term synaptic plasticity, with paired-pulse facilitation (PPF) values reaching 185% at a gate voltage of −5.0 V and decreasing to 180% at +5.0 V, confirming gate-dependent modulation of synaptic weight. Repeated stimulation enhanced learning efficiency and memory retention, as demonstrated by reduced pulse numbers for relearning and slower EPSC decay. Wickelgren’s power law analysis further revealed a decrease in the forgetting rate under negative gate bias, indicating improved long-term memory characteristics. A 3 × 3 synaptic device array visualized visual memory formation through EPSC-based color mapping, with darker intensities and slower fading observed under −5.0 V bias. These results highlight the critical role of gate-voltage-induced charge injection through the SiO2 dielectric in controlling optical potentiation and electrical depression, establishing ZnO NP-based optoelectronic synaptic devices as promising platforms for energy-efficient, light-driven neuromorphic computing. Full article
(This article belongs to the Special Issue The Interaction of Electron Phenomena on the Mesoscopic Scale)
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15 pages, 1759 KiB  
Article
Quantum Simulation Study of Ultrascaled Label-Free DNA Sensors Based on Sub-10 nm Dielectric-Modulated TMD FETs: Sensitivity Enhancement Through Downscaling
by Khalil Tamersit, Abdellah Kouzou, José Rodriguez and Mohamed Abdelrahem
Micromachines 2025, 16(6), 690; https://doi.org/10.3390/mi16060690 - 8 Jun 2025
Viewed by 1199
Abstract
In this article, the role of downscaling in boosting the sensitivity of a novel label-free DNA sensor based on sub-10 nm dielectric-modulated transition metal dichalcogenide field-effect transistors (DM-TMD FET) is presented through a quantum simulation approach. The computational method is based on self-consistently [...] Read more.
In this article, the role of downscaling in boosting the sensitivity of a novel label-free DNA sensor based on sub-10 nm dielectric-modulated transition metal dichalcogenide field-effect transistors (DM-TMD FET) is presented through a quantum simulation approach. The computational method is based on self-consistently solving the quantum transport equation coupled with electrostatics under ballistic transport conditions. The concept of dielectric modulation was employed as a label-free biosensing mechanism for detecting neutral DNA molecules. The computational investigation is exhaustive, encompassing the band profile, charge density, current spectrum, local density of states, drain current, threshold voltage behavior, sensitivity, and subthreshold swing. Four TMD materials were considered as the channel material, namely, MoS2, MoSe2, MoTe2, and WS2. The investigation of the scaling capability of the proposed label-free gate-all-around DM-TMDFET-based biosensor showed that gate downscaling is a valuable approach not only for producing small biosensors but also for obtaining high biosensing performance. Furthermore, we found that reducing the device size from 12 nm to 9 nm yields only a moderate improvement in sensitivity, whereas a more aggressive downscaling to 6 nm leads to a significant enhancement in sensitivity, primarily due to pronounced short-channel effects. The obtained results have significant technological implications, showing that miniaturization enhances the sensitivity of the proposed nanobiosensor. Full article
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17 pages, 3485 KiB  
Article
Development of an Oblique Cone Dielectric Elastomer Actuator Module-Connected Vertebrate Fish Robot
by Taro Hitomi, Ryuki Sato and Aiguo Ming
Biomimetics 2025, 10(6), 365; https://doi.org/10.3390/biomimetics10060365 - 4 Jun 2025
Viewed by 595
Abstract
As a soft actuator for fish robots, an oblique cone dielectric elastomer actuator (DEA) module inspired by the structure of white muscles in fish was proposed in the authors’ previous study. However, a mathematical model of an oblique cone DEA was not established, [...] Read more.
As a soft actuator for fish robots, an oblique cone dielectric elastomer actuator (DEA) module inspired by the structure of white muscles in fish was proposed in the authors’ previous study. However, a mathematical model of an oblique cone DEA was not established, and designing a drive module that took into account its driving characteristics and passivity for integration into a fish robot remained a challenge. The purpose of this paper is to develop a vertebrate fish robot using multiple oblique cone DEA modules to achieve fish-like bending capability. First, an oblique cone DEA module was modeled for the design of a fish robot. The relationships among bending angle, blocking torque, driving voltage, and design parameters were established and confirmed by comparing the calculated and experimental results. Based on the modeling results, we designed an oblique cone DEA module-connected vertebrate fish robot. Finally, the experimental results of the fabricated fish robot demonstrated that the model-based design enabled flexible body swinging and swimming through a multiple-module-connected vertebrate structure. Full article
(This article belongs to the Section Locomotion and Bioinspired Robotics)
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12 pages, 2708 KiB  
Article
Starch–Glycerol-Based Hydrogel Memristors for Bio-Inspired Auditory Neuron Applications
by Jiachu Xie, Yuehang Ju, Zhenwei Zhang, Dianzhong Wen and Lu Wang
Gels 2025, 11(6), 423; https://doi.org/10.3390/gels11060423 - 1 Jun 2025
Viewed by 447
Abstract
In the era of artificial intelligence, the demand for rapid and efficient data processing is growing, and traditional computing architectures are increasingly struggling to meet these needs. Against this backdrop, memristor devices, capable of mimicking the computational functions of brain neural networks, have [...] Read more.
In the era of artificial intelligence, the demand for rapid and efficient data processing is growing, and traditional computing architectures are increasingly struggling to meet these needs. Against this backdrop, memristor devices, capable of mimicking the computational functions of brain neural networks, have emerged as key components in neuromorphic systems. Despite this, memristors still face many challenges in biomimetic functionality and circuit integration. In this context, a starch–glycerol-based hydrogel memristor was developed using starch as the dielectric material. The starch–glycerol–water mixture employed in this study has been widely recognized in literature as a physically cross-linked hydrogel system with a three-dimensional network, and both high water content and mechanical flexibility. This memristor demonstrates a high current switching ratio and stable threshold voltage, showing great potential in mimicking the activity of biological neurons. The device possesses the functionality of auditory neurons, not only achieving artificial spiking neuron discharge but also accomplishing the spatiotemporal summation of input information. In addition, we demonstrate the application capabilities of this artificial auditory neuron in gain modulation and in the synchronization detection of sound signals, further highlighting its potential in neuromorphic engineering applications. These results suggest that starch-based hydrogel memristors offer a promising platform for the construction of bio-inspired auditory neuron circuits and flexible neuromorphic systems. Full article
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15 pages, 5629 KiB  
Article
Phase and Valence State Engineering of MOFs-Derived Iron Oxide@Carbon Polyhedrons for Advanced Microwave Absorption
by Xiaojiao Yang, Shuai Han, Hongna Xing, Yi Dong, Xia Deng, Yan Zong, Juan Feng, Xiuhong Zhu, Xinghua Li and Xinliang Zheng
Nanomaterials 2025, 15(11), 806; https://doi.org/10.3390/nano15110806 - 27 May 2025
Viewed by 377
Abstract
MOFs-derived magnetic carbon-based composites are considered to be valuable materials for the design of high-performance microwave absorbents. Regulating phase structures and introducing mixed-valence states within the composites is a promising strategy to enhance their charge transfer properties, resulting in improved microwave absorption performance. [...] Read more.
MOFs-derived magnetic carbon-based composites are considered to be valuable materials for the design of high-performance microwave absorbents. Regulating phase structures and introducing mixed-valence states within the composites is a promising strategy to enhance their charge transfer properties, resulting in improved microwave absorption performance. In this study, iron oxide components show a temperature-dependent phase evolution process (α-Fe2O3→Fe3O4→Fe3O4/FeO), during which the valence states of iron ions are regulated. The tunable phases modulate the magnetic Fe3O4 component, resulting in enhanced magnetic loss. The changed valence states affect the polarization relaxation by adjusting the electronic structure and tune the electron scattering by introducing defects, leading to enhanced dielectric loss. The microwave absorption properties of iron oxide@carbon composites display phase- and valence state-dependent characteristics. Especially, Fe3O4@C composites exhibit superior microwave absorption properties, ascribed to the improved magnetic/dielectric losses induced by good impedance matching and strong microwave attenuation capacity. The minimum reflection loss of Fe3O4@C composites reaches −73.14 dB at 10.35 GHz with an effective absorption bandwidth of 4.9 GHz (7.69–12.59 GHz) when the absorber thickness is 2.31 mm. This work provides new insights into the adjustment of electromagnetic parameters and microwave absorption properties by regulating the phase and valence state. Full article
(This article belongs to the Section 2D and Carbon Nanomaterials)
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16 pages, 9992 KiB  
Article
Quantitative Dissection of Relaxation Processes in Hybrid Epoxy Composites: Combining Dielectric Spectroscopy with Activation Energy Analysis
by Xingqiao Li, Hongliang Zhang, Yansheng Bai, Hai Jin, Hong Wang, Kangle Li and Xiaonan Li
Polymers 2025, 17(10), 1405; https://doi.org/10.3390/polym17101405 - 20 May 2025
Viewed by 461
Abstract
The dielectric relaxation dynamics in polymer composites critically determine their functional performance in advanced electrical systems. This study systematically investigates hybrid epoxy composites comprising neat epoxy resin (EP) and paper-reinforced systems (EIP), modified with 10–50 wt% polypropylene glycol diglycidyl ether (PEGDGE) plasticizer. Through [...] Read more.
The dielectric relaxation dynamics in polymer composites critically determine their functional performance in advanced electrical systems. This study systematically investigates hybrid epoxy composites comprising neat epoxy resin (EP) and paper-reinforced systems (EIP), modified with 10–50 wt% polypropylene glycol diglycidyl ether (PEGDGE) plasticizer. Through synergistic application of differential scanning calorimetry (DSC) and broadband dielectric spectroscopy (10−1–106 Hz), the quantitative relationships between plasticizer content, glass transition temperature (Tg), and dielectric relaxation processes were established. DSC analysis reveals a linear Tg dependence with increasing PEGDGE content, attributed to enhanced molecular mobility. Dielectric characterization demonstrates three distinct relaxation regimes: α-relaxation below Tg, interfacial polarization at epoxy/PEGDGE boundaries, and paper/epoxy interfacial effects in EIP systems. A quantitative dielectric relaxation model was developed based on complex modulus formalism, coupled with Vogel–Fulcher–Tammann (VFT) analysis of DC conductivity. Activation energy mapping through Arrhenius decomposition reveals three characteristic values: (1) 82.01–87.80 kJ/mol for α-relaxation, (2) 55.96–64.64 kJ/mol for epoxy/PEGDGE interfaces, and (3) 30.88–44.38 kJ/mol for epoxy/paper interfaces. Crucially, the plasticizer content modulates these activation energies, demonstrating its role in tailoring interfacial dynamics. Full article
(This article belongs to the Section Polymer Analysis and Characterization)
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