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Search Results (1,579)

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Keywords = dielectric losses

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19 pages, 2254 KB  
Article
A Comparative Study on the Insulation Properties of Different Epoxy Materials for UHV DC Bushing Insulators
by Xining Li, Hao Tang, Kai Liu, Huichuan Tang, Yi Zhang and Guangning Wu
Inventions 2026, 11(4), 66; https://doi.org/10.3390/inventions11040066 (registering DOI) - 24 Jun 2026
Abstract
Ultra-high-voltage direct-current (UHVDC) transmission systems impose stringent requirements on the reliability of insulation materials used in converter transformer bushings. Epoxy resin systems are key insulating materials in resin-impregnated paper (RIP) capacitor bushings, and their processing characteristics, curing behavior, and electrical properties directly affect [...] Read more.
Ultra-high-voltage direct-current (UHVDC) transmission systems impose stringent requirements on the reliability of insulation materials used in converter transformer bushings. Epoxy resin systems are key insulating materials in resin-impregnated paper (RIP) capacitor bushings, and their processing characteristics, curing behavior, and electrical properties directly affect bushing performance. In this study, two epoxy insulation systems used for resin-impregnated paper (RIP) bushings, namely the imported Araldite LY1564/Aradur 3486 system and the domestic EP-2020/CA-3015 system, were systematically investigated through viscosity, curing, and electrical property tests. The results show that the viscosities of both resins decreased significantly with increasing temperature. At 60 °C, the viscosities of Resin A and Resin B were 151.6 mPa·s and 156.3 mPa·s, respectively. The mixed resin–hardener systems exhibited similar viscosity evolution and comparable pot life characteristics. DSC measurements revealed two-stage curing reactions for both materials, with first exothermic peak temperatures of 65.4 °C and 96.3 °C and second peak temperatures of 269.3 °C and 269.8 °C for Materials A and B, respectively. Electrical testing demonstrated that both materials exhibited similar temperature-dependent dielectric and resistivity behavior, with dielectric loss increasing at elevated temperatures and resistivity decreasing as temperature increased. The volume resistivity trends and dielectric characteristics of the two materials remained highly consistent throughout the investigated temperature range. The results indicate that Material B exhibits processing performance, curing characteristics, and electrical insulation properties comparable to those of Material A. Therefore, Material B demonstrates strong potential for application in UHVDC RIP bushing insulation systems and provides a promising alternative for the localization of key insulating materials. Full article
17 pages, 1889 KB  
Article
Improving UV Stability of SiO2/SiNx-Passivated Silicon Photodiodes Through Shallow Junction Implantation and Oxide Regrowth
by Michael N. Getz, Ozhan Koybasi, Fredrik Edhborg, Ørnulf Nordseth, Steven Hesse, Tobias Pohl, Marco Povoli, Stefan Källberg, Lutz Werner, Erkki Ikonen and Jarle Gran
Sensors 2026, 26(13), 3991; https://doi.org/10.3390/s26133991 (registering DOI) - 24 Jun 2026
Abstract
Induced-junction silicon photodiodes based on SiO2/SiNx surface passivation are attractive for high-accuracy radiometry, but their use in the deep ultraviolet is limited by UV-induced degradation of the dielectric stack. In this work, we investigate the degradation of SiO2/SiN [...] Read more.
Induced-junction silicon photodiodes based on SiO2/SiNx surface passivation are attractive for high-accuracy radiometry, but their use in the deep ultraviolet is limited by UV-induced degradation of the dielectric stack. In this work, we investigate the degradation of SiO2/SiNx-passivated p-type silicon photodiodes under UV irradiation and evaluate strategies for improving stability through shallow implanted junctions and oxide processing. Capacitance–voltage measurements on MIS capacitors and lifetime measurements on symmetrically passivated wafers show that UV exposure causes a rapid reduction in effective dielectric charge and carrier lifetime, followed by saturation at higher dose, consistent with filling of a finite population of electrically active trap states. Induced-junction photodiodes exhibit rapid photocurrent loss at 222 nm and, in some cases, eventual collapse, indicating that the remaining effective dielectric charge is insufficient to sustain the induced junction. To maintain junction functionality after UV exposure, shallow As- and Sb-implanted junctions are employed, resulting in an initial reduction during 222 nm exposure followed by stabilization at around 80–85% of the initial value up to the highest tested dose of 200 J/cm2. Further improvement is achieved by stripping and regrowing the implanted screen oxide before SiNx deposition, yielding nearly unchanged photocurrent after prolonged 222 nm exposure up to ca. 500 J/cm2. These results show that UV stability can be substantially improved by reducing device dependence on dielectric-induced inversion and by improving post-implantation interfacial oxide quality. Full article
(This article belongs to the Section Electronic Sensors)
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15 pages, 25234 KB  
Article
Design and Numerical Demonstration of All-Optical Logic Devices Based on Topological Valley Photonic Crystals with Circular Ring Dielectric Columns
by Youjun Ma, Yongqiang Li, Cheng Ju and Changhong Li
Crystals 2026, 16(7), 405; https://doi.org/10.3390/cryst16070405 (registering DOI) - 23 Jun 2026
Abstract
One of the bottlenecks in realizing all-optical computing is the lack of on-chip all-optical logic devices that combine compactness, low loss, and high robustness. Valley photonic crystals (VPCs) have become an important solution for realizing such devices, relying on the excellent transmission characteristics [...] Read more.
One of the bottlenecks in realizing all-optical computing is the lack of on-chip all-optical logic devices that combine compactness, low loss, and high robustness. Valley photonic crystals (VPCs) have become an important solution for realizing such devices, relying on the excellent transmission characteristics of topological valley states. However, existing structures still face issues such as limited design flexibility. In this paper, a high-performance topological all-optical logic device based on VPCs consisting of circular ring dielectric columns is designed and demonstrated. By introducing the inner radius as an independent design parameter, we construct a new type of VPC and systematically investigate its influence on the photonic band gap. Based on this, we design a beam splitter with high operational bandwidth and low insertion loss (<0.5 dB) and then realize fundamental OR and XOR logic gates, achieving extinction ratios of 18.9 dB for the OR gate and up to 44 dB for the XOR gate at an operating frequency of 193.5 THz. The platform also supports the NOT gate and, through cascading, can implement more logic functions such as the AND gate. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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10 pages, 2554 KB  
Proceeding Paper
Integrated Assessment Methodology for Asphalt Pavement Integrity Under Accelerated Loading Conditions and GPR
by Qian Liu
Eng. Proc. 2026, 146(1), 5; https://doi.org/10.3390/engproc2026146005 (registering DOI) - 22 Jun 2026
Viewed by 26
Abstract
Ensuring the integrity of pavement structures necessitates a thorough evaluation of both surface-level damage and subsurface mechanical performance. This study proposes an integrated, non-destructive assessment framework tailored for semi-rigid base asphalt pavements subjected to repeated vehicular loading via MLS66 full-scale accelerated testing equipment. [...] Read more.
Ensuring the integrity of pavement structures necessitates a thorough evaluation of both surface-level damage and subsurface mechanical performance. This study proposes an integrated, non-destructive assessment framework tailored for semi-rigid base asphalt pavements subjected to repeated vehicular loading via MLS66 full-scale accelerated testing equipment. The proposed methodology integrates ground-penetrating radar (GPR) using the CO4080 system and dynamic response measurements from a falling weight deflectometer (FWD) to characterize structural conditions across multiple depths. Comparative analysis between pre-loading and post-loading data revealed significant deterioration trends in the surface layers, with stiffness loss closely associated with increasing load repetitions. In contrast, the underlying base layers exhibited stable deformation characteristics, with variations in deflection basin indices remaining within ±5%. Subgrade dielectric properties derived from GPR data confirmed consistent compaction quality throughout the test site. Statistical analysis further validated the synergy between GPR and FWD results, demonstrating that the combined application enhances diagnostic accuracy. The dual-method approach improved overall evaluation reliability by approximately 22–35% compared to using individual techniques alone under accelerated pavement testing scenarios. These findings support broader implementation of integrated sensing systems and highlight the potential for application across varied pavement types and loading conditions. Full article
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14 pages, 3334 KB  
Article
Magnetic-Field-Enhanced Microwave Absorption of Superparamagnetic Fe3O4/RGO Composites
by Guijiang Liu, Xingbao Lyu, Yiqun Ma, Chengxun Yuan and Zhongxiang Zhou
Micromachines 2026, 17(6), 754; https://doi.org/10.3390/mi17060754 (registering DOI) - 22 Jun 2026
Viewed by 137
Abstract
Superparamagnetic materials have attracted increasing attention for high-frequency microwave absorption because superparamagnetic relaxation can partially overcome the high-frequency limitations of conventional magnetic absorbers. Herein, Fe3O4/rGO composite powders were prepared by electrostatic self-assembly and subsequently incorporated into an epoxy matrix, [...] Read more.
Superparamagnetic materials have attracted increasing attention for high-frequency microwave absorption because superparamagnetic relaxation can partially overcome the high-frequency limitations of conventional magnetic absorbers. Herein, Fe3O4/rGO composite powders were prepared by electrostatic self-assembly and subsequently incorporated into an epoxy matrix, and magnetic-field-induced alignment was introduced during curing. Owing to the synergistic effects of interfacial polarization, magnetic dissipation, and improved impedance matching, the optimized composites exhibited markedly enhanced microwave absorption performance. In particular, when the rGO content was 10 wt% and an external magnetic field was applied, the composite achieved effective absorption across the entire X-band (8–12 GHz) within a thickness range of 1–3 mm, together with a minimum reflection loss of −40.3 dB. The enhanced performance is attributed to the combined contributions of abundant heterogeneous interfaces, superparamagnetic relaxation, and field-induced orientation of Fe3O4-decorated rGO sheets. This work provides a simple physical strategy for the microstructural regulation of magnetic–dielectric composites toward high-performance microwave absorption. Full article
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22 pages, 5273 KB  
Article
Structure–Property Relationships in PEI/PET Polymer Blends: Morphological, Rheological, Thermal, Mechanical Behavior, and Electromagnetic Response
by Elshod Olmosovich Khakberdiev, Hülya Kaftelen Odabaşı, Akın Odabaşı, Selcuk Helhel, Qodirbek Nuridin ugli Berdinazarov, Nizomiddin Zokir ugli Dusiyorov and Nigmat Rustamovich Ashurov
Polymers 2026, 18(12), 1528; https://doi.org/10.3390/polym18121528 - 19 Jun 2026
Viewed by 566
Abstract
In this study, twin screw extruded Polyetherimide (PEI)/Poly(ethylene terephthalate) (PET) polymer blends (90/10, 70/30, 50/50 w/w%) were investigated to elucidate the composition–property relationship governed by morphological, structural, rheological, thermomechanical, mechanical, and electromagnetic shielding (EMI) performance behavior. Among other polymer blends, [...] Read more.
In this study, twin screw extruded Polyetherimide (PEI)/Poly(ethylene terephthalate) (PET) polymer blends (90/10, 70/30, 50/50 w/w%) were investigated to elucidate the composition–property relationship governed by morphological, structural, rheological, thermomechanical, mechanical, and electromagnetic shielding (EMI) performance behavior. Among other polymer blends, the 70/30 blend exhibits superior thermomechanical stability with a significant glass transition temperature of 132.7 °C, where a robust confinement effect effectively restricts the mobility of PET chains. This morphology, characterized by a domain size of 562 nm, provides proof of concept for interface-driven attenuation, reaching a maximum EMI shielding effectiveness of 2.54 dB within the investigated blends. This performance is primarily governed by Maxwell–Wagner–Sillars polarization at the immiscible boundaries, alongside an optimized dielectric loss of tan δ ≈ 0.065. The design of these high-temperature PEI blends provides a proof of concept for interface-driven attenuation and demonstrates their potential for developing advanced EMI shielding matrices. Full article
(This article belongs to the Section Polymer Chemistry)
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19 pages, 3884 KB  
Article
Linking Dielectric Response with Transformer Moisture Content Through Vector Fitting Analysis and Havriliak–Negami Model
by Giovanni Hernandez, Abner Ramirez and Parminder Panesar
Processes 2026, 14(12), 1953; https://doi.org/10.3390/pr14121953 - 15 Jun 2026
Viewed by 125
Abstract
This paper presents a method for estimating moisture content (%MC) in power transformers. It primarily relies on the analysis of the statistical properties of relaxation times characterizing the dielectric frequency response (DFR), which is fitted as a sum of rational functions using the [...] Read more.
This paper presents a method for estimating moisture content (%MC) in power transformers. It primarily relies on the analysis of the statistical properties of relaxation times characterizing the dielectric frequency response (DFR), which is fitted as a sum of rational functions using the Vector Fitting (VF) tool. The DFR is modeled as a sum of Debye terms (accounting for materials exhibiting different relaxation times due to multiple polarization processes) characterized by poles and residues provided by VF. These parameters are then used to derive statistical factors that correlate with the shape of the dielectric response curve in the context of the Havriliak–Negami (HN) model, which is known for its effectiveness in characterizing materials with multiple relaxation times. By correlating the statistical factors with the HN model parameters, substantial insights into the insulation condition can be achieved. A moisture index (MI) is proposed from these parameters, which, when combined with conductivity, allows for accurate %MC estimation in the solid insulation system (cellulose). The combined MI and conductivity capture combined effects on moisture behavior, addressing both conductivity and polarization losses at different frequencies. The proposed method provides an efficient and straightforward non-invasive approach to insulation assessment without complex optimization algorithms. Experimental work on transformers at varying moisture levels provides validation of the proposed approach and demonstrates strong correlation with industry standards. The results confirm its reliability for moisture evaluation in transformer monitoring. Full article
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26 pages, 8124 KB  
Article
Dielectric Properties and Electromagnetic–Thermal–Moisture Coupling of Frozen Soil Under Microwave Irradiation
by Baoyi He, Zixin He, Zhuo Chen, Yixiang Zhang, Hongge Han, Yu Li, Zihan Li, Litao Zhao, Anshuai Wang and Xuehui Yu
Materials 2026, 19(12), 2583; https://doi.org/10.3390/ma19122583 - 15 Jun 2026
Viewed by 196
Abstract
To reveal the electromagnetic response characteristics and hydro-thermal evolution mechanism of frozen soil under microwave irradiation, we used remolded frozen soil prepared from undisturbed parent soil collected in Hegang, China, as the research object. We conducted dielectric parameter tests across the 715–1150 MHz [...] Read more.
To reveal the electromagnetic response characteristics and hydro-thermal evolution mechanism of frozen soil under microwave irradiation, we used remolded frozen soil prepared from undisturbed parent soil collected in Hegang, China, as the research object. We conducted dielectric parameter tests across the 715–1150 MHz and 2250–2650 MHz frequency bands and 1.5 kW microwave heating tests on specimens with three gravimetric water contents (15%, 20%, and 25%) paired with a coupled numerical simulation of electromagnetic field-heat transfer-moisture migration. The results show that water content is the dominant factor controlling the dielectric response of frozen soil. The dielectric loss and water content sensitivity of frozen soil in the low-frequency band (dominated by unfrozen water) are significantly higher than those in the high-frequency band (dominated by ice phase and soil matrix). Microwave-induced temperature rise exhibits a three-stage characteristic, as follows: slow temperature rise, isothermal plateau at the freezing point, and rapid temperature rise. Specimens with a lower initial water content show a higher temperature rise efficiency in the late heating stage, with a maximum rate of 1.112 °C·s−1 for the 15% water content specimen. Mass loss is negatively correlated with initial water content, with a maximum value of 1.8 g after 120 s of irradiation. In addition, the non-uniformity of the electromagnetic field results in a temperature field pattern characterized by a high-temperature core at the specimen center and lower temperatures at the edges. This study provides fundamental theoretical support and technical guidance for the application of microwave thawing technology in geotechnical engineering, particularly for frozen soil foundation treatment in cold regions. Full article
(This article belongs to the Special Issue Advances in Materials Processing via Microwave Energy)
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21 pages, 5424 KB  
Review
Process Integration and Reliability Challenges of Through-Glass Vias for Glass-Based Advanced Packaging: A Focused Review
by Dong Bae Park, Jinho Jo, Seonwoo Kim, Da-Yeong Lee, Suin Chae, Soobin Park, Se-Hoon Park, Tae-Young Lee, Kyoung-Min Kim, Nam Son Park, Seong-Eui Lee, Sang O Kim and Hyunjin Nam
Micromachines 2026, 17(6), 720; https://doi.org/10.3390/mi17060720 - 14 Jun 2026
Viewed by 223
Abstract
Recent advances in chiplet architectures, heterogeneous integration, 2.5D/3D packaging, high-performance computing, and RF applications have increased the demand for high-density vertical interconnects and low-loss packaging platforms. Glass substrates have attracted considerable attention for next-generation advanced packaging because of their low dielectric loss, high [...] Read more.
Recent advances in chiplet architectures, heterogeneous integration, 2.5D/3D packaging, high-performance computing, and RF applications have increased the demand for high-density vertical interconnects and low-loss packaging platforms. Glass substrates have attracted considerable attention for next-generation advanced packaging because of their low dielectric loss, high dimensional stability, smooth surface, and compatibility with large-area panel-level processing. Through-glass vias (TGVs) are essential vertical interconnect structures that enable the electrical integration of glass substrates. This focused review summarizes TGV technologies for glass-based advanced packaging from the perspectives of via formation, seed layer deposition, metallization, Cu filling, defect formation, reliability, and plugging-based alternative architectures. Representative TGV formation methods, including laser drilling, selective laser etching, laser-induced deep etching, wet/dry etching, and photosensitive glass processing, are compared. Metallization approaches based on sputtering, electroless plating, ALD/CVD, and hybrid processes are discussed together with Cu electroplating strategies such as conformal plating, bottom-up filling, pulse or pulse-reverse plating, and engineered-geometry filling. Key defects, including voids, seams, pinch-off, seed discontinuity, Cu/glass interfacial delamination, glass cracking, and Cu protrusion, are reviewed in relation to thermomechanical reliability. Finally, polymer/dielectric plugging, plugging/re-drilling, conductive paste plugging, and hybrid Cu/plugging structures are discussed as application-specific alternatives for balancing electrical performance, reliability, manufacturability, yield, and cost. Full article
(This article belongs to the Collection Microdevices and Applications Based on Advanced Glassy Materials)
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33 pages, 6006 KB  
Article
Deep Learning-Enhanced Dielectric Sensing for Rapid Quality Assessment of ‘Starks Gold’ Sweet Cherries
by Erhan Kavuncuoglu, Kamil Sacilik, Mehmet Akif Buzpinar, Burak Ozbey, Necati Cetin and Fernando Auat Cheein
Agronomy 2026, 16(12), 1161; https://doi.org/10.3390/agronomy16121161 - 13 Jun 2026
Viewed by 326
Abstract
Soluble solids content (SSC) is one of the most important indicators of sweetness, ripeness, and market quality in sweet cherries. However, conventional SSC determination is destructive, labor-intensive, and unsuitable for rapid or large-scale quality assessment. Therefore, there is a need for fast, non-destructive, [...] Read more.
Soluble solids content (SSC) is one of the most important indicators of sweetness, ripeness, and market quality in sweet cherries. However, conventional SSC determination is destructive, labor-intensive, and unsuitable for rapid or large-scale quality assessment. Therefore, there is a need for fast, non-destructive, and data-driven sensing approaches that can estimate internal fruit quality without damaging the sample. This study aimed to develop a non-destructive approach for SSC prediction in sweet cherries by combining open-ended coaxial probe dielectric spectroscopy with deep learning models. An open-ended coaxial probe measurement system was designed and developed to determine the dielectric properties of sweet cherries and was coupled with an Agilent E4991A impedance analyzer operating over a frequency range of 5–3005 MHz. A total of 10,080 dielectric measurements and 2100 reference SSC measurements were collected over 26 experimental days. The dielectric constant (ε′), loss factor (ε″), and loss tangent (tan δ) were extracted and used to construct separate ε′, ε″, tan δ, and integrated combined datasets. Six deep learning architectures, namely convolutional neural network (CNN), long short-term memory (LSTM), bidirectional long short-term memory (BiLSTM), gated recurrent unit (GRU), CNN-LSTM, and convolutional long short-term memory (ConvLSTM), were trained and optimized using Bayesian optimization and early stopping. CNN achieved the best performance on the tan δ dataset (test R2 = 0.9099, RMSE = 0.8354 °Brix, MAE = 0.6599 °Brix), whereas GRU yielded the highest accuracy on the integrated combined dataset (test R2 = 0.8622, RMSE = 1.0331 °Brix, MAE = 0.7958 °Brix). ConvLSTM provided the most consistent performance across all four datasets (test R2 = 0.8081–0.8651), demonstrating strong predictive capability and practical computational efficiency. These findings confirm the potential of reduced-range dielectric spectroscopy combined with deep learning for rapid, non-destructive SSC assessment in sweet cherries. Full article
(This article belongs to the Special Issue Smart Farming: Advancing Techniques for High-Value Crops)
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18 pages, 5579 KB  
Article
Research on the Absorption Properties of Fe70Ni30 Alloy/SiO2 Coated Continuous Glass Fiber Composites by Magnetron Sputtering
by Zhuohui Zhou, Mengyu Zhou, Zhiyong Wang and Yan Zhao
Materials 2026, 19(12), 2552; https://doi.org/10.3390/ma19122552 - 12 Jun 2026
Viewed by 234
Abstract
In this study, Fe70Ni30 metal was deposited onto continuous glass fiber composites via magnetron sputtering, followed by surface coating with SiO2. The effects of key process parameters-including Fe70Ni30 sputtering duration (2, 5, 10, 20, and [...] Read more.
In this study, Fe70Ni30 metal was deposited onto continuous glass fiber composites via magnetron sputtering, followed by surface coating with SiO2. The effects of key process parameters-including Fe70Ni30 sputtering duration (2, 5, 10, 20, and 30 min) and SiO2 surface coating-on the electromagnetic properties and microwave absorption performance of the materials were systematically investigated. Scanning electron microscopy (SEM) characterization revealed that as sputtering time increased, the metal coating evolved from discrete small particles into a continuous film. Cross-sectional SEM analysis further demonstrated the formation of a bilayer structure after SiO2 introduction. X-ray diffraction (XRD) patterns confirmed the presence of diffraction peaks corresponding to the Fe70Ni30 alloy solid solution. Electromagnetic parameter measurements indicated that the influence of sputtering time on electromagnetic properties was primarily pronounced during the metal layer growth stage; once a continuous film was formed, the variation in electromagnetic parameters diminished. Concurrently, the SiO2 coating exhibited a significant regulatory effect on dielectric parameters. Reflection coefficient calculations showed that the optimal absorption thickness for the single-layer material ranged from 2.5 to 3.0 mm, with the absorption peak shifting toward lower frequencies as thickness increased. However, the effective absorption bandwidth (EAB) was only 3–5 GHz, failing to meet wideband requirements. In contrast, the three-layer composite structure (total thickness: 3.8 mm) optimized via genetic algorithm achieved impedance gradient and loss synergy, expanding the EBW (R < −10 dB) from 4.8 GHz (single layer) to 10 GHz (8–18.0 GHz)-a substantial improvement over the single-layer configuration. This work provides experimental evidence and technical support for the structural design and process optimization of lightweight, high-efficiency, wideband microwave-absorbing materials. Full article
(This article belongs to the Topic Advanced Composite Materials)
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18 pages, 7247 KB  
Article
Fabrication of Sub-10 μm Microvias Using Nanosecond UV Laser Drilling and a Sacrificial Metal Barrier Layer for Advanced Fine-Pitch Packaging
by Nam-Son Park, Tae-Young Lee, Kyoung-Min Kim, Hyun-Jin Nam and Hee-Chul Lee
Micromachines 2026, 17(6), 709; https://doi.org/10.3390/mi17060709 - 10 Jun 2026
Viewed by 276
Abstract
Advanced packaging requires high-density interconnects with sub-10 μm design rules; however, conventional processes involving laser drilling and plasma desmearing increase dielectric surface roughness and degrade signal performance. A nanosecond ultraviolet (ns-UV) laser microvia process using a sacrificial metal barrier layer (SMBL) was developed [...] Read more.
Advanced packaging requires high-density interconnects with sub-10 μm design rules; however, conventional processes involving laser drilling and plasma desmearing increase dielectric surface roughness and degrade signal performance. A nanosecond ultraviolet (ns-UV) laser microvia process using a sacrificial metal barrier layer (SMBL) was developed to enable sub-10 μm via formation while preserving dielectric surface integrity. A Cu SMBL was introduced to block debris redeposition during laser irradiation and shield the dielectric from ion bombardment during plasma processing. By optimizing laser power, shot count, and SMBL thickness, approximately 8 μm microvias were formed in 10 μm thick Ajinomoto Build-up Film (ABF). The Cu SMBL facilitated heat dissipation, reducing the heat-affected zone and limiting lateral widening at the via entrance, resulting in improved via geometry and higher taper. The dielectric surface roughness increased significantly (>80 nm) when no SMBL was used during processing, whereas it remained nearly constant with the SMBL (Ra: 6.36 → 6.43 nm), thereby reducing current scattering at high frequencies. Adhesion of 0.46 kgf/cm was maintained after quick-via-pull testing without mechanical interlocking, with no interfacial separation observed, confirming reliable interconnect formation. Therefore, the SMBL process enables precise microvia fabrication and low-loss interconnects for high-frequency packaging. Full article
(This article belongs to the Special Issue Laser-Assisted Ultra-Precision Machining)
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22 pages, 4522 KB  
Article
Dielectric Relaxation and Conduction Mechanisms in Se90Sn6Pb4 Chalcogenide Glass for Memory and Sensor Applications
by Adel A. Shaheen, Mousa M. A. Imran, Vladimír Holcman, Ammar Alsoud and Rashid Dallaev
Appl. Sci. 2026, 16(12), 5788; https://doi.org/10.3390/app16125788 - 8 Jun 2026
Viewed by 240
Abstract
This study investigates the dielectric relaxation and conduction mechanisms in Se90Sn6Pb4 chalcogenide glassy material, which is of interest for applications in phase-change memory devices, optical memory, and thermoelectric sensors. Despite previous studies on chalcogenide glasses, [...] Read more.
This study investigates the dielectric relaxation and conduction mechanisms in Se90Sn6Pb4 chalcogenide glassy material, which is of interest for applications in phase-change memory devices, optical memory, and thermoelectric sensors. Despite previous studies on chalcogenide glasses, the conduction mechanisms at varying temperatures and the role of correlated barrier hopping (CBH) remain unclear. Using impedance spectroscopy in the frequency range 1 Hz–1 MHz at temperatures from 288 K to 318 K, the real (Z) and imaginary (Z) parts of the complex impedance were recorded. The sample was also characterized by X-ray diffraction (XRD) to confirm its glassy nature, and X-ray photoelectron spectroscopy (XPS) to determine the surface chemical composition and oxidation states of the elements. Peaks in Z at each temperature were used to evaluate the relaxation time τ, revealing thermally activated processes with an activation energy of 0.62 eV. Nyquist plots showed semicircular behavior with decreasing radii at higher temperatures, indicating enhanced d.c. conductivity with an activation energy of 0.63 eV. A.C. conductivity analysis demonstrated frequency-dependent behavior consistent with the CBH model, with hopping energy calculated as 0.32 eV. The dielectric loss increased with temperature and decreased with frequency, stabilizing above 250 Hz at 318 K. These findings provide new insights into the dielectric and conduction properties of Se90Sn6Pb4 glasses, supporting their optimization for practical electronic applications. Full article
(This article belongs to the Section Chemical and Molecular Sciences)
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27 pages, 7899 KB  
Article
Thermal Treatment-Induced Coercivity Modulation in Magnetodielectric LaFe0.7Ni0.3O3
by Ximena Jocelyn Téllez-Tovar, Félix Sánchez-De Jesús, Claudia Alicia Cortés-Escobedo, María Isabel Reyes-Valderrama and Ana María Bolarín-Miró
Physics 2026, 8(2), 51; https://doi.org/10.3390/physics8020051 - 8 Jun 2026
Viewed by 275
Abstract
This study investigates the modulation of coercivity and magnetodielectric coupling in heat-treated, nickel-substituted lanthanum ferrite. LaFe0.7Ni0.3O3 samples were synthesized by high-energy ball milling and sintered at temperatures between 1073 and 1473 K. Chemical composition, crystalline structural evolution, surface [...] Read more.
This study investigates the modulation of coercivity and magnetodielectric coupling in heat-treated, nickel-substituted lanthanum ferrite. LaFe0.7Ni0.3O3 samples were synthesized by high-energy ball milling and sintered at temperatures between 1073 and 1473 K. Chemical composition, crystalline structural evolution, surface morphology, magnetic, dielectric, and electrical properties, as well as magnetodielectric coupling, were analyzed. The XPS spectra revealed the presence of adsorbed oxygen, associated with the high oxygen affinity of the material. This behavior is interpreted as a charge-compensation mechanism, related both to the formation of oxygen vacancies and to the partial oxidation of Fe3+ to Fe4+. XRD and Rietveld refinement confirmed a single-phase orthorhombic Pnma structure, and structural simulations revealed progressive octahedral distortions with increasing temperature, affecting the octahedral tilting and electronic bandwidth. Magnetic characterization revealed that thermal processing modifies the magnetic behavior, inducing weak ferromagnetism and a significant increase in coercivity, correlating with progressive densification, greater domain stability, and reduced microstrain. Impedance measurements revealed magnetodielectric coupling, the Maxwell–Wagner interfacial polarization mechanism, and reduced dielectric losses. These findings demonstrate that the coercivity and magnetodielectric response in cationic nickel-substituted lanthanum ferrite can be tuned through thermal processing. A semi-empirical magnetocrystalline anisotropy model is proposed to explain the coercivity evolution and associated multiferroic behaviors, thus contributing to the study of functional ferrites as sustainable alternatives to rare-earth magnetic materials with potential in sensors and memory devices. Full article
(This article belongs to the Section Applied Physics)
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14 pages, 3833 KB  
Article
Terahertz Dielectric Characterization and Hybrid Debye–Lorentz Modeling of Silicone Rubber Composites for Composite Insulators
by Tengyi Zhang, Li Cheng, Shuo Zhang, Bo Tao and Qingyue Tan
Polymers 2026, 18(12), 1427; https://doi.org/10.3390/polym18121427 - 8 Jun 2026
Viewed by 333
Abstract
High-temperature vulcanized (HTV) silicone rubber serves as the core material for composite insulators, and its high-frequency dielectric properties directly dictate its macroscopic insulation performance. However, traditional electrical detection methods encounter a “high-frequency blind zone” above the gigahertz (GHz) range due to limited precision [...] Read more.
High-temperature vulcanized (HTV) silicone rubber serves as the core material for composite insulators, and its high-frequency dielectric properties directly dictate its macroscopic insulation performance. However, traditional electrical detection methods encounter a “high-frequency blind zone” above the gigahertz (GHz) range due to limited precision and ambiguous physical mechanisms. In this study, terahertz time-domain spectroscopy (THz-TDS) was employed to characterize the complex permittivity spectra of silicone rubber specimens, incorporated with varying ratios of alumina trihydrate (ATH) and silica (SiO2) fillers, across the 0.1–3.0 THz frequency range. Experimental results reveal that the terahertz dielectric characteristics of silicone rubber exhibit a pronounced filler dependency: as the ATH content increases from 95 phr to 185 phr, the real part of the permittivity at 1 THz increases by 32%. Notably, all specimens manifest a sharp dielectric transition near 1.2 THz, characterized by distinct dual absorption peaks in the imaginary permittivity spectra. To characterize this non-linear transition, a hybrid Debye–Lorentz model is innovatively introduced. This approach overcomes the inherent limitations of traditional double Debye models, which are restricted to relaxation processes and fail to account for high-frequency resonance. Fitting results and physical analysis demonstrate that the response at 1.2 THz is primarily attributed to the bending vibrations of Si-O-Si bonds in the polymer backbone, alongside the collective vibration modes of Al-O bonds and the hydrogen-bonded network within the fillers. The hybrid model successfully decouples three distinct polarization mechanisms: conduction loss (<0.5 THz), dipole relaxation (0.5–1.0 THz), and lattice resonance (>1.0 THz). This work provides a robust characterization framework for the quantitative evaluation of the high-frequency dielectric response and microstructural integrity of composite insulators. Full article
(This article belongs to the Section Polymer Physics and Theory)
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