Search Results (552)

The escalating production of sewage sludge presents a significant environmental challenge, while the construction industry simultaneously seeks sustainable raw materials to improve its circularity. This review analyses the technical and regulatory landscape for valorizing SS within the Latvian construction sector, set against the divergent strategies of its Baltic neighbours. While global research confirms the technical viability of using SS in fired-clay bricks and as a supplementary cementitious material (SCM), national management approaches differ starkly. Lithuania has adopted widespread incineration, and Estonia has focused on advanced composting. In contrast, Latvia’s national strategy is failing, with 51% of its 2024 sludge production diverted to “temporary storage”. This review identifies this crisis as a unique opportunity, arguing that incorporating dewatered digestate into fired-clay bricks is the most logical and economically viable pathway for Latvia, as it leverages existing industrial infrastructure. The primary obstacle to this circular solution is not technical but legal, specifically the lack of a national “End-of-Waste” (EoW) criterion for sludge-derived construction materials. Therefore, this article proposes a strategic roadmap for Latvia, centred on developing this essential legal framework, creating a national sludge characterization map, and initiating a pilot project to bridge the research-to-industry gap. Although Latvia is the primary focus of this review, the regulatory, infrastructural and material constraints analysed here are common in many small and mid-sized countries, making the insights applicable beyond the Latvian context. Full article

Sustainable xanthan gum (XG) production is increasingly prioritized as global demand rises, and conventional processes face economic and environmental constraints. Traditional manufacturing depends heavily on refined sugars, intensive fermentation control, and solvent-based purification, which elevate production costs and ecological impact. This review highlights recent advancements designed to improve sustainability across the XG value chain, focusing on alternative substrates, optimized fermentation, and greener extraction methods. Agricultural residues, food-processing waste, lignocellulosic biomass, and industrial effluents have emerged as promising low-cost substrates that reduce reliance on refined sugar sources while supporting waste valorization. Pretreatment strategies, such as acid hydrolysis, enzymatic processing, and integrated biological–chemical methods, significantly enhance the accessibility of complex biomass for microbial fermentation. Concurrently, improvements in strain selection, metabolic engineering, and process control have increased XG yield, molecular weight, and rheological performance. Environmentally friendly extraction technologies, including ultrasound-assisted extraction, pulsed electric fields, membrane filtration, and electro-dewatering, further reduce solvent consumption and energy demand in downstream processing. However, challenges persist, including substrate variability, formation of inhibitory compounds, strain instability, and regulatory considerations for waste-derived substrates or genetically modified strains. Future progress will rely on integrating bioprocess intensification, genetic engineering, and techno-economic assessment to build scalable, low-impact, and circular XG production systems. Full article

High-ash coal slime water, characterized by its stable colloidal suspension of fine kaolinite particles, poses a significant challenge in the coal preparation industry because it is hard to achieve efficient solid–liquid separation. While traditional coagulants and flocculants often suffer from limited bridging capabilities and distinct pH sensitivity, novel molecular architectures offer potential solutions. In this study, a star-shaped inorganic–organic hybrid flocculant (Al-PAM) was synthesized via in situ polymerization. Its flocculation performance and interfacial adsorption mechanism on the specifically targeted aluminol basal plane of kaolinite were systematically investigated and compared with Polyaluminum Chloride (PAC), Non-ionic Polyacrylamide (NPAM), and their combination (PAC + NPAM). Settling tests revealed that Al-PAM exhibited superior performance at a significantly lower dosage (10 mg∙L⁻¹) compared to the PAC + NPAM binary reagent system. It achieved a rapid initial settling velocity and reduced the supernatant turbidity to 48.45 NTU, while maintaining a near-neutral pH favorable for water recycling. Furthermore, Quartz Crystal Microbalance with Dissipation (QCM-D) monitoring confirmed that Al-PAM forms a thick, viscoelastic, and irreversible adsorption layer on the Al₂O₃ substrate. The dissipation shifts (ΔD) revealed that the star-shaped architecture promotes distinct bridging and electrostatic adsorption, overcoming the limitation of linear polymers. This work elucidates the specific contribution of the alumina-surface interaction with flocculants and proposes an efficient strategy for treating refractory coal slime water. Full article

Plastic microfibers (PMFs) increasingly accumulate in wastewater treatment plants, impairing sludge dewatering and raising operational costs. This study combines a bibliometric analysis (2000–2025) with a critical review of the recent mechanistic literature to map the evolving research landscape on PMF–extracellular polymeric substance (EPS) interactions. The bibliometric trajectory (R² = 0.9786) underscores a paradigm shift towards a molecular understanding of the sludge matrix. Our synthesis of recent experimental studies reveals that PMF-induced interference is often driven by the selective adsorption of hydrophobic extracellular proteins, with one study reporting up to 32.5% sequestration. This has been linked to deteriorated dewatering, such as a 45% increase in capillary suction time (CST) under controlled conditions. Proteomic studies have identified more than 40 extracellular proteins with altered expression, directly linking PMFs to impaired sludge rheology. However, this review critically assesses the underlying evidence, highlighting significant methodological heterogeneity, a lack of standardized protocols, and a reliance on laboratory-scale models as key limitations that prevent broad generalization. By identifying these gaps, this work reframes the PMF–EPS research agenda, emphasizing the need for harmonized methods and multi-omics integration to transform mechanistic insights into robust biotechnological solutions for sustainable sludge management within a circular bioeconomy. Full article

Coal preparation plants generate large volumes of fine tailings containing negatively charged colloidal particles that remain stable in suspension and hinder efficient water recovery. In this study, the flocculation performance of coal tailings was statistically evaluated using inorganic and organic reagents, namely ferric chloride (FeCl₃) and chitosan. The effects of chitosan dosage, FeCl₃ dosage, pH, stirring speed, and pulp density on turbidity and water recovery were investigated through Response Surface Methodology (RSM). Zeta potential measurements revealed that the sample exhibited a negative surface charge over the entire pH range. In contrast, chitosan effectively shifted the surface charge toward positive values under acidic and near-neutral conditions, indicating charge neutralization and polymer bridging mechanisms. ANOVA results revealed that pH, chitosan dosage, and pulp density were the most significant parameters influencing turbidity and water recovery. Under optimized conditions, turbidity was reduced to 9.86 NTU with a water recovery of 76.92%. Using chitosan alone provided an effective and statistically validated strategy for dewatering samples by enhancing floc formation through combined charge neutralization and interparticle bridging mechanisms, resulting in minimal turbidity. Although chitosan alone was sufficient to achieve effective flocculation, its synergistic combination with FeCl₃ resulted in the highest water recovery values under optimized conditions. Full article

To address the challenges of water hazard control in the thick water-rich sandstone aquifer of the roof under monoclinal structure conditions at Panel 110504 of Wangwa Coal Mine, as well as the problems of excessive ineffective drainage and high cost associated with the traditional full-face pre-drainage method, a study on the coordinated technology of mining progress and roof water drainage was carried out. By analyzing the geological and hydrogeological conditions of the panel, it was determined that the height of the water-conducting fracture zone reaches 228 m, which has penetrated the Yan’an Formation and entered the sandstone aquifer of the Zhiluo Formation, forming a unified composite water-filling source from the two aquifers. Based on calculations using the Theis equation and field drainage tests, the stable drainage time was determined to be 95 d and the advance drainage distance 300 m. Accordingly, a coordinated technical scheme of “sectional drainage while mining” was proposed, optimizing the layout parameters of drainage boreholes and the division of drainage sections. Field application results show that this technology reduced the average water inflow of the panel by 255.94 m³/h compared with the traditional mode, cumulatively saved 5.1413 million m³ of drainage water, cut drainage costs by 20.5652 million CNY, and no water hazard occurred. The research results can provide a technical reference for mining coal seams with water-rich roof under similar monoclinal structure conditions. Full article

Compost-derived humic acids (HAs) and fulvic acids (FAs) play an essential role in enhancing soil microbial diversity and activity by facilitating metabolic processes through electron transfer. Herein, the effect of bioleaching dewatered sludge (BDS) in comparison with filter press dewatered sludge (FDS) on the electron transfer capacity (ETC) of humic substances during composting was investigated as a novel attempt. A variety of characterization methods including UV-Vis, FTIR, 3D-EEM, and electrochemical measurements, were used to explore the change in humic substances during composting. The results indicated that bioleaching treatment significantly influenced the organic matter composition and hindered the accumulation of redox-active functional groups during composting. Notably, the ETC of HA increased by 24.07% in the FDS group but declined by 40.62% in the BDS group. This divergence stemmed from the organic matter loss during bioleaching, leading to reduced quinone-like and tryptophan-like substances associated with electron transfer in HA during composting. Furthermore, BDS showed lower pH, water content, and organic matter, but higher concentrations of ammonium nitrogen (${\mathrm{NH}}_4^{+}\text{-}\mathrm{N}$) and ammonia nitrogen ${\mathrm{NH}}_3^{-}\text{-}\mathrm{N}$, all of which potentially influenced humification efficiency. These findings not only clarify the electron-transfer dynamics of humic fractions but also highlight the importance of optimizing sludge pretreatment for improved composting performance and resource recovery. Full article

In addressing the challenge that the settlement behavior of granite residual soil in South China during foundation pit dewatering cannot be fully understood due to its unsaturated characteristics, this study proposes and validates an unsaturated fluid–solid coupling calculation method for dewatering-induced settlement analysis. This method is implemented by compiling FISH language code within a finite difference software framework. Validation was carried out by comparing thes simulated groundwater drawdown–time response with the measured drawdown from a field pumping test, demonstrating the improved agreement of the proposed unsaturated coupling approach relative to the conventional coupling scheme. Furthermore, to elucidate the soil settlement mechanisms, a sensitivity analysis of the deformation behavior of granite residual soil during dewatering was performed. The results demonstrate that, compared to the traditional fluid–solid coupling method, the unsaturated fluid–solid coupling method exhibits superior agreement with field dewatering experiments. The sensitivity analysis reveals that the differential settlement observed in the soil surrounding a dewatering well under the same target drawdown is primarily attributed to variations in drainage consolidation time and pore water pressure dissipation. Finally, a normalized analysis correlating the dewatering depth at the well with the resulting soil settlement deformation was conducted, establishing a practical relationship applicable under similar ground conditions and dewatering durations. This analysis provides theoretical guidance for selecting appropriate dewatering schemes during engineering practice. Full article

Vast quantities of liquid hydrocarbon and oil-containing wastes are generated and accumulate annually. Dewatering such sludges presents a significant technological challenge due to the high content of emulsified and chemically bound water. Consequently, the development of integrated approaches, particularly thermomechanical methods, have emerged as a promising strategy. These methods aim to disrupt the emulsion stability and enhance water evaporation efficiency. This study provides a theoretical basis for stabilizing the evaporation of the aqueous phase through mechanical agitation within boiling emulsions. A quantitative mathematical model is developed to identify critical conditions that prevent explosive boiling. Under intensive mixing, water globule diameters decrease by 80–85% within the first 5 s, while their settling time exceeds the dispersion time by hundreds of times—effectively inhibiting the accumulation of a critical aqueous-phase mass. Energy analysis reveals that, at a superheat temperature of 110 °C, the maximum permissible droplet diameter is approximately 0.5 mm; at 150 °C, it must not exceed 0.25 mm to avoid explosive boiling. To ensure safe operation, mixer rotational speeds of at least 100–200 rpm are required, with higher speeds (>200 rpm) necessary near 150 °C. The mechanical agitation modes proposed herein enable controlled, non-explosive evaporation of water from complex emulsions. Collectively, these findings lay a theoretical foundation for the industrial-scale deployment of thermomechanical dewatering technologies—offering a safer, more efficient pathway for managing challenging sludge streams. Full article

A floating surface skimmer is a device that regulates dewatering in a sediment basin. Skimmers decant from the top of the water column, allowing for greater capture of suspended sediment. Skimmer dewatering rates depend on design and vary by manufacturer. Theoretical flow rates yield errors when estimating dewatering times; therefore, there is a need to conduct experimental testing to obtain accurate flow rates. This study evaluated the discharge rates of eight skimmers with varying inlet sizes across different orifice openings using an adjustable slider. Testing was conducted in a 29.8 m³ (1053 ft³) evaluation tank assessing inlet sizes ranging from 3.8 cm (1.5 in.) to 20.3 cm (8 in.). For the five largest skimmers, four adjustable slider configurations were assessed, while three slider configurations were assessed for the three smallest skimmers. Each configuration was triplicated for 87 total experiments. Results indicate that skimmers can achieve flow rates ranging as high as 2622 m³/d (92,585 ft³/d) to as low as 28 m³/d (981 ft³/d) across all sizes. Collected data was used to model flow characteristics and develop two interactive skimmer sizing tools for designers and engineers. An alternative flow rate calculation method was also considered to maximize data analysis efficiency. Full article

Effective treatment of coal slime water is essential for sustainable coal preparation plant operation but hindered by the stable suspension of fine, negatively charged particles. To address this, a novel star-shaped inorganic–organic hybrid polymer (aluminum hydroxide-polyacrylamide, Al-PAM) was synthesized via in situ polymerization. Its performance was systematically compared with well-established coagulants/flocculants—polyaluminum chloride (PAC), non-ionic polyacrylamide (NPAM), and their binary combination through settling tests and quartz crystal microbalance with dissipation monitoring (QCM-D). The results showed a positive correlation between the molecular weight of Al-PAM and its flocculation efficiency. The optimal variant, Al-PAM-442, achieved an exceptionally high initial settling rate (50.4 m/h) and low supernatant turbidity (45.77 NTU) at an ultralow dosage of 6 mg/L. QCM-D analysis elucidated the mechanism: Al-PAM forms a thick, soft, and irreversibly adsorbed hydrated layer on silica, enabling strong electrostatic anchoring and effective polymer bridging. In contrast, PAC adsorption was reversible, while NPAM formed a thin, compact film with poor bridging capacity. Although the combined PAC/NPAM system showed synergistic performance, it required a significantly higher dosage (70 mg/L). This study demonstrates that the star-shaped Al-PAM architecture successfully integrates charge neutralization and bridging into a single molecule, offering a highly efficient and practical solution for industrial coal slurry dewatering. Full article

In the context of increasingly complex offshore drilling operations and stricter environmental regulations, the efficient handling and volume reduction of drilling cuttings has emerged as a crucial focus in the advancement of solids control equipment. “Airflow-assisted screening” is a technique that uses directed air currents to enhance the separation of solid cuttings from drilling fluid on a shaker screen, thereby improving dewatering efficiency and reducing waste volume during drilling. This study proposes and designs novel negative-pressure suction-type cuttings reduction equipment by integrating this technology with screw conveying principles. The system features a compact, vacuum-generator-centered design that integrates suction and screening. Key components were optimized, and a monitoring scheme was implemented for real-time performance evaluation. In the mechanism analysis, the relationship between inlet pressure, geometric parameters, and suction performance was explored based on Bernoulli’s principle and Laval nozzle characteristics, and internal flow field characteristics were revealed through computational fluid dynamics (CFDs) simulations. In the experimental section, a prototype system and testing platform were constructed to evaluate the effects of inlet pressure and screen mesh configurations on suction and screening performance. The results indicate that the system achieved optimal performance at an inlet pressure of 400 kPa with a 100-mesh screen, reaching a cuttings reduction efficiency of 9.225%. This study effectively validates the theoretical and simulation findings, providing technical support for the application of this equipment in complex drilling environments and demonstrating strong potential for practical implementation. Full article

The territory of the Republic of Armenia (RA) lies within the central Arabia–Eurasia collision zone and is characterized by rugged mountain landscapes, complex geology, active faulting, and seismicity. Armenia is highly vulnerable to seismic and landslide hazards, with more than 2504 active landslides mapped in the country. A significant landslide in the Tumanyan Community, Lori Marz, was activated in January 2018 and threatened critical infrastructure, including the railway linking Armenia to Georgia and the M6 interstate highway. The landslide’s activation was driven by groundwater, a nearby water reservoir leak, and adjacent infrastructure. Preliminary hazard analysis revealed that further movement of the landslide could dam the Debed River, leading to potentially catastrophic downstream impacts. In response, the Minister of Emergency Situations of RA requested urgent studies by the Institute of Geological Sciences of NAS RA. Surveys began on 22 January 2018, involving an interdisciplinary approach including geotechnical study, UAV-based digital mapping, and application of geophysical methods, such as MASW, microtremor recordings, GPR, and VES. The combination of these methods provided reliable information on the landslide’s geotechnical structure, identified the sliding plane, and allowed for numerical slope stability modeling, which confirmed the landslide’s unstable condition and susceptibility to reactivation from earthquakes or elevated groundwater. Based on this complex research, protective measures were developed and applied, including, in particular, horizontal drilling to dewater the sliding plane. These emergency measures stabilized the landslide, mitigating immediate threats to infrastructure and ensuring relative safety. Full article

Wet flue gas desulfurization (WFGD) is a widely used process for controlling SO₂ emissions in coal-fired power plants. However, the slow dissolution kinetics of limestone (CaCO₃) and the poor dewatering properties of gypsum crystals significantly limit the performance of this process. In this study, the effects of adding adipic acid, an organic acid, at different concentrations (0, 500, 1000, and 1500 ppm) to limestone slurry in the WFGD process were investigated. SO₂ removal performance, limestone consumption, and gypsum quality were evaluated. SO₂ removal efficiency remained unaffected by the addition of adipic acid. The addition of adipic acid reduced limestone consumption by 6.89%, 8.35%, and 9.92% in WFGD, respectively. The moisture content of gypsum decreased from 22.4% to 9.2%. The results revealed that adipic acid accelerates limestone dissolution via a ligand-assisted proton-transfer mechanism and improves the overall efficiency of the WFGD process by controlling gypsum crystallization. The physical quality and structure of gypsum obtained from the WFGD were evaluated by Scanning Electron Microscopy (SEM). Adipic acid led to the development of larger, smoother, and potato-like morphologies in the gypsum crystals and improved dewatering performance. This study demonstrates that using adipic acid in WFGD processes is a significant improvement strategy that enhances process efficiency by accelerating limestone dissolution and controlling gypsum crystallization. Adipic acid addition is an effective optimization strategy for full-scale industrial WFGD systems. Full article

The rising volume of sludge production poses significant environmental threats. Sludge has a high moisture content (MC), which increases its disposal and transport expenses. On the other hand, sludge has low dewaterability due to its high concentration of soluble organic compounds. To reduce sludge production, understanding and improving preconditioning and mechanical dewatering are crucial for breakthroughs in advanced sludge dewatering. The sludge samples used in this analysis were obtained from the Sarabium municipal wastewater treatment plant, with a moisture content of 97% and a specific filtration resistance (SRF) of 9.15463 × 10¹⁵ m/kg. Sludge dewatering was enhanced by treating the samples chemically with ferric chloride, aluminum sulfate, Moringa olifera, and cationic polyacrylamide CPAM and physically with wood chips, slag, rice husk, and wheat straw. The experiments examined the sludge’s initial characterization (specific resistance to filtration (SRF) and time to filtrate (TTF)). To verify the structural characteristics (density), elemental composition, and the presence of various functional groups, a characterization investigation was conducted using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and energy-dispersive X-ray spectroscopy (EDS). The results showed that chemical conditioning with ferric chloride is better than aluminum sulfate and Moringa. Wood chips also provide better results for physical conditioning than rice husk, wheat straw, and slag. The reaction occurred at the carbonyl group, where FTIR showed more activated sites during SEM analysis, as evidenced by the FTIR results. Still, when CPAM was added to conditioned sludge, there was no difference in sludge dewatering performance, and the activated sites remained unchanged. Hence, this research found that mechanical sludge dewatering was improved by conditioning with ferric chloride (pH of 6 and dose of 0.12 g/g of dry solid) and wood chips (dose of 1.5 g/g of dry solid), which reduced sludge volume after dewatering by 82.5% under low pressure, which in turn minimizes transportation, energy, and handling costs. This study supports SDG 3 and SDG 6 by improving sludge dewatering efficiency and promoting sustainable wastewater management using natural wood chips. Full article