Search Results (6,670)

Background/Objectives: Higher education requires students to communicate in complex academic and social contexts, including oral presentations, group work, help-seeking, assessment, and peer interaction. For students with developmental communication disorders, and communication-related developmental profiles, these demands may create hidden participation vulnerabilities that affect mental health, academic engagement, and belonging. This scoping review mapped empirical evidence among tertiary students, focusing on mental health, academic participation, social belonging, institutional support, and contextual influences. Methods: A scoping review was conducted in accordance with PRISMA-ScR guidance. Five databases, PubMed, PsycINFO, CINAHL, Scopus, and Web of Science, were searched for English-language, peer-reviewed empirical studies published from 2000 onwards. Eligible studies involved university, college, or tertiary students with developmental speech, language, fluency, pragmatic communication, or communication-related developmental profiles, who reported at least one mental health, academic, or social participation outcome. Data were charted and synthesised thematically, with methodological quality appraised using CASP-informed criteria. Results: Twenty-one studies were included. Evidence was strongest for stuttering and fluency-related participation, while research on developmental language disorder, speech sound disorder, pragmatic language impairment, cluttering, and mixed communication profiles was limited. Across studies, communication needs intersected with anxiety, depression, stress, self-efficacy, oral assessment, help-seeking, disclosure, stigma, accommodation access, and belonging. Key limitations included reliance on self-report, cross-sectional or retrospective designs, inconsistent diagnostic confirmation, and limited evidence for intervention. Conclusions: The available evidence suggests that developmental communication disorders and communication-related developmental profiles can function as hidden participation vulnerabilities in higher education. These vulnerabilities are shaped by students’ communication profiles and by communication-intensive university environments. Universities may therefore need communication-accessible teaching, flexible assessment, visible support pathways, and coordinated support across disability services, counselling, academic support, and speech–language pathology. Full article

High-sensitivity detection of formaldehyde is critically important for environmental protection and public health. Zinc oxide (ZnO) is a widely used core material for chemiresistive gas sensors; however, its conventional low-index facets suffer from a limited number of active sites, creating a bottleneck for further sensitivity enhancement. To overcome this limitation, this study pioneers the application of the highly reactive ZnO $\left[20\overline{2}1\right]$ high-index polar surface for formaldehyde detection. By leveraging its unique stepped atomic configuration and unprecedented density of coordination-unsaturated active sites, we systematically investigate the formaldehyde adsorption behavior and the underlying sensing mechanism using first-principles calculations based on density functional theory (DFT). The pristine ZnO $\left[20\overline{2}1\right]$ surface exhibits intrinsic metallic character. At a coverage of 1 monolayer (ML), the most stable G1 configuration achieves an adsorption energy of −1.54 eV per CH₂O molecule. Within a 2 × 1 supercell, formaldehyde adopts both associative and dissociative adsorption modes. At a lower coverage, formaldehyde forms a stable bidentate structure through dual C–O and Zn–O bonding interactions. Electronic structure analysis reveals significant orbital hybridization and interfacial charge redistribution upon adsorption. Notably, associative adsorption opens a bandgap of 0.04 eV at the Fermi level, inducing a metal-to-semiconductor transition. In contrast, dissociative adsorption results in pronounced n-type doping, thereby elucidating the microscopic origin of the resistivity decrease observed in ZnO-based sensors. Overall, this work highlights the structural advantages of high-index facets and demonstrates for the first time the superior formaldehyde adsorption capability of the ZnO $\left[20\overline{2}1\right]$ facet, providing robust theoretical guidance for the rational design of next-generation, high-performance gas-sensing materials. Full article

Demand for greener and safer chemistries has driven the innovation of bioinspired and enzyme-mimicking catalysts for selective and efficient oxidation and hydrogenation under mild conditions. Natural catalysts, including peroxidases, oxidases, hydrogenases, oxygenases and dehydrogenases, boast remarkable activity, specificity, stability, selectivity, low energy requirements and atom economy. Disadvantages of enzymes, such as poor thermal stability, a narrow operational range, low recovery yield and the expense of purification, are motivating the discovery and design of enzyme substitutes. Several artificial platforms have appeared recently: nanozymes, artificial metalloenzymes, biomimetic metal Complexes, MOFs, atomic catalysts, bioinorganic hybrid systems, among others. These systems aim to replicate key structural and mechanistic features of enzymes while providing greater operational stability, recyclability, and scalability. Recent work has demonstrated the benefit of enzyme mimics in increasing eco-sustainability in reactions such as alcohol oxidation, selective alkane oxidation, waste degradation, catalytic photooxygen activation and biomass waste conversion. Similarly, biomimetic hydrogenation catalysts have shown outstanding activity in asymmetrically hydrogenating chemicals, reducing CO₂ into chemicals, hydrogenation by hydrogen transfer and creating hydrogen through water. Through control of active sites, second coordination sites, defects and electrons/protons in the system, significant gains have been seen in reaction selectivity and frequency of turning over substrate into product. Nanozymes, biohybrid catalysis and artificial catalysts guided by deep learning are further broadening the applications of biomimetic catalysis in oxidation and hydrogenation. The article review aims to provide a summary of the most current progress with bioinspired and enzyme-mimicking catalysts, focusing on catalytic mechanisms, how to design such catalysts, how green chemistry benefits from their development and where further application is likely in the coming years. Full article

Brittle geomaterials such as coal and rock are prone to unstable failure under high stress and dynamic disturbances, where rapid release of stored elastic strain energy can trigger dynamic disasters. Polyurea, a high-strength and high-ductility elastomer, can form a continuous flexible coating on the surface of coal/rock to regulate their deformation–fracture behavior. Here, uniaxial compression tests were performed on coal specimens coated with polyurea layers of different thicknesses (0–1.25 mm). Acoustic emission (AE) and digital image correlation (DIC) were jointly employed to characterize macroscopic deformation, microcrack evolution, fracture-mode transition, and energy partitioning. The results show that polyurea provides passive lateral confinement that suppresses lateral expansion and shifts macroscopic failure from brittle splitting to progressive ductile damage. AE-based AF–RA analysis indicates that thicker coatings increase the normal stress and shear resistance along potential fracture planes, promoting a microfracture transition from shear-dominated to tension-dominated cracking. Energy analysis demonstrates that the coating enhances pre-peak energy dissipation via coordinated deformation with the coal, while thicker coatings (≥1.00 mm) exhibit pronounced post-peak elastic tensile deformation to absorb and buffer fracture-released energy, impeding the instantaneous energy release typical of bare coal. Moreover, the elastic energy index shows that polyurea markedly reduces impact tendency, with an appropriate thickness stabilizing specimens from strong to weak/non-impact propensity. These findings clarify the coupled confinement–fracture–energy regulation mechanisms of polyurea coatings and provide quantitative guidance for coating-thickness design to mitigate dynamic failure hazards in brittle materials. Full article

Despite the large amount of successful existing methods and frameworks for planning sets of multiple unmanned aerial systems (UASs), there is still a lack of coordination frameworks that are capable of coping with real-world operational conditions. This paper presents U-Plan, an integrated management framework for the coordination of multi-UAS missions. U-Plan is designed to plan, schedule, monitor, and replan a heterogeneous set of UASs to complete point of interest (PoI) visiting missions while ensuring that all the generated trajectories are safe, feasible, and compliant with the required PoIs’ arrival times, UAS kinematics and energy constraints, and the existing 3D no-fly zones (NFZs). U-Plan is designed as a practical tool for strongly dynamic missions and is built upon three core components: (1) an NFZ-aware route computation method that explicitly accounts for NFZs prior to vehicle routing problem (VRP) optimization, resulting in shorter NFZ-safe routes; (2) a trajectory smoothing module that ensures the generation of kinematically feasible trajectories for fixed-wing UASs; and (3) a mission supervision module for real-time monitoring and replanning in case of changes in the UAS, mission, wind speed, or airspace restrictions. To validate the proposed architecture, we conducted rigorous experiments utilizing the VECTOR-SIL autopilot and Visionair Ground Control Station to realistically replicate the behavior of certified fixed-wing autopilots under various weather conditions using the exact same hardware and flight control software that runs onboard the physical drones. The validation shows U-Plan’s capacity to efficiently satisfy complex mission requirements with strong scalability. Due to its high computational efficiency, U-Plan enables online mission replanning, allowing UAS fleets to seamlessly adapt to changes that are typical of real-world operational scenarios. Full article

Energy communities (ECs) are becoming a key institutional instrument for decentralizing the European energy transition, yet their implementation remains constrained by fragmented legal interpretation, uneven national transposition, and unresolved socio-technical coordination problems. This review synthesizes the peer-reviewed literature, EU primary legal texts, and national legislation to clarify the distinction between Renewable Energy Communities (RECs) and Citizen Energy Communities (CECs), alongside the amendment relationship between the RED II and RED III directives. The analysis demonstrates that the scalability of these initiatives depends less on theoretical legal recognition and more on aligning operational frameworks, including metering, settlement, cybersecurity, and equitable allocation rules. The Romanian case illustrates this challenge clearly: rapid prosumer growth creates valuable distributed generation but also exposes physical grid constraints, asymmetric socio-economic participation capacity, and weak experience with cooperative energy governance. To address these vulnerabilities, this paper contributes a focused analytical framework linking energy justice, peer-to-peer game-theoretic modeling, and the strategic integration of “anchor-prosumers.” The study argues that larger renewable self-consumers can act as stabilizing community anchors when internal energy prices are designed between wholesale export values and retail import prices, thereby improving both producer incentives and consumer affordability. Future research developments, including targeted surveys and longitudinal empirical validations, will sustain this claim and optimize the socio-economic resilience of decentralized energy markets. Full article

Cruise ship fire evacuation is affected not only by fire product spread, but also by how evacuation information is delivered and how passenger flow is organized. However, existing fire evacuation studies have mainly focused on fire products or individual occupant characteristics, while the effects of evacuation organization strategies under dynamic fire conditions, especially in cruise ship environments, remain insufficiently investigated. Therefore, this study designs and compares three evacuation strategies representing different levels of information availability and organizational coordination: a static signage strategy, in which passengers mainly follow predefined evacuation signs; a system warning strategy, in which passengers adjust routes according to threshold-triggered risk information; and a centralized diversion strategy, in which passenger flow is coordinated across zones based on global risk and congestion information. The strategies are evaluated under representative cruise ship fire scenarios. The results show that static signage does not account for the dynamic influence of fire products on the evacuation environment, while system warning strategy provides relatively limited improvement in evacuation performance because of its threshold-triggered mechanism. In contrast, centralized diversion improves evacuation safety by redistributing passenger flow and reducing local congestion, achieving a 98.53% evacuation success rate and reducing the average cumulative congestion time to 4.1159 s in the galley fire scenario. Full article

Carbon aerogels possess continuous three-dimensional conductive networks, hierarchical pore architectures, and tunable surface chemistry. These structural characteristics make them suitable electrode materials for alkali-metal-ion batteries. This review examines the controlled synthesis and heteroatom doping of carbon aerogels. The discussion links framework construction, electronic-structure modulation, and storage mechanism matching with their electrochemical behavior. The rational design of carbon aerogels should move beyond the simple pursuit of high specific surface area or high dopant content. Effective electrodes require the coordinated regulation of pore architecture, conductive continuity, heteroatom-doped sites, and ion-storage pathways. The current application status of carbon aerogels in alkali-metal-ion batteries is also analyzed from an industrial perspective. A mechanism-oriented and application-oriented framework is therefore required to translate carbon aerogel-based electrodes from structural optimization to a practical battery. Full article

The rapid expansion of the global gaming industry has intensified concern about Gaming Disorder (GD), creating a need for strategies that protect player well-being while remaining feasible for industry implementation. Using a PRISMA 2020-guided systematic review method, the study synthesised evidence from 40 peer-reviewed studies published between 2015 and 2025 on responsible gaming interventions implemented by game developers, platform operators, and digital storefronts. The review identified four main strategy clusters: structural design features, behavioural tools, monetisation controls, and regulatory measures. Across the literature, some interventions, including break reminders, spending controls, adaptive warnings, and design modifications that interrupt continuous play, showed potential to reduce excessive gaming and support self-regulation. However, effectiveness was often constrained by fragmented implementation, inconsistent evaluation, jurisdictional differences, and limited evidence from low- and middle-income settings. Digital storefronts were notably underexamined despite their growing influence on access and monetisation. The findings suggest that isolated technical or behavioural measures are unlikely to be sufficient on their own. In response, this review proposes the Integrated Responsible Gaming Strategy Framework (IRGSF), which brings together ethical design, behavioural support, socio-technical coordination, and stakeholder governance to guide more coherent and sustainable approaches to GD prevention. Full article

To address the parameter coordination and system integration issues in nonlinear discrete-time cascade control systems, this paper proposes, for the first time, a novel collaborative PI-P controller design method. First, an augmented state-space model for the PI-P controller is introduced, where the integral term is embedded into the state variables. Then, stability conditions are derived using Lyapunov stability theory, which are formulated as linear matrix inequality (LMI) constraints, enabling the simultaneous design of both primary and secondary controllers. The method is validated through simulations on a steam temperature control system. The results demonstrate that the proposed method outperforms conventional methods, achieving a faster response, reduced overshoot, and enhanced robustness. Moreover, the proposed method shows strong disturbance rejection capability and improved overall dynamic performance, further confirming its effectiveness and potential for application in nonlinear discrete-time cascade control systems. Full article

The study presents the results of research aimed at developing digital models for determining the operating parameters of railway power supply systems equipped with distributed generation plants based on renewable energy sources (RESs). RESs can be used in railway transport to increase the reliability of power supply to facilities located in areas with insufficiently developed power grids. This primarily applies to consumers, for whom a power failure can lead to significant damage, accidents, and a threat to human life. RES can serve as independent power sources for special-group consumers and can increase energy conversion efficiency. Furthermore, large-scale implementation of renewable energy sources can significantly reduce energy supply costs and improve power quality. The study employs phase-coordinate modeling, which is characterized by the following features: a systems approach, which implies determining operating conditions while considering the properties and characteristics of complex traction and supply networks; versatility, which enables modeling of power supply systems of various structures and designs; and comprehensiveness, which involves calculating normal, emergency, and special operating parameters—crucial for scenarios such as ice melting on catenary wires. The modeling results obtained using the Fazonord AC-DC software (ver. 5.3.5.2) show that RES-based distributed generation plants provide a variety of beneficial effects: reduction in electricity consumption from power system networks; decrease in voltage unbalance and harmonic distortion on the busbars of regional windings of traction substations; and stabilization of voltage levels on current collectors of electric locomotives. Full article

Calcium-induced polysaccharide hydrogels have attracted growing interest in food science because of their mild gelation conditions, tunable structures, and compatibility with food-grade formulation. This review focuses on edible Ca²⁺-mediated polysaccharide hydrogels and related composite networks, focusing on alginate, low-methoxyl pectin, gellan gum, and carrageenan. Rather than treating all calcium-containing polysaccharide materials as well-defined complexes, we distinguish direct coordination, ionic bridging, charge screening, helix stabilization, and composite-assisted network regulation. Current evidence indicates that Ca²⁺-mediated assembly is governed by polysaccharide fine structure, calcium-release behavior, pH, ionic strength, and processing conditions, thereby determining crosslinking density, digestibility gel strength, water distribution, rheological properties, release behavior, and texture-related functionality. For texture-modified foods for older adults, these hydrogels may provide a useful material basis for designing swallowing-friendly matrices, sustained nutrient-delivery systems, and soft composite foods. However, available evidence is still largely derived from model gels, in vitro characterization, and static digestion models, while validation in real food matrices, dynamic gastrointestinal conditions, oral processing, sensory acceptance, and older-adult populations remains limited. Future studies should establish structure–function–population evidence chains linking molecular assembly to reliable geriatric food performance. Full article

Preserving cultural heritage sites requires an interoperable digital framework capable of integrating heterogeneous spatial data and supporting immersive interaction for inspection and management. This study investigates the integration of multiple heritage data representations—including IFC-based Heritage Building Information Modeling (HBIM), terrestrial and UAV LiDAR point clouds, and 3D Gaussian Splatting reconstructions—into a unified digital management environment for the East Hall (Aula Timur) heritage site within the Bandung Institute of Technology (ITB) campus. A semantic–spatial interoperability workflow is proposed to harmonize BIM, point cloud, and landscape-scale data within a common georeferenced context, supported by a CityGML-based base map of the surrounding site. An immersive virtual environment was implemented using a head-mounted display to enable walkthrough-based inspection and damage annotation. All datasets were georeferenced within a unified coordinate system, allowing spatial registration between digital objects and the physical heritage site. The results demonstrate that multi-source heritage datasets can be integrated with high geometric accuracy, achieving TLS registration errors of approximately 2 mm and georeferencing residuals within 11.1 cm (horizontal) and 0.95 cm (vertical), while preserving semantic information and ensuring spatial coherence across HBIM, GIS, and immersive environments. The system is implemented in VR, with an architecture designed to support future MR-based on-site annotation and visualization. The proposed framework establishes a foundation for future heritage digital twin deployments and supports informed conservation decisions. Full article

Against the coordinated advancement of building a maritime power, high-quality development of marine tourism and ecological civilization construction, realizing positive interaction between marine resource conservation and tourism industrial development has emerged as a pivotal issue for high-quality growth in coastal regions. Taking 11 coastal provincial-level administrative regions in China spanning 2008 to 2024 as the research sample, this paper first establishes an evaluation indicator system covering marine resources and the tourism industry. It further adopts an integrated empirical framework encompassing the coupling coordination degree model, spatial Markov chain model, obstacle degree model, fixed-effect model and geographically and temporally weighted regression (GTWR) model to systematically unpack the spatiotemporal differentiation characteristics, internal restrictive obstacle factors and external driving determinants of the two-system coupling coordination. On this basis, a marine resource compensation mechanism for tourist destinations is formulated. Empirical results demonstrate four core findings: (1) In terms of temporal evolution, the overall coupling coordination level keeps rising and goes through three phases: initial development, rapid improvement and post-shock recovery. After a short-term decline triggered by the pandemic, the index rebounds markedly after 2023, showing that the two systems can recover and stabilize. (2) In terms of spatial layout, a persistent stratified spatial pattern featuring “higher coordination in southern coast versus lower coordination in northern coast with three-tier hierarchical differentiation” is identified; high-level neighboring regions exert prominent positive spatial spillover effects, whereas low-level adjacent areas are prone to fall into development lock-in traps. (3) For internal constraint obstacles, the marine resource subsystem is persistently restricted by resource exploitation limits and coastal spatial scarcity, while the dominant bottleneck of the tourism industrial subsystem shifts from insufficient market scale to inadequate human capital supply. (4) Regarding external driving forces, the proportion of tertiary industry and the digital infrastructure constitute core driving contributors, whereas marketization progress and opening-up degree act as primary restrictive factors, with pronounced spatial heterogeneity existing across all driving indicators. Finally, in line with the quasi-public-good attribute and ecological externality of marine resources, this study constructs a differentiated and synergistic marine resource compensation mechanism from three dimensions: stakeholder identification, compensation implementation pathways and institutional guarantee systems. The proposed framework provides theoretical references and practical policy options to facilitate high-level coupling and coordinated development between marine resource preservation and the coastal tourism industry. The marginal contribution of this research lies in integrating coupling coordination measurement, obstacle factor diagnosis, driving mechanism identification and compensation mechanism design into an integrated analytical framework, which delivers theoretical foundations and operable policy solutions for coastal marine resource protection, tourism industrial upgrading and differentiated compensation system construction. Full article

Achieving long-term urban sustainability requires energy subsidy frameworks that evolve with changing technological conditions and system needs. Renewable energy subsidy regimes have played a decisive role in accelerating building-integrated solar photovoltaic deployment, but many were designed for an earlier expansion phase focused mainly on increasing generation capacity and reducing technology costs. As electricity systems move toward an integration phase characterized by higher renewable penetration, flexibility constraints, storage needs, and cross-sectoral coordination, generation-centric subsidy architectures may become increasingly misaligned with system-level requirements. This study conducts a structured comparative analysis of subsidy design in Hong Kong, Chinese Mainland, and Australia, examining legal foundations, target scope, incentive structures, and technology orientation across expansion and integration phases. Despite major differences in governance systems and market organization, the findings show a common pattern: Principal subsidy instruments remain anchored in output-based performance metrics, while storage, hydrogen, and hybrid technologies are generally supported through supplementary rather than core mechanisms. The study argues that this policy layering may limit technological inclusiveness and reduce alignment between subsidy design and evolving system needs. It therefore proposes a system-value-oriented comparative framework for subsidy redesign that recognizes flexibility, reliability, and integrated clean energy performance in the built environment. Full article