Search Results (18)

Transpiration cooling that utilizes the phase change of a liquid coolant is recognized as an effective thermal protection technique for extreme environments. However, the introduction of phase change within the porous structure brings about challenges, such as vapor blockage, pressure fluctuations, and temperature inversion, which critically influence system reliability. This study conducts numerical analyses of coupled processes of heat transfer, flow, and phase change in transpiration cooling using a Two-Phase Mixture Model. The simulation incorporates a Local Thermal Non-Equilibrium approach to capture the distinct temperature fields of the solid and fluid phases, enabling accurate prediction of the thermal response within two-phase and single-phase regions. The results reveal that under low heat flux, dominant capillary action suppresses dry-out and expands the two-phase region. Conversely, high heat flux causes vaporization to overwhelm the capillary supply, forming a superheated vapor layer and constricting the two-phase zone. The analysis also explains a paradoxical pressure drop, where an initial increase in flow rate reduces pressure loss by suppressing the high-viscosity vapor phase. Furthermore, a local temperature inversion, where the fluid becomes hotter than the solid matrix, is identified and attributed to vapor counterflow and its subsequent condensation. Full article

The oxidation of filter cake particles (FCPs) is beneficial for preventing filter media blockage during the hot filtration of raw biomass gasification gas. The influence of particle characteristics on hot oxidative filtration was investigated through characterization, kinetic study, and lab-scale experiments. The characterization results indicated that FCPs are particles with C content of more than 60%, containing –CH_n and C=O functional groups. After pyrolysis treatment, these functional groups gradually diminished, while the degree of atomic nucleus condensation increased. The oxidation kinetic calculation indicated that the oxidation activation energy of particles ranged from 55.24 to 117.84 kJ/mol, and higher treatment temperatures could reduce the particle reactivity. The hot oxidative filtration at 400 °C revealed that the primary reaction was C + O₂ = CO₂ rather than combustion or oxidation of combustive gas components. Furthermore, it was observed that the active minerals on the surface of carbon particles would promote the catalytic oxidation of CO. Experimental findings confirmed that the untreated FCPs containing abundant –CH_n functional groups could effectively react with low-concentration O₂. However, the presence of active minerals on the particle surface likely promoted CO oxidation within the FCP layer, thereby reducing the calorific value of the product gas. Full article

Carbon capture, utilization and storage are facilitated through carbon dioxide (CO₂) transport. Pipe transportation is the main method for transporting CO₂. However, hydrate blockages reduce transport efficiency in the pipelines, and the throttling devices are the main location of hydrate blockages. In this paper, the mechanism of hydrate formation in the throttling of CO₂-containing trace moisture was investigated. The throttling device in a pipe was mimicked using a cylindrical orifice plate. The work also studied the effects of moisture content, upstream pressure and upstream temperature on hydrate formation. The results indicate that the Joule–Thomson cooling effect is a key contributor, and promotes the condensation of trace moisture, resulting in the free water necessary for hydrate nucleation. Under the effect of gas flow back-mixing, it is easy for the hydrate to adhere to the inner surface of the pipe behind the orifice plate. When the moisture content in the gas increases from 123 μmol/mol to 1024 μmol/mol, the hydrate induction time decreases from infinity to 792 s. However, the moisture content has no effect on the adhesion strength of the hydrate to the inner surface of the pipe. When the initial upstream pressure increases from 2.0 MPa to 3.5 MPa, the hydrate induction time decreases from infinity to 306 s. When the upstream temperature decreases from 291.15 K to 285.15 K, the hydrate induction time decreases from infinity to 330 s. With the decrease in the initial upstream temperature, the adhesion of hydrate particles to the inner surface of the pipe is promoted. This study provides experimental evidence for the characteristics of hydrate formation in the process of CO₂ throttling. Full article

Hydrocarbon fields that contain non-associated gas, such as gas condensate, are highly valuable in terms of production. They yield significant amounts of condensate alongside the gas, but their unique behavior presents challenges. These reservoirs experience constant changes in composition and phases during production, which can lead to condensate blockage near wells. This blockage forms condensate bridges that hinder flow and potentially decrease gas production. To address these challenges, engineers rely on numerical simulation as a crucial tool to determine the most effective project management strategy for producing these reservoirs. In particular, relative permeability curves are used in these simulations to represent the physical phenomenon of interest. However, the representativeness of these curves in industry laboratory tests has limitations. To obtain more accurate inputs, simulations at the pore network level are performed. These simulations incorporate models that consider alterations in interfacial tension and flow velocity throughout the reservoir. The validation process involves reproducing a pore network flow simulation as close as possible to a commercial finite difference simulation. A scale-up methodology is then proposed, utilizing an optimization process to ensure fidelity to the original relative permeability curve at a microporous scale. This curve is obtained by simulating the condensation process in the reservoir phenomenologically, using a model that captures the dependence on velocity. To evaluate the effectiveness of the proposed methodology, three relative permeability curves are compared based on field-scale productivities and the evolution of condensate saturation near the wells. The results demonstrate that the methodology accurately captures the influence of condensation on well productivity compared to the relative permeability curve generated from laboratory tests, which assumes greater condensate mobility. This highlights the importance of incorporating more realistic inputs into numerical simulations to improve decision-making in project management strategies for reservoir development. Full article

In recent years, the problematic circumstances of the constant cropping problem in facility crops have become increasingly serious. Compared to chemical disinfection, soil steam disinfestation offers the benefits of environmental protection and being pollution-free, which can effectively reduce the problem of constant cropping in crops. However, during the steam disinfection procedure, a large quantity of liquid water is formed due to the condensation of high-temperature steam, which causes soil pore blockage, seriously affecting the mass and heat transfer efficacy of steam and, thus, affecting the disinfection efficiency. Therefore, to solve this problem, this paper proposes the use of hot air dehumidification to remove excess water from soil pores and achieve the goal of dredging the pores. However, further exploration is needed on how to efficiently remove excess water from different pore structures through hot air applications. Therefore, this paper first used CFD simulation technology to simulate and analyze the hot air flow field, mass, and heat transfer in soil aggregates of different sizes (<2 mm to >8 mm). Then, based on the soil hot air heating experimental platform, research was conducted on the mass and heat transfer mechanism of hot air under diverse soil pore conditions. The results show that as the soil particle size increases from <2 mm to >8 mm, the number of soil macropores also increases, which makes the soil prone to the formation of macropore thermal currents, and the efficiency of hot air heating for dehumidification first increases and then decreases. Among them, the 4–6 mm treatment has the best dehumidification effect through hot air heating, with a deep soil temperature of up to 90 °C and a water content reduction of 6%. The 4–6 mm treatment has a high-temperature heating and dehumidification area of 15–20 cm deep. The above results lay the theoretical foundations for the parameters of hot air heating and dehumidification operations, as well as the placement of the hot air pipe. This paper aims to combine hot air dehumidification technology, for the removal of excess water from soil, and dredging soil pores, ultimately achieving the goal of improving soil steam disinfection efficiency. Full article

Fog conditions at the offshore wind farm Horns Rev 2 were photographed on 16 April 2018. In this study, we present the results of an analysis of the meteorological conditions on the day of the photographs. The aim of the study was to examine satellite images, meteorological observations, wind turbine data, lidar data, reanalysis data, and wake and blockage model results to assess whether wind farm blockage was a likely cause for the formation of fog upstream of the wind farm. The analysis indicated the advection of warm and moist air mass from the southwest over a cool ocean, causing cold sea fog. Wind speeds at hub height were slightly above cut-in, and there was a strong veer in the shallow stable boundary layer. The most important finding is that the wake and blockage model indicated stagnant air mass arcs to the south and west of the wind farm. In the photographs, sea fog is visible in approximately the same area. Therefore, it is likely that the reduced wind triggered the sea fog condensation due to blockage in this area. A discrepancy between the blockage model and sea fog in the photographs appears in the southwest direction. Slightly higher winds might have occurred locally in a southwesterly direction, which may have dissolved sea fog. The wake model predicted long and narrow wind turbine wakes similar to those observed in the photographs. The novelty of the study is new evidence of wind farm blockage. It fills the gap in knowledge about flow in wind farms. Implications for future research include advanced modeling of flow phenomena near large offshore wind farms relevant to wind farm operators. Full article

At present, partial oxidation is applied in the filtration processes of biomass hot gas to aid in solving the blockage problems caused by tar and dust condensates. However, in the resulting high-temperature and oxygen-limited environment, the risk of tar polymerization forming soot is created during the purification processes. Thus, this work established a hardware-in-the-loop simulation model using the Lagrangian method coupled with the chemical reactions on the particle surface. The model was then used to simulate the entire evolution process of soot, including its formation, growth, and interception. The simulation results confirmed that under partial oxidation conditions, the increase in tar’s conversion rate promotes the formation of soot. Further analysis indicated that the high-temperature field formed as a result of oxidation and the increase in the naphthalene/oxygen ratio are the main reasons for the soot formation. On the other hand, the growth process of soot was inhibited by partial oxidation, which is mainly reflected in the relatively smaller increasing magnitude of soot particle mass and the decrease in the soot formation rate. Although the formation and growth of biomass soot cannot be completely avoided, the growth process is beneficial to interception and the soot escape rate can be minimized by varying the premixed oxygen content. On this basis, the potential of the partial oxidation-assisted hot gas filtration method can be further investigated and analyzed. Full article

The commercial proton exchange membrane fuel cell (PEMFC) system needs to be equipped with the capacity to survive a harsh environment, including sub-freezing temperatures. The cold start of PEMFC brings about great technical challenges, mainly due to the ice blockage in the components, which seriously hinders the multi physical transmission process. A multiscale, two-dimensional model was established to explore the gas purging in PEMFC under different electrochemical reaction intensities. The results indicate that the optimal case is obtained by B_3-1 with a power density of 0.796 W cm⁻², and the power density increases first and then decreases, followed by stoichiometric flow ratio (ξ) changes. It is worth noting that the water mole fraction in the PEM is closely related to the water concentration gradient. However, the differences in the initial water distribution in porous media have little bearing on the condensed water in the gas channel, and the liquid water in the gas diffusion layer (GDL) is preferably carried away ahead of other porous parts. The results also show that the increase in the purge speed and temperature can remove the excess water on GDL and the catalytic layer in a short time. For a nitrogen-based purge, the operating condition in case B_3-1 is shown as the best strategy based on the output performance and economic analysis during the shutdown and purge process. Full article

In deep coal mining, grouting reinforcement and water blockage are the most effective means for reinforcing the rock mass of extremely broken coal. However, traditional cement grouting materials are not suitable for use in complex strata because of their insufficient early mechanical strength and slow setting time. This study innovatively proposes using alkali-activated grouting material to compensate for the shortcomings of traditional grouting materials and strengthen the reinforcement of extremely unstable broken coal and rock mass. The alkali-activated grouting material was prepared using slag as raw material combined with sodium hydroxide and liquid sodium silicate activation. The compressive strength of specimens cured for 1 d, 3 d, and 28 d was regularly measured and the condensation behavior was analyzed. Using X-ray diffraction and scanning electron microscopy, formation behavior of mineral crystals and microstructure characteristics were further analyzed. The results showed that alkali-activated slag grouting material features prompt and high strength and offers the advantages of rapid setting and adjustable setting time. With an increase in sodium hydroxide content, the compressive strength first increased (maximum increase was 21.1%) and then decreased, while the setting time continued to shorten. With an increase in liquid sodium silicate level, the compressive strength increased significantly (and remained unchanged, maximum increase was 35.9%), while the setting time decreased significantly (and remained unchanged). X-ray diffraction analysis identified the formation of aluminosilicate minerals as the main reason for the excellent mechanical properties and accelerated coagulation rate. Full article

Condensate oil is increasingly valued as the high-quality conventional hydrocarbon resources generally decline. The efficient development of condensate oil, however, has always been a world problem; massive condensate oil will be retained in reservoirs in case of improper exploitation process, resulting in a significant resource waste and economic loss. One of the problems closely related to enhancing condensate oil recovery is wax precipitation and deposition in wellbore. Therefore, it is vital to investigate the characterization methods for the wax precipitation and deposition behavior in wellbores. The current status of research on modelling characterization methods, experimental characterization methods and molecular dynamics representation of wax precipitation and deposition behavior is reviewed in this paper; the applicability and limitation of modeling and experiment studies for characterizing wax precipitation and deposition of condensate oil in the wellbore are critically summarized and discussed. Moreover, the molecular dynamics simulation technique characterizes wax precipitation and deposition behavior from the micro scale, which makes up for the deficiencies of macroscopic experiment, enriches the investigation of wax precipitation and deposition, and provides important guidance and reference value for the development of unconventional hydrocarbon exploitation processes. Full article

Although cigarette smoking has been postulated to be a potential risk factor for Alzheimer’s disease (AD), the toxic mechanism is still unclear. Additionally, astrocytes have been identified as a potential target, given they play multiple roles in maintaining normal brain function. In this study, we explored the toxic mechanism of whole cigarette smoke condensates (WCSC) using murine astrocytes. Cell proliferation, the percentage of cells in the G2/M phase, and LDH concentrations in the cell supernatants were all reduced in WCSC-treated cells. In addition, oxidative stress was induced, together with shortening of processes, structural damage of organelles, disturbances in mitochondrial function, blockage of autophagic signals, accumulation of amyloid β precursor protein, and loss of chemotactic functions. Based on these results, we hypothesize that dysfunction of astrocytes may contribute to the occurrence of cigarette-smoking-induced AD. Full article

Amongst the issues associated with the commercialization of biomass gasification, the presence of tars has been one of the most difficult aspects to address. Tars are an impurity generated from the gasifier and upon their condensation cause problems in downstream equipment including plugging, blockages, corrosion, and major catalyst deactivation. These problems lead to losses of efficiency as well as potential maintenance issues resulting from damaged processing units. Therefore, the removal of tars is necessary in order for the effective operation of a biomass gasification facility for the production of high-value fuel gas. The catalytic activity of montmorillonite and montmorillonite-supported nickel as tar removal catalysts will be investigated in this study. Ni-montmorillonite catalyst was prepared, characterized, and tested in a laboratory-scale reactor for its efficiency in reforming tars using naphthalene as a tar model compound. Efficacy of montmorillonite-supported nickel catalyst was tested as a function of nickel content, reaction temperature, steam-to-carbon ratio, and naphthalene loading. The results demonstrate that montmorillonite is catalytically active in removing naphthalene. Ni-montmorillonite had high activity towards naphthalene removal via steam reforming, with removal efficiencies greater than 99%. The activation energy was calculated for Ni-montmorillonite assuming first-order kinetics and was found to be 84.5 kJ/mole in accordance with the literature. Long-term activity tests were also conducted and showed that the catalyst was active with naphthalene removal efficiencies greater than 95% maintained over a 97-h test period. A little loss of activity was observed with a removal decrease from 97% to 95%. To investigate the decrease in catalytic activity, characterization of fresh and used catalyst samples was performed using thermogravimetric analysis, transmission electron microscopy, X-ray diffraction, and surface area analysis. The loss in activity was attributed to a decrease in catalyst surface area caused by nickel sintering and coke formation. Full article

Prediction of the timing and location of condensate build-up around the wellbore in gas condensate reservoirs is essential for the selection of appropriate methods for condensate recovery from these challenging reservoirs. The present work focuses on the use of a novel phase change tracking approach in monitoring the formation of condensate blockage in a gas condensate reservoir. The procedure entails the simulation of tight, low and high permeability reservoirs using global and local grid analysis in determining the size and timing of three common regions (Region 1, near wellbore; Region 2, condensate build-up; and Region 3, single-phase gas) associated with single and two-phase gas and immobile and mobile gas condensate. The results show that permeability has a significant influence on the occurrence of the three regions around the well, which in turn affects the productivity of the gas condensate reservoir studied. Predictions of the timing and location of condensate in reservoirs with different permeability levels of 1 mD to 100 mD indicate that local damage enhances condensate formation by 60% and shortens the duration of the immobile phase by 45%. Meanwhile, the global change in permeability increases condensate formation by 80% and reduces the presence of the immobile phase by 60%. Finally, this predictive approach can help in mitigating condensate blockage around the wellbore during production. Full article

Liquid banking in the near wellbore region can lessen significantly the production from gas reservoirs. As reservoir rocks commonly consist of liquid-wet porous media, they are prone to liquid trapping following well liquid invasion and/or condensate dropout in gas-condensate systems. For this reason, wettability alteration from liquid to gas-wet has been investigated in the past two decades as a permanent gas flow enhancement solution. Numerous experiments suggest flow improvement for immiscible gas-liquid flow in wettability altered cores. However, due to experimental limitations, few studies evaluate the method’s performance for condensing flows, typical of gas-condensate reservoirs. In this context, we present a compositional pore-network model for gas-condensate flow under variable wetting conditions. Different condensate modes and flow patterns based on experimental observations were implemented in the model so that the effects of wettability on condensing flow were represented. Flow analyses under several thermodynamic conditions and flow rates in a sandstone based network were conducted to determine the parameters affecting condensate blockage mitigation by wettability alteration. Relative permeability curves and impacts factors were calculated for gas flowing velocities between 7.5 and 150 m/day, contact angles between ${45}^{°}$ and ${135}^{°}$, and condensate saturations up to 35%. Significantly different relative permeability curves were obtained for contrasting wettability media and impact factors below one were found at low flowing velocities in preferentially gas-wet cases. Results exhibited similar trends observed in coreflooding experiments and windows of optimal flow enhancement through wettability alteration were identified. Full article

Gas-wetting alteration is a versatile and effective approach for alleviating liquid-blockage that occurs when the wellbore pressure of a gas-condensate reservoir drops below the dew point. Fluorochemicals are of growing interest in gas-wetting alteration because of their high density of fluorine groups and thermal stability, which can change the reservoir wettability into more favorable conditions for liquids. This review aims to integrate the overlapping research between the current knowledge in organic chemistry and enhanced oil and gas recovery. The difference between wettability alteration and gas-wetting alteration is illustrated, and the methods used to evaluate gas-wetting are summarized. Recent advances in the applications of fluorochemicals for gas-wetting alteration are highlighted. The mechanisms of self-assembling adsorption layers formed by fluorochemicals with different surface morphologies are also reviewed. The factors that affect the gas-wetting performance of fluorochemicals are summarized. Meanwhile, the impacts of gas-wetting alteration on the migration of fluids in the pore throat are elaborated. Furthermore, the Wenzel and Cassie-Baxter theories are often used to describe the wettability model, but they are limited in reflecting the wetting regime of the gas-wetting surface; therefore, a wettability model for gas-wetting is discussed. Considering the promising prospects of gas-wetting alteration, this study is expected to provide insights into the relevance of gas-wetting, surface morphology and fluorochemicals, further exploring the mechanism of flow efficiency improvement of fluids in unconventional oil and gas reservoirs. Full article