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20 pages, 3807 KB  
Article
Analysis of Multi-Environment-Driven Variations in Net Photosynthetic Rate and Predictive Model Development for Tomatoes During Early Flowering and Fruit Development Stages in Winter Solar Greenhouses
by Yongsan Cheng, Nianhua Li, Zongyao Li, Aiwu Zhou, Bin Li and Yanxiu Miao
Horticulturae 2025, 11(11), 1367; https://doi.org/10.3390/horticulturae11111367 - 13 Nov 2025
Cited by 1 | Viewed by 669
Abstract
In protected horticulture, precise regulation of light intensity [i.e., photosynthetic photon flux density (PPFD)], ambient temperature, and ambient CO2 concentration is crucial for optimizing crop photosynthesis. Tomatoes, a key greenhouse crop, exhibit temporal variations in photosynthetic efficiency across their growth cycle. However, [...] Read more.
In protected horticulture, precise regulation of light intensity [i.e., photosynthetic photon flux density (PPFD)], ambient temperature, and ambient CO2 concentration is crucial for optimizing crop photosynthesis. Tomatoes, a key greenhouse crop, exhibit temporal variations in photosynthetic efficiency across their growth cycle. However, the differences in the dynamic responses of net photosynthetic rate (Pn) of tomatoes to environmental factors during flowering and fruit development stages in winter solar greenhouses, as well as how to utilize these differences respectively to achieve more precise on-demand environmental regulation, still require in-depth exploration. Based on measured data, this study employed decision tree (DT), random forest (RF), and XGBoost (XGB) models to predict net photosynthetic rate (Pn) across two growth periods. The results demonstrated that, in comparison with the early flowering stage, the photosynthetic potential of tomato leaves increased during the fruit development stage, with the Pn peak increasing by 11.5%. The proportion of observed data points in the high Pn range (25–35 μmol m−2 s−1) at the fruit development stage was 14.2%, which was significantly higher than the 6.7% observed at the early flowering stage. Meanwhile, the sensitivity of tomato leaves to changes in environmental factors also increased during the fruit development stage. On the independent test set, the XGB model exhibited the best predictive performance: the root mean square error (RMSE) for the early flowering stage model was 0.47 μmol m−2 s−1, with a mean absolute error (MAE) of 0.36 μmol m−2 s−1; for the fruit development stage, the RMSE was 0.60 μmol m−2 s−1, and the MAE was 0.41 μmol m−2 s−1. This study demonstrated the variation patterns of photosynthetic characteristics of tomatoes at different growth stages in response to environment factors. The established XGB model and the generated three-dimensional visualized Pn prediction surfaces provide a quantitative basis and decision-support tools to facilitate precise environmental management strategies for the coordinated dynamic regulation of light, temperature, and CO2 in solar greenhouses. Full article
(This article belongs to the Special Issue Artificial Intelligence in Horticulture Production)
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32 pages, 9121 KB  
Review
Generative Design of Concentrated Solar Thermal Tower Receivers—State of the Art and Trends
by Jorge Moreno García-Moreno and Kypros Milidonis
Energies 2025, 18(22), 5890; https://doi.org/10.3390/en18225890 - 8 Nov 2025
Viewed by 660
Abstract
The rapid advances in artificial intelligence (AI) and high-performance computing (HPC) are transforming the landscape of engineering design, and the concentrated solar power (CSP) tower sector is no exception. As these technologies increasingly penetrate the energy domain, they bring new capabilities for addressing [...] Read more.
The rapid advances in artificial intelligence (AI) and high-performance computing (HPC) are transforming the landscape of engineering design, and the concentrated solar power (CSP) tower sector is no exception. As these technologies increasingly penetrate the energy domain, they bring new capabilities for addressing the complex, multi-variable nature of receiver design and optimisation. This review explores the application of AI-driven generative design techniques in the context of CSP tower receivers, with a particular focus on the use of metaheuristic algorithms and machine learning models. A structured classification is presented, highlighting the most commonly employed methods, such as Genetic Algorithms (GAs), Particle Swarm Optimisation (PSO), and Artificial Neural Networks (ANNs), and mapping them to specific receiver types: cavity, external, and volumetric. GAs are found to dominate multi-objective optimisation tasks, especially those involving trade-offs between thermal efficiency and heat flux uniformity, while ANNs offer strong potential as surrogate models for accelerating design iterations. The review also identifies existing gaps in the literature and outlines future opportunities, including the integration of high-fidelity simulations and experimental validation into AI design workflows. These insights demonstrate the growing relevance and impact of AI in advancing the next generation of high-performance CSP receiver systems. Full article
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18 pages, 4181 KB  
Article
Numerical Investigation of a New Segmented Annular Ring Tube for Heat Transfer Enhancement in Solar Water Heating Systems
by Mohamed Said Kahaleras, Sabbah Ataya, Lina Chouichi, Yacine Karmi, Omar Reffas, Issam Bousba, Abdessalam Otmani and Haithem Boumediri
Energies 2025, 18(21), 5831; https://doi.org/10.3390/en18215831 - 5 Nov 2025
Viewed by 440
Abstract
This study presents a numerical investigation of a parabolic trough absorber tube equipped with a novel Angularly Segmented Ring Turbulator (ASRT), designed to enhance heat transfer through periodic flow disturbance and improved wall–fluid interaction. The proposed ASRT geometry consists of segmented annular rings [...] Read more.
This study presents a numerical investigation of a parabolic trough absorber tube equipped with a novel Angularly Segmented Ring Turbulator (ASRT), designed to enhance heat transfer through periodic flow disturbance and improved wall–fluid interaction. The proposed ASRT geometry consists of segmented annular rings arranged along the tube length, characterized by two key parameters: the number of angular segments per ring (Nr = 4, 6, 8) and the angular spacing of each segment (α = 20° and 40°). Three dimensional simulations were performed using the finite volume method under turbulent flow conditions, with Reynolds numbers ranging from 3300 to 11,000. A non-uniform solar heat flux, obtained via Monte Carlo Ray Tracing (MCRT), was applied as a boundary condition at the outer wall to replicate realistic solar concentration. The results reveal that the ASRT significantly improves convective heat transfer, with the Nusselt number ratio Nu/Nus reaching up to 3.7 for α = 20° and Nr = 8. This enhancement is accompanied by a moderate rise in the friction factor ratio f/fs, reaching approximately 7.5 at Re = 3300, indicating efficient turbulence promotion with acceptable hydraulic penalties. The Performance Evaluation Criterion (PEC) ranges from 1.7 to 1.9, confirming the superiority of ASRT over the smooth tube. Full article
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48 pages, 5238 KB  
Article
Chemodynamics of Mercury (Hg) in a Southern Reservoir Lake (Cane Creek Lake, Cookeville, TN, USA): II—Estimation of the Hg Water/Air Exchange Coefficient Using the Two-Thin Film Model and Field-Measured Data of Hg Water/Air Exchange and Dissolved Gaseous Hg
by Hong Zhang, Lesta S. Fletcher and William C. Crocker
Water 2025, 17(20), 2931; https://doi.org/10.3390/w17202931 - 10 Oct 2025
Viewed by 835
Abstract
This paper reports a novel effort to estimate and evaluate the coefficients of Hg transfer across the water/air interface in lakes such as Cane Creek Lake (CCL, Cookeville, TN, USA). This was accomplished by calculating the coefficients (kw) using the [...] Read more.
This paper reports a novel effort to estimate and evaluate the coefficients of Hg transfer across the water/air interface in lakes such as Cane Creek Lake (CCL, Cookeville, TN, USA). This was accomplished by calculating the coefficients (kw) using the Two-Thin Film (TTF) Model for Hg transfer together with the field-measured data of Hg emission flux (F), dissolved gaseous mercury concentration (DGM), air Hg concentration (Ca), and water temperature for Henry’s coefficient (KH) obtained from a separate field study at the CCL. The daily mean kw values range from 0.045 to 0.21 m h−1, with the min. at 0.0025–0.14 and the max. at 0.079–0.41 m h−1, generally higher for the summer, and from 0.0092 to 0.15, with the min. at 0.0032–0.033 and the max. at 0.017–0.31 m h−1, generally lower for the fall and winter, exhibiting an apparent seasonal trend. The highest kw values occur in August (mean: 0.21, max.: 0.41 m h−1). Our kw results add to and enrich the aquatic interfacial Hg transfer coefficient database and provide an alternative avenue to evaluate and select the coefficients for the TTF Model’s application. The kw results are of value in gaining insights into the Hg transfer actually occurring across the water/air interface under environmental influences (e.g., wind/wave, solar radiation). Our kw results do not show a clear, consistent correlation of kw with wind/wave effect, nor sunlight effect, in spite of some correlations in sporadic cases. Generally, the kw values do not exbibit the trends prescribed by the model sensitivity study. The comparisons of our kw results with those obtained using wind-based transfer models (the Liss/Merlivat Model, the Wanninkhof Model, and the modified linear model) show that they depart from each other. The findings of this study indicate that the TTF Model has limitations and weaknesses. One major assumption of the TTF Model is the equilibrium of the Hg distribution between the air and water films across the water/air interface. The predominant oversaturation of DGM shown by our DGM data evidently challenges this assumption. This study suggests that aquatic interfacial Hg transfer is considerably more complicated, involving a group of factors, more than just wind and wave. Full article
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18 pages, 4806 KB  
Article
Solarized Auger Reactor for Organic Waste Upgrading Through Pyrolysis
by Ernesto Anguera Romero, Nidia Aracely Cisneros-Cárdenas, Arturo Aspiazu-Méndez, Heidi Isabel Villafán Vidales, Pablo Pizarro Medina and Claudio A. Estrada
Processes 2025, 13(10), 3216; https://doi.org/10.3390/pr13103216 - 9 Oct 2025
Cited by 1 | Viewed by 904
Abstract
This study reports the initial thermal and thermochemical performance of a novel solarized Auger-type reactor for Pyrolysis (SARP), specifically developed for the valorization of organic solid waste into solar-derived fuels. A key innovation of this system lies in its integration with a high-flux, [...] Read more.
This study reports the initial thermal and thermochemical performance of a novel solarized Auger-type reactor for Pyrolysis (SARP), specifically developed for the valorization of organic solid waste into solar-derived fuels. A key innovation of this system lies in its integration with a high-flux, point-focus solar concentrator that enables controlled delivery of concentrated solar radiation to drive endothermic processes. At the front of the reactor, the thermal evaluation under solar irradiation shows that surface temperatures reached up to approximately 750 °C on the exterior, while the hottest section of the interior briefly reached approximately 700 °C, in the pyrolysis zone. In contrast, the preheating zone inside the reactor exhibits temperatures ranging from 160 °C to 306 °C, indicating a non-uniform thermal profile for the incoming feedstock. The campaign focused on thermochemical pyrolysis, in which pecan walnut tree pruning residue biomass was processed under controlled semicontinuous operation. Batches of 600 g were pyrolyzed, yielding approximately 390 g of biochar and achieving a peak hydrogen concentration of 14.5% vol in the product gases. These findings demonstrate the reactor’s potential for solar-driven waste-to-fuel conversion. Full article
(This article belongs to the Special Issue Advances in Solid Waste Treatment and Design (2nd Edition))
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16 pages, 530 KB  
Article
Investigating the Cosmic and Solar Drivers of Stratospheric 7Be Variability
by Alessandro Rizzo, Giuseppe Antonacci, Massimo Astarita, Enrico Maria Borra, Luca Ciciani, Nadia di Marco, Giovanna la Notte, Patrizio Ripesi, Luciano Sperandio, Ignazio Vilardi and Francesca Zazzaron
Environments 2025, 12(9), 312; https://doi.org/10.3390/environments12090312 - 4 Sep 2025
Viewed by 1071
Abstract
Space weather exerts a significant influence on the Earth’s atmosphere, driving a variety of physical processes, including the production of cosmogenic radionuclides. Among these, 7Be is a naturally occurring radionuclide formed through spallation reactions induced by cosmic-ray showers interacting with atmospheric constituents, [...] Read more.
Space weather exerts a significant influence on the Earth’s atmosphere, driving a variety of physical processes, including the production of cosmogenic radionuclides. Among these, 7Be is a naturally occurring radionuclide formed through spallation reactions induced by cosmic-ray showers interacting with atmospheric constituents, primarily oxygen and nitrogen. Over long timescales, the atmospheric concentration of 7Be exhibits a direct correlation with the cosmic-ray flux reaching the Earth and an inverse correlation with solar activity, which modulates this flux via variations of the heliosphere. The large availability of 7Be concentration data, resulting from its use as a natural tracer employed in atmospheric transport studies and in monitoring the fallout from radiological incidents such as the Chernobyl disaster, can also be exploited to investigate the impact of space weather conditions on the terrestrial atmosphere and related geophysical processes. The present study analyzes a long-term dataset of monthly 7Be activity concentrations in air samples collected at ground level since 1987 at the ENEA Casaccia Research Center in Rome, Italy. In particular, the linear correlation of this time series with the galactic cosmic ray flux on Earth and solar activity have been investigated. Data from a ground-based neutron monitor and sunspot numbers have been used as proxies for galactic cosmic rays and solar activity, respectively. A centered running-mean low-pass filter was applied to the monthly 7Be time series to extract its low-frequency component associated with cosmic drivers, which is partially hidden by high-frequency modulations induced by atmospheric dynamics. For Solar Cycles 22, 23, 24, and partially 25, the analysis shows that a substantial portion of the relationship between stratospheric 7Be concentrations and cosmic drivers is captured by linear correlation. Within a statistically consistent framework, the evidence supports a correlation between 7Be and cosmic drivers consistent with solar-cycle variability. The 7Be radionuclide can therefore be regarded as a reliable atmospheric tracer of cosmic-ray variability and, indirectly, of solar modulation. Full article
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19 pages, 772 KB  
Article
Earth-Lens Telescope for Distant Axion-like Particle Sources with Stimulated Backward Reflection
by Taiyo Nakamura and Kensuke Homma
Universe 2025, 11(9), 287; https://doi.org/10.3390/universe11090287 - 25 Aug 2025
Viewed by 606
Abstract
We propose a novel telescope concept based on Earth’s gravitational lensing effect, optimized for the detection of distant dark matter sources, particularly axion-like particles (ALPs). When a unidirectional flux of dark matter passes through Earth at sufficiently high velocity, gravitational lensing can concentrate [...] Read more.
We propose a novel telescope concept based on Earth’s gravitational lensing effect, optimized for the detection of distant dark matter sources, particularly axion-like particles (ALPs). When a unidirectional flux of dark matter passes through Earth at sufficiently high velocity, gravitational lensing can concentrate the flux at a distant focal region in space. Our method combines this lensing effect with stimulated backward reflection (SBR), arising from ALP decays that are induced by directing a coherent electromagnetic beam toward the focal point. The aim of this work is to numerically analyze the structure of the focal region and to develop a framework for estimating the sensitivity to ALP–photon coupling via this mechanism. Numerical calculations show that, assuming an average ALP velocity of 520 km/s—as suggested by the observed stellar stream S1—the focal region extends from 9×109 m to 1.4×1010 m, with peak density near 9.6×109 m. For a conservative point-like ALP source located approximately 8 kpc from the solar system, based on the S1 stream, the estimated sensitivity in the eV mass range reaches g/M=O(1022)GeV1. This concept thus opens a path toward a general-purpose, space-based ALP observatory that could, in principle, detect more distant sources—well beyond O(10)kpc—provided that ALP–photon coupling is sufficiently strong, that is, MMPlanck. Full article
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16 pages, 6774 KB  
Article
Optical Fiber Performance for High Solar Flux Measurements in Concentrating Solar Power Applications
by Manuel Jerez, Alejandro Carballar, Ricardo Conceição and Jose González-Aguilar
Sensors 2025, 25(16), 4973; https://doi.org/10.3390/s25164973 - 11 Aug 2025
Cited by 1 | Viewed by 793
Abstract
Extreme operating conditions in solar receivers of concentrated solar thermal power plants, such as high temperatures, intense irradiance, and thermal cycling, pose significant challenges for conventional sensors. Optical fibers offer a promising alternative for flux measurement in such environments, but their long-term performance [...] Read more.
Extreme operating conditions in solar receivers of concentrated solar thermal power plants, such as high temperatures, intense irradiance, and thermal cycling, pose significant challenges for conventional sensors. Optical fibers offer a promising alternative for flux measurement in such environments, but their long-term performance and degradation mechanisms require detailed investigation and characterization. This work presents a proof of concept for high solar flux measurement by using optical fibers as photon-capturing elements and showcases the behavior and damage that these optical fibers undergo when exposed to relevant conditions, including temperatures over 600 °C and flux levels exceeding 400 kW/m2. Three fiber configurations, including polyimide and gold-coated fibers, were tested at a high-flux solar simulator and analyzed via scanning electron microscopy to assess structural integrity and material degradation. Results reveal significant coating deterioration, fiber retraction, and thermal-induced stress effects, which impact measurement reliability. These findings provide essential insights for improving the durability and accuracy of optical fiber-based sensing technologies in concentrating solar energy. Full article
(This article belongs to the Special Issue Optical Fiber Sensors in Radiation Environments: 2nd Edition)
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33 pages, 16026 KB  
Article
Spatiotemporal Analysis of BTEX and PM Using Me-DOAS and GIS in Busan’s Industrial Complexes
by Min-Kyeong Kim, Jaeseok Heo, Joonsig Jung, Dong Keun Lee, Jonghee Jang and Duckshin Park
Toxics 2025, 13(8), 638; https://doi.org/10.3390/toxics13080638 - 29 Jul 2025
Viewed by 1134
Abstract
Rapid industrialization and urbanization have progressed in Korea, yet public attention to hazardous pollutants emitted from industrial complexes remains limited. With the increasing coexistence of industrial and residential areas, there is a growing need for real-time monitoring and management plans that account for [...] Read more.
Rapid industrialization and urbanization have progressed in Korea, yet public attention to hazardous pollutants emitted from industrial complexes remains limited. With the increasing coexistence of industrial and residential areas, there is a growing need for real-time monitoring and management plans that account for the rapid dispersion of hazardous air pollutants (HAPs). In this study, we conducted spatiotemporal data collection and analysis for the first time in Korea using real-time measurements obtained through mobile extractive differential optical absorption spectroscopy (Me-DOAS) mounted on a solar occultation flux (SOF) vehicle. The measurements were conducted in the Saha Sinpyeong–Janglim Industrial Complex in Busan, which comprises the Sasang Industrial Complex and the Sinpyeong–Janglim Industrial Complex. BTEX compounds were selected as target volatile organic compounds (VOCs), and real-time measurements of both BTEX and fine particulate matter (PM) were conducted simultaneously. Correlation analysis revealed a strong relationship between PM10 and PM2.5 (r = 0.848–0.894), indicating shared sources. In Sasang, BTEX levels were associated with traffic and localized facilities, while in Saha Sinpyeong–Janglim, the concentrations were more influenced by industrial zoning and wind patterns. Notably, inter-compound correlations such as benzene–m-xylene and p-xylene–toluene suggested possible co-emission sources. This study proposes a GIS-based, three-dimensional air quality management approach that integrates variables such as traffic volume, wind direction, and speed through real-time measurements. The findings are expected to inform effective pollution control strategies and future environmental management plans for industrial complexes. Full article
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13 pages, 1895 KB  
Article
Class-Dependent Solar Flare Effects on Mars’ Upper Atmosphere: MAVEN NGIMS Observations of X8.2 and M6.0 from September 2017
by Junaid Haleem and Shican Qiu
Universe 2025, 11(8), 245; https://doi.org/10.3390/universe11080245 - 25 Jul 2025
Viewed by 979
Abstract
Transient increments of X-ray radiation and extreme ultraviolet (EUV) during solar flares are strong drivers of thermospheric dynamics on Mars, yet their class-dependent impacts remain poorly measured. This work provides the first direct, side-by-side study of Martian thermospheric reactions to flares X8.2 on [...] Read more.
Transient increments of X-ray radiation and extreme ultraviolet (EUV) during solar flares are strong drivers of thermospheric dynamics on Mars, yet their class-dependent impacts remain poorly measured. This work provides the first direct, side-by-side study of Martian thermospheric reactions to flares X8.2 on 10 September 2017 and M6.0 on 17 September 2017. This study shows nonlinear, class-dependent effects, compositional changes, and recovery processes not recorded in previous investigations. Species-specific responses deviated significantly from irradiance proportionality, even though the soft X-ray flux in the X8.2 flare was 13 times greater. Argon (Ar) concentrations rose 3.28× (compared to 1.13× for M6.0), and radiative cooling led CO2 heating to approach a halt at ΔT = +40 K (X8.2) against +19 K (M6.0) at exobase altitudes (196–259 km). N2 showed the largest class difference, where temperatures rose by +126 K (X8.2) instead of +19 K (M6.0), therefore displaying flare-magnitude dependent thermal sensitivity. The 1.95× increase in O concentrations during X8.2 and the subsequent decrease following M6.0 (−39 K cooling) illustrate the contradiction between photochemical production and radiative loss. The O/CO2 ratio at 225 km dropped 46% during X8.2, revealing compositional gradients boosted by flares. Recovery timeframes varied by class; CO2 quickly re-equilibrated because of effective cooling, whereas inert species (Ar, N2) stabilized within 1–2 orbits after M6.0 but needed >10 orbits of the MAVEN satellite after the X8.2 flare. The observations of the X8.2 flare came from the western limb of the Sun, but the M6.0 flare happened on the far side. The CME shock was the primary driver of Mars’ EUV reaction. These findings provide additional information on atmospheric loss and planetary habitability by indicating that Mars’ thermosphere has a saturation threshold where strong flares induce nonlinear energy partitioning that encourages the departure of lighter species. Full article
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17 pages, 4255 KB  
Article
Exploring the Global and Regional Factors Influencing the Density of Trachurus japonicus in the South China Sea
by Mingshuai Sun, Yaquan Li, Zuozhi Chen, Youwei Xu, Yutao Yang, Yan Zhang, Yalan Peng and Haoda Zhou
Biology 2025, 14(7), 895; https://doi.org/10.3390/biology14070895 - 21 Jul 2025
Viewed by 712
Abstract
In this cross-disciplinary investigation, we uncover a suite of previously unexamined factors and their intricate interplay that hold causal relationships with the distribution of Trachurus japonicus in the northern reaches of the South China Sea, thereby extending the existing research paradigms. Leveraging advanced [...] Read more.
In this cross-disciplinary investigation, we uncover a suite of previously unexamined factors and their intricate interplay that hold causal relationships with the distribution of Trachurus japonicus in the northern reaches of the South China Sea, thereby extending the existing research paradigms. Leveraging advanced machine learning algorithms and causal inference, our robust experimental design uncovered nine key global and regional factors affecting the distribution of T. japonicus density. A robust experimental design identified nine key factors significantly influencing this density: mean sea-level pressure (msl-0, msl-4), surface pressure (sp-0, sp-4), Summit ozone concentration (Ozone_sum), F10.7 solar flux index (F10.7_index), nitrate concentration at 20 m depth (N3M20), sonar-detected effective vertical range beneath the surface (Height), and survey month (Month). Crucially, stable causal relationships were identified among Ozone_sum, F10.7_index, Height, and N3M20. Variations in Ozone_sum likely impact surface UV radiation levels, influencing plankton dynamics (a primary food source) and potentially larval/juvenile fish survival. The F10.7_index, reflecting solar activity, may affect geomagnetic fields, potentially influencing the migration and orientation behavior of T. japonicus. N3M20 directly modulates primary productivity by limiting phytoplankton growth, thereby shaping the availability and distribution of prey organisms throughout the food web. Height defines the vertical habitat range acoustically detectable, intrinsically linking directly to the vertical distribution and availability of the fish stock itself. Surface pressures (msl-0/sp-0) and their lagged effects (msl-4/sp-4) significantly influence sea surface temperature profiles, ocean currents, and stratification, all critical determinants of suitable habitats and prey aggregation. The strong influence of Month predominantly reflects seasonal changes in water temperature, reproductive cycles, and associated shifts in nutrient supply and plankton blooms. Rigorous robustness checks (Data Subset and Random Common Cause Refutation) confirmed the reliability and consistency of these causal findings. This elucidation of the distinct biological and physical pathways linking these diverse factors leading to T. japonicus density provides a significantly improved foundation for predicting distribution patterns globally and offers concrete scientific insights for sustainable fishery management strategies. Full article
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15 pages, 4738 KB  
Article
Mechanical Performance of Ceria-Coated 3D-Printed Black Zirconia Cellular Structures After Solar Thermochemical CO/H2 Fuel Production Cycles
by Fernando A. Costa Oliveira, Manuel Sardinha, Joaquim M. Justino Netto, Miguel Farinha, Marco Leite, M. Alexandra Barreiros, Stéphane Abanades and Jorge Cruz Fernandes
Crystals 2025, 15(7), 629; https://doi.org/10.3390/cryst15070629 - 8 Jul 2025
Viewed by 827
Abstract
Solar fuels production requires developing redox active materials with porous structures able to withstand thermochemical cycles with enhanced thermal stability under concentrated solar irradiation conditions. The mechanical performance of 3D-printed, macroporous black zirconia gyroid structures, coated with redox-active ceria, was assessed for their [...] Read more.
Solar fuels production requires developing redox active materials with porous structures able to withstand thermochemical cycles with enhanced thermal stability under concentrated solar irradiation conditions. The mechanical performance of 3D-printed, macroporous black zirconia gyroid structures, coated with redox-active ceria, was assessed for their suitability in solar thermochemical cycles for CO2 and H2O splitting. Experiments were conducted using a 1.5 kW solar furnace to supply the high-temperature concentrated heat to a windowed reaction chamber to carry out thermal redox cycling under realistic on-sun conditions. The ceria coating on ceramic structures improved the thermal stability and redox efficiency while minimizing the quantity of the redox material involved. Crushing strength measurements showed that samples not directly exposed to the concentrated solar flux retained their mechanical performance after thermal cycling (~10 MPa), while those near the concentrated solar beam focus exhibited significant degradation due to thermal stresses and the formation of CexZr1−xO2 solid solutions (~1.5 MPa). A Weibull modulus of 8.5 was estimated, marking the first report of such a parameter for fused filament fabrication (FFF)-manufactured black zirconia with gyroid architecture. Failure occurred via a damage accumulation mechanism at both micro- and macro-scales. These findings support the viability of ceria-coated cellular ceramics for scalable solar fuel production and highlight the need for optimized reactor designs. Full article
(This article belongs to the Section Materials for Energy Applications)
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51 pages, 5106 KB  
Article
Evaluating Solar Energy Potential Through Clear Sky Index Characterization Across Elevation Profiles in Mozambique
by Fernando Venâncio Mucomole, Carlos Augusto Santos Silva and Lourenço Lázaro Magaia
Solar 2025, 5(3), 30; https://doi.org/10.3390/solar5030030 - 1 Jul 2025
Viewed by 1880
Abstract
The characteristics and types of the sky can greatly influence photovoltaic (PV) power generation, potentially leading to a reduction in both the lifespan and efficiency of the entire system. Driven by the challenge of addressing fluctuations in solar PV energy utilization, the aim [...] Read more.
The characteristics and types of the sky can greatly influence photovoltaic (PV) power generation, potentially leading to a reduction in both the lifespan and efficiency of the entire system. Driven by the challenge of addressing fluctuations in solar PV energy utilization, the aim was to assess the solar energy potential by analyzing the clear sky index Kt* across elevation profiles. To achieve this, a theoretical model for determining Kt* was employed, which encapsulated the solar energy analysis. Initially, solar energy data collected from approximately 16 stations in various provinces of Mozambique, as part of the solar energy measurement initiatives by INAM, FUNAE, AERONET, and Meteonorm, was processed. Subsequently, the clear sky radiation was calculated, and Kt* was established. The statistical findings indicate a reduction in energy contribution from the predictors, accounting for 28% of the total incident energy; however, there are progressive increases averaging around ~0.02, with Kt* values ranging from 0.4 to 0.9, demonstrating a strong correlation between 0.7 and 0.9 across several stations and predictor parameters. No significant climate change effects were noted. The radiation flux is directed from areas with higher Kt* to those with lower values, as illustrated in the heat map. The region experiences an increase in atmospheric parameter deposition, with concentrations around ~0.20, yet there remains a substantial energy flow potential of 92% for PV applications. This interaction can also be applied in other locations to assess the potential for available solar energy, as the analyzed solar energy spectrum aligns closely with the theoretical statistical calibration of energy distribution relevant to the global solar energy population process. Full article
(This article belongs to the Topic Solar Forecasting and Smart Photovoltaic Systems)
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14 pages, 705 KB  
Technical Note
Sensing Lunar Dust Density Using Radio Science Signals of Opportunity
by Kamal Oudrhiri, Yu-Ming Yang and Daniel Erwin
Remote Sens. 2025, 17(11), 1940; https://doi.org/10.3390/rs17111940 - 4 Jun 2025
Viewed by 1932
Abstract
Previous lunar missions, such as Surveyor, Apollo, and the Lunar Atmosphere and Dust Environment Explorer (LADEE), have played a pivotal role in advancing our understanding of the lunar exosphere’s dynamics and its relationship with solar wind flux. The insights gained from these missions [...] Read more.
Previous lunar missions, such as Surveyor, Apollo, and the Lunar Atmosphere and Dust Environment Explorer (LADEE), have played a pivotal role in advancing our understanding of the lunar exosphere’s dynamics and its relationship with solar wind flux. The insights gained from these missions have laid a strong foundation for our current knowledge. However, due to insufficient near-surface observations, the scientific community has faced challenges in interpreting the phenomena of lunar dust lofting and levitation. This paper introduces the concept of signals of opportunity (SoOP), which utilizes radio occultation (RO) to retrieve the near-surface dust density profile on the Moon. Gravity Recovery and Interior Laboratory (GRAIL) radio science beacon (RSB) signals are used to demonstrate this method. By mapping the concentration of lunar near-surface dust using RO, we aim to enhance our understanding of how charged lunar dust interacts with surrounding plasma, thereby contributing to future research in this field and supporting human exploration of the Moon. Additionally, the introduced SoOP will be able to provide observational constraints to physical model development related to lunar surface particle sputtering and the reactions of near-surface dust in the presence of solar wind and electrostatically charged dust grains. Full article
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1 pages, 133 KB  
Correction
Correction: Fernández-Reche et al. Measuring Concentrated Solar Radiation Flux in a Linear Fresnel-Type Solar Collector. Solar 2022, 2, 401–413
by Jesús Fernández-Reche, Loreto Valenzuela and Diego Pulido-Iparraguirre
Solar 2025, 5(2), 19; https://doi.org/10.3390/solar5020019 - 14 May 2025
Viewed by 2879
Abstract
Following publication, the Editorial Office became aware that the original article [...] Full article
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