Search Results (127)

Aging of Styrene–butadiene–styrene (SBS)-modified asphalt accelerates the degradation of both the SBS polymer network and asphalt components, resulting in deterioration of the durability of asphalt concrete. This study investigates the use of zinc diethyldithiocarbamate (ZDC), a multifunctional antioxidant, in SBS-modified asphalt to improve its aging resistance. Physical property tests, dynamic rheological analysis, multiple stress creep recovery (MSCR) and Fourier transform infrared spectroscopy (FTIR) assays were conducted to evaluate the rheological and chemical properties of asphalt binders before and after thermo-oxidative and UV aging. The results indicate that the incorporation of ZDC improved the deformation resistance and elastic recovery of SBS-modified asphalt. After aging, the ZDC/SBS composite-modified asphalt exhibited lower performance change rate than conventional SBS-modified asphalt, indicating enhanced resistance to permanent deformation and aging-induced damage. FTIR analysis demonstrated that ZDC effectively inhibited the formation of oxygen-containing functional groups during aging, suggesting suppressed oxidative reactions within the asphalt binder. The 5% ZDC dosage reduces the carbonyl index of SBS-modified asphalt by 36.48% after thermo-oxidative aging, and by 21.89% after UV aging, showing a stronger chemical inhibition effect on thermo-oxidative reactions. From the perspective of rheological performance stability, ZDC lowers the variation amplitude of non-recoverable creep compliance by 35.32% before and after thermo-oxidative aging and 41.46% before and after UV aging, and delivers a more prominent mitigating effect on property fluctuations triggered by UV aging. This indicates that ZDC exerts differentiated anti-aging mechanisms on thermo-oxidative and UV aging, with considerable potential to improve the comprehensive aging resistance of polymer-modified asphalt binders. Full article

Waste biomass powders and waste oils are promising sustainable modifiers for asphalt binders, but solid-phase biomass powders and oil-phase modifiers often have competing effects on high-temperature stability and low-temperature relaxation. In this study, peanut shell powder (PSP) and waste cooking oil (WCO) were combined at a fixed mass ratio of 1:1 to modify No. 70 base asphalt binder, and the material characteristics, physical properties, rheological responses, and chemical interactions of unaged PSP/WCO-modified asphalt binders with total modifier dosages of 5%, 10%, and 15% were evaluated. The results showed that PSP had a rough, wrinkled, and locally porous lignocellulosic structure and showed no obvious thermal decomposition near the preparation temperature of approximately 150 °C. As the PSP/WCO dosage increased from 0% to 15%, the softening point increased from 50.2 °C to 53.9 °C, while penetration decreased from 66.2 to 62.6 (0.1 mm) and ductility decreased from 74.0 mm to 69.5 mm, indicating increased binder consistency and improved high-temperature flow resistance. DSR and MSCR results showed enhanced high-temperature deformation resistance; at 15% dosage, Jnr at 3.2 kPa decreased from 2.35 to 1.25 kPa⁻¹, while R increased from 0.51% to 1.36%. However, BBR results showed increased creep stiffness and decreased m-value, indicating reduced low-temperature relaxation capacity. FTIR spectra showed no new strong characteristic absorption peaks, suggesting that the modification was mainly associated with physical blending, compositional regulation, and weak intermolecular interactions. The main novelty of this work is that it demonstrates a fixed-ratio PSP/WCO composite modification strategy that combines biomass-powder reinforcement with oil-phase regulation to improve the unaged high-temperature rheological performance of asphalt binders while promoting the resource utilization of peanut shells and waste cooking oil. Full article

The integration of biochar into asphalt binders represents a significant advancement toward global sustainability in pavement engineering. Produced through biomass pyrolysis, biochar enables the valorization of agricultural and industrial waste while reducing dependence on petroleum-derived binder constituents. This review critically synthesizes current research regarding the impact of biochar on the physical, rheological, and aging performance of bitumen. The evidence consistently shows that biochar improves binder stiffness, raises softening points, and strengthens rutting resistance at elevated temperatures, largely due to its porous microstructure and high carbon content. Biochar-modified binders also exhibit enhanced aging resistance through the adsorption of volatile light fractions. These improvements are primarily ascribed to the carbonaceous composition and high porosity of the biochar particles. However, systemic challenges, including phase stability at high concentrations, long-term oxidative aging, and a lack of standardized characterization protocols, hinder widespread implementation. By identifying consistent findings, contradictions, and critical research gaps across the literature, this review provides a consolidated foundation to guide the transition of biochar-modified bitumen from laboratory investigation to large-scale pavement infrastructure applications. Full article

Conventional crumb-rubber-modified asphalt (CRMA) often shows high viscosity, storage separation, and limited low-temperature relaxation, whereas existing engineered rubber or single-activation methods do not fully clarify the combined contribution of biomass–oil swelling and microwave treatment. This study develops a rapeseed heavy oil (RHO)–microwave composite activation route for CRMA. Microwave activation, RHO pre-swelling, and their composite treatment were compared by varying rubber size, microwave intensity, and oil-to-rubber ratio. Binder workability, storage stability, DSR/MSCR/BBR rheology, FTIR, SEM, fluorescence microscopy, TGA, and AC-13C mixture performance were evaluated. Microwave activation mainly reduced viscosity and improved rubber dispersion, whereas RHO pre-swelling improved ductility and storage stability. The optimal F84 binder (80-mesh rubber, RHO-to-rubber ratio 1:2, 1.2 kJ/g microwave) reduced 180 °C viscosity and top–bottom softening-point difference by 42.95% and 55.68%, respectively, and increased 10 °C ductility from 10.5 to 19.5 cm relative to inactivated CRMA. Although F84 weakened creep recovery compared with inactivated CRMA, it improved low-temperature relaxation and mixture failure strain (3527.8 µε). The composite route is therefore suitable for CRMA applications prioritizing workability, storage stability, low-temperature cracking resistance, and rubber valorization, while rutting-critical projects require mixture-level verification. Full article

Moisture-induced damage is one of the primary causes of premature distress in asphalt pavements, leading to reduced service life and increased maintenance costs. Although nanomaterials have shown potential in enhancing asphalt performance, the underlying composite interaction mechanisms among nanomaterials, asphalt binder, and aggregate phases under moisture exposure are still not fully understood. In addition, comparative evaluations under consistent experimental conditions remain limited. This study investigates the influence of five nanomaterials: nano-silica (NS), nano-alumina (NA), nano-titanium dioxide (NT), nano-zinc oxide (NZ), and carbon nanotubes (CNT) on the physical and mechanical properties of asphalt binders and mixtures, with particular emphasis on moisture damage resistance. The nanomaterials were incorporated at dosages of 1.5%, 3.0%, 4.5%, and 6.0% by binder weight. Binder performance was evaluated using conventional and performance grading (PG) tests, while mixture performance was assessed through Marshall properties and moisture susceptibility indicators, including the tensile strength ratio (TSR) and the index of retained strength (IRS). Fluorescence microscopy (FM), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) were employed to investigate nanomaterial dispersion characteristics, microstructural morphology, and physicochemical interactions within the asphalt composite system. The results indicate that nanomaterial modification reduced penetration and increased softening point and Marshall stability, reflecting enhanced stiffness and thermal resistance, although ductility decreased at higher dosages. Significant improvements in moisture resistance were observed, particularly under conditioned states. The TSR increased from 81.2% for the control mixture to 92.4% for NS and 91.7% for NA, while the IRS improved from 72.7% to 88.5% for NS. Statistical analysis indicated that both nanomaterial type and dosage significantly affected TSR and IRS performance, with dosage exhibiting comparatively greater influence on moisture resistance improvement. FM and SEM analyses revealed comparatively better dispersion and lower agglomeration tendency for NS and NA, which corresponded to their superior moisture resistance performance. FTIR analysis indicated that the modification process was predominantly physical, with no major formation of new chemical functional groups. Among the investigated nano materials, NS at 6% dosage exhibited the most pronounced improvement, followed by NA at similar dosage levels. Overall, the findings suggest that nanomaterial modification can considerably improve the moisture resistance and mechanical performance of asphalt mixtures under laboratory conditions. However, higher nanomaterial dosages may adversely affect binder workability due to increased viscosity, particularly in CNT-modified binders. Full article

The degradation of styrene-butadiene-styrene (SBS) modified asphalt under thermal-oxidative aging can reduce pavement service life. Lignin is a renewable material with active phenolic hydroxyl groups. Incorporating lignin into SBS modified asphalt may provide a potential bio-based auxiliary modification route. To investigate the antioxidative effect and rheological properties of SBS modified asphalt after adding lignin, a molecular dynamics test and experimental tests were employed. The molecular simulation results suggested that lignin preferentially associated with asphaltene and resin molecules and changed the molecular mobility of asphalt components in a component-dependent manner. The SBS/lignin composite modified asphalt was evaluated by temperature sweep (TS), Multiple Stress Creep and Recovery (MSCR), Linear Amplitude Sweep (LAS) and Fourier transform infrared spectroscopy (FTIR). Rheological tests showed that lignin increased the complex shear modulus and rutting factor. LAS results showed that lignin reduced the fatigue life of SBS-modified asphalt in the unaged state due to increased stiffness and embrittlement. However, after long-term aging, the lignin-containing binders retained higher fatigue resistance than the SBS-only control, which may be related to the slower evolution of oxidation-related functional groups and SBS-related spectral indices. FTIR analysis provided semi-quantitative evidence that lignin addition reduced the growth of sulfoxide-related bands and helped maintain the polybutadiene-related index during aging. Overall, lignin may serve as a potential auxiliary antioxidant modifier for SBS modified asphalt, while its exact source-specific molecular mechanism requires further verification. Full article

Standard laboratory protocols for simulating short-term asphalt aging, including the Thin-Film Oven Test (TFOT) and Rolling Thin-Film Oven Test (RTFOT), are widely adopted but frequently lack sensitivity to the distinct thermo-oxidative kinetics of high-viscosity and polymer-modified systems. This study evaluates a severity-graded aging matrix incorporating the Pressure Aging Vessel (PAV) at variable durations (2, 5, and 10 h at 163 °C/2.1 MPa) as a potential alternative to conventional thin-film methods. Three binder systems BA-70 (PG 64-22), SBS-modified, and compatibilized functional thermoplastic (CFT)-modified asphalt were subjected to TFOT, RTFOT, and PAV variants. Comprehensive rheological characterization (DSR frequency/temperature sweeps, rutting parameter, MSCR) and SARA fractionation were employed to quantify oxidative stiffening, permanent deformation resistance, and compositional evolution. An Aging Severity Index (ASI) was developed to normalize multi-parameter responses and establish quantitative protocol equivalence thresholds. BA and SBS-modified binders exhibited pronounced protocol-dependent stiffening, with PAV-5h vs. RTFOT ASI gaps of 30.0% and 33.0%, respectively, confirming distinct aging severity under the tested conditions. Conversely, the CFT-modified binder demonstrated a compressed aging signature, maintaining stable complex modulus, minimal non-recoverable compliance escalation, and near-complete elastic recovery across all protocols. The ASI gap between PAV-5h and RTFOT for CFT was 6.0%, falling within the pre-defined ≤7% equivalence threshold established from combined rheological test uncertainty, specification-aligned engineering tolerance, and empirical gap clustering. SARA analysis corroborated these findings, showing CFT retained higher aromatic/resin fractions while limiting asphaltene accumulation compared to BA-70 and SBS. Importantly, the observed interchangeability between PAV-5h and RTFOT is strictly limited to the specific CFT-modified binder formulation tested under laboratory conditions. Broader specification adoption requires targeted validation across diverse modifier chemistries, dosages, and field-aged binders before generalization. Full article

To address the issues of high energy consumption and unstable construction quality caused by high-temperature heating during the preparation of traditional hot-mixed/grouted semi-flexible pavement (SFP) mixtures, a cold-mixed integrated (CMI) process was proposed. In addition, the material composition of the mixtures was optimized. The effects of the preparation process and binder type on the high- and low-temperature performance, water stability, and fatigue performance were then analyzed. Furthermore, the microstructural characteristics of the semi-flexible mixture were also investigated. The results indicated that the CMI process facilitated the formation and uniform distribution of calcium silicate hydrate (C-S-H), enhanced the binder’s ability to encapsulate aggregates and fill skeletal voids, significantly reduced the mixture’s void ratio, and improved its pavement performance. The proposed procedure was a means of enhancing high-temperature stability and fatigue life (an increase of 80% and 200 times compared to the hot-mixed/grouted (HMG) process, and 5 times and 300 times compared to AC-13, respectively). Compared with the HMG process, the CMI process offered greater advantages in enhancing the high-temperature stability and fatigue resistance of the mixture, particularly when using SBS-modified asphalt, where fatigue performance exhibited an order-of-magnitude improvement. Furthermore, while SBS modification could improve the road performance of SFP materials, mixtures prepared with SBS-modified emulsified asphalt demonstrated more significant enhancements in high-temperature stability and fatigue resistance, approximately 2 times and 10 times higher than SBS-modified mixtures, respectively. The addition of styrene–acrylic emulsion (SAE) could further enhance the low-temperature crack resistance by approximately 7%. The research results can provide a reference for the development and application of preparation processes for semi-flexible mixtures. Full article

The disposal of waste tyres presents a significant environmental challenge, necessitating sustainable, high-value recycling solutions. This study explores the incorporation of waste tyre metal fibre (WTMF) into hot mix asphalt (HMA) to enhance mechanical performance while reducing its electrical resistivity as well as the landfill burden. The primary goal of this research is to apply response surface methodology (RSM) to experimental data for modelling and optimizing WTMF-modified HMA mixes by capturing the coupled effects of fibre reinforcement and binder content on mechanical and functional performance. The microstructural characteristics of WTMF were examined using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD). WTMF-modified mixes containing five WTMF dosages (from 0% to 1.50%) and bitumen contents from 4% to 6% were prepared and tested in the laboratory. The resulting dataset was used for RSM modelling, with WTMF and bitumen contents as input factors and Marshall stability, flow, porosity, and electrical resistivity as response variables. The central composite design (CCD) technique was employed to quantify interaction effects and to identify statistically significant trends. The developed models were validated using statistical indicators, and optimal mixture compositions were determined and experimentally verified. Microstructural analysis revealed WTMF’s irregular, rough surface with microcracks and pits, aiding crack-bridging and stress transfer. RSM results indicated 0.71% WTMF and 5.1% bitumen as an optimal combination of factors. Furthermore, high R² (>0.80) and adequate precision (>4.0) values from analysis of variance (ANOVA) underscore the significance of the proposed models, revealing a robust correlation between experimental and predicted data. This study demonstrated WTMF’s potential to be used in conventional HMA mixes, offering a sustainable recycling pathway for waste tyres. Full article

Asphalt pavements are frequently subjected to fatigue cracking, rutting, and surface wear, which accelerate maintenance needs and shorten service life. This study evaluates the performance enhancement of NHA Class B dense-graded asphalt mixtures (12.5 mm NMAS) prepared with a 60/70 penetration grade binder through carbon fiber (CF) reinforcement. Chopped fibers (~12.7 mm) were incorporated via the dry mixing process at dosages of 0.5%, 1.0%, and 1.5% by binder weight. The results indicate that the 1.0% CF mixture delivered optimal performance, with ITS increasing by 51.9%, Marshall stability improving by 38.4%, resilient modulus rising by 42.6%, and rut depth decreasing by 69.2% compared to the unmodified control. Dynamic stability reached 33,750 passes/mm, demonstrating substantial resistance to permanent deformation. Statistical analysis using one-way ANOVA confirmed that all improvements were significant (p < 0.05). Despite a ~6.7% increase in initial cost, the CF-modified mix exhibited strong economic viability, achieving a benefit–cost ratio of 4.79 and significant life-cycle savings over 20 years. These findings underscore carbon fiber as an effective modifier for developing durable, high-performance asphalt composites with reduced maintenance requirements. This work contributes to the advancement of smart and sustainable pavement technologies for resilient transportation infrastructure. Full article

The use of resource-saving technology in road construction material production is a current problem, the solution of which will allow us to increase the environmental and economic efficiency of the road construction industry. Nowadays, secondary raw materials are widely used in highway construction, obtained both from the waste of old road construction materials and collected from other industries. During asphalt production, up to 90% of raw materials can be replaced by reclaimed asphalt pavement (RAP). This technology requires residual binder modification to reduce the negative impact on the technological and operational asphalt concrete properties. On the other hand, the use of rubber crumbs or granules obtained from the disposal of old car tires in asphalt–concrete mixtures is widespread. However, some types of car tires cannot be used as raw materials to produce an effective modifier. Truck tires and tires from special vehicles are suitable for use as a modifier for asphalt–concrete mixtures. Tires designed for passenger cars do not contain enough polymer. As an experiment on asphalt–concrete mixture production using secondary resources only, a testing facility was developed. The testing facility uses hot gas obtained by burning automobile tires in a special oven as a heat source. Rubber residues from the recycling of automobile tires are used as fuel, which cannot be used to produce rubber powder or granules. RAP obtained by cold milling of the pavements of city and public roads was used as the object of the research. When studying the characteristics of the asphalt–concrete-mixture-based binder, it was found that the sulfur compounds present in the composition of hot gases change the properties of the binder, leading to a serious deterioration in the technological characteristics of asphalt–concrete mixtures. The asphalt–concrete mixture obtained during RAP processing is characterized by a narrow temperature range in which it can be laid and compacted to the required density values. After laying the pavement, quality control revealed a significant variation (the number of air voids ranged from 0.8 to 5.5%) in the average density of samples taken from the compacted layer. In addition, there were significant violations of the longitudinal evenness of the finished coating. Experiments were carried out to extract the binder from asphalt–concrete mixtures before and after regeneration. The physico-mechanical and rheological characteristics were studied and qualitative analysis of the binder was realized by IR spectroscopy. The data obtained allow us to establish the mechanism of how sulfur-containing gases influence the bitumen binder’s properties in asphalt mixtures. Additionally, the features of thermo-oxidative degradation occurring during the hot recycling of asphalt–concrete mixtures were established. A justification is also given for the need to use anti-aging modifiers to restore the properties of the residual binder. Full article

Alginate, primarily sodium alginate, is a biopolymer derived from brown algae or bacterial sources that forms hydrogels via ionic crosslinking with certain divalent cations. Its incorporation into soils, earthen materials, cementitious composites, and asphalt mixtures improves mechanical performance and durability. This review collates recent advances in alginate-based treatments for geotechnical and construction applications, highlighting how alginate dosage, substrate type, gelation method, mixing strategy, and curing regime influence mechanical strength, physical properties, and self-healing efficiency. In soil stabilization, alginate treatments increase unconfined compressive strength (UCS) by 0.2–1.5 MPa in sand, with some studies reporting increases of over 2 MPa. Reported UCS improvements in alginate-treated clayey soils generally fall within the range of 50–150% compared to untreated samples, although isolated studies document increases exceeding 200%, depending on material composition and curing conditions. In cementitious systems, alginate-based capsules and hydrogels facilitate self-healing, achieving high closure rates of 70–100% for microcracks <0.4 mm, with some studies achieving complete sealing of macrocracks up to 4 mm while also recovering significant mechanical strength. Depending on dosage and formulation, alginate can also serve as a viscosity-modifying admixture, increasing the plastic viscosity and yield stress of the fresh mix, with this thickening effect becoming pronounced at dosages above approximately 0.1 w/w% by cementitious binder mass. For asphalt pavements, alginate-encapsulated rejuvenators facilitate high healing efficiency under cyclic loading and thermal cycling; rheological tests confirm elevated complex modulus and improved viscoelastic response. This review also synthesizes an explanatory framework for the divergent results found in the literature, advocates for standardized experimental protocols and material characterization, and outlines future research directions to advance alginate as a suitable alternative to conventional stabilizers. Full article

This study aims to address the issue of asphalt pavement performance deterioration caused by chloride salt erosion. Layered double hydroxides (CLDHs) calcined at different temperatures, including 400 °C, 500 °C, and 600 °C, were used for the modification of asphalt binder. The structural evolution and chloride ion adsorption characteristics of CLDHs were analyzed. The adsorption kinetic behavior of CLDHs for chloride ions was investigated by combining adsorption kinetic experiments and electrochemical titration experiments. Through characterizing the interfacial adhesion performance between CLDH-modified asphalt binder and aggregates, the chemical composition of asphalt–ash binder before and after salt corrosion, and the leaching stability of organic substances in an environment with abundant chloride ions, the influence of CLDHs on the salt corrosion resistance of asphalt–ash binder was quantified. The results indicate that chloride adsorption by CLDHs is predominantly chemisorption-driven. With increasing calcination temperature, the chloride adsorption capacity of CLDHs gradually improved. In chloride-rich environments, CLDHs significantly enhanced the interfacial adhesion between asphalt binder and aggregates, particularly for coarse aggregates with a particle size of 9.5–13.2 mm. Furthermore, CLDHs effectively suppressed the formation of carbonyl and sulfoxide groups during salt corrosion and substantially decreased the leaching of organic components from asphalt binder. In summary, CLDHs can specifically enhance the salt corrosion resistance of asphalt binder, with the 600 °C-CLDHs demonstrating the most significant improvement, followed by the 400 °C-CLDHs, while the 500 °C-CLDHs performed the least effectively. Full article

The mitigation of traffic noise is essential for the development of sustainable and livable urban environments, a goal that is directly contingent on addressing tire-pavement interaction noise (TPIN) as the dominant acoustic pollutant at medium to high vehicle speeds. This comprehensive review addresses a critical gap in the literature by systematically analyzing the damping properties of pavement systems through a unified, multi-scale framework—from the molecular-scale viscoelasticity of asphalt binders to the composite performance of asphalt mixtures. The analysis begins by synthesizing state-of-the-art testing and characterization methodologies, which establish a clear connection between macroscopic damping performance and the underlying viscoelastic mechanisms coupled with the microscopic morphology of the binders. Subsequently, the review critically assesses the influence of critical factors, such as polymer modifiers including rubber and Styrene-Butadiene-Styrene (SBS), temperature, and loading frequency. This examination elucidates how these variables govern molecular mobility and relaxation processes to ultimately determine damping efficacy. A central and synthesizing conclusion emphasizes the paramount importance of the asphalt binder’s properties, which serve as the primary determinant of the composite mixture’s overall acoustic performance. By delineating this structure-property-performance relationship across different scales, the review consolidates a foundational scientific framework to guide the rational design and informed material selection for next-generation asphalt pavements. The insights presented not only advance the fundamental understanding of damping mechanisms in pavement materials but also provide actionable strategies for creating quieter and more sustainable transportation infrastructures. Full article

This review examines scientific and engineering strategies for adapting bituminous and asphalt concrete materials to the highly diverse climates of Central Asia. The region’s sharp gradients—from arid lowlands to cold mountainous zones—expose pavements to thermal fatigue, photo-oxidative aging, freeze–thaw cycles, and wind abrasion. Existing climatic classifications and principles for designing thermally and radiatively resilient pavements are summarized. Special emphasis is placed on linking binder morphology, rheology, and climate-induced transformations in composite bituminous systems. Advanced characterization methods—including dynamic shear rheometry (DSR), multiple stress creep recovery (MSCR), bending beam rheometry (BBR), and linear amplitude sweep (LAS), supported by FTIR, SEM, and AFM—enable quantitative correlations between phase composition, oxidative chemistry, and mechanical performance. The influence of polymeric, nanostructured, and biopolymeric modifiers on stability and durability is critically assessed. The review promotes region-specific material design and the use of integrated accelerated aging protocols (RTFOT, PAV, UV, freeze–thaw) that replicate local climatic stresses. A climatic rheological profile is proposed as a unified framework combining climate mapping with microstructural and rheological data to guide the development of sustainable and durable pavements for Central Asia. Key rheological indicators—complex modulus (G*), non-recoverable creep compliance (Jnr), and the BBR m-value—are incorporated into this profile. Full article