Search Results (1,117)

The large-scale generation of asphalt dust waste (ADW) has raised increasing environmental concerns, while its high-value utilization in cementitious materials remains insufficiently explored, particularly in terms of mechanical performance, durability-related properties, and integrated sustainability evaluation. In this study, a graded utilization strategy based on particle size was proposed to incorporate ADW into alkali-activated concrete paving blocks, in which fine ADW fraction (<0.075 mm) was used as a partial replacement of blast furnace slag (BFS), while the coarser ADW fraction was used as a partial replacement of river sand, aiming at sustainable pavement applications. In addition, two types of ADW with different lithologies, namely limestone ADW and basalt ADW, along with their combined system, were investigated. The results show that the incorporation of ADW effectively enhances the engineering performance of paving blocks. The compressive strength increased from 45.3 MPa to 56.6 MPa, while water absorption decreased from 5.3% to 4.1%. All mixtures satisfied the requirements for abrasion resistance and slip resistance, demonstrating their compliance with the performance criteria for pedestrian pavement applications. Among all mixtures, the combined use of limestone ADW and basalt ADW exhibited the best overall performance. The improved performance may be attributed to the combined effects of graded particle utilization and the potential compositional complementarity between calcium-rich limestone ADW and silica–alumina-rich basalt ADW, which is consistent with the denser microstructure observed in SEM images. In addition, the proposed strategy contributes to improved solid waste utilization and reduced consumption of natural resources, as reflected in the quantitative sustainability assessment. Overall, this study demonstrates that graded utilization of ADW is a feasible approach for developing alkali-activated paving materials, with promising performance and sustainability potential. Full article

Hydraulic concrete suffers severe damage from high-velocity sand-bearing water flow. Traditional single-layer coating materials struggle to simultaneously satisfy the requirements of strong adhesion, high abrasion resistance, and long-term durability. In this study, a functionally graded multilayer composite coating system, designated HIR (Hybrid Epoxy–Interfacial Primer–Rubber), was developed. The HIR system comprises a hybrid acrylic–epoxy resin (HEP) top layer, a modified epoxy-based interfacial primer (EIP), and a sprayed liquid rubber (SLR) middle layer, realizing synergistic enhancement of interfacial bonding, deformation adaptability, and abrasion resistance. The results showed that the HIR achieved an adhesion strength exceeding 2.0 MPa to concrete. The HEP exhibited an elongation at break exceeding 30%, while the SLR showed an elongation at break higher than 1000%. The anti-abrasion strength of the HIR-coated concrete reached 254.35 h/(kg/m²), which is 15 times that of uncoated concrete. Moreover, the coated concrete maintained a relative dynamic elastic modulus above 95% after 300 freeze–thaw cycles. DMA revealed multiple glass transition temperatures in both SLR (24 °C, 101 °C, 137 °C) and HEP (62 °C), enabling effective energy dissipation over a wide temperature range. Through interlayer property matching and synergistic enhancement, the HIR significantly enhances both abrasion resistance and freeze–thaw durability of hydraulic concrete. Full article

Soil adhesion and abrasive wear severely degrade the performance and service life of soil-covering rollers in no-tillage seeders, particularly in the heavy clay black soil regions of Northeast China. To address the critical issues of soil adhesion and wear on soil-covering rollers used in no-tillage seeders within black soil regions, this study presents a surface engineering strategy that integrates a bionic micro-texture with a functional composite coating. Inspired by the crescent-shaped pits on the body surface of Procambarus clarkii, a bionic texture was designed and combined with a PTFE/PDMS/TiO₂ composite coating. Key parameters were optimized using response surface methodology, yielding a TiO₂ mass fraction of 6%, coating thickness of 40 μm, remaining texture depth of 50 μm, and texture spacing of 250 μm. A prototype was fabricated and evaluated through orthogonal field experiments in two distinct soil environments. In clay soil (15–25% moisture content), soil moisture and vertical load significantly influenced anti-adhesion performance, with recommended operating parameters of 600 N vertical load and a speed range of 10.8–14.4 km·h⁻¹. In sandy soil (8–18% moisture content), vertical load and operating speed had significant effects on wear resistance, with optimal parameters identified as 600 N vertical load and 10.8 km·h⁻¹. Verification tests confirmed stable low-adhesion and low-wear performance under varying moisture conditions. Compared to conventional and PTFE-coated rollers, the bionic roller reduced soil adhesion by 82.62% and 74.02%, respectively, in high-moisture clay soil, and reduced wear loss by 36.81% and 28.97%, respectively, in dry sandy soil. These results demonstrate that the synergistic “structure–material” design, which leverages stress dispersion and storage from the bionic texture alongside low surface energy and enhanced wear resistance from the composite coating, offers a promising approach for improving the durability and performance of soil-engaging agricultural components. Full article

Superhydrophobic coatings are regarded as a promising passive anti-icing strategy; however, their practical engineering application, particularly in electrical insulation, is severely hindered by the performance deterioration caused by mechanical damage and a lack of theoretical understanding of microscopic ice adhesion mechanisms. In this study, a layered polymer composite coating was designed to resolve the trade-off between abrasion resistance and low ice adhesion. The chemistry of the coating relies on a synergistic “primer–topcoat” design: the primer consists of an epoxy resin matrix chemically modified by amino silicone oil to lower its surface energy and improve toughness, while the topcoat features hierarchical SiO₂ clusters functionalized with hexamethyldisilazane (HMDS) and silane coupling agents. This architecture was fabricated via a controllable layer-by-layer spraying method. Systematic investigations revealed that the hierarchical micro/nanostructure, composed of microscale protrusions and nanoscale SiO₂ clusters, provides excellent superhydrophobicity (contact angle of 155.2°, sliding angle of 2°). Crucially, the crosslinked polymer network and stable siloxane (Si-O-Si) covalent bonding ensure that the coating maintains its functionality after a cumulative sand impact of 3 kg, demonstrating superior mechanical durability. Furthermore, differentiated theoretical models for ice adhesion in Cassie–Baxter and Wenzel states were established based on intermolecular interactions, identifying that maintaining a stable Cassie–Baxter state is key to reducing adhesion. This study offers a robust approach to balancing functionality and durability in polymer composites through synergistic structural design, providing both a scalable fabrication strategy and a quantitative theoretical framework for understanding interfacial ice adhesion. Full article

This study evaluated the partial and total replacement of zinc oxide (ZnO) with magnesium oxide (MgO) in styrene–butadiene rubber (SBR) composites, as well as the incorporation of ground tire rubber (GTR), aiming to develop more sustainable elastomer formulations. Ten formulations were prepared with varying ZnO/MgO ratios (100/0 to 0/100), with and without 20 phr of GTR. The composites were characterized by particle size distribution, morphology, rheometric behavior, density, crosslink density, mechanical properties, abrasion resistance, compression behavior, and thermo-oxidative aging. The results showed that hybrid ZnO/MgO activation systems exhibited a synergistic effect, enhancing vulcanization kinetics and mechanical performance compared to single-activator systems. Total replacement of ZnO by MgO was less effective, leading to reduced crosslink density and inferior properties. The addition of GTR increased compound viscosity and altered morphology but improved abrasion and compression resistance without significantly affecting tensile strength. Aging tests indicated good thermal stability, with maintenance or improvement of tensile properties due to post-curing effects. Overall, the combination of reduced ZnO content with MgO and GTR represents a viable approach for producing SBR composites with adequate performance and lower environmental impact. Full article

The development of protective coatings that integrate self-healing and environmental tolerance is vital for extending substrate lifespan. In this study, a multifunctional hydrogel composite coating is developed based on a waterborne polyacrylate dynamic covalent network containing oxime–carbamate bonds. The functional monomer MEOC, which contains an oxime–carbamate dynamic bond, was synthesized and incorporated into the waterborne polyacrylate matrix to form a hydrogel network (OC-PA) with intrinsic self-healing capability. Prussian blue (PB) and nano-SiO₂ were incorporated to form a photothermal functional layer, imparting hydrophobicity and converting light into heat for de-icing, while also activating dynamic bond rearrangement within the substrate. When the MEOC content was 7 wt% and the PB content was 2 wt%, the coating temperature rose to 110 °C within 2 min under 0.6 W/cm² irradiation, and the scratch healed within 5 min. After 1 h of fracture repair, the tensile strength reached 6.68 MPa, with a repair rate as high as 92.91%, and de-icing time was reduced from 343 s to 183 s. The coating achieved a water contact angle >100°. At −20 °C, the icing delay time increased by 215%. The hydrogel coating also exhibited excellent abrasion resistance, chemical stability, UV aging resistance, and anti-fouling properties, offering a durable solution for demanding environments. Full article

CoNiV medium-entropy alloy (MEA) composite coatings reinforced with 40 wt.% tungsten carbide (WC/W₂C) particles were fabricated on carbon steel via laser cladding under nominal heat inputs ranging from 75 to 150 J/mm. The phase constituents and microstructural evolution were investigated, revealing that the coatings were primarily composed of an FCC matrix, retained WC/W₂C particles, and in situ formed V-rich and VWC₂ carbides. While the phase compositions remained generally consistent, the features of the reinforcement architecture varied with the extent of WC/W₂C dissolution governed by laser heat inputs. At low heat inputs, limited particle dissolution yielded sparsely distributed in situ carbides, whereas excessive dissolution at high heat inputs promoted the agglomeration of dense and coarse carbides, driving the microhardness to peak at 570.5 HV_0.5. However, the coating deposited at 150 J/mm exhibited compromised wear resistance due to the fragmentation and detachment of these coarse carbides, which intensified abrasive wear. In contrast, moderate dissolution at intermediate heat input (100 J/mm) facilitated the formation of fine in situ carbides in interparticle regions. This resulted in a homogeneous multiscale synergistic reinforcement microstructure that endowed the coating with optimal wear performance. By precisely controlling heat input to regulate in-situ precipitation, this study established a solid foundation for tailoring wear resistance and expanding the application of composite coatings. Full article

Artificial composite stones have recently attracted attention as multifunctional materials for construction and defense-related applications. In this study, a novel composite stone was developed using waste limestone as the primary mineral filler, combined with an unsaturated polyester resin matrix and reinforced with glass powder and chopped glass fibers. The influence of binder content and reinforcement type on physico-mechanical and microstructural behavior was investigated. Experimental characterization included water absorption, compressive strength, abrasion resistance, acid resistance, and optical microscopy. The results demonstrated that fine fillers improved matrix densification and reduced porosity, while short glass fiber reinforcement enhanced load-bearing capacity. Abrasion resistance and durability were found to depend on binder content and particle packing characteristics. Overall, the developed composite material exhibits promising mechanical performance, low water absorption, and improved durability, suggesting its potential as a candidate material for applications requiring environmental resistance, including potential use in defense-related camouflage applications. Full article

This study examines the effect of tool rotational speed on the microstructure and dry sliding wear behavior of brass–tungsten (brass/W) surface composites fabricated through friction stir processing. Microstructural analysis confirmed a uniform distribution of tungsten particles within the stir zone, with no observable clustering. Improved properties were achieved at a lower traverse speed of 40 mm/min combined with a higher rotational speed of 1168 rpm, which promoted finer grain formation (~4 µm) and better particle dispersion. An increase in rotational speed led to a corresponding rise in hardness, from 142 HV at 832 rpm to 165 HV at 1168 rpm. In terms of wear behavior, the sample processed at lower rotational speed exhibited abrasive and micro-cutting wear, whereas the sample processed at higher rotational speed predominantly showed adhesive wear. Full article

High-entropy alloys (HEAs) are typically produced using high-temperature metallurgical routes; however, alternative synthesis approaches based on wet-chemical processing remain relatively unexplored. In this study, a compositionally complex two-phase AgCuCoNiFe high-entropy alloy was synthesized using a precipitation–reduction strategy involving co-precipitation of mixed metal carbonates followed by thermal reduction in a reducing atmosphere. The objective of the work was to evaluate the feasibility of this hydrometallurgical route for preparing compositionally complex alloys and to investigate the structural evolution of the material as a function of reduction time. Quantitative MP-AES analysis confirmed efficient co-precipitation of all five elements, enabling the preparation of a precursor with near-equimolar metal composition. Structural characterization using SEM, EDS, and XRD revealed the presence of surface compositional heterogeneity in the as-reduced state, characterized by Ag-enriched domains. After controlled surface abrasion, the internal material exhibited significantly more uniform elemental distribution, although the obtained composition was not equimolar. X-ray diffraction patterns showed a transition from multiple sharp reflections at the surface to broadened peaks in the bulk, consistent with enhanced alloying within the bulk compared to the surface, while still revealing a two-phase character. Microhardness measurements indicated moderate hardness with mean values in the range of 187–221 HV with no significant dependence on reduction time, while wettability analysis revealed moderately hydrophilic behavior with contact angles in the range of approximately 75–83°. The results suggest that precipitation–reduction can be a viable alternative route for the synthesis of multicomponent HEAs, enabling the formation of chemically mixed alloy structures without the use of conventional melting-based processing. However, the obtained alloy exhibits incomplete chemical homogeneity, indicating that further optimization of the synthesis conditions is required to achieve a fully uniform composition. Full article

To improve the tribological performance of 40Cr steel, a biomimetic composite micro-texture consisting of sinusoidal grooves and circular dimples was designed based on the periodic corrugated structures on the shell surface of Fimbria fimbriata. The texture parameter ranges were determined through microscopic characterization of the shell surface and orthogonal design. The composite micro-textures were fabricated on 40Cr steel by femtosecond laser processing and characterized by confocal microscopy, white light interferometry (WLI), and scanning electron microscopy (SEM). Their tribological behavior was evaluated under oil-lubricated reciprocating sliding conditions against a GCr15 counter-body in a ball-on-flat contact configuration. The results showed that laser power significantly affected the forming quality of the sinusoidal textures, and 4.50 W provided the best overall cross-sectional morphology. All textured specimens exhibited lower steady-state average coefficients of friction (COF) than the untextured specimen, with the textured groups ranging from 0.1678 to 0.1905. Among them, specimen L6 showed the lowest steady-state average COF of 0.1678, corresponding to a reduction of approximately 19.4%, together with the best wear resistance as indicated by the relative displacement volume ratio (K_w). Surface analyses revealed that abrasive wear and adhesive wear were the dominant wear mechanisms, while the optimized composite micro-texture effectively suppressed wear-groove development, material pile-up, and transfer-layer formation. Overall, the biomimetic sinusoidal-circular composite micro-texture effectively improved the tribological performance of 40Cr steel under oil lubrication through the synergistic effects of contact-state regulation, lubricant retention, and wear-debris capture. This study provides theoretical and experimental support for the engineering application of biomimetic composite micro-textures on mechanical surfaces. Full article

This study investigates the influence of design factors and key process parameters—including explosive welding (EXW), rolling, and laser processing—on the formation, microstructure, and tribological properties of Ti–Cu–Ni intermetallic coatings. A combined manufacturing approach was employed, starting with the EXW of an MN19 cupronickel alloy to a VT1-0 titanium substrate, followed by multi-pass rolling to achieve a cladding thickness of approximately 0.3 mm. Subsequently, laser surface remelting was performed to facilitate controlled mass transfer and homogenization within the reaction zone. Numerical simulation using COMSOL Multiphysics v. 5.4 was utilized to optimize the thermal cycles and determine the ideal energy density (42 J/mm²) for phase formation. The results demonstrate that the primary structural components of the coatings produced under optimal conditions are solid solutions based on the ternary-modified titanium cuprides Ti₂Cu(Ni) and TiCu(Ni). The transition from a layered bimetal to a finely dispersed intermetallic structure significantly enhances the surface characteristics. This specific phase composition provides a sustained microhardness of ~5 GPa across the coating cross-section. Comparative wear tests against fixed abrasive revealed that the wear resistance of the Ti–Cu–Ni coatings is 2.5 times higher at room temperature and 1.5 times higher at 600 °C than that of the base VT1-0 titanium. Full article

In this work, the tribological and corrosion behavior of commercially pure titanium—Ti-Gr2 with coatings obtained by mechanized contactless local electrospark deposition (LESD) with low pulse energy and a rotating electrode of TiB₂-TiAl reinforced with ZrO₂ and NbC nanoparticles was investigated. The current research is driven by the need for improved corrosion and abrasion resistance of titanium surfaces in automotive components, shipbuilding, aerospace, petrochemical and many other industrial and domestic areas. This work is a continuation of our previous study, in which the dependences of the relief, roughness, thickness, microhardness, composition and structure of the coatings obtained with this electrode on the electrical parameters of the LESD mode were studied and analyzed. In this work, the influence of the pulse parameters of the LESD process (respectively, roughness, thickness, composition and structure of the coatings) on the tribological and corrosion characteristics of the coatings has been investigated and the possibility of simultaneous protection of titanium surfaces from wear and corrosion has been demonstrated. Coatings containing nanocrystalline and amorphous-like structures have been formed, with synthesized new compounds and phases, and with increased hardness up to 13 GPa, low roughness Ra = 1.5–3 μm, thickness 8–20 μm and minimal structural defects. By comparing the potentiodynamic polarization curves, polarization resistance, electrochemical impedance and tribological characteristics of the coated surfaces, it has been established that their corrosion resistance increases by more than 1–2 orders of magnitude and their wear resistance during friction increases by 4–5 times compared to those of the substrate. Appropriate values of the electrical parameters of the LESD mode are presented, which allow obtaining uniform coatings with reduced roughness and structural defects, with predictable thickness, roughness and hardness, and with maximized corrosion and abrasive wear resistance to allow for uniform coatings with reduced roughness and structural defects, with predictable thickness, roughness and hardness, and with maximized corrosion and abrasive wear resistance. Full article

Durability of clay-based mixes is often considered a limitation for their use in modern construction projects, especially in those involving additive manufacturing techniques. This study focuses on developing sustainable extrudable cob mixes and investigating the effect of sand particle grading, curing regime and mix composition on compressive strength, flexural strength, stress–strain response, capillary water absorption, wetting-drying cycles effect, and abrasion resistance. Results showed a significant positive impact of fine-sized sand addition into the mix on the mechanical strength and durability, due to better compaction and denser final cob mixes. Extending oven curing improves the compressive and flexural strength of all mixes due to the accelerated strength development from the higher temperature exposure. Lastly, the addition of high clay content allows for improving the compressive and flexural strength at prolonged curing aging under normal air-drying conditions. These mixes also exhibit low water absorption. Conversely, results revealed that the lime content plays a crucial role in reducing surface wear, with lime-rich mixes exhibiting lower erosion rates than the other mixes. Lime-stabilized cob mixes also demonstrate improved durability under cyclic wetting and drying. Full article

Tree contact discharge is a key contributing factor to wildfires caused by medium-voltage insulated conductors. Prolonged abrasion of the insulation layer by branches gradually creates weak points in the insulation. When subjected to lightning strikes, these areas are prone to forming lightning-induced pinholes, which can subsequently trigger partial discharge and even ignition. This study systematically investigates the discharge-induced ignition mechanism for 10 kV overhead insulated conductors in tree contact scenarios by establishing an experimental platform integrated with high-speed imaging, ultraviolet detection, and simulation methods. Three types of typical defects were set up in the experiments: complete insulation abrasion, lightning puncture holes accompanied by localized abrasion, and lightning puncture holes without abrasion. The development process and characteristics of different discharge forms were observed and analyzed. The results indicate that the tree contact discharge ignition mechanism can be categorized into two types: thermal accumulation and direct arcing. The former occurs when insulation abrasion or composite defects exist, where sustained partial discharge or a high-resistance current leads to gradual heat accumulation, resulting in an ignition delay lasting tens of seconds. The latter occurs when only small defects such as lightning puncture holes exist in the insulation layer. A concentrated arc forms due to gap breakdown under high voltage, leading to a millisecond-level ignition process. The study found that different discharge forms produce significantly distinct ablation and carbonization patterns on both the insulation layer and the branch surface, reflecting differences in energy transfer pathways. Simulation analysis further indicated that the thickness of the insulation layer affects the electric field distribution in the tree contact gap, with the initial discharge field strength decreasing as the thickness increases. This study provides experimental evidence and classification guidance for tree contact fault monitoring, insulation condition assessment, and wildfire prevention and control in medium-voltage distribution networks. Full article