Search Results (19)

Ultra-tight gas reservoirs present severe flow constraints due to complex interactions between rock–fluid properties and hydraulic fracturing. This study investigates the impact of unconventional capillary pressure correlations and permeability jail effects on post-fracture cleanup in multiple-fractured horizontal wells (MFHWs) using high-resolution numerical simulations. A novel modelling approach is applied to represent both weak and strong permeability jail phenomena in heterogeneous rock systems. A comprehensive suite of parametric simulations evaluates gas production loss (GPL) and produced fracture fluid (PFF) across varying fracture fluid volumes, shut-in times, drawdown pressures, and matrix permeabilities. The analysis leverages statistically designed experiments and response surface models to isolate the influence of rock heterogeneity and saturation-dependent flow restrictions on cleanup efficiency. The results reveal that strong jail zones drastically hinder fracture fluid recovery, while weak jail configurations interact with heterogeneity to produce non-linear cleanup trends. Notably, reducing the pore size distribution index in Pc models improves predictive accuracy for ultra-tight conditions. These findings underscore the need to integrate unconventional Kr and Pc behaviour in hydraulic fracturing design to optimise flowback and long-term gas recovery. This work provides critical insights for improving reservoir performance and supports ambitions in energy resilience and net-zero transition strategies. Full article

Wireline formation fluid sampling is extensively utilized to acquire downhole fluid samples. Due to mud filtrate invasion, enough time is required to pump out the formation fluid so that an acceptable level of contaminant is reached. Excessive cleanup time would increase costs and the risk of the testing tool becoming stuck within the drilling mud. The challenge lies in deciding what type of formation-tester probe should be used to ensure minimally contaminated measurements for a specific tool configuration and when the withdrawal sample is sufficiently purged of contaminants. A numerical simulator to simulate the virgin formation fluid sampling was developed, and the accuracy of the simulator was validated based on the spherical flow theory. Through running 2515 simulation cases, the effects of various operational and formation conditions on the breakthrough and pumpout times with three different probes (i.e., the standard probe, the elliptical probe, the elongated probe, and their corresponding 3D radial probes) were compared and analyzed quantitatively. We numerically investigated the key factors influencing the breakthrough and pumpout times and delved into the impact of the formation anisotropy. This study reveals the parameters that encompass the first-order effect on the breakthrough and pumpout times, enabling the determination of the probe-type selection and the early predictions of pumpout time. By leveraging these insights, sampling operations can be optimized to enhance sample quality, reduce operational time, and mitigate the risks associated with tool entrapment. Full article

This study delves into the complexities of fluid cleanup processes post-hydraulic fracturing in unconventional gas deposits, focusing on the pivotal role of capillary pressure (P_c) correlations in tight and ultra-tight formations. Utilising Geo2Flow software, this research evaluates the efficacy of existing P_c models, identifying the Brooks and Corey model as notably precise for these formations, albeit recommending an adjustment to the pore size distribution index for a more accurate representation of rock behaviours. Further investigation centres on the cleanup process in multiple fractured horizontal wells, examining the impact of the P_c, matrix permeability, drawdown pressure, and fracturing fluid volume. A significant portion of this study addresses the influence of interfacial tension-reducing chemicals on post-fracturing production, highlighting their utility in ultra-tight formations, but advising against their use in tight formations due to environmental concerns and limited efficacy. The findings underscore the nuanced interplay between geological parameters and fracturing fluid dynamics, advocating for tailored fluid cleanup strategies that enhance the hydraulic fracturing efficiency while minimising the environmental impact. This comprehensive analysis offers valuable insights into optimising fracture cleanup and understanding the underlying physics, thereby contributing to more effective hydraulic fracturing practices. Full article

Due to their ease of collecting and transporting from the field and their ability to accumulate pollutants, bird feathers are increasingly being used as a non-invasive biomonitoring tool for environmental monitoring programs. Polycyclic aromatic compounds (PACs) are a diverse class of environmental pollutants, and because of their deleterious impacts on biological species, monitoring these compounds in wildlife is of high importance. Current approaches to measuring PACs in bird feathers involve a time-consuming acid treatment with a concomitant solvent extraction step. Here, a validated method for measuring a suite of PACs in bird feathers using pressurized fluid extraction and identification and quantitation by gas chromatography-tandem mass spectrometry is presented. Chicken (Gallus domesticus) feathers were purposely fortified with a suite of 34 PACs separately at three fortification levels and placed inside a pressurized fluid extraction cell containing silica gel/deactivated alumina to provide in situ clean-up of the sample. Except for anthracene and naphthalene, the accuracy of our method ranged for PAHs from 70–120% (irrespective of fortification level), and our intra- and inter-day repeatability was smaller than 28%. For APAHs, our accuracies ranged from 38–158%, and the inter- and intra-day repeatability was less than 35%. Our limits of detection and quantitation for both groups of compounds ranged from 0.5–13 and 1.5–44.3 ng/g, respectively. Overall, the developed method represents an effective and efficient approach for the extraction and quantitation of PACs from bird feathers that negated the need for the time-consuming and potentially harmful acid treatment. Full article

Aflatoxins (AFs) frequently contaminate food and animal feeds, especially in (sub) tropical countries. If animals consume contaminated feeds, AFs (mainly aflatoxin B1 (AFB1), B2 (AFB2), G1 (AFG1), G2 (AFG2) and their major metabolites aflatoxin M1 (AFM1) and M2 (AFM2)) can be transferred to edible tissues and products, such as eggs, liver and muscle tissue and milk, which ultimately can reach the human food chain. Currently, the European Union has established a maximum level for AFM1 in milk (0.05 µg kg⁻¹). Dietary adsorbents, such as bentonite clay, have been used to reduce AFs exposure in animal husbandry and carry over to edible tissues and products. To investigate the efficacy of adding bentonite clay to animal diets in reducing the concentration of AFB1, AFB2, AFG1, AFG2, and the metabolites AFM1 and AFM2 in animal-derived foods (chicken muscle and liver, eggs, and cattle milk), chicken and cattle plasma and cattle ruminal fluid, a sensitive and selective ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) method has been developed. High-throughput sample preparation procedures were optimized, allowing the analysis of 96 samples per analytical batch and consisted of a liquid extraction using 1% formic acid in acetonitrile, followed by a further clean-up using QuEChERS (muscle tissue), QuEChERS in combination with Oasis^® Ostro (liver tissue), Oasis^® Ostro (egg, plasma), and Oasis^® PRiME HLB (milk, ruminal fluid). The different procedures were validated in accordance with European guidelines. As a proof-of-concept, the final methods were used to successfully determine AFs concentrations in chicken and cattle samples collected during feeding trials for efficacy and safety evaluation of mycotoxin detoxifiers to protect against AFs as well as their carry-over to animal products. Full article

An oil spill accident will cause serious harm to marine ecology and the environment. Rapid response and effective prevention methods are required to minimize the damage of oil spill accidents. The critical problems that marine emergency rescue teams face are when the spilled oil reaches the sea surface, the extent of the spilled oil, and how far they are from the drilling platform. However, there is no reliable model to predict the diffusion distance of spilled oil. Accurately predicting the diffusion characteristics of underwater spilled oil can provide timely and accurate information for the treatment of oil spill accidents and guide the correct implementation of emergency treatment. In this paper, the computational fluid dynamics (CFD) method was used to establish a two-phase flow model for the diffusion of a submarine oil spill. The volume-of-fluid (VOF) technique was implemented to track the interface between oil–water phases. The effects of different parameters on leakage and diffusion characteristics were investigated by adjusting spilled oil velocity, ocean current velocity, crude oil density, and crude oil viscosity. The logarithmic velocity profile was adopted for ocean currents to conform to the actual flow near the sea surface. A user-defined function (UDF) was developed and applied for CFD modeling. The focus was on analyzing the diffusion range (rising height H_p and lateral migration distance W_p) from full-field data. The results indicate that the oil spill velocity, ocean current velocity, crude oil density, and crude oil viscosity impact the viscous shear force, the oil spill’s inertia force, and the current shear effect. The formula for calculating the lateral migration distance of spilled oil under different working conditions was obtained by fitting. The results of this study can provide a scientific basis for formulating an emergency treatment plan for offshore oil spill accidents and minimizing the harm to marine ecology and the environment. Full article

Alcoholic beverages contaminated with scopolamine (SCP) are often employed for criminal purposes due to their sedative effect. The determination of the residual levels of SCP in body fluids (e.g., urine) can help to track possible victims of induced ingestions. Biological sample analysis usually requires a preconcentration step to enhance their detectability and to provide sample clean-up. Molecularly imprinted polymers (MIPs) in lieu of conventional solid sorbents represent an enhancement of selectivity, due to their specific recognition sites. Additionally, the adaptation of the solid-phase extraction (SPE) cartridge into a disposable pipette tip extraction (DPX) contributes to the miniaturization of the sample preparation step. Herein, an analytical method for the determination of SCP in synthetic urine samples via the integration of molecularly imprinted solid-phase extraction (MISPE) with DPX as a preconcentration step prior to capillary electrophoresis analysis (also known as MISPE-DPX-CE) is presented. The extraction and elution steps were optimized using a factorial design. Using the optimized conditions, a preconcentration factor of 20 was obtained, leading to a working range of 0.5–6 µM with LOD of 0.04 µM and repeatability of 6.4% (n = 7) and adequate recovery values (84 and 101%) The proposed MISPE-DPX-CE approach was successfully applied to selective extraction, preconcentration, and determination of SCP in synthetic urine samples. Full article

Currently, volume fracturing of horizontal wells is the main technology for shale oil development. A large amount of fracturing fluid is injected into the formation, but the flowback efficiency is very low. Besides, the impact of fluid retention on productivity is not fully clear. There is still a debate about fast-back or slow-back after fracturing, and the formulation of a reasonable cleanup scheme is lacking a theoretical basis. To illustrate the injected-fluid recovery and production performance of shale oil wells, an integrated workflow involving a complex fracture model and oil-water production simulation was presented, enabling a confident history match of flowback data. Then, the impacts of pumping rate, slick water ratio, cluster spacing, stage spacing and flowback rate were quantitatively analyzed. The results show that the pumping rate is negatively correlated with injected-fluid recovery, but positively correlated with oil production. A high ratio of slick water would induce a quite complex fracture configuration, resulting in a rather low flowback efficiency. Meanwhile, the overall conductivity of the fracture networks would also be reduced, as well as the productivity, which indicates that there is an optimal ratio for hybrid fracturing fluid. Due to the fracture interference, the design of stage or cluster spacing is not the smaller the better, and needs to be combined with the actual reservoir conditions. In addition, the short-term flowback efficiency and oil production increase with the flowback rate. However, considering the damage of pressure sensitivity to long-term production, a slow-back mode should be adopted for shale oil wells. The study results may provide support for the design of a fracturing scheme and the optimization of the flowback schedule for shale oil reservoirs. Full article

Chiral pesticides with S atoms as asymmetric centers are gaining great importance in the search for new pesticides with new modes of action. As for the rest of the chiral pesticides, the determination of the stereoisomers separately has become crucial in the environmental risks assessment of these pesticides. Therefore, the development of suitable extraction and clean-up methods as well as efficient stereoselective analytical techniques for stereoisomers determination in environmental samples is essential. Currently, liquid/solid phase extraction, microextraction, and QuEChERS-based methods are most commonly used to obtain chiral pesticides from environmental samples. Gas, liquid, and supercritical fluid chromatography together with capillary electrophoresis techniques are the most important for the determination of the stereoisomers of chiral pesticides containing S atoms in its structure. In this study, all these techniques are briefly reviewed, and the advantages and disadvantages of each are discussed. Full article

The process of well cleanup involves the removal of an impermeable layer of filter cake from the face of the formation. The inefficient removal of the filter cake imposes difficulty on fracturing operations. Filter cake’s impermeable features increase the required pressure to fracture the formation. In this study, a novel method is introduced to reduce the required breakdown pressure to fracture the formation containing the water-based drilling fluid filter cake. The breakdown pressure was tested for five samples of similar properties using different solutions. A simulated borehole was drilled in the core samples. An impermeable filter cake using barite-weighted drilling fluid was built on the face of the drilled hole of each sample. The breakdown pressure for the virgin sample without damage (filter cake) was 6.9 MPa. The breakdown pressure increased to 26.7 MPa after the formation of an impermeable filter cake. Partial removal of filter cake by chelating agent reduced the breakdown pressure to 17.9 MPa. Complete dissolution of the filter cake with chelating agents resulted in the breakdown pressure approximately equivalent to the virgin rock breakdown pressure, i.e., 6.8 MPa. The combined thermochemical and chelating agent solution removed the filter cake and reduced the breakdown pressure to 3.8 MPa. Post-treatment analysis was carried out using nuclear magnetic resonance (NMR) and scratch test. NMR showed the pore size redistributions with good communication between different pores after the thermochemical removal of filter cake. At the same time, there was no communication between the different pores due to permeability impairment after filter cake formation. The diffusion coupling through NMR scans confirmed the higher interconnectivity between different pores systems after the combined thermochemical and chelating agent treatment. Compressive strength was measured from the scratch test, confirming that filter cake formation caused added strength to the rock that impacts the rock breakdown pressure. The average compressive strength of the original specimen was 44.5 MPa that increased to 73.5 MPa after the formation of filter cake. When the filter cake was partially removed, the strength was reduced to 61.7 MPa. Complete removal with chelating agents removed the extra strength that was added due to the filter cake presence. Thermochemical and chelating agents resulted in a significantly lower compressive strength of 25.3 MPa. A numerical model was created to observe the reduction in breakdown pressure due to the thermochemical treatment of the filter cake. The result presented in this study showed the engineering applications of thermochemical treatment for filter cake removal. Full article

Studies of the effects produced by the solubilization of hydrophobic substances by micellar aggregates in water medium are quite important for applications of viscoelastic surfactant solutions for enhanced oil recovery (EOR), especially in hydraulic fracturing technology. The present paper aims at the investigation of the structural transformations produced by the absorption of an aliphatic hydrocarbon (n-decane) by mixed wormlike micelles of cationic (n-octyltrimethylammonium bromide, C8TAB) and anionic (potassium oleate) surfactants enriched by C8TAB. As a result of contact with a small amount (0.5 wt%) of oil, a highly viscoelastic fluid is transformed to a water-like liquid. By small-angle neutron scattering (SANS) combined with cryo-TEM, it was shown that this is due to the transition of long wormlike micelles with elliptical cross-sections to ellipsoidal microemulsion droplets. The non-spherical shape was attributed to partial segregation of longer- and shorter-tail surfactant molecules inside the surfactant monolayer, providing an optimum curvature for both of them. As a result, the long-chain surfactant could preferably be located in the flatter part of the aggregates and the short-chain surfactant—at the ellipsoid edges with higher curvature. It is proven that the transition proceeds via a co-existence of microemulsion droplets and wormlike micelles, and upon the increase of hydrocarbon content, the size and volume fraction of ellipsoidal microemulsion droplets increase. The internal structure of the droplets was revealed by contrast variation SANS, and it was shown that, despite the excess of the cationic surfactant, the radius of surfactant shell is controlled by the anionic surfactant with longer tail. These findings open a way for optimizing the performance of viscoelastic surfactant fluids by regulating both the mechanical properties of the fluids and their clean-up from the fracture induced by contact with hydrocarbons. Full article

Hydraulic fracturing using water-soluble polymers has been extensively used to enhance the productivity of oil and gas wells. However, the production enhancement can be significantly impaired due to polymer residue generated within the proppant pack in the created fractures. This work describes an approach to establish a suitable fracturing fluid cleanup process by characterizing broken polymer residues generated from the use of different gel breaker types. Commonly used gel breakers such as inorganic oxidizers (bromate and persulfate salts), specific enzymes, and acids were evaluated in this work. The influence of each gel breaker was examined using High-Pressure/High-Temperature (HP/HT) rheometer, aging cells, zeta potential, Gel Permeation Chromatography (GPC), and Environmental Scanning Electron Microscope/Energy Dispersive X-ray Spectroscopy (ESEM/EDS). Experiments were performed on a carboxymethylhydroxypropyl guar (CMHPG) fracturing fluid at temperatures up to 300 °F. The developed GPC methodology showed that the size of the broken polymer chains was mainly dependent on the type of gel breakers used. Moreover, laboratory tests have revealed that some gel breakers may negatively influence the performance of polymeric clay stabilizers. Additionally, this work showed damaging precipitations that can be generated due to the interactions of gel breakers with H₂S. Full article

Oil well cleanup fluids (pre-flushes) are intermediate fluids pumped ahead of the cement slurry; they are able to clean the well walls by removing the filter cake formed by the drilling fluid, and leave the surface water-wet. This work’s main objective was to use biodegradable microemulsion systems as cleanup fluids in order to reduce the environmental impact. Three microemulsion systems were formulated, each composed of an oil phase, a surfactant and three different aqueous phases: glycerol, glycerol:water (mass ratio 1:1), and fresh water. The results show that all microemulsion systems were effective with 100% filter cake removal, with a removal time of less than 60 s. The wettability test and fluid compatibility analyses exhibited advantageous performances, without phase separation, variations in viscosity, gelation, or flocculation. The compressive strength and X-ray diffractometry (XRD) analysis showed the influence of the glycerol on the cement slurry properties, with the compressive strength resistance ranging from 8.0 to 10.7 MPa, and resulted in the formation of portlandite. Full article

As a class of mycotoxins with regulatory and public health significance, aflatoxins (e.g., aflatoxin B₁, B₂, G₁ and G₂) have attracted unparalleled attention from government, academia and industry due to their chronic and acute toxicity. Aflatoxins are secondary metabolites of various Aspergillus species, which are ubiquitous in the environment and can grow on a variety of crops whereby accumulation is impacted by climate influences. Consumption of foods and feeds contaminated by aflatoxins are hazardous to human and animal health, hence the detection and quantification of aflatoxins in foods and feeds is a priority from the viewpoint of food safety. Since the first purification and identification of aflatoxins from feeds in the 1960s, there have been continuous efforts to develop sensitive and rapid methods for the determination of aflatoxins. This review aims to provide a comprehensive overview on advances in aflatoxins analysis and highlights the importance of sample pretreatments, homogenization and various cleanup strategies used in the determination of aflatoxins. The use of liquid-liquid extraction (LLE), supercritical fluid extraction (SFE), solid phase extraction (SPE) and immunoaffinity column clean-up (IAC) and dilute and shoot for enhancing extraction efficiency and clean-up are discussed. Furthermore, the analytical techniques such as gas chromatography (GC), liquid chromatography (LC), mass spectrometry (MS), capillary electrophoresis (CE) and thin-layer chromatography (TLC) are compared in terms of identification, quantitation and throughput. Lastly, with the emergence of new techniques, the review culminates with prospects of promising technologies for aflatoxin analysis in the foreseeable future. Full article

Until now, the available data regarding citrinin (CIT) levels in food and the consumption of contaminated foods are insufficient to allow a reliable estimate of intake. Therefore, biomonitoring configuring analysis of parent compound and/or metabolites in biological fluids, such as urine or blood, is being increasingly applied in the assessment of human exposure to CIT and its metabolite, dihydrocitrinone (DH-CIT). Most studies report urinary levels lower for the parent compound when compared with DH-CIT. A high variability either in the mean levels or in the inter-individual ratios of CIT/DH-CIT between the reported studies has been found. Levels of DH-CIT in urine were reported as being comprised between three to seventeen times higher than the parent mycotoxin. In order to comply with this objective, sensitive analytical methodologies for determining biomarkers of exposure are required. Recent development of powerful analytical techniques, namely liquid chromatography coupled to mass spectrometry (LC-MS/MS) and ultra-high-performance liquid chromatography (UHPLC-MS/MS) have facilitated biomonitoring studies, mainly in urine samples. In the present work, evidence on human exposure to CIT through its occurrence and its metabolite, in biological fluids, urine and blood/plasma, in different countries, is reviewed. The analytical methodologies usually employed to evaluate trace quantities of these two molecules, are also presented. In this sense, relevant data on sampling (size and pre-treatment), extraction, cleanup and detection and quantification techniques and respective chromatographic conditions, as well as the analytical performance, are evidenced. Full article