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Search Results (524)

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Keywords = circular design strategies

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26 pages, 2995 KiB  
Article
A New High-Efficiency Fertilization System from Waste Materials for Soil Protection: Material Engineering, Chemical-Physical Characterization, Antibacterial and Agronomic Performances
by Martina Napolitano, Gianluca Malavasi, Daniele Malferrari, Giulio Galamini, Michelina Catauro, Veronica Viola, Fabrizio Marani and Luisa Barbieri
Materials 2025, 18(15), 3492; https://doi.org/10.3390/ma18153492 - 25 Jul 2025
Viewed by 221
Abstract
The development of slow-release fertilizers (SRFs) based on production residues is a promising strategy to improve nutrient use efficiency and promote circular economy practices in agriculture. In this study, a series of experimental formulations were designed and tested using pumice scraps, liquid and [...] Read more.
The development of slow-release fertilizers (SRFs) based on production residues is a promising strategy to improve nutrient use efficiency and promote circular economy practices in agriculture. In this study, a series of experimental formulations were designed and tested using pumice scraps, liquid and dried blood, and bone meal, aiming at producing sustainable and low-cost N-P-K SRFs. These were processed through mixing and granulation, both in the laboratory and on a semi-industrial scale. The formulations were evaluated through release tests in 2% citric acid solution simulating the acidic conditions of the rhizosphere, and in acetic acid to assess potential nutrient leaching under acid rain conditions. The results showed a progressive cumulative release of macronutrients (NPKs), ranging from approximately 8% at 24 h to 73% after 90 days for the most effective formulation (WBF6). Agronomic trials on lettuce confirmed the effectiveness of WBF6, resulting in significant biomass increases compared with both the untreated control and a conventional fertilizer. The use of livestock waste and minerals facilitated the development of a scalable product aligned with the principles of sustainable agriculture. The observed release behavior, combined with the simplicity of production, positions these formulations as a promising alternative to conventional slow-release fertilizers. Full article
(This article belongs to the Section Green Materials)
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29 pages, 2251 KiB  
Article
Embedding Circular Operations in Manufacturing: A Conceptual Model for Operational Sustainability and Resource Efficiency
by Antonius Setyadi, Suharno Pawirosumarto and Alana Damaris
Sustainability 2025, 17(15), 6737; https://doi.org/10.3390/su17156737 - 24 Jul 2025
Viewed by 248
Abstract
In response to growing environmental pressures and material constraints, circular economy principles are gaining traction across manufacturing sectors. However, most existing frameworks emphasize design and supply chain considerations, with limited focus on how circularity can be operationalized within internal manufacturing systems. This paper [...] Read more.
In response to growing environmental pressures and material constraints, circular economy principles are gaining traction across manufacturing sectors. However, most existing frameworks emphasize design and supply chain considerations, with limited focus on how circularity can be operationalized within internal manufacturing systems. This paper proposes a conceptual model that embeds circular operations at the core of production strategy. Grounded in circular economy theory, operations management, and socio-technical systems thinking, the model identifies four key operational pillars: circular input management, looping process and waste valorization, product-life extension, and reverse logistics. These are supported by enabling factors—digital infrastructure, organizational culture, and leadership—and mediated by operational flexibility, which facilitates adaptive, closed-loop performance. The model aims to align internal processes with long-term sustainability outcomes, specifically resource efficiency and operational resilience. Practical implications are outlined for resource-intensive industries such as automotive, electronics, and FMCG, along with a readiness assessment framework for guiding implementation. This study offers a pathway for future empirical research and policy development by integrating circular logic into the structural and behavioral dimensions of operations. The model contributes to advancing the Sustainable Development Goals (SDGs), particularly SDG 9 and SDG 12, by positioning circularity as a regenerative operational strategy rather than a peripheral initiative. Full article
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32 pages, 858 KiB  
Review
Designing Sustainable and Acoustically Optimized Dental Spaces: A Comprehensive Review of Soundscapes in Dental Office Environments
by Maria Antoniadou, Eleni Ioanna Tzaferi and Christina Antoniadou
Appl. Sci. 2025, 15(15), 8167; https://doi.org/10.3390/app15158167 - 23 Jul 2025
Viewed by 249
Abstract
The acoustic environment of dental clinics plays a critical role in shaping patient experience, staff performance, and overall clinical effectiveness. This comprehensive review, supported by systematic search procedures, investigates how soundscapes in dental settings influence psychological, physiological, and operational outcomes. A total of [...] Read more.
The acoustic environment of dental clinics plays a critical role in shaping patient experience, staff performance, and overall clinical effectiveness. This comprehensive review, supported by systematic search procedures, investigates how soundscapes in dental settings influence psychological, physiological, and operational outcomes. A total of 60 peer-reviewed studies were analyzed across dental, healthcare, architectural, and environmental psychology disciplines. Findings indicate that mechanical noise from dental instruments, ambient reverberation, and inadequate acoustic zoning contribute significantly to patient anxiety and professional fatigue. The review identifies emerging strategies for acoustic optimization, including biophilic and sustainable design principles, sound-masking systems, and adaptive sound environments informed by artificial intelligence. Special attention is given to the integration of lean management and circular economy practices for sustainable dental architecture. A design checklist and practical framework are proposed for use by dental professionals, architects, and healthcare planners. Although limited by the predominance of observational studies and geographic bias in the existing literature, this review offers a comprehensive, interdisciplinary synthesis. It highlights the need for future clinical trials, real-time acoustic assessments, and participatory co-design methods to enhance acoustic quality in dental settings. Overall, the study positions sound design as a foundational element in creating patient-centered, ecologically responsible dental environments. Full article
(This article belongs to the Special Issue Soundscapes in Architecture and Urban Planning)
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23 pages, 1958 KiB  
Article
A Comparative Life Cycle Assessment of End-of-Life Scenarios for Light Electric Vehicles: A Case Study of an Electric Moped
by Santiago Eduardo, Erik Alexander Recklies, Malina Nikolic and Semih Severengiz
Sustainability 2025, 17(15), 6681; https://doi.org/10.3390/su17156681 - 22 Jul 2025
Viewed by 288
Abstract
This study analyses the greenhouse gas reduction potential of different end-of-life (EoL) strategies based on a case study of light electric vehicles (LEVs). Using a shared electric moped scooter as a reference, four EoL scenarios are evaluated in a comparative life cycle assessment [...] Read more.
This study analyses the greenhouse gas reduction potential of different end-of-life (EoL) strategies based on a case study of light electric vehicles (LEVs). Using a shared electric moped scooter as a reference, four EoL scenarios are evaluated in a comparative life cycle assessment (LCA). The modelling of the scenarios combines different R-strategies (e.g., recycling, reusing, and repurposing) regarding both the vehicle itself and the battery. German and EU regulations for vehicle and battery disposal are incorporated, as well as EU directives such as the Battery Product Pass. The global warming potential (GWP100) of the production and EoL life cycle stages ranges from 644 to 1025 kg CO2 eq among the four analysed scenarios. Landfill treatment led to the highest GWP100, with 1.47 times higher emissions than those of the base scenario (status quo treatment following EU directives), while increasing component reuse and repurposing the battery cells achieved GWP100 reductions of 2.8% and 7.8%, respectively. Overall, the importance of implementing sustainable EoL strategies for LEVs is apparent. To achieve this, a product design that facilitates EoL material and component separation is essential as well as the development of political and economic frameworks. This paper promotes enhancing the circularity of LEVs by combining the LCA of EoL strategies with eco-design considerations. Full article
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35 pages, 1469 KiB  
Article
Enhancing Sustainable Innovations in Intelligent Wood Pellets Through Smart Customized Furniture and Total Quality Management
by Hsu-Hua Lee and Chin-Mao Hsu
Sustainability 2025, 17(14), 6604; https://doi.org/10.3390/su17146604 - 19 Jul 2025
Viewed by 301
Abstract
This study aimed to enhance sustainable innovations in intelligent wood pellets by integrating smart customized furniture design with Total Quality Management (TQM) principles. Through qualitative interviews with manufacturers and the application of lean production frameworks, the research explored how sustainability-driven customization can lead [...] Read more.
This study aimed to enhance sustainable innovations in intelligent wood pellets by integrating smart customized furniture design with Total Quality Management (TQM) principles. Through qualitative interviews with manufacturers and the application of lean production frameworks, the research explored how sustainability-driven customization can lead to optimized resource usage, reduced environmental impact, and increased market competitiveness. While the study was exploratory and limited in sample size, it provided practical insights for green manufacturing strategies and product differentiation in circular economies. Full article
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31 pages, 1708 KiB  
Systematic Review
Circular Economy and Water Sustainability: Systematic Review of Water Management Technologies and Strategies (2018–2024)
by Gary Christiam Farfán Chilicaus, Luis Edgardo Cruz Salinas, Pedro Manuel Silva León, Danny Alonso Lizarzaburu Aguinaga, Persi Vera Zelada, Luis Alberto Vera Zelada, Elmer Ovidio Luque Luque, Rolando Licapa Redolfo and Emma Verónica Ramos Farroñán
Sustainability 2025, 17(14), 6544; https://doi.org/10.3390/su17146544 - 17 Jul 2025
Viewed by 318
Abstract
The transition toward a circular water economy addresses accelerating water scarcity and pollution. A PRISMA-2020 systematic review of 50 peer-reviewed articles (January 2018–April 2024) mapped current technologies and management strategies, seeking patterns, barriers, and critical bottlenecks. Bibliometric analysis revealed the following three dominant [...] Read more.
The transition toward a circular water economy addresses accelerating water scarcity and pollution. A PRISMA-2020 systematic review of 50 peer-reviewed articles (January 2018–April 2024) mapped current technologies and management strategies, seeking patterns, barriers, and critical bottlenecks. Bibliometric analysis revealed the following three dominant patterns: (i) rapid diffusion of membrane bioreactors, constructed wetlands, and advanced oxidation processes; (ii) research geographically concentrated in Asia and the European Union; (iii) industry’s marked preference for by-product valorization. Key barriers—high energy costs, fragmented regulatory frameworks, and low social acceptance—converge as critical constraints during scale-up. The following three practical action lines emerge: (1) adopt progressive tariffs and targeted tax credits that internalize environmental externalities; (2) harmonize water-reuse regulations with comparable circularity metrics; (3) create multi-actor platforms that co-design projects, boosting local legitimacy. These findings provide policymakers and water-sector practitioners with a clear roadmap for accelerating Sustainable Development Goals 6, 9, and 12 through circular, inclusive, low-carbon water systems. Full article
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23 pages, 20067 KiB  
Article
On-Site Construction and Experimental Study of Prefabricated High-Strength Thin Concrete Segment Liners for the Reinforcement of Underground Box Culverts
by Shi-Qing Wang, Yanpo Bai, Hongwen Gu, Ning Zhao and Xu-Yang Cao
Buildings 2025, 15(14), 2509; https://doi.org/10.3390/buildings15142509 - 17 Jul 2025
Viewed by 240
Abstract
Conventional trenchless pipeline rehabilitation technologies are primarily designed for circular pipelines, with limited applicability to box culvert structures. Even when adapted, these methods often lead to significant reductions in the effective cross-sectional area and fail to enhance the structural load-bearing capacity due to [...] Read more.
Conventional trenchless pipeline rehabilitation technologies are primarily designed for circular pipelines, with limited applicability to box culvert structures. Even when adapted, these methods often lead to significant reductions in the effective cross-sectional area and fail to enhance the structural load-bearing capacity due to geometric incompatibilities. To overcome these limitations, this study proposes a novel construction approach that employs prefabricated high-strength thin concrete segment liners for the reinforcement of underground box culverts. The feasibility of this method was validated through full-scale (1:1) experimental construction in a purpose-built test culvert, demonstrating rapid and efficient installation. A static stacking load test was subsequently conducted on the reinforced upper section of the culvert. Results indicate that the proposed reinforcement method effectively restores structural integrity and satisfies load-bearing and serviceability requirements, even after removal of the original roof slab. Additionally, a finite element analysis was performed to simulate the stacking load test conditions. The simulation revealed that variations in the mechanical properties of the grout between the existing structure and the new lining had minimal impact on the internal force distribution and deformation behavior of the prefabricated segments. The top segment consistently exhibited semi-rigid fixation behavior. This study offers a promising strategy for the rehabilitation of urban underground box culverts, achieving structural performance recovery while minimizing traffic disruption and enhancing construction efficiency. Full article
(This article belongs to the Topic Resilient Civil Infrastructure, 2nd Edition)
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22 pages, 1089 KiB  
Article
Servitization as a Circular Economy Strategy: A Brazilian Tertiary Packaging Industry for Logistics and Transportation
by Alexandre Fernandes Andrade, Heloisa Candia Hollnagel and Fernando de Almeida Santos
Sustainability 2025, 17(14), 6492; https://doi.org/10.3390/su17146492 - 16 Jul 2025
Viewed by 455
Abstract
Leadership is essential for promoting the circular economy (CE) by fostering systemic thinking, promoting resource efficiency, and driving innovative practices that close material loops and minimize environmental impact. In addition, the principles of CE recommend changing production chains to balance economic development, sustainability, [...] Read more.
Leadership is essential for promoting the circular economy (CE) by fostering systemic thinking, promoting resource efficiency, and driving innovative practices that close material loops and minimize environmental impact. In addition, the principles of CE recommend changing production chains to balance economic development, sustainability, and social well-being. This study examines a tertiary packaging company’s circular economy implementation, by using a framework and a circular business model canvas (CBMC) and by identifying the challenges and opportunities for improving environmental management. The method was a participatory research case study using interviews and frameworks. In the context of this company, servitization in logistics was highlighted as an alternative to overcome growth challenges and to add value; however, the company faces significant challenges in implementing it. In addition, it is necessary to increase consciousness among those involved about the concept of the CE and its benefits to improve operational efficiency and review product design to expand environmental management. This research concludes that servitization (as a circular economy strategy), environmental education, and innovation practices can help companies achieve greater financial performance in the packaging industry and contribute to sustainable development goals—SDG achievements. Full article
(This article belongs to the Special Issue Sustainable Organization Management and Entrepreneurial Leadership)
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29 pages, 8563 KiB  
Article
A Bridge Crack Segmentation Algorithm Based on Fuzzy C-Means Clustering and Feature Fusion
by Yadong Yao, Yurui Zhang, Zai Liu and Heming Yuan
Sensors 2025, 25(14), 4399; https://doi.org/10.3390/s25144399 - 14 Jul 2025
Viewed by 302
Abstract
In response to the limitations of traditional image processing algorithms, such as high noise sensitivity and threshold dependency in bridge crack detection, and the extensive labeled data requirements of deep learning methods, this study proposes a novel crack segmentation algorithm based on fuzzy [...] Read more.
In response to the limitations of traditional image processing algorithms, such as high noise sensitivity and threshold dependency in bridge crack detection, and the extensive labeled data requirements of deep learning methods, this study proposes a novel crack segmentation algorithm based on fuzzy C-means (FCM) clustering and multi-feature fusion. A three-dimensional feature space is constructed using B-channel pixels and fuzzy clustering with c = 3, justified by the distinct distribution patterns of these three regions in the image, enabling effective preliminary segmentation. To enhance accuracy, connected domain labeling combined with a circularity threshold is introduced to differentiate linear cracks from granular noise. Furthermore, a 5 × 5 neighborhood search strategy, based on crack pixel amplitude, is designed to restore the continuity of fragmented cracks. Experimental results on the Concrete Crack and SDNET2018 datasets demonstrate that the proposed algorithm achieves an accuracy of 0.885 and a recall rate of 0.891, outperforming DeepLabv3+ by 4.2%. Notably, with a processing time of only 0.8 s per image, the algorithm balances high accuracy with real-time efficiency, effectively addressing challenges, such as missed fine cracks and misjudged broken cracks in noisy environments by integrating geometric features and pixel distribution characteristics. This study provides an efficient unsupervised solution for bridge damage detection. Full article
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36 pages, 2939 KiB  
Systematic Review
A Systematic Review and Bibliometric Analysis for the Design of a Traceable and Sustainable Model for WEEE Information Management in Ecuador Based on the Circular Economy
by Marlon Copara, Angel Pilamunga, Fernando Ibarra, Silvia-Melinda Oyaque-Mora, Diana Morales-Urrutia and Patricio Córdova
Sustainability 2025, 17(14), 6402; https://doi.org/10.3390/su17146402 - 12 Jul 2025
Viewed by 505
Abstract
The rapid increase in waste electrical and electronic equipment (WEEE) creates major environmental and governance issues in developing countries like Ecuador struggle because they with minimal formal collection and recycling rates. This research presents a potential sustainable management approach that tracks products through [...] Read more.
The rapid increase in waste electrical and electronic equipment (WEEE) creates major environmental and governance issues in developing countries like Ecuador struggle because they with minimal formal collection and recycling rates. This research presents a potential sustainable management approach that tracks products through their life cycles while following circular economy principles that include product extension and material extraction and waste minimization. A systematic literature review (SLR) using the PRISMA methodology combined with a bibliometric analysis found essential global strategies and technological frameworks and regulatory frameworks. The analysis of articles demonstrates that information management systems (IMSs) together with digital technologies and consistent regulations serve as essential elements for enhancing traceability and material recovery and formal recycling processes. A WEEE management IMS model was developed for the Ecuadorian market through an analysis of the findings; it follows a five-stage development process, starting from the technological infrastructure setup to complete data visualization integration. The proposed model is designed to enable public–private–community partnerships using digital tools that promote sustainable practices. The combination of circular strategies with traceability technologies and strong regulatory frameworks leads to improved WEEE governance, which supports sustainable system transitions in emerging economies. Full article
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25 pages, 2181 KiB  
Article
Discovery of a Potent Antimicrobial Peptide Through Rational Design: A New Frontier in Pathogen Control
by Bruna Agrillo, Monica Ambrosio, Rosa Luisa Ambrosio, Marta Gogliettino, Marco Balestrieri, Alessandra Porritiello, Maria Francesca Peruzy, Andrea Mancusi, Luigi Nicolais and Gianna Palmieri
Biomolecules 2025, 15(7), 989; https://doi.org/10.3390/biom15070989 - 11 Jul 2025
Viewed by 379
Abstract
The increasing circulation of multi-drug-resistant pathogens, coupled with the sluggish development of new antibiotics, is weakening our capacity to combat human infections, resulting in elevated death tolls. To address this worldwide crisis, antimicrobial peptides (AMPs) are viewed as promising substitutes or adjuvants for [...] Read more.
The increasing circulation of multi-drug-resistant pathogens, coupled with the sluggish development of new antibiotics, is weakening our capacity to combat human infections, resulting in elevated death tolls. To address this worldwide crisis, antimicrobial peptides (AMPs) are viewed as promising substitutes or adjuvants for combating bacterial infections caused by multidrug-resistant organisms. Here, the antimicrobial activity and structural characterization of a novel 13-amino acid cationic peptide named RKW (RKWILKWLRTWKK-NH2), designed based on known AMPs sequences and the identification of a key tryptophan-rich structural motif, were described. RKW displayed a broad-spectrum and potent antimicrobial and antibiofilm activity against Gram-positive and Gram-negative pathogens, including ESKAPE bacteria and fungi with minimal inhibitory concentrations (MBC) ranging from 5 µM to 20 μM. Structural results by fluorescence and Circular Dichroism (CD) spectroscopy revealed that the peptide was folded into a regular α-helical conformation in a membrane-like environment, remaining stable in a wide range of pH and temperature for at least 48 h of incubation. Furthermore, RKW showed low toxicity in vitro against mammalian fibroblast cells, indicating its potential as a promising candidate for the development of new antimicrobial or antiseptic strategies. Full article
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21 pages, 4047 KiB  
Article
Valorization of Spent Coffee Grounds as a Substrate for Fungal Laccase Production and Biosorbents for Textile Dye Decolorization
by Eduardo da Silva França, Adriana Ferreira de Souza, Dayana Montero Rodríguez, Nazareth Zimiani de Paula, Anna Gabrielly Duarte Neves, Kethylen Barbara Barbosa Cardoso, Galba Maria de Campos-Takaki, Marcos Antonio Barbosa de Lima and Ana Lucia Figueiredo Porto
Fermentation 2025, 11(7), 396; https://doi.org/10.3390/fermentation11070396 - 10 Jul 2025
Viewed by 414
Abstract
Spent coffee grounds (SCG) are a widely available agro-industrial residue rich in carbon and phenolic compounds, presenting significant potential for biotechnological valorization. This study evaluated the use of SCG as a suitable substrate for fungal laccase production and the application of the resulting [...] Read more.
Spent coffee grounds (SCG) are a widely available agro-industrial residue rich in carbon and phenolic compounds, presenting significant potential for biotechnological valorization. This study evaluated the use of SCG as a suitable substrate for fungal laccase production and the application of the resulting fermented biomass (RFB), a mixture of fermented SCG and fungal biomass as a biosorbent for textile dye removal. Two fungal strains, namely Lentinus crinitus UCP 1206 and Trametes sp. UCP 1244, were evaluated in both submerged (SmF) and solid-state fermentation (SSF) using SCG. L. crinitus showed superior performance in SSF, reaching 14.62 U/g of laccase activity. Factorial design revealed that a lower SCG amount (5 g) and higher moisture (80%) and temperature (30 °C ± 0.2) favored enzyme production. Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) analyses confirmed significant structural degradation of SCG after fermentation, especially in SSF. Furthermore, SCG and RFB were chemically activated and evaluated as biosorbents. The activated carbon from SCG (ACSCG) and RFB (ACRFB) exhibited high removal efficiencies for Remazol dyes, comparable to commercial activated carbon. These findings highlight the potential of SCG as a low-cost, sustainable resource for enzyme production and wastewater treatment, contributing to circular bioeconomy strategies. Full article
(This article belongs to the Special Issue Application and Research of Solid State Fermentation, 2nd Edition)
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44 pages, 7563 KiB  
Review
Green Batteries: A Sustainable Approach Towards Next-Generation Batteries
by Annu, Bairi Sri Harisha, Manesh Yewale, Bhargav Akkinepally and Dong Kil Shin
Batteries 2025, 11(7), 258; https://doi.org/10.3390/batteries11070258 - 10 Jul 2025
Viewed by 712
Abstract
The rising demand for sustainable energy storage has fueled the development of green batteries as alternatives to conventional systems. However, a major research gap lies in the unified integration of environmentally friendly materials and processes across all battery components—electrodes, electrolytes, and separators—without compromising [...] Read more.
The rising demand for sustainable energy storage has fueled the development of green batteries as alternatives to conventional systems. However, a major research gap lies in the unified integration of environmentally friendly materials and processes across all battery components—electrodes, electrolytes, and separators—without compromising performance or scalability. This review addresses this gap by highlighting recent advances in eco-conscious battery technologies, focusing on green electrode fabrication using water-based methods, electrophoretic deposition, solvent-free dry-press coating, 3D printing, and biomass-derived materials. It also examines the shift toward safer electrolytes, including ionic liquids, deep eutectic solvents, water-based systems, and solid biopolymer matrices, which improve both environmental compatibility and safety. Additionally, biodegradable separators made from natural polymers such as cellulose and chitosan offer enhanced thermal stability and ecological benefits. The review emphasizes the importance of lifecycle considerations like recyclability and biodegradability, aligning battery design with circular economy principles. While significant progress has been made, challenges such as standardization, long-term stability, and industrial scalability remain. By identifying key strategies and future directions, this article contributes to the foundation for next-generation green batteries, promoting their adoption in environmentally sensitive applications ranging from wearable electronics to grid storage. Full article
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22 pages, 3937 KiB  
Article
Selective Ammonium Recovery from Livestock and Organic Solid Waste Digestates Using Zeolite Tuff: Efficiency and Farm-Scale Prospects
by Matteo Alberghini, Giacomo Ferretti, Giulio Galamini, Cristina Botezatu and Barbara Faccini
Recycling 2025, 10(4), 137; https://doi.org/10.3390/recycling10040137 - 8 Jul 2025
Viewed by 269
Abstract
Implementing efficient strategies for the circular recovery and reuse of nutrients from wastewaters is mandatory to meet the Green Deal objectives and Sustainable Development Goals. In this context we investigated the use of zeolitic tuff (containing chabazite and phillipsite) in the selective recovery [...] Read more.
Implementing efficient strategies for the circular recovery and reuse of nutrients from wastewaters is mandatory to meet the Green Deal objectives and Sustainable Development Goals. In this context we investigated the use of zeolitic tuff (containing chabazite and phillipsite) in the selective recovery and reuse of N from various anaerobic liquid digestates in view of their implementation in farm-scale treatment plants. We tested the method on three livestock digestates and two municipal organic solid waste digestates. Adsorption isotherms and kinetics were assessed on each digestate, and a large set of parameters, including (i) contact time, (ii) initial NH4+ concentration, (iii) presence of competing ions, (iv) total solids content, and (vi) separation methods (microfiltration and clarification), were considered in the experimental design. Our results showed that the adsorption mechanism can be explained by the Freundlich model (R2 up to 0.97), indicating a multilayer and heterogeneous adsorption, while the kinetic of adsorption can be explained by the pseudo-second-order model, indicating chemical adsorption and ion exchange. The efficiency in the removal of NH4+ was indirectly related to the K+ and total solids content of the digestate. Maximum NH4+ removal exceeded 90% in MSW-derived digestates and 80% within 60 min in livestock-derived digestates at a 5% solid/liquid ratio. Thermodynamic parameters confirmed favorable and spontaneous adsorption (ΔG up to −7 kJ⋅mol−1). Farm-scale projections estimate a nitrogen recovery potential of 1.2 to 16 kg N⋅day−1, depending on digestate type and process conditions. These findings support the application of natural zeolitic tuffs as a low-cost, chemical-free solution for ammonium recovery, contributing to sustainable agriculture and circular economy objectives. Full article
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15 pages, 3286 KiB  
Article
Enhanced Sensitivity Microfluidic Microwave Sensor for Liquid Characterization
by Kim Ho Yeap, Kai Bor Tan, Foo Wei Lee, Han Kee Lee, Nuraidayani Effendy, Wei Chun Chin and Pek Lan Toh
Processes 2025, 13(7), 2183; https://doi.org/10.3390/pr13072183 - 8 Jul 2025
Viewed by 329
Abstract
This paper presents the development and analysis of a planar microfluidic microwave sensor featuring three circular complementary split-ring resonators (CSRRs) fabricated on an RO3035 substrate. The sensor demonstrates enhanced sensitivity in characterizing liquids contained in a fine glass capillary tube by leveraging a [...] Read more.
This paper presents the development and analysis of a planar microfluidic microwave sensor featuring three circular complementary split-ring resonators (CSRRs) fabricated on an RO3035 substrate. The sensor demonstrates enhanced sensitivity in characterizing liquids contained in a fine glass capillary tube by leveraging a novel configuration: a central 5-split-ring CSRR with a drilled hole to suspend the capillary, flanked by two 2-split-ring CSRRs to improve the band-stop filtering effect. The sensor’s performance is benchmarked against another CSRR-based microwave sensor with a similar configuration. High linearity is observed (R2 > 0.99), confirming its capability for precise ethanol concentration prediction. Compared to the replicated square CSRR design from the literature, the proposed sensor achieves a 35.22% improvement in sensitivity, with a frequency shift sensitivity of 567.41 kHz/% ethanol concentration versus 419.62 kHz/% for the reference sensor. The enhanced sensitivity is attributed to several key design strategies: increasing the intrinsic capacitance by enlarging the effective area and radial slot width to amplify edge capacitive effects, adding more split rings to intensify the resonance dip, placing additional CSRRs to improve energy extraction at resonance, and adopting circular CSRRs for superior electric field confinement. Additionally, the proposed design operates at a lower resonant frequency (2.234 GHz), which not only reduces dielectric and radiation losses but also enables the use of more cost-effective and power-efficient RF components. This advantage makes the sensor highly suitable for integration into portable and standalone sensing platforms. Full article
(This article belongs to the Special Issue Development of Smart Materials for Chemical Sensing)
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