Search Results (26,861)

This study investigated how different organic fertilization practices affect productivity, stability, and nitrogen use efficiency in the rotation systems of the Hetao Irrigation District. The research was based on a long-term field experiment (2015–2025), with a chemical fertilizer-only treatment as the control (CK). Four organic fertilization treatments were evaluated: farmyard manure application (CM), straw incorporation (CS), green manure cultivation and incorporation (CG), and a combined green manure plus straw treatment (CGS). Based on three consecutive years of observations (2023–2025), the impacts of these treatments on crop yield, yield composition and stability, plant nitrogen accumulation and allocation, and nitrogen use efficiency were systematically analyzed. Both CM and CS significantly increased maize equivalent yield (MEY) compared with the other treatments, by 33.68–66.04% and 16.05–24.21%, respectively. CM’s productivity advantage was primarily driven by higher biomass accumulation, whereas CS’s advantage was largely due to improvements in the harvest index. In terms of stability, CM exhibited the lowest coefficient of variation (CV), indicating the highest static stability, while CS showed a regression coefficient (b_i) close to 1, indicating stronger dynamic stability. CM also significantly enhanced total plant nitrogen accumulation, nitrogen recovery efficiency (NRE), and nitrogen use efficiency (NUE), while optimizing nitrogen allocation to grain. CS significantly improved nitrogen internal efficiency (NIE), promoting more efficient conversion of absorbed nitrogen into grain yield. CG and CGS did not show clear advantages across productivity, stability, or most nitrogen use efficiency-related indices. Overall, in the Hetao Irrigation District, farmyard manure application is an effective strategy for achieving both high and stable yields, whereas straw incorporation offers stronger environmental adaptability. Both practices represent practical and effective approaches for improving the sustainability of rotation systems. Full article

Bamboo is a rapidly renewable lignocellulosic resource widely used in construction, composites, and bio-based materials. However, its practical applications are often limited by high hygroscopicity, biological degradation, and dimensional instability under humid conditions. This review synthesizes current research on bamboo structure, microbial interactions, and material modification strategies to better understand how bamboo-associated microbiomes influence both deterioration and potential material enhancement. We summarize conventional chemical and thermal modification approaches that improve hydrophobicity, durability, and mechanical stability while also discussing their technical limitations. Emerging studies on bamboo-associated microbial communities reveal complex interactions between fungi, bacteria, and lignocellulosic substrates, including enzymatic degradation, nutrient cycling, and potential bioprotective functions. Advances in multi-omics technologies have further provided insights into the functional gene pools and metabolic pathways involved in bamboo–microbe interactions. Recent conceptual developments in microbiome engineering and engineered living materials (ELMs) suggest possible future directions for integrating microbial functionality into bamboo-based materials. However, direct experimental evidence for microbial enhancement of bamboo structural performance remains limited. Future interdisciplinary research integrating material science, microbial ecology, and synthetic biology will be essential to evaluate the feasibility and safety of such biohybrid systems. Full article

Pomegranate peel is a food industry waste rich in polyphenols. To date, its effect in alleviating fatigue remains unclear. This study aimed to characterize the chemical composition of pomegranate peel polyphenols (PPPs), evaluate its antioxidant and anti-fatigue capacities, and investigate the underlying mechanism. In the current study, twenty main compounds, primarily flavonoids, phenolic acids, and anthocyanins, were identified from PPPs using LC-MS/MS. In H₂O₂-induced HepG2 cells, PPPs promoted cellular repair and reduced the production of intracellular malondialdehyde (MDA) and reactive oxygen species (ROS) via enhancing the activity of antioxidant enzymes (SOD, CAT, and GSH-Px). In the endurance swimming-induced fatigue mice model, PPPs prolonged mice exhaustion times, reduced accumulation of fatigue-related metabolites (BUN, LA, BA, LDH and CK), and alleviated liver and muscle tissue damage. Mechanistically, PPPs mitigated oxidative stress via activation of the Keap1/Nrf2 pathway, leading to increased expression of hemeoxygenase-1 (HO-1) and NAD(P)H quinone oxidoreductase 1 (NQO1). Furthermore, PPPs stimulated energy metabolism by activating the AMPK/PGC-1α/PPAR-α pathway, promoting mitochondrial biogenesis, enhancing glycogen storage, increasing ATPase activity (Na⁺-K⁺-ATPase, Ca²⁺-Mg²⁺-ATPase, and T-ATPase) and accelerating lipid β-oxidation. These findings suggest that PPPs is a promising anti-fatigue supplement and could be further utilized in the nutritional industry. Full article

Recently, there has been growing interest in the synthesis of thin films made from metal diboride. Boron forms binary compounds with a wide variety of metals. These diborides are refractory, ultra-hard solids characterized by high melting points, exceptional thermal stability, and pronounced chemical inertness. This work describes the preparation of metal diboride coatings made of binary ZrHfB₂, HfTiB₂ and ZrTiB₂ as well as ternary HfZrTiB₂. In the low-pressure chemical vapor deposition (LPCVD) process used, MeCl₄ (Me = Zr, Hf, Ti), BCl₃, H₂, and Ar were employed at deposition temperatures of 850 °C. The coatings were characterized with respect to phase composition, crystal structure, hardness, residual stress and wear behavior. A hardness of 38 GPa was achieved with a modulus of elasticity of around 700 GPa and a moderate tensile residual stress of approx. 400 MPa was obtained for the ternary alloys as well as 44 to 633 MPa for the binary alloys, respectively. The phase composition and structure of the deposited layers were examined using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) analysis. The investigations revealed dense, crack-free, well defined crystalline single-phase diboride layers with grain sizes of 0.1–1.5 µm. A TiN interlayer applied prior to diboride deposition significantly enhanced adhesion between the diboride coating and hard-metal inserts. Scratch test measurements revealed critical loads of approximately 90 N. In the wear test milling against TiAl6V4, the HfZrTiB₂ coating (with ZrCl₄:HfCl₄:TiCl₄ = 1:2:1) demonstrated the best tool life with ~15% improvement over the state-of-the-art CVD TiB₂ reference coating using a single cutting condition. The tool life for the ZrTiB₂ coating was 20% below the tool life of the reference coating. Full article

The article presents a novel, energy-efficient composite of clinoptilolite and an organic phase change material (PCM), exhibiting a greater heat storage capacity than would be expected based solely on the PCM content within the composite. The study included a structural and textural analysis of clinoptilolite powder as a fine-grained material, with particular emphasis on its properties and compatibility with paraffin-based phase change materials. The second stage of the research involved determining changes in the enthalpy of melting and solidification of the composites, as well as evaluating their ability to retain the liquid phase and confirming the absence of chemical reactions between individual composite components. The obtained results demonstrated an increase in the enthalpy of the composite by approximately 14% and 44% relative to the expected values for PCM contents of 50% and 40%, respectively. Furthermore, the approximate content of paraffin-based PCM in the clinoptilolite composite at which no leakage occurs during the melting process was determined. This work represents a new approach to the integration of porous materials and phase change materials, enabling the formation of energetically favorable structures that significantly enhance the effective thermal storage capacity of PCM-based composites. Full article

Classification of vehicle engines using the chemical composition of the exhaust from these engines can be used to identify the engine’s design and verify compliance with environmental regulations through the vehicle’s emissions. This paper describes a method to identify the type of vehicles using machine learning (ML), where low-cost MQ series sensors measure the gases and particle emissions from a vehicle exhaust system, while simultaneously collecting and measuring the vehicle’s temperature and humidity levels. A custom-designed multi-sensor exhaust sensing module is employed to capture real-time exhaust emissions prior to entering the atmosphere. Exhaust samples are collected from vehicles representing three major engine categories: petrol, diesel, and compressed natural gas (CNG). In addition, fresh air samples are collected as a baseline environmental reference for comparison. All exhaust measurements are collected under controlled and consistent engine operating conditions to ensure comparable emission profiling across vehicle classes. To ensure consistent combustion-based emission profiling, this study focuses on conventional fuel-powered vehicles. MQ-series gas sensors are sensitive to combustion by-products emitted during engine operation, such as carbon monoxide (CO), hydrocarbons (HC), while also exhibiting cross-sensitivity to other gaseous components present in exhaust mixtures. Nevertheless, the proposed system performs pattern-based classification using relative sensor response signatures. Standardization of data is achieved through z-score normalization. The best models developed (based on three separate experimental designs) are trained and validated using six supervised machine learning algorithms such as Logistic Regression, Support Vector Machine (RBF), k-Nearest Neighbors, Random Forest, Gradient Boosting Decision Tree, and XGBoost and are compared against one another. Evaluation of the tested algorithms using various evaluation metrics demonstrated that ensemble models outperformed all other algorithms, achieving the highest accuracy of 99.5%. Furthermore, noise analysis confirms that the proposed solution maintains high classification accuracy (more than 89%) even under substantial sensor perturbations mimicking the real-world deployment. The solution proposed below illustrates how using gas sensors and advanced algorithms can provide accurate exhaust identification and identify engines in real-time. Full article

The accelerated processes of industrialization and urbanization have led to increasingly prominent environmental risks by emerging organic contaminants (EOCs) in wastewater. These contaminants are characterized by low concentrations, high toxicity, and complex composition, making their efficient removal crucial for safeguarding ecological security and human health. Advanced oxidation processes exhibit significant potential for the removal of EOCs due to their high degradation efficiency. However, current treatment paradigms remain constrained by several critical issues. Notably, the routine over-oxidation of low-toxicity small-molecule organics solely aims to satisfy chemical oxygen demand (COD) compliance standards. This unnecessary practice not only increases operational costs and carbon footprint but also leads to energy waste and reduced overall treatment efficiency. Based on the current technological landscape, this paper analyzes the core challenges in the removal of EOCs at present. In light of policy orientations and technological trends, it outlines future research directions and industrial development pathways, providing insights for achieving the synergistic goals of efficient removal of EOCs, low carbon emissions, and cost-effective operation. Full article

Zinc–antimony–boro–germanate glasses highly doped with Sm₂O₃ were synthesized by the conventional melt-quenching method. Their structural, optical, and luminescent properties were systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance UV–Vis (DR-UV–Vis), and photoluminescence (PL) spectroscopy. XRD analysis confirmed the amorphous nature of all prepared samples. XPS measurements were used to examine the surface chemical composition of the Sm₂O₃-doped glasses, with particular focus on verifying samarium incorporation and identifying its oxidation state after synthesis, since Sm ions act as the luminescent centers in these materials. For the sample containing the highest Sm₂O₃ concentration, the DR-UV–Vis spectrum exhibited ten absorption bands assigned to intra 4f electronic transitions. Based on these data, the nephelauxetic and bonding parameters were determined, indicating that increasing Sm₂O₃ content enhances the ionic character of the bonds within the glass network. PL spectra revealed three characteristic emission bands associated with Sm³⁺ luminescent centers. The emission intensity reached a maximum at 3 mol% Sm₂O₃, while further increases in samarium content led to luminescence quenching. The most intense emission band was in the yellow–orange region of the visible spectrum, highlighting the potential of these materials for yellow–orange-emitting solid-state laser applications. The excitation spectra show that the optical response is strongly dependent on concentration, with a sample doped with 3 mol% Sm₂O₃ exhibiting the highest excitation efficiency. The dominant excitation band centered near 402 nm, together with weaker bands in the blue region, indicating that these glasses are promising candidates for near-UV-pumped orange-emitting photonic devices. Full article

Chia seed mucilage (CSM) is a promising plant-derived hydrocolloid characterized by unique physicochemical and functional properties that are strongly influenced by the extraction methodology. In this research, an optimized sonication–freezing-assisted extraction (SFAE) process was developed to obtain mucilage while preserving its structural integrity. Results indicate that the extracted mucilage has a high total dietary fiber content of 75.87% and a moderate protein level of 8.71%. Fourier transform infrared spectroscopy (FTIR) confirmed the presence of hydroxyl and ionized carboxylate (COO⁻) groups associated with uronic acids, highlighting the anionic and polyelectrolyte nature of the system. Rheological characterization of optimized-CSM revealed Newtonian behavior in dilute solutions, indicating minimal intermolecular interactions and permitting accurate measurement of intrinsic viscosity and viscosity-average molecular weight. A critical overlap concentration (c** ≈ 0.2% w/v) was identified, marking the transition to semi-dilute regimes, chain entanglement, and the onset of shear-thinning and viscoplastic behavior. Functionally, the optimized-CSM exhibited high water holding capacity and competitive emulsifying properties (emulsion activity index (EAI): 62.50%; emulsion stability index (ESI): 49.32%), attributed to synergistic interactions between proteins and polysaccharides. Overall, this work provides new insights into how processing conditions influence the chemical composition and molecular structure, which fundamentally govern the rheological and functional performance of CSM. These findings underscore its potential as a versatile hydrocolloid for food and biomedical applications. Full article

The present study aims to determine the properties of sandwich mycelium-based composite panels (sandwich-MBC-panel) fabricated with a lightweight core of mycelium-based composites (MBCs) of Ganoderma lucidum and Pleurotus ostreatus and veneers of Gmelina arborea and Vochysia guatemalensis wood. Physical and mechanical properties, acoustic capacity, chemical composition (determined by FT-IR), thermal degradation, and inorganic components were evaluated. The results showed that the sandwich-MBC-panel presented a density of 0.27–0.40 g/cm³, an MC between 14.56 and 24.71%, and a water absorption between 43.64 and 61.32%. Regarding mechanical characteristics, the sandwich-MBC-panel with the highest MOR, MOE, and internal bond was that composed of G. lucidum and G. arborea. The treatment with the best tensile force value was the mixture of G. lucidum with O. pyramidale. The sandwich-MBC-panel constructed with balsawood showed the lowest noise reduction coefficient, while the panel composed of G. lucidum and P. ostreatus showed good substrate properties and appropriate carbon and nitrogen content. FT-IR spectroscopy revealed substrate degradation by fungal mycelium formation, and TGA curves showed that the MBC containing G. lucidum presented higher thermal degradation than the panel without G. lucidum, without fungal attack. The main results of this study showed that sandwich MBC panels, in which the MBC is used as a lightweight core and wood veneers are used on the faces, have the potential for use as acoustic panels and could represent a sustainable alternative to panels that are generally fabricated from synthetic materials and of low densities. Full article

Why should a genome be protected? Because it contains our most private data! A genome contains an organism’s set of genetic material (DNA and, in viruses, RNA), and it contains all genes and non-coding sequences. The structure of DNA was described by Watson and Crick in 1953, but the first studies were conducted a century earlier by Miescher, who described the structure and chemical composition of the nucleus. The first action aimed at securing the results of genetic research was the creation of databases for the results obtained using genetic fingerprinting technology. The discovery of the sequencing method and the introduction of the polymerase chain reaction laid the foundations for understanding the genome’s function. Automated DNA sequencing proved to be hundreds of times faster than traditional methods, thus reducing the cost and time of genome analyses. Thousands of genomic data points are stored in private and governmental databases. The security of patients’ genomic data must be ensured by protecting it from unauthorized use while, at the same time, enabling research for the sake of public health. The falling prices of genome sequencing and the increasing availability of commercial sequencing for the public could result in ethical problems and undermine the safety of personal information. Full article

The essential oil (EO) of Sideritis L. has attracted great interest due to its pharmacological activities. At the same time, there is significant variability within the type, related, among other things, to the origin of the raw material. The aim of this work was to study the EO chemical composition of Sideritis scardica Griseb. from Bulgaria and Türkiye. The plant material (air-dried above-ground parts) was purchased from herbal and medical stores in Lublin, Poland. The crushed raw material was used for distillation of the EO. Distillation was performed in a Clevenger apparatus. The EO content was expressed in ml per 100 g of air-dried herb. Analysis of the qualitative and quantitative composition of the obtained EO was performed using gas chromatography coupled with a mass spectrometer (450-GC + 240-MS). The antimicrobial activity of the S. scardica EO was evaluated using the broth microdilution method in accordance with the guidelines of the European Committee on Antimicrobial Susceptibility Testing (EUCAST) guidelines. We have demonstrated that the chemical composition and biological activity of sideritis EO depend on the origin of the raw material. Our results indicate that S. scardica EO can be considered a promising antimicrobial agent. Full article

To address the slow curing and low early strength of conventional modified epoxy emulsified asphalt repair materials, this study introduced steel slag aggregate into epoxy emulsified asphalt mixtures. Experimental techniques including heat absorption–heat transfer rate tests, Marshall stability tests, COMSOL numerical simulation, and scanning electron microscopy (SEM) were adopted to analyze rapid and uniform heating under microwave radiation. The influence of steel slag’s chemical composition, content, and particle size on epoxy curing, asphalt demulsification, and early strength of the mixture was systematically examined. Results show that steel slag containing Fe and Mg elements exhibits higher microwave absorption efficiency. When its content exceeds 15%, the heating rate increases by approximately 0.335 °C/s under the tested conditions. Particles sized 0.6~2.36 mm show better wavelength matching with the applied microwave frequency (2.45 GHz), thereby enhancing absorption. After 140 s of microwave radiation, the core temperature of the mixture reaches 110 °C, which is the appropriate temperature to achieve rapid epoxy curing and synchronous asphalt demulsification. These two processes synergistically form a continuous network structure, thereby improving the compactness and initial laboratory Marshall stability of the mixture. Nevertheless, this study has several limitations. The microwave absorption efficiency depends strongly on the specific mineralogy and Fe/Mg content of steel slag, both of which may vary with source. The conclusions are based on laboratory-scale tests under fixed microwave power and mixture proportions. Despite these limitations, the results demonstrate that steel slag can serve as an effective microwave-absorbing component in epoxy emulsified asphalt mixtures, enabling rapid curing and demulsification to accelerate early strength development. Full article

In the context of global carbon neutrality goals, substituting hydrogen for carbon as a reductant represents a critical pathway for mitigating emissions in the iron and steel industry. Hydrogen-based molten reduction technology, characterized by its rapid reaction kinetics and high feedstock flexibility, has emerged as a pivotal direction for the industry’s low-carbon transition. This article systematically reviews research progress on the hydrogen-based reduction of molten iron oxides. The thermodynamic behavior of molten systems is discussed, confirming the feasibility of reducing molten FeO with hydrogen at elevated temperatures. Furthermore, discrepancies and nonlinear characteristics within current mainstream thermodynamic databases regarding the high-temperature molten region are identified. Kinetic studies demonstrate that reduction rates in the molten state significantly exceed those in the solid state. The rate-limiting step is shown to vary with reaction conditions, primarily shifting between interfacial chemical reaction and liquid-phase mass transfer control. Additionally, the influence mechanisms of key parameters—including temperature, reaction time, gas flow rate, gas composition, and slag composition—on the reduction process are comprehensively reviewed. By synthesizing existing methodologies and theoretical advancements, this review aims to provide a theoretical reference for optimizing hydrogen-based molten reduction processes for iron oxides. Full article

Plastic waste is estimated to represent 40–80% of the total amount of marine litter, with polyethylene (PE) and polypropylene (PP) being the most abundant polymeric components. The recovery and recycling of marine plastic debris are therefore essential to mitigate environmental pollution and limit the generation of secondary microplastics. In this work, a mechanical recycling strategy was investigated for the valorization of a polyethylene-rich plastic fraction (PE-rf) recovered from the marine environment, characterized by high heterogeneity and persistent inorganic contamination. Different pre-treatment routes, including cryogenic grinding and planetary ball milling, as well as blending approaches with recycled polyethylene and compatibilizing additives, were explored. The effects of composition and processing on the thermal, mechanical, and morphological properties of the resulting materials were systematically analyzed. The results show that intense mechanical homogenization and chemical compatibilization are not sufficient to overcome the intrinsic limitations imposed by contamination and compositional variability. As a proof of concept, selected formulations were processed into filaments and tested in fused filament fabrication, demonstrating basic 3D printability. Full article