Search Results (2,629)

The construction sector consumes significant amounts of natural resources and contributes substantially to global CO₂ emissions, making it necessary to develop materials with a reduced environmental impact. In this context, the valorization of reusable industrial waste as secondary raw materials represents a strategic direction for applying circular economy principles and for decarbonizing the construction materials industry. The scientific problem addressed in this review is the urgent need to develop construction materials with a reduced environmental footprint, given that the construction sector is a major consumer of natural resources and a significant contributor to global CO₂ emissions. This challenge requires the identification and critical evaluation of sustainable solutions that support decarbonization and the transition toward a circular economy. The main findings indicate that the valorization of industrial waste offers high decarbonization potential: supplementary cementitious materials (SCMs), such as ground granulated blast furnace slag and fly ash, can reduce CO₂ emissions by approximately 20–50%, while alkali-activated binders and geopolymers achieve reductions of 40–80% compared to Portland cement. These materials also enhance durability, extending service life by 10–20% in aggressive environments, although early-age strength may decrease by 10–30%; recycled aggregates derived from construction and demolition waste (CDW) can substitute up to 100% of natural aggregates, while rubber fibers can increase impact resistance by 30–50% and reduce density by 10–20%. However, key limitations relate to waste variability, heavy metal leaching risks (requiring immobilization efficiencies > 90%), and the relatively low technological maturity of many solutions (TRL < 7), leading to the TRL–CO₂ paradox and highlighting the need for standardization and performance-based regulatory frameworks. The synthesized results indicate that the appropriate integration of industrial waste enables a significant reduction in clinker content, lowers associated CO₂ emissions, and decreases primary energy consumption while maintaining physical–mechanical properties and durability characteristics comparable to or in some cases superior to those of traditional materials, if mix design is based on clear performance criteria, stratified according to the type of waste, dosage used, curing regime, binder chemistry, and the target application. Full article

Water-induced deterioration of silty soil subgrade in the lower Yellow River floodplain poses a critical, long-standing engineering challenge. Most existing studies on silty soil modification prioritize strength enhancement via traditional cementitious binders (i.e., cement, lime), yet these strategies fail to fundamentally block water migration in the soil matrix. A distinct scientific gap persists: the capillary water inhibition mechanism of nano-superhydrophobic modified Yellow River alluvial silt, along with the correlation between its microstructural evolution and macroscopic engineering performance, has yet to be systematically elucidated. To fill this gap, we conducted hydrophobic modification of the targeted silt using a nano-superhydrophobic material (NSHM), and performed a systematic suite of laboratory tests to characterize its hydrophobicity, mechanical properties, water stability, and microstructural characteristics. Quantitative experimental results demonstrate that NSHM imparts remarkable water resistance to the silt: at an NSHM dosage ≥0.5%, the modified soil exhibits stable superhydrophobicity across all tested compaction degrees, with over a 99% reduction in saturated hydraulic conductivity. Notably, the hydrophobic modification only incurs a <12% reduction in the dry unconfined compressive strength (UCS) of the silt. Microscopic characterization results reveal that NSHM modifies the silt via two core pathways: uniform particle encapsulation and pore infilling, without altering the inherent mineral functional groups of the soil. This microstructural regulation reduces the average pore diameter by 38.2% and total porosity by 15.6%, while optimizing the uniformity of pore size distribution. Based on comprehensive evaluation of overall performance, a minimum NSHM dosage of 0.5% is recommended for in situ application in local silty soil subgrade. This study provides critical theoretical guidance and technical support for water damage mitigation in alluvial silty soil subgrade. Full article

The complexity of physicochemical properties in iron ore tailings has led to extensive and varied study avenues. Moreover, changes in these features resulting from source discrepancies have complicated the identification of consistent patterns in study findings, thereby hindering the standardization and advancement of resource exploitation technologies. This paper provides a comprehensive analysis of the utilization pathways for iron tailings. It identifies the mainstream recovery processes for rare earth minerals, a relatively less-researched direction. It also describes research progress on the use of iron tailings for the preparation of fertilizers and soil conditioners, as well as their application as cementitious materials or aggregates in building materials and mine backfilling engineering. It incorporates various activation methods for the preparation of cementitious materials from iron tailings into a unified comparative framework and quantifies the key performance indicators of different activation pathways through a summary table. It also summarizes studies on the ecological reclamation of tailings ponds based on bioremediation techniques. The essential physicochemical properties of iron deposits are meticulously analyzed, and this is followed by a specialized overview of the principal treatment techniques, critical performance indicators, and their foundational mechanisms. The current application of various technical approaches is examined to identify key problems, and future development opportunities are outlined. Full article

Engineered cementitious composite (ECC) is an advanced material known for its superior flexibility, high durability, and crack resistance, making it ideal for a variety of structural applications. However, it uses cement at a rate of 2–3 times more than conventional concrete which raises environmental concerns. This study focused on the production of eco-friendly ECC by incorporating various waste materials as partial cement and sand substitutes. Cement kiln dust (CKD), ceramic powder waste (CPW), and eggshell waste (ESW) were used as partial substitutes for cement in doses of 10% and 20%. Crumb rubber (CR) was used as a partial substitute for sand in doses of 25, 50, 75, and 100%. Chemical treatments using sodium hydroxide, sodium silicate, and a mix of both of them were carried out for the CR in the production of the proposed ECC. Physical treatment using the same cement substitute materials (CKD, CP and ESP) was also carried out for the CR. The effect of fiber type—such as basalt fibers (BF), polypropylene fibers (PPF), and steel fibers (S_tF)—on the performance of ECC was also investigated. Slump, compressive strength, uniaxial tensile strength, flexural strength, and sorptivity were the measured properties for the proposed ECC. Microstructure analyses were also conducted on some selected ECC mixtures. Among the tested mixtures, the results showed that replacing 10% of the cement with CKD improved the compressive strength by up to 22.6% and the tensile strength by up to 18.3%. Using 50% untreated CR reduced compressive and tensile strength by 32.8% and 28.1%, respectively, compared to the control ECC. The physical treatment of CR using CKD improved the compressive strength by up to 12.7% and the tensile strength by up to 3.2% compared to untreated CR. The microstructure analyses revealed an improvement in fiber-matrix bonding and a reduction in crack width in the mixtures, especially in the BF and PPF blends. Full article

The global construction industry urgently requires sustainable alternatives to ordinary Portland cement (OPC) to mitigate its immense carbon footprint. Red mud (RM), a highly alkaline bauxite residue, presents tremendous but challenging potential as a supplementary cementitious material. This review systematically bridges the gap between atomic-level interfacial bonding mechanisms and macroscopic engineering performance, highlighting how these properties are significantly dictated by specific RM sources (e.g., Bayer vs. Sintering processes). We first elucidate advanced pretreatment strategies, notably CO₂ mineralization, which synergistically mitigates extreme alkalinity and sequesters carbon. Crucially, the fundamental bonding mechanisms are decoded: beyond physical filling, RM integration induces significant micro-morphological densification via intense aluminosilicate depolymerization—evidenced by the Al[VI] to Al[IV] coordination shift—and the quantitative integration of approximately 40% reactive iron phases into stable Fe-S-H networks. By clearly distinguishing between traditional hydration and clinker-free alkali-activation pathways, we evaluate holistic structural parameters beyond mere 28-day compressive strength (40–67 MPa), explicitly addressing flexural capacity, modulus of elasticity, and volume stability. Environmental assessments confirm exceptional heavy metal immobilization (>95% efficiency, leaching < 0.010 mg/L) and a substantial 50–80% reduction in Global Warming Potential (GWP), provided the environmental burden of alkaline activators is rigorously accounted for. Furthermore, the long-term risk of Alkali–Silica Reaction (ASR) is evaluated as a primary durability concern. Finally, to overcome persistent rheological bottlenecks, this paper highlights transformative future trajectories, particularly data-driven Machine Learning (ML) for complex mix optimization and 3D concrete printing for advanced infrastructure. Ultimately, this review provides a robust theoretical foundation and a pragmatic roadmap for upcycling RM into safe, high-performance, and ultra-low-carbon building materials. Full article

Cement stabilized macadam (CSM) bases are prone to cracking and void damage under long-term traffic loading and environmental actions, which accelerates structural deterioration. Although grouting is an effective method for treating such concealed defects, laboratory-based evaluation of repair effectiveness remains limited. In this study, field-cored CSM specimens were recombined in a cylindrical mold to simulate four void conditions (1/4, 2/4, 3/4, and 4/4), and repaired using an inorganic cementitious composite grouting material based on ultra-fine cement and high-belite sulphoaluminate cement (HBSAC), and modified with ethylene-vinyl acetate (EVA) latex, wollastonite (WO) whiskers, and polyvinyl alcohol (PVA) fibers. The repair effectiveness was evaluated through ultrasonic testing, capacitance measurement, uniaxial compression with acoustic emission (AE) monitoring, and computed tomography (CT). The results show that the longitudinal wave velocity of all repaired groups increases continuously with curing time, with a maximum increase of 21.98% at 28 days. The normalized capacitance response exhibits clear time- and layer-dependent variation, with the 4/4 group showing the most pronounced spatial heterogeneity. In the uniaxial compression tests, the peak load increases from 181 kN in the control group to 201–286 kN in the repaired groups, while the tensile-related AE event proportion increases from 77.35% in the 1/4 group to 89.38% in the 4/4 group. CT analysis shows that the proportion of micropores smaller than 1 mm³ increases from 66.3% to 82.7%, whereas the proportion of pores larger than 100 mm³ decreases from 46.5% to 21.6% after repair. These results demonstrate that the composite grouting material provides effective filling, structural reconstruction, and mechanical enhancement for void-damaged CSM, and that the proposed multi-source characterization framework is suitable for evaluating grouting repair performance. Full article

Using solid waste as supplementary cementitious materials (SCMs) is an effective strategy for promoting low-carbon construction development. However, single or binary systems often exhibit mismatched reaction kinetics, thereby limiting their performance at high cement replacement rates. This study focuses on a novel low-carbon concrete designed based on reaction sequence coordination, containing recycled brick powder (RBP), ground granulated blast-furnace slag (GGBS), and self-combusting coal gangue (SCCG). The effects of RBP, GGBS, and SCCG on the hydration process and microstructure of the novel low-carbon concrete with different replacement levels have been studied by testing compressive strength, workability, and durability and observing microstructural changes. The results showed that an optimized ternary composition with an RBP:GGBS:SCCG ratio of 4:3:1 achieves a cement replacement level of 30% while exhibiting a 28-day compressive strength of 38.26 MPa, representing a 14.2% increase compared with plain cement mortar. Microstructural analyses indicate that this enhanced performance results from a time-dependent reaction sequence, in which GGBS contributes predominantly at early ages by supplying calcium, whereas RBP and SCCG mainly participate through delayed pozzolanic reactions and pore refinement at later ages. Consequently, the optimized ternary mortar exhibits a water absorption of 11.12% and a 27.2% reduction in electrical flux. This study aims to provide practical strategies for enhancing the performance of low-carbon cementitious materials through a reaction sequence coordination design approach, thereby improving the utilization efficiency of solid waste in the production of low-carbon building materials. Full article

This study used calcium hydroxide (CH) to simulate the alkaline environment of cement and to activate lithium slag (LS), aiming to reveal the mechanism of LS in cement. The early-age hydration of LS blended with 10 wt.% CH was monitored via isothermal calorimetry (ICC) at ambient temperature, followed by a comparative analysis of phase assemblage, microstructure, and macroscopic properties under standard and steam curing conditions. The results show that LS exhibits superior early reactivity within the first 9 h, which is attributed to abundant ettringite formation. Two distinct exothermic peaks were identified during LS-CH hydration, corresponding to (i) ettringite formation accompanied by LS dissolution and C–S–H precipitation, and (ii) CaCO₃ crystallization and renewed ettringite formation. The hydrated paste consists of abundant AFt, CaCO₃ polymorphs, unreacted LS particles, and a small amount of C–S–H gel with a low Ca/Si ratio and incorporating Al and S. This unique phase assemblage results in a coarser pore structure and lower specific surface area compared with conventional cement paste. Nevertheless, the system achieves a relatively high 28-day compressive strength, highlighting the promise of LS-CH blends as sustainable cementitious materials. Full article

In recent years, bacteria-based self-healing has emerged as a promising bioengineering strategy to address the self-repair of cracks in cement-based materials, which represent one of the persistent durability challenges. This approach relies on microbiologically induced calcium carbonate (CaCO₃) precipitation (MICP), in which metabolically active bacteria promote CaCO₃ formation of crystals that can heal cracks and restore material integrity. This study compares the self-healing potential of a natural (N-) alkaline soil Bacillus licheniformis strain with a UV-strain (phenotypic mutant) generated through controlled UV exposure followed by adaptive evolution. Both strains were evaluated under conditions relevant to cementitious environments. The UV-strain exhibited enhanced ureolytic performance, reaching urease activity of 0.32 U/mg compared to 0.24 U/mg in the N-strain. This translated into improved biomineralization, with CaCO₃ precipitation reaching 2.37 mg versus 2.23 mg/100 mL in the N-strain. Additionally, the UV-strain showed increased cell hydrophobicity and aggregation, indicating improved nucleation potential and surface-mediated mineral deposition. Multivariate analysis confirmed strong correlations between ureolytic metabolism, alkalization, and mineral formation, while artificial neural network (ANN) modeling (MLP 6-10-14) successfully predicted biomineralization-related parameters with high accuracy (R² > 0.90 for urease activity, NH₄⁺, ΔpH, and CaCO₃). The results demonstrate that UV-induced phenotypic adaptation can enhance biomineralization efficiency with minor trade-offs in physiological robustness. For the first time, that controlled UV-induced phenotypic adaptation can be used as a targeted strategy to enhance biomineralization efficiency in B. licheniformis, while maintaining functional stability under cement-relevant conditions. These findings provide a novel framework for tailoring bacterial performance in self-healing systems for construction biotechnology. Full article

Despite being fundamental to modern infrastructure, the cement and concrete industry is a major contributor to global carbon emissions, necessitating urgent decarbonisation strategies to mitigate climate change and achieve net-zero targets by 2050. This review explores technological pathways and innovations essential for lowering carbon emissions, including low-carbon materials, energy-efficient processes, carbon capture, utilization and storage (CCUS), and advanced production technologies. It also highlights the importance of supportive policy frameworks, financial incentives, and international collaboration in accelerating the transition to a low-carbon industry. While challenges such as high initial costs, resistance to change, and knowledge gaps persist, these can be addressed through innovation, education, and robust financial mechanisms. Furthermore, circular economy principles, sustainable procurement practices, and continued research and development are emphasized as critical enablers of the industry’s transformation. The paper concludes with recommendations for future actions, highlighting the role of cross-sector cooperation, research funding, and knowledge sharing in achieving a sustainable and decarbonised cement and concrete sector that can “go green” for eco-constructions. Full article

Driven by global carbon reduction targets, supersulfated cement has emerged as a promising low-carbon cementitious material. This study investigates the influence of a polycarboxylate superplasticizer (PCE) on the rheological behavior and early interfacial evolution of phosphogypsum-based supersulfated cement (PSSC). Rheological measurements, pore solution ion analysis, hydration heat analysis, X-ray diffraction (XRD), and scanning electron microscopy coupled with energy-dispersive spectroscopy (SEM–EDS) are employed to correlate early hydration processes with structural development. The results indicate that the incorporation of PCE significantly reduces the initial yield stress and moderates the structural build-up rate. At a PCE dosage of 0.3 wt.%, the initial static yield stress decreases from 1313 Pa to approximately 125 Pa, while the structural build-up index I_s,s reaches 10.19, indicating improved particle dispersion while maintaining progressive structural reconstruction during hydration. Phosphogypsum (PG) functions not only as a sulfate source but also as an active interfacial substrate that promotes the preferential nucleation of AFt on its surface. In the absence of PCE, continuous Ca–P-enriched layers form on PG particles, accompanied by localized AFt accumulation. After the incorporation of PCE, the primary crystalline phases remain unchanged; however, gypsum dissolution and AFt formation are delayed. Meanwhile, Ca–P enrichment shifts from continuous coverage to a more dispersed distribution, promoting the spatially separated growth of AFt crystals rather than dense localized aggregation. Overall, PCE influences the evolution of the structure and properties of the system by regulating early interfacial reactions and the spatial organization of hydration products. Full article

This study investigates the mechanical properties and internal pore structure characteristics of raw phosphogypsum–basalt fiber (RPG-BF) cementitious materials with varying raw phosphogypsum (PG) replacement ratios. Specifically, six different PG addition levels (0%, 3%, 6%, 9%, 12%, and 15% by mass of cementitious materials) with a constant basalt fiber dosage of 0.1% (by volume of concrete) were adopted. The mechanical properties of RPG-BF cementitious materials were evaluated by testing the 7-day and 28-day compressive strengths, 28-day split tensile strength, and 28-day flexural strength. Meanwhile, the pore distribution characteristics of the RPG-BF cementitious materials were systematically analyzed using liquid nitrogen adsorption (LNA) tests and scanning electron microscopy (SEM) observations. The experimental results indicate the following: (a) With an increase in PG content, the mechanical properties of RPG-BF cementitious materials exhibit a significant downward trend: the 28-day compressive strength, split tensile strength, and flexural strength decrease by 49%, 44%, and 43%, respectively. (b) The internal pores of the RPG-BF cementitious materials possess excellent fractal characteristics, with fractal dimensions ranging from 2.52 to 2.62. As the PG content increases, the pore structure becomes more intricate and less homogeneous, which is a microstructural factor associated with the degradation of mechanical properties. (c) There exists a strong Pearson’s linear correlation (R > 0.82, with R² ranging from 0.67 to 0.94) between the pore fractal dimension of RPG-BF cementitious materials and their 7-day/28-day compressive strength, split tensile strength, and flexural strength. (d) SEM observations show that the quantity of micropores and microcracks in the RPG-BF cementitious materials increases with increasing PG content, further confirming deterioration of the material microstructure. Full article

Conductive core–shell superabsorbent polymers (SAPs) are emerging as multifunctional additives for cementitious materials, combining moisture management with electrical functionality. In cement-based systems, a swellable polymeric core enables internal curing and crack-sealing through controlled water uptake and release, while a conductive shell introduces ionic and/or electronic charge transport, addressing key limitations of conventional non-conductive SAPs. This dual functionality provides a pathway toward smart cementitious composites with enhanced durability, self-sensing capability, and moisture-responsive behavior. This review focuses on the physical chemistry mechanisms governing conductive core–shell SAPs in cementitious environments, with emphasis on swelling thermodynamics, water transport kinetics, interfacial phenomena, and charge transport mechanisms. The roles of osmotic pressure, elastic network constraints, ionic effects, and pore solution chemistry are critically discussed, together with their impact on conductivity, hydration processes, microstructure development, and long-term performance. The relative contributions of ionic and electronic conduction are examined in relation to hydration state, shell morphology, and percolation of conductive networks. In addition, the relevance of core–shell SAP architectures to sustainable packaging is briefly discussed as a secondary application, illustrating how similar physicochemical principles—such as moisture buffering and functional coatings—apply beyond construction materials. Finally, key knowledge gaps are identified, including long-term stability in highly alkaline environments, trade-offs between swelling capacity and conductivity, environmental impacts of conductive phases, and the need for integrated experimental and modeling approaches. Addressing these challenges is essential for the rational design and practical implementation of conductive core–shell SAPs in next-generation cementitious materials. Full article

Red mud (RM), a waste residue from alumina extraction, poses serious environmental impacts on water resources, land resources, and ecological systems due to its large production, high alkalinity, and low resource utilization. To enhance the overall utilization rate of RM solid-waste materials, this study focuses on RM, blast furnace slag (BFS), and fly ash (FA) cementitious materials as the research objects. Through mechanical tests and microstructural analysis, the optimal mix ratio of the ternary RM-based cementitious material is determined, and a systematic study of its microstructural evolution is conducted. Concurrently, fractal theory was used to quantify the microstructure of the material, revealing the evolution laws of the mechanical properties of ternary red-mud-based cementitious materials from a mesoscopic perspective. The results indicate that reducing the proportion of RM or slag alone to increase the FA content yields inferior modification effects compared to simultaneously reducing the proportions of both RM and BFS to increase FA content. Compared with the binary RM-based cementitious material made of RM and BFS, the 28-day compressive strength increases by approximately 25%, reaching 50 MPa. The incorporation of FA can reduce the volume of harmful pores in the cementitious matrix, providing ample reactive material for subsequent hydration reactions, promoting later hydration products, and improving the distribution of the internal pore structure. This leads to increases in both fractal dimensions, and a rational mix proportion can effectively improve the microstructure and mechanical properties of the ternary RM-based cementitious material. Full article

The cement industry contributes approximately 7–8% of global CO₂ emissions, motivating the development of sustainable supplementary materials. This study evaluates the partial replacement (10 wt.%) of Portland cement with calcium carbonate (CaCO₃) derived from oyster shells, both untreated and thermally treated at 600 °C, in non-structural mortar blocks. Structural and physicochemical characterization was performed using XRD, SEM, EDS, BET, and TGA to assess phase composition, morphology, and surface properties. Thermal treatment modified the textural characteristics of CaCO₃, reducing the crystallite size and increasing the specific surface area (from 5.8 to 25.6 m²/g), without phase transformation. Compressive strength results, relative to a reference mortar (13.6 MPa), showed comparable performance, with variations generally within ±10%, although slightly larger deviations were observed for specific particle sizes. Finer calcined particles yielded the highest strength (15.0 MPa), reinforcing the combined influence of particle size and thermal treatment. These results suggest that CaCO₃ acts primarily through a filler effect, improving particle packing and matrix interaction. Both untreated and heat-treated CaCO₃ satisfied strength requirements for non-structural applications, supporting the valorization of oyster shell waste as a sustainable material in cement-based systems. Full article