Search Results (809)

To reduce the carbon footprint of the concrete industry and promote a circular economy, this study explores the reuse of waste materials such as glass powder (GP) and nitrile rubber (NR) fibres in concrete. However, the inclusion of these waste materials results in lower compressive strength compared to conventional concrete, limiting their application to non-structural elements. To overcome this limitation, this study adopts the concept of confined concrete by developing concrete-filled steel tube (CFST) stub columns. In total, twelve concrete mix variations were developed, with and without steel tube confinement. GP was utilised at replacement levels of 10–30% by weight of cement, while NR fibres were introduced at 0.5% and 1% by volume of concrete. The findings demonstrate that the incorporation of GP and NR fibres leads to a reduction in compressive strength, with a compounded effect observed when both materials are combined. Steel confinement within CFST columns effectively mitigated the strength reductions, restoring up to 17% of the lost capacity and significantly improving ductility and energy absorption capacity. All CFST columns exhibited consistent local outward buckling failure mode, irrespective of the concrete mix variations. A comparison with predictions from existing design codes and empirical models revealed discrepancies, underscoring the need for refined design approaches for CFST columns incorporating sustainable concrete infill. This study contributes valuable insights into the development of eco-friendly, high-performance structural systems, highlighting the potential of CFST technology in facilitating the adoption of waste materials in the construction sector. Full article

This study explores the application of low-power vibrothermography (LVT) for detecting barely visible impact damage (BVID) in carbon fibre-reinforced polymer (CFRP) laminates. Composite specimens with varying impact energies (2.5–20 J) were excited using a single piezoelectric transducer with a nominal centre frequency of 28 kHz, operated at a fixed excitation frequency of 28 kHz. Thermal data were captured using an infrared camera. To enhance defect visibility and suppress background noise, the raw thermal sequences were processed using principal component analysis (PCA) and robust principal component analysis (RPCA). In LVT, RPCA and PCA provided comparable signal-to-noise ratios (SNR), with no consistent advantage for either method across all cases. In contrast, for pulsed thermography (PT) data, RPCA consistently resulted in higher SNR values, except for one sample. The LVT results were further validated by comparison with PT and phased array ultrasonic testing (PAUT) data to confirm the location and shape of detected damage. These findings demonstrate that LVT, when combined with PCA or RPCA, offers a reliable method for identifying BVID and can support safer, more efficient structural health monitoring of composite materials. Full article

The aerospace industry is increasingly turning to composite materials due to their exceptional strength, stiffness, and beneficial physical properties. However, increased reliance on carbon fibre composites has substantial environmental implications, particularly concerning waste management. Recycling these materials is a potential solution to these sustainability issues, provided the recycled fibres retain adequate mechanical strength and durability. This study evaluates the mechanical capabilities of recycled carbon fibres in a scaled-down aircraft spar model (AMT-600 GURI), contrasting them with the capabilities of conventional spars. The primary objective is to ascertain whether recycled composites can fulfil the stringent structural requirements of aerospace applications, employing both simulation and experimental validation methods. The recycled carbon fibre composites were manufactured using hand lay-up and vacuum bagging techniques, and their properties were validated through rigorous tensile and compressive strength testing. These validated results were then used to inform a finite element model developed in HyperWorks software. Simulations revealed that the recycled spar achieved maximum stress values of 3.87 MPa under lift forces, a slight increase of +8.95% compared to the original spar, and 55.05 MPa under drag forces, a significant improvement of +36%. Aerodynamic evaluations further confirmed the structural resilience of the recycled spar, with displacement measurements of 141.4 mm for lift and 504.8 mm for drag, closely aligning with the original spar’s performance. In summary, this study demonstrates that recycled carbon fibre composites can serve as effective substitutes for traditional aerospace materials, thereby supporting sustainability initiatives without compromising performance. The outlined approach provides a reliable framework for incorporating recycled materials. Full article

Three-dimensionally printed cement-based composites emerge as a research hotspot in the fields of construction engineering in recent years. Current research primarily focuses on the reinforcement mechanisms of individually incorporated fibres, while a significant gap remains in the synergistic effects of hybrid fibre systems. This study investigates the effects of mono-doping (0.2 wt.% and 0.4 wt.% by the mass of the cement) and hybrid-doping (0.1 wt.% + 0.1 wt.% by the mass of the cement) with 3 mm polypropylene, basalt, and carbon fibres on the fresh-state properties and mechanical behaviours. Through quantitative characterisation of the flowability and mechanical performance of short-fibre-reinforced 3D-printed cementitious composites (SFR3DPC), coupled with comprehensive testing including digital image correlation, X-ray diffraction, and scanning electron microscopy, several key findings are obtained. The experimental results indicate that the addition of excess fibres reduces fluidity, which affects the mechanical performance and make the anisotropy of the composites more pronounced. While the single addition of 0.2 wt.% CF shows the most significant improvement in flexural and compressive strengths, the hybrid combination of 0.1 wt.% CF and 0.1 wt.% BF shows the greatest increase in interlayer bond strength by 26.7%. The complementary effect of the hybrid fibres contributes to the damage mode of the composites from brittle fracture to quasi-brittle behaviour at the physical level. These findings offer valuable insights into optimising the mechanical performance and improving defects of 3D-printed cementitious composites with short fibres. Full article

There has been a growing interest in polymer-based materials in recent years, and current research is focused on reducing fossil-derived epoxy compounds. This review examines the potential of epoxidised vegetable oils (EVOs) as sustainable alternatives to these systems. Epoxidation processes have been systematically analysed and their influence on chemical, thermal, and mechanical properties has been assessed. Results indicate that basic, low-toxicity epoxidation methods resulted in resins with comparable performance to those obtained through more complex common/commercial procedures. In total, 5–7% oxirane oxygen content (OOC) was found to be optimal to achieve a balanced crosslink density, thus enhancing tensile strength. Furthermore, mechanical properties have been insufficiently studied, as less than half of the studies were conducted at least tensile or flexural strength. Reinforcement strategies were also explored, with nano-reinforcing carbon nanotubes (CBNTs) showing the best mechanical and thermal results. Natural fibres reported better mechanical performance when mixed with EVOs than conventional systems. On the other hand, one of the main constraints observed is the lack of consistency in reporting key chemical and mechanical parameters across studies. Environmental properties and end-of-life use are significant challenges to be addressed in future studies, as there remains a significant gap in understanding the end-of-life of these materials. Future research should focus on the exploration of eco-friendly epoxidation reagents and standardise protocols to compare and measure oil properties before and after being epoxidised. Full article

In this study, a new fibre combination for an interlayer hybrid fibre-reinforced polymer laminate was investigated to achieve pseudo-ductile behaviour in tensile tests. The chosen high-strain fibre for this purpose was S-Glass, and the low-strain fibre was flax. These materials were chosen because of their relatively low environmental impact compared to carbon/carbon and carbon/glass hybrids. An analytical model was used to find an ideal combination of the two materials. With that model, the expected stress–strain relation could also be predicted analytically. The modelling was based on preliminary tensile tests of the two basic components investigated in this research: unidirectional laminates reinforced with either flax fibres or S-Glass fibres. Hybrid specimens were then designed, produced in a heat-assisted pressing process, and subjected to tensile tests. The strain measurement was performed using distributed fibre optic sensing. Ultimately, it was possible to obtain repeatable pseudo-ductile stress–strain behaviour with the chosen hybrid when the specimens were subjected to quasi-static uniaxial tension in the direction of the fibres. The intended damage-mode, consisting of a controlled delamination at the flax-fibre/glass-fibre interface after the flax fibres failed, followed by a load transfer to the glass fibre layers, was successfully achieved. The pseudo-ductile strain averaged 0.52% with a standard deviation of 0.09%, and the average load reserve after delamination was 145.5 MPa with a standard deviation of 48.5 MPa. The integrated fibre optic sensors allowed us to monitor and verify the damage process with increasing strain and load. Finally, the analytical model was compared to the measurements and was partially modified by neglecting the Weibull strength distribution of the high-strain material. Full article

This study investigates the influence of cerium nitrate (Ce(NO₃)₃·6H₂O) content on the performance of Ce(III)/CF/BN/EPN coatings intended for heat exchangers. A series of Ce(III)/carbon fibre (CF)/boron nitride (BN)/epoxy phenolic (EPN) coatings are fabricated with varying concentrations of Ce(NO₃)₃·6H₂O. The results of SEM and EDS show that the dissolution of cerium nitrate in acetone due to the particulate form causes it to be distributed in a diffuse state in the coating. This diffuse distribution does not significantly alter the porosity or structural morphology of the coating. With the increase in cerium nitrate content, both the EIS test results and mechanical damage tests indicate a progressive improvement in the corrosion resistance and self-healing properties of the coatings, while the thermal conductivity (TC) remains largely unaffected. The Ce in the coating reacts with the water molecules penetrating into the coating to generate Ce₂O₃ and CeO₂ with protective properties to fill the permeable pores inside the coating or to form a passivation film at the damaged metal–coating interface, which enhances the anticorrosive and self-repairing properties of the coating. However, the incorporation of Ce(NO₃)₃·6H₂O does not change the distribution structure of the filler inside the coating. As a result, the phonon propagation path, rate, and distance remain unchanged, leading to negligible variation in the thermal conductivity. Therefore, at a cerium nitrate content of 2.5 wt%, the coating exhibits the best overall performance, characterised by a |Z|_0.1Hz value of 6.08 × 10⁹ Ω·cm² and a thermal conductivity of approximately 1.4 W/(m·K). Full article

Nylon reinforced with short carbon fibres exhibits superior mechanical properties. Its use as a feedstock for fused deposition modelling (FDM) can extend its applications to consumer goods and industrial products. To investigate the flexural and impact properties of the FDM-printed short carbon fibre-reinforced nylon, a central composite face-centred (CCF) design with four factors and three levels and the response surface method (RSM) were employed. The four primary process parameters are the extrusion and bed temperatures, printing speed, and layer thickness. The three investigated responses were the flexural strength, flexural modulus, and impact strength. Perturbation curves and contour plots were used to analyse the influences of the individual and two-way interactions of the response parameters, respectively. Second-order statistical models were constructed to predict and optimise the mechanical properties. The optimal comprehensive mechanical properties were determined using a desirability function combined with the entropy weighting method. The predicted results of best comprehensive mechanical properties are 169.881 MPa for the flexural strength, 9249.11 MPa for the flexural modulus, and 29.659 kJ∙m⁻² for the impact strength, achieved under the parameter combination of extrusion temperature of 318 °C, bed temperature of 90 °C, printing speed of 30 mm∙s⁻¹, and layer thickness of 0.1 mm. A small deviation between the predicted and experimental results indicated the high reliability of the proposed method. The optimal outcomes under the studied parameters showed higher robustness and integrity than previously reported results. Full article

Concrete and other cementitious materials are among the most widely used construction materials worldwide. However, their high embodied carbon emissions and energy-intensive manufacturing processes pose significant environmental challenges. This study assesses the carbon emissions, cost implications, and circularity potential of a novel concrete mix, Tex-crete, which incorporates recycled textile and cardboard fibres as sustainable alternatives to conventional reinforcement and cementitious materials in concrete. The study employs a cradle-to-gate life cycle assessment (LCA) approach to compare carbon emissions and costs across different mix designs, using two case studies: a temporary construction site compound and a footpath. Experimental results indicate that Tex-crete, particularly the KFT mix design (including 2.5% textile fibres with treated kraft fibres), achieves comparable compressive and tensile strength to traditional concrete while demonstrating a net reduction in both carbon emissions (3.38%) and production costs (2.56%). A newly introduced circularity index (CI) further evaluated the reuse, repair, and recycling potential of the novel mix, revealing that KFT exhibits the highest circularity score (0.44). Parametric analysis using Monte Carlo simulations highlighted transportation distance and energy consumption during fibre processing as key factors influencing emissions. The findings provide valuable insights for industry stakeholders seeking sustainable concrete solutions aligned with circular economy principles, offering an optimized balance between environmental performance, structural integrity, and cost-effectiveness. Full article

This study presents a novel methodology for the real-time characterisation and quantitative assessment of damage in fibre-reinforced polymers (FRPs) using acoustic emission (AE) techniques. While FRPs offer superior mechanical properties for structural applications, their anisotropic nature introduces complex damage mechanisms that are challenging to detect with conventional inspection methods. Our approach advances beyond traditional peak frequency analysis by implementing a multi-variant frequency assessment that can detect and evaluate simultaneously occurring damage modes. By applying the fast Fourier transform and examining multiple frequency peaks within AE signals, we successfully identified five distinct damage mechanisms in carbon fibre composites: matrix cracking (100–200 kHz), delamination (205–265 kHz), debonding (270–320 kHz), fibre fracture (330–385 kHz), and fibre pullout (395–490 kHz). A comparative analysis with wavelet transform methods demonstrated that our approach provides earlier detection of critical damage events, with delamination identified approximately 28 s sooner than with conventional techniques. The proposed methodology enables a more accurate quantitative assessment of structural health, facilitating timely maintenance interventions for large-scale FRP structures, such as wind turbine blades, thereby enhancing reliability while reducing operational downtime and maintenance costs. Full article

Geopolymer composite materials are a viable alternative to conventional construction materials. The research problem of geopolymer composites revolves around the imperative to comprehensively address their synthesis, structural performance, and environmental impact. The derived mathematical model facilitates precisely determining the optimal proportions of two crucial constituents in the geopolymer matrix: silica sand and secondary aluminum by-product. A mathematical model for optimizing the composition of geopolymer composites has been developed based on the integrated use of Markov chains, criterion methods, and an orthogonally compositional plan. The optimal composition of the geopolymer matrix is determined and predicted using a mathematical model. Specifically, the recommended content mixing ratio is as follows: metakaolin at 1000 g, activator at 900 g, silica fume at 1052.826 g, carbon fibre at 10 g, and secondary aluminum by-product at 62.493 g. This study analyzes the influence of different secondary aluminum industry by-products on the geopolymerization process and assesses the mechanical, thermal, and environmental properties of the resulting composites to establish a comprehensive understanding of their structural viability. Full article

This study focuses on improving the recycled coarse aggregate (RCA) replacement ratio in recycled aggregate concrete products. First, the mix design and compressive performance of recycled aggregate concrete (RAC, RCA replacement percentages of 20%, 35%, and 50%) were evaluated using the monofactor analysis method and response surface methodology under three different conditions: single addition of nano-calcium carbonate (NC, dosages of 0.1%, 0.2%, and 0.3%), single addition of basalt fibre (BF, volume content of 0.1%, 0.2%, and 0.3%), and combined addition of both. The results show that the compressive strength of RAC at 7 and 28 days rises as the BF or NC content increases and then falls as the NC content increases. According to the sensitivity analysis, RAC’s compressive strength is significantly impacted by the replacement ratio of RCA, with NC having a more considerable effect on RAC’s 7-day compressive strength than BF, while BF affects the 28-day compressive strength more than NC does. Based on the desirability function, the ideal BF and NC content in RAC was optimised and confirmed by the compressive strength test. It demonstrates that the best compressive performance is achieved by RAC with 1% NC and 0.3% BF. Finally, concrete pavement brick models were created using the ideal mix proportion provided by the compressive strength test. The model compression test results show that RAC pavement bricks (RCA replacement ratio of 60%) with 1% NC and 0.3% BF had a 28d compressive strength of 5.7% and 15.8% higher than NAC and RAC pavement bricks, respectively. Full article

Crosslinked phenolic resin was prepared using hexamethylenetetramine (HMTA) as a crosslinking agent in hydrochloric acid solution. The ablation-heat-resistant material was prepared by a pressure-assisted RTM (resin transfer molding) process with reinforcing material (quartz fibre 2.5D needle-punched fabric/satin fibre cloth/fibre mesh tire) and matrix (crosslinked phenolic resin). The thermal stability of the cured product was studied by a thermogravimetric analyser (TG and DTG). The mechanical properties, heat resistance, and ablation properties of the composites were tested. The ablation morphology, element analysis, and phase structure of the composites were analysed by scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), and X-ray diffraction (XRD), respectively. The results show that the phenolic resin has a lower initial viscosity and a longer pot life at 80 °C, and a higher carbon residue rate (70.18%). The tensile strength of the composites is close to 40 MPa, the tensile modulus is higher than 1.35 GPa, the compression modulus is higher than 10 MPa, and the elongation at break is higher than 1.55%. SiO₂, SiC, and ZrO₂ ceramic phases were formed after ablation, which effectively improved the ablation performance of the composites. Full article

Carbon fibre reinforced composite (CFRP) laminates are widely used in high-tech industries. However, their assembly often requires a drilling process that can create defects. Therefore, studies on the drill tip angle have sought to minimize the surface area affected by these defects and improve the internal hole quality. In this work, drilling was carried out under dry conditions at a constant cutting speed for four different feed rates in the epoxy–carbon-based thermosetting laminate (EPX-C). Two carbide drills with point angles of 118° and 140° were used. The results showed the occurrence of chipping-type delaminations on both the hole entry and exit surfaces, with the latter being more severely affected. The delamination factor values obtained indicated that the 118° drill performed better than the 140° drill. The results were also compared with those obtained in a previous study using drills with angles of 60° and 130°. Although the values were higher, they followed the same trend of reduction with increasing feed. In terms of surface finish, the average roughness (Ra) values obtained with the 140° drill were better at the lowest feed rate. Full article

Lignin, one of the most abundant biopolymers on Earth, holds significant promise as a feedstock for applications such as resins, biofuels, foams, and carbon fibres. However, despite extensive research, lignin remains largely underutilised, with its primary use limited to combustion for energy. While lignin’s structural features are well documented, there is a lack of consistent data on its key physical properties such as density. This study addresses that gap by providing experimentally determined values for skeletal and bulk densities of lignins obtained through different extraction methods, including Kraft; soda pulping; and particularly the ionoSolv process, using ionic liquids such as N,N-dimethyl butyl ammonium hydrogen sulphate ([DMBA][HSO₄]). The results reveal correlations between lignin chemical structure and density in ionoSolv-extracted lignins from Eucalyptus Red Grandis, suggesting opportunities to tune the extraction parameters for targeted material properties. The skeletal density of the lignin samples ranged from 1.3370 to 1.4598 g/cm³, while the bulk density varied more widely—from 0.0944 to 0.5302 g/cm³—reflecting significant differences in particle packing and porosity depending on the biomass source and extraction method. These findings contribute valuable data for process design and scale-up, advancing the commercial viability of lignin-based products. Full article