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31 pages, 469 KiB  
Article
Enhancing Cryptographic Solutions for Resource-Constrained RFID Assistive Devices: Implementing a Resource-Efficient Field Montgomery Multiplier
by Atef Ibrahim and Fayez Gebali
Computers 2025, 14(4), 135; https://doi.org/10.3390/computers14040135 - 6 Apr 2025
Viewed by 448
Abstract
Radio Frequency Identification (RFID) assistive systems, which integrate RFID devices with IoT technologies, are vital for enhancing the independence, mobility, and safety of individuals with disabilities. These systems enable applications such as RFID navigation for blind users and RFID-enabled canes that provide real-time [...] Read more.
Radio Frequency Identification (RFID) assistive systems, which integrate RFID devices with IoT technologies, are vital for enhancing the independence, mobility, and safety of individuals with disabilities. These systems enable applications such as RFID navigation for blind users and RFID-enabled canes that provide real-time location data. Central to these systems are resource-constrained RFID devices that rely on RFID tags to collect and transmit data, but their limited computational capabilities make them vulnerable to cyberattacks, jeopardizing user safety and privacy. Implementing the Elliptic Curve Cryptography (ECC) algorithm is essential to mitigate these risks; however, its high computational complexity exceeds the capabilities of these devices. The fundamental operation of ECC is finite field multiplication, which is crucial for securing data. Optimizing this operation allows ECC computations to be executed without overloading the devices’ limited resources. Traditional multiplication designs are often unsuitable for such devices due to their excessive area and energy requirements. Therefore, this work tackles these challenges by proposing an efficient and compact field multiplier design optimized for the Montgomery multiplication algorithm, a widely used method in cryptographic applications. The proposed design significantly reduces both space and energy consumption while maintaining computational performance, making it well-suited for resource-constrained environments. ASIC synthesis results demonstrate substantial improvements in key metrics, including area, power consumption, Power-Delay Product (PDP), and Area-Delay Product (ADP), highlighting the multiplier’s efficiency and practicality. This innovation enables the implementation of ECC on RFID assistive devices, enhancing their security and reliability, thereby allowing individuals with disabilities to engage with assistive technologies more safely and confidently. Full article
(This article belongs to the Special Issue Wearable Computing and Activity Recognition)
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20 pages, 10592 KiB  
Article
Use of Uncrewed Aerial System (UAS)-Based Crop Features to Perform Growth Analysis of Energy Cane Genotypes
by Ittipon Khuimphukhieo, Lei Zhao, Benjamin Ghansah, Jose L. Landivar Scott, Oscar Fernandez-Montero, Jorge A. da Silva, Jamie L. Foster, Hua Li and Mahendra Bhandari
Plants 2025, 14(5), 654; https://doi.org/10.3390/plants14050654 - 21 Feb 2025
Cited by 1 | Viewed by 999
Abstract
Plant growth analysis provides insight regarding the variation behind yield differences in tested genotypes for plant breeders, but adopting this application solely for traditional plant phenotyping remains challenging. Here, we propose a procedure of using uncrewed aerial systems (UAS) to obtain successive phenotype [...] Read more.
Plant growth analysis provides insight regarding the variation behind yield differences in tested genotypes for plant breeders, but adopting this application solely for traditional plant phenotyping remains challenging. Here, we propose a procedure of using uncrewed aerial systems (UAS) to obtain successive phenotype data for growth analysis. The objectives of this study were to obtain high-temporal UAS-based phenotype data for growth analysis and investigate the correlation between the UAS-based phenotype and biomass yield. Seven different energy cane genotypes were grown in a random complete block design with four replications. Twenty-six UAS flight missions were flown throughout the growing season, and canopy cover (CC) and canopy height (CH) measurements were extracted. A five-parameter logistic (5PL) function was fitted through these temporal measurements of CC and CH. The first- and second-order derivatives of this function were calculated to obtain several growth parameters, which were then used to assess the growth of different genotypes with respect to weed competitiveness and biomass yield traits. The results show that CC and CH growth rates significantly differed among genotypes. TH16-16 was outstanding for its ground cover growth; therefore, it was identified as a weed-competitive genotype. Furthermore, TH16-22 had a higher CH maximum growth rate per day, yielding a higher biomass compared to other genotypes. The CH-based multi-temporal data as well as the growth parameters had a better relationship with biomass yield. This study highlights the application of UAS-based high-throughput phenotyping (HTP), along with growth analysis, for assisting plant breeders in decision-making. Full article
(This article belongs to the Special Issue Modeling of Plants Phenotyping and Biomass)
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17 pages, 2623 KiB  
Article
Exploring the Grape Agrivoltaic System: Climate Modulation and Vine Benefits in the Puglia Region, Southeastern Italy
by Andrea Magarelli, Andrea Mazzeo and Giuseppe Ferrara
Horticulturae 2025, 11(2), 160; https://doi.org/10.3390/horticulturae11020160 - 3 Feb 2025
Cited by 5 | Viewed by 2696
Abstract
Climate change poses significant challenges to agriculture, a sector with a long-standing tradition in the Mediterranean basin. The region faces altered rainfall patterns, extreme temperatures, aridification, loss of biodiversity, and changes in crop yield and quality. These impacts, combined with intensive farming practices, [...] Read more.
Climate change poses significant challenges to agriculture, a sector with a long-standing tradition in the Mediterranean basin. The region faces altered rainfall patterns, extreme temperatures, aridification, loss of biodiversity, and changes in crop yield and quality. These impacts, combined with intensive farming practices, threaten long-term agricultural sustainability. This study investigates agrivoltaics (AVs), a dual-use technology that integrates solar energy production (photovoltaic panels) with agriculture, as a potential solution to enhance resilience and adaptation of crops. Research at an AV system in Puglia (Southeastern Italy), combined with grapevine (Vitis vinifera L.), assessed soil moisture, temperature, and microclimate conditions together with vine yield and fruitfulness. Results showed that shading from photovoltaic panels increased soil moisture and moderated soil temperature, thus benefiting crops. Vines beneath the panels yielded more grapes (+277%) than in the full sun, confirmed by even the better bud fruitfulness of the shaded canes. While panels had minimal impact on air temperature, they reduced wind speed and vapor pressure deficit, creating a better microenvironment for vines. Spectral analysis revealed an increase in UV and blue light under the panels, potentially affecting photosynthesis. The AV system also produced substantial electricity, more than 90% compared to a ground-mounted system, demonstrating its dual-use application. The higher land equivalent ratio (LER) achieved by the AV system (3.54) confirmed that such systems can be advantageous in areas with a Mediterranean climate, allowing crop and energy production on the same land. Full article
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21 pages, 51133 KiB  
Article
Energy Cane Ash: Property Assessment for Its Valorization in Sustainable Cementing Systems
by Gabriela Pitolli Lyra, Lisiane Brichi, Josefa Roselló, María Victoria Borrachero, Lourdes Soriano, Jordi Payá and João Adriano Rossignolo
Sustainability 2025, 17(2), 803; https://doi.org/10.3390/su17020803 - 20 Jan 2025
Viewed by 1077
Abstract
Cogeneration with energy cane, a highly productive variety compared to conventional sugarcane, significantly increases ash generation, presenting waste management challenges for the sugar and ethanol industries. This study evaluates the potential of energy cane ash as a sustainable alternative material for partial cement [...] Read more.
Cogeneration with energy cane, a highly productive variety compared to conventional sugarcane, significantly increases ash generation, presenting waste management challenges for the sugar and ethanol industries. This study evaluates the potential of energy cane ash as a sustainable alternative material for partial cement replacement in construction, contributing to circular economy practices. A productivity analysis was conducted for planted areas, and the different parts of sugarcane and energy cane were dried and examined using scanning electron microscopy. These parts were calcined at 450 °C and 600 °C and analyzed using scanning electron microscopy, X-ray fluorescence, particle size distribution, and thermal analysis. The reactivity of the ashes was tested in cement mortars with 5%, 10%, and 20% cement replacement using washed ash. The results revealed that energy cane produces approximately four times more ash per hectare than sugarcane, with leaf ash containing up to 60% silica and stalk ash being rich in potassium. The highest compressive strength was observed in a mortar with 10% cement replacement using washed energy cane ash, achieving 102.43% of the reference value after 28 days of curing, indicating excellent pozzolanic reactivity. These findings highlight the potential of energy cane ash to enhance sustainability in cementitious systems by reducing Portland cement use and promoting waste valorization. Furthermore, the reuse of ash can mitigate waste accumulation and support the development of more sustainable construction materials, contributing to a circular economy and a low-carbon society. Full article
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19 pages, 1952 KiB  
Review
Applications of Machine Learning Technologies for Feedstock Yield Estimation of Ethanol Production
by Hyeongjun Lim and Sojung Kim
Energies 2024, 17(20), 5191; https://doi.org/10.3390/en17205191 - 18 Oct 2024
Cited by 5 | Viewed by 1568
Abstract
Biofuel has received worldwide attention as one of the most promising renewable energy sources. Particularly, in many countries such as the U.S. and Brazil, first-generation ethanol from corn and sugar cane has been used as automobile fuel after blending with gasoline. Nevertheless, in [...] Read more.
Biofuel has received worldwide attention as one of the most promising renewable energy sources. Particularly, in many countries such as the U.S. and Brazil, first-generation ethanol from corn and sugar cane has been used as automobile fuel after blending with gasoline. Nevertheless, in order to continuously increase the use of biofuels, efforts are needed to reduce the cost of biofuel production and increase its profitability. This can be achieved by increasing the efficiency of a sequential biofuel production process consisting of multiple operations such as feedstock supply, pretreatment, fermentation, distillation, and biofuel transportation. This study aims at investigating methodologies for predicting feedstock yields, which is the earliest step for stable and sustainable biofuel production. Particularly, this study reviews feedstock yield estimation approaches using machine learning technologies that focus on gradually improving estimation accuracy by using big data and computer algorithms from traditional statistical approaches. Given that it is becoming increasingly difficult to stably produce biofuel feedstocks as climate change worsens, research on developing predictive modeling for raw material supply using the latest ML techniques is very important. As a result, this study will help researchers and engineers predict feedstock yields using various machine learning techniques, and contribute to efficient and stable biofuel production and supply chain design based on accurate predictions of feedstocks. Full article
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19 pages, 3447 KiB  
Article
Development of a Two-Stage Bioprocess for the Production of Bioethanol from the Acid Hydrolysate of Brewer’s Spent Grain
by Renata Vičević, Marko Božinović, Nikolina Zekić, Mario Novak, Dajana Kučić Grgić, Anita Šalić and Bruno Zelić
Energies 2024, 17(16), 3975; https://doi.org/10.3390/en17163975 - 11 Aug 2024
Cited by 2 | Viewed by 2300
Abstract
Bioethanol, an alcohol produced by microbial fermentation, is traditionally produced from sugar-rich plants such as sugar cane, sugar beet and maize. However, there is growing interest in the use of lignocellulose, an abundant and inexpensive renewable energy source, as a potential substitute for [...] Read more.
Bioethanol, an alcohol produced by microbial fermentation, is traditionally produced from sugar-rich plants such as sugar cane, sugar beet and maize. However, there is growing interest in the use of lignocellulose, an abundant and inexpensive renewable energy source, as a potential substitute for the production of biofuels and biochemicals. Yeast Saccharomyces cerevisiae, which is commonly used for ethanol fermentation, cannot cope with lignocellulose due to a lack of lignocellulolytic enzymes and the inefficient functioning of the pentose phosphate pathway. The aim of this research was to isolate yeasts that can efficiently produce bioethanol and valuable byproducts from both glucose and xylose in a two-stage fermentation process using brewer’s spent grains. This approach should maximize sugar utilization and improve the economic viability of bioethanol production while contributing to waste valorization and sustainability. Kluyveromyces marxianus and Candida krusei were identified and tested with different initial concentrations of glucose and xylose. The results showed that both yeasts produced bioethanol from glucose but were inefficient with xylose, yielding valuable compounds, such as 2,3-butanediol and glycerol instead. A two-stage fermentation was then carried out with weak acidic hydrolysate from brewer’s spent grain. In the first stage, glucose was fermented by S. cerevisiae to produce bioethanol; in the second stage, xylose was fermented by K. marxianus and C. krusei to obtain other valuable products. Full article
(This article belongs to the Section A4: Bio-Energy)
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19 pages, 1828 KiB  
Article
Carbon Footprint for Jeans’ Circular Economy Model Using Bagasse
by Toshiro Semba, Ryuzo Furukawa and Norihiro Itsubo
Sustainability 2024, 16(14), 6044; https://doi.org/10.3390/su16146044 - 15 Jul 2024
Cited by 2 | Viewed by 3293
Abstract
To date, clothing has been produced and disposed of in large quantities. It is also known that each process, from the procurement of raw materials to production, transportation, sales, laundry, and disposal, has a significant environmental impact. According to the Global Fashion Agenda, [...] Read more.
To date, clothing has been produced and disposed of in large quantities. It is also known that each process, from the procurement of raw materials to production, transportation, sales, laundry, and disposal, has a significant environmental impact. According to the Global Fashion Agenda, greenhouse gas (GHG) emissions from the fashion industry account for 4% of the global total. Therefore, apparel makers are shifting from a linear economy to a circular economy. For example, the Japanese start-up Curelabo Co., Ltd. (Okinawa, Japan) developed jeans (bagasse washi jeans) made from bagasse, which is a residual material derived from sugarcane after the extraction of cane juice. Furthermore, the use of improved dyeing reduces boiler fuel consumption and eliminates the need for detergents and acid. For disposal, the used jeans and their production waste are processed into biochar for carbon sequestration. In this study, we attempted to calculate GHG emissions using life cycle assessment (LCA) for the circular economy model developed by Curelabo Co., Ltd. GHG emissions from the production of bagasse washi jeans were 1.09 × 101 kg-CO2e. Dyeing, bleaching, and fabric finishing, known as the wet processes, were found to contribute a large proportion of GHG emissions due to their high energy consumption. Furthermore, the entire lifecycle of GHG emissions from bagasse washi jeans, including transport, sales, laundry, and disposal, were 1.53 × 101 kg-CO2e. First, the use of bagasse washi yarn for the weft reduced by 2.99 × 10−1 kg-CO2e compared with the use of conventional 100% bleached cotton yarn. Second, compared with conventional dyeing, GHG emissions from the improved dyeing process were reduced by 2.78 kg-CO2e. Third, the disposal of the used jeans and their production waste into biochar reduced GHG emissions by 9.01 × 10−1 kg-CO2e. Additionally, GHG emissions can be reduced by re-inputting waste in the paper-making process and by using liquefied natural gas as boiler fuel in the dyeing process. Full article
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12 pages, 3229 KiB  
Article
Evaluation of Growth and Energy Parameters of One-Year-Old Raspberry Shoots, Depending on the Variety
by Grzegorz Maj, Kamil Buczyński, Kamila E. Klimek and Magdalena Kapłan
Energies 2024, 17(13), 3153; https://doi.org/10.3390/en17133153 - 26 Jun 2024
Cited by 4 | Viewed by 1481
Abstract
The article examines the influence of six varieties of primocane raspberries, Rubus idaeus L., on the growth parameters and energy properties of the biomass. The unique aim of this study was to show the impact of primocane raspberry varieties, grown for a single [...] Read more.
The article examines the influence of six varieties of primocane raspberries, Rubus idaeus L., on the growth parameters and energy properties of the biomass. The unique aim of this study was to show the impact of primocane raspberry varieties, grown for a single harvest, on the growth parameters of the bushes and the energy and emission characteristics of the biomass obtained from the pruned canes. To the best of our knowledge, there is no such analysis connected to varieties of raspberries available in the literature. The following primocane raspberries were assessed: Polana, Polesie, Delniwa, Poemat, Polonez, and Poranek. Among the studied raspberry varieties, Polana was characterized by the highest number of side shoots and the greatest sum of the shoot lengths, while the Polonez variety was characterized by the highest average shoot length and shoot thickness. In the tested raspberry varieties, the weight of the shoots per hectare varied significantly, ranging from 6.06 t in the Poranek variety to 9.05 t in the Delniwa variety. It was shown that the raspberry variety had a significant impact on the higher heating value (HHV) and the lower heating value (LHV). The lowest energy value was found in the Delniwa (HHV—17.32 MJ·kg−1; LHV—16.07 MJ·kg−1) and Polana (HHV—17.33 MJ·kg−1, LHV—16.19 MJ·kg−1) varieties, and the significantly highest value was observed in the Poranek variety (HHV—17.63 MJ·kg−1, LHV—16.39 MJ·kg−1). The assessment of the total volume of exhaust gases showed the highest value of this parameter for the Polesie and Delniwa varieties (6.89 m3·kg−1), with the lowest for the Polana variety (6.69 m3·kg−1). Full article
(This article belongs to the Section B: Energy and Environment)
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25 pages, 5297 KiB  
Article
A Multiomics Perspective on Plant Cell Wall-Degrading Enzyme Production: Insights from the Unexploited Fungus Trichoderma erinaceum
by Michelle A. de Assis, Jovanderson J. B. da Silva, Lucas M. de Carvalho, Lucas S. Parreiras, João Paulo L. F. Cairo, Marina P. Marone, Thiago A. Gonçalves, Desireé S. Silva, Miriam Dantzger, Fernanda L. de Figueiredo, Marcelo F. Carazzolle, Gonçalo A. G. Pereira and André Damasio
J. Fungi 2024, 10(6), 407; https://doi.org/10.3390/jof10060407 - 5 Jun 2024
Cited by 2 | Viewed by 2520
Abstract
Trichoderma erinaceum is a filamentous fungus that was isolated from decaying sugarcane straw at a Brazilian ethanol biorefinery. This fungus shows potential as a source of plant cell wall-degrading enzymes (PCWDEs). In this study, we conducted a comprehensive multiomics investigation of T. erinaceum [...] Read more.
Trichoderma erinaceum is a filamentous fungus that was isolated from decaying sugarcane straw at a Brazilian ethanol biorefinery. This fungus shows potential as a source of plant cell wall-degrading enzymes (PCWDEs). In this study, we conducted a comprehensive multiomics investigation of T. erinaceum to gain insights into its enzymatic capabilities and genetic makeup. Firstly, we performed genome sequencing and assembly, which resulted in the identification of 10,942 genes in the T. erinaceum genome. We then conducted transcriptomics and secretome analyses to map the gene expression patterns and identify the enzymes produced by T. erinaceum in the presence of different substrates such as glucose, microcrystalline cellulose, pretreated sugarcane straw, and pretreated energy cane bagasse. Our analyses revealed that T. erinaceum highly expresses genes directly related to lignocellulose degradation when grown on pretreated energy cane and sugarcane substrates. Furthermore, our secretome analysis identified 35 carbohydrate-active enzymes, primarily PCWDEs. To further explore the enzymatic capabilities of T. erinaceum, we selected a β-glucosidase from the secretome data for recombinant production in a fungal strain. The recombinant enzyme demonstrated superior performance in degrading cellobiose and laminaribiose compared to a well-known enzyme derived from Trichoderma reesei. Overall, this comprehensive study provides valuable insights into both the genetic patterns of T. erinaceum and its potential for lignocellulose degradation and enzyme production. The obtained genomic data can serve as an important resource for future genetic engineering efforts aimed at optimizing enzyme production from this fungus. Full article
(This article belongs to the Section Fungal Cell Biology, Metabolism and Physiology)
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1 pages, 124 KiB  
Abstract
Agro-Industrial Residues from Sugar Cane for Energy Use and Application in Energy Storage Devices
by Arthur Pimentel and Leonardo Paim
Proceedings 2024, 105(1), 107; https://doi.org/10.3390/proceedings2024105107 - 28 May 2024
Viewed by 401
Abstract
Obtaining new materials from waste plays an important role in contributing to sustainability and innovation and reducing the environmental impact of industrial activities, thus contributing to the circular economy of the main production process that gives rise to that waste [...] Full article
16 pages, 5917 KiB  
Article
Design and Experiment of Profiling Furrow-Ridge Terrain by Cane Leaf-Chopping and Returning Machine
by Biao Zhang, Cheng Gao, Weimin Shen and Baoshan Chen
Agriculture 2024, 14(3), 413; https://doi.org/10.3390/agriculture14030413 - 3 Mar 2024
Viewed by 1681
Abstract
Conventional straw-returning machines were incompatible with ridge cultivation terrain and unevenly distributed materials, resulting in substandard operations such as insufficient leaf fragmentation, damage to ratoon stumps, and high cutting energy consumption. In this regard, this paper proposes a novel profiling configuration of chopping [...] Read more.
Conventional straw-returning machines were incompatible with ridge cultivation terrain and unevenly distributed materials, resulting in substandard operations such as insufficient leaf fragmentation, damage to ratoon stumps, and high cutting energy consumption. In this regard, this paper proposes a novel profiling configuration of chopping and returning machine to adapt to the coverage characteristics of cane leaves in furrow-ridge terrain. The leaves piled at furrow sole are intensively collected and fed into the whirling space by the flexible hook teeth assembly, and are cooperatively broken by the unequal-length swing blades densely arranged along the double helix. Based on the measured topographic trends and dynamic analysis of the leaf-shredding process, experimental factors affecting profiling cutting and picking capabilities of the main components were determined. Further, using chopping qualification rate (CQR) and fragmentation degree (CFD) as indicators, field trails were conducted through a response surface method to test the comprehensive crushing performance of the machine. After multi-objective optimization, the optimal structural and operating parameters were determined as: blade length gradient of 1.57 cm, teeth spacing of 6.84 cm and feed speed of 3.2 km/h. With such adaptive configurations, CQR and CFD reached 81.14% and 0.101, respectively, which were significantly improved by 60.50% and 47.99% compared to those of conventional machines. Crushed leaves appeared to be more thoroughly mixed with the soil and more evenly spread in the field. Meanwhile, the traction resistance tended to be stable, with an effective RSM 45.85% lower than the value of higher-level blade gradient, indicating a better overall fit with the irregular terrain. This study can provide a reference for the development of leaf-chopping and returning machines suitable for ridge-type crops. Full article
(This article belongs to the Section Agricultural Technology)
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12 pages, 1457 KiB  
Article
Sugarcane Rapadura: Characteristics of the Oldest Historical Energy Food and Its Native Production Method
by Ricardo Santos, Renata Assis, Raquel Freitas, Isabele Barbosa and Vânia Ceccatto
Processes 2024, 12(3), 511; https://doi.org/10.3390/pr12030511 - 1 Mar 2024
Cited by 1 | Viewed by 2194
Abstract
Rapadura is a well-recognized sugar-cane-derived product with a sweet, characteristic flavor and hard texture. This product is a cultural Brazilian landmark, particularly in Ceará, Brazil, where it is usually produced by small family businesses and consumed locally. This feature contributes to the difficulties [...] Read more.
Rapadura is a well-recognized sugar-cane-derived product with a sweet, characteristic flavor and hard texture. This product is a cultural Brazilian landmark, particularly in Ceará, Brazil, where it is usually produced by small family businesses and consumed locally. This feature contributes to the difficulties of rapadura production standardization, a requirement for the global market. Against this backdrop, this study focuses on analyzing the centesimal composition and mineral content of rapadura. Six samples from different cities in Ceará were analyzed for moisture, ash, lipids, proteins, carbohydrates, energy value, and minerals. The results ranged from 6.42–11.74% for moisture, 0.23–1.12% for ash, 0.49–0.92% for protein, 85.18–89.12% for lipids, and 352.00–391.19 Kcal for energy value. Significant variations were observed between the samples, showing a lack of standardization in the production process. The analysis of micronutrients revealed low levels, with copper and iron standing out in sample D. It can be concluded that the rapadura analyzed meets the physical-chemical parameters established by national legislation and is a food rich in carbohydrates and energy. Full article
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15 pages, 2957 KiB  
Article
Effect of Alkali Treatment under Ambient and Heated Conditions on the Physicochemical, Structural, Morphological, and Thermal Properties of Calamus tenuis Cane Fibers
by Arup Kar, Dip Saikia, Sivasubramanian Palanisamy, Carlo Santulli, Cristiano Fragassa and Sabu Thomas
Fibers 2023, 11(11), 92; https://doi.org/10.3390/fib11110092 - 2 Nov 2023
Cited by 26 | Viewed by 2810
Abstract
This study explores the effect of alkali treatment at ambient (25 °C) and elevated temperatures (100 °C) on the physicochemical, structural, morphological, and thermal properties of Calamus tenuis cane fibers (CTCFs) for the first time. Our purpose is to investigate their potential use [...] Read more.
This study explores the effect of alkali treatment at ambient (25 °C) and elevated temperatures (100 °C) on the physicochemical, structural, morphological, and thermal properties of Calamus tenuis cane fibers (CTCFs) for the first time. Our purpose is to investigate their potential use as reinforcement in polymer composites, since cane fibers are generally known for their accurate and consistent geometrical orientation. Treatment with 8% (w/v) sodium hydroxide (NaOH) is carried out at ambient temperature and at 100 °C for 4 h. Chemical analysis and Fourier transform IR spectroscopy (FTIR) indicate some removal of non-cellulosic elements from CTCFs during alkali treatment, resulting in increased surface roughness, as confirmed by using SEM micrographs. This removal of non-cellulosic elements leads to an enhancement in the density of the treated CTCFs. Untreated and treated fibers are analyzed for maximum degradation temperature, thermal stability, and kinetic activation energy (Ea) using thermogravimetric analysis (TGA). In particular, Ea was considerably diminished with treatment and temperature. X-ray diffraction (XRD) results show an improved crystallinity index (37.38% to 44.02%) and crystallite size (2.73 nm to 2.98 nm) for fibers treated with 8% NaOH at ambient temperature. In conclusion, a general benefit was achieved by treating CTCFs, though the influence of increasing temperature treatment appears controversial. Full article
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13 pages, 1063 KiB  
Article
Development of a Strategy for L-Lactic Acid Production by Rhizopus oryzae Using Zizania latifolia Waste and Cane Molasses as Carbon Sources
by Feng-Wei Yin, Xiao-Long Sun, Wei-Long Zheng, Long-Fei Yin, Xi Luo, Ying-Ying Zhang, Yan-Fei Wang and Yong-Qian Fu
Molecules 2023, 28(17), 6234; https://doi.org/10.3390/molecules28176234 - 24 Aug 2023
Cited by 8 | Viewed by 3002
Abstract
As a biodegradable and renewable material, polylactic acid is considered a major environmentally friendly alternative to petrochemical plastics. Microbial fermentation is the traditional method for lactic acid production, but it is still too expensive to compete with the petrochemical industry. Agro-industrial wastes are [...] Read more.
As a biodegradable and renewable material, polylactic acid is considered a major environmentally friendly alternative to petrochemical plastics. Microbial fermentation is the traditional method for lactic acid production, but it is still too expensive to compete with the petrochemical industry. Agro-industrial wastes are generated from the food and agricultural industries and agricultural practices. The utilization of agro-industrial wastes is an important way to reduce costs, save energy and achieve sustainable development. The present study aimed to develop a method for the valorization of Zizania latifolia waste and cane molasses as carbon sources for L-lactic acid fermentation using Rhizopus oryzae LA-UN-1. The results showed that xylose derived from the acid hydrolysis of Z. latifolia waste was beneficial for cell growth, while glucose from the acid hydrolysis of Z. latifolia waste and mixed sugars (glucose and fructose) from the acid hydrolysis of cane molasses were suitable for the accumulation of lactic acid. Thus, a three-stage carbon source utilization strategy was developed, which markedly improved lactic acid production and productivity, respectively reaching 129.47 g/L and 1.51 g/L·h after 86 h of fermentation. This work demonstrates that inexpensive Z. latifolia waste and cane molasses can be suitable carbon sources for lactic acid production, offering an efficient utilization strategy for agro-industrial wastes. Full article
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14 pages, 6923 KiB  
Article
CO2-Assisted Sugar Cane Gasification Using Transition Metal Catalysis: An Impact of Metal Loading on the Catalytic Behavior
by Daria A. Beldova, Artem A. Medvedev, Alexander L. Kustov, Mikhail Yu. Mashkin, Vladislav Yu. Kirsanov, Irina V. Vysotskaya, Pavel V. Sokolovskiy and Leonid M. Kustov
Materials 2023, 16(16), 5662; https://doi.org/10.3390/ma16165662 - 17 Aug 2023
Cited by 3 | Viewed by 1636
Abstract
To meet the increasing needs of fuels, especially non-fossil fuels, the production of “bio-oil” is proposed and many efforts have been undertaken to find effective ways to transform bio-wastes into valuable substances to obtain the fuels and simultaneously reduce carbon wastes, including CO [...] Read more.
To meet the increasing needs of fuels, especially non-fossil fuels, the production of “bio-oil” is proposed and many efforts have been undertaken to find effective ways to transform bio-wastes into valuable substances to obtain the fuels and simultaneously reduce carbon wastes, including CO2. This work is devoted to the gasification of sugar cane bagasse to produce CO in the process assisted by CO2. The metals were varied (Fe, Co, or Ni), along with their amounts, in order to find the optimal catalyst composition. The materials were investigated by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray diffraction (XRD), and electron diffraction, and were tested in the process of CO2-assisted gasification. The catalysts based on Co and Ni demonstrate the best activity among the investigated systems: the conversion of CO2 reached 88% at ~800 °C (vs. 20% for the pure sugarcane bagasse). These samples contain metallic Co or Ni, while Fe is in oxide form. Full article
(This article belongs to the Special Issue Biomass Materials: Conversion Routes and Modern Applications)
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