Search Results (182)

This study explores the valorization of agro-industrial by-products—riceberry broken rice (RBR) and soybean meal (SBM)—as cost-effective substrates for enhancing exopolysaccharide (EPS) production by Bacillus tequilensis PS21. Eight Bacillus strains were screened, and B. tequilensis PS21 demonstrated the highest EPS yield (2.54 g/100 mL DW). The EPS displayed a strong antioxidant capacity with 65.5% DPPH and 80.5% hydroxyl radical scavenging, and a FRAP value of 6.51 mg Fe²⁺/g DW. Antimicrobial testing showed inhibition zones up to 10.07 mm against Streptococcus agalactiae and 7.83 mm against Staphylococcus aureus. Optimization using central composite design (CCD) and the response surface methodology (RSM) revealed the best production at 5% (w/v) RBR, 3% (w/v) SBM, pH 6.66, and 39.51 °C, yielding 39.82 g/L EPS. This EPS is a moderate-molecular-weight (11,282 Da) homopolysaccharide with glucose monomers. X-ray diffraction (XRD) showed an amorphous pattern, favorable for solubility in biological applications. Thermogravimetric analysis (TGA) demonstrated thermal stability up to ~250 °C, supporting its suitability for high-temperature processing. EPS also exhibited anticancer activity with IC₅₀ values of 226.60 µg/mL (MCF-7) and 224.30 µg/mL (HeLa) at 72 h, reduced colony formation, inhibited cell migration, and demonstrated anti-tyrosinase, anti-collagenase, and anti-elastase effects. This study demonstrates the successful valorization of agro-industrial by-products—RBR and SBM—for the high-yield production of multifunctional EPS with potent antioxidant, antimicrobial, and anticancer properties. The findings highlight the sustainable potential of these low-cost substrates in supporting the development of green and value-added bioproducts, with promising utilizations across the food, pharmaceutical, and cosmetic sectors. Full article

Meloidogyne enterolobii, a highly virulent and broad-host-range plant-parasitic nematode, poses an increasing threat to global agricultural production. By inducing the formation of nutrient-rich giant cells in host roots and deploying a diverse array of effector proteins to modulate plant immune responses, this nematode achieves efficient colonization and invasion, resulting in impaired crop growth and significant economic losses. In recent years, global climate warming combined with the rapid development of protected agriculture has broken the traditional geographical limits of tropical and subtropical regions, thereby increasing the risk of M. enterolobii occurrence in temperate and high-latitude areas. Concurrently, conventional chemical control methods are increasingly limited by environmental pollution and the development of resistance, steering research toward green control strategies. This review systematically summarizes the latest research progress of M. enterolobii in terms of ecological diffusion trends, pathogenic mechanisms, and green control, and explored the feasibility of integrating multidisciplinary technologies to construct an efficient and precise control system. The ultimate aim is to provide theoretical support and technical supports for green and sustainable development of global agriculture. Full article

In bulk liquid or on solid surfaces, nanobubbles (NBs) are gaseous domains at the nanoscale. They stand out due to their extended (meta)stability and great potential for use in practical settings. However, due to the high energy cost of bubble generation, maintenance issues, membrane bio-fouling, and the small actual population of NBs, significant advancements in nanobubble engineering through traditional mechanical generation approaches have been impeded thus far. With the introduction of the electric field approach to NB creation, which is based on electrostrictive NB generation from an incoming population of “electro-fragmented” meso-to micro bubbles (i.e., with bubble size broken down by the applied electric field), when properly engineered with a convective-flow turbulence profile, there have been noticeable improvements in solid-state operation and energy efficiency, even allowing for solar-powered deployment. Here, these innovative methods were applied to a selection of upstream and downstream activities in the oil–water–fuels nexus: advancing core flood tests, oil–water separation, boosting the performance of produced-water treatment, and improving the thermodynamic cycle efficiency and carbon footprint of internal combustion engines. It was found that the application of electric field NBs results in a superior performance in these disparate operations from a variety of perspectives; for instance, ~20 and 7% drops in surface tension for CO₂- and air-NBs, respectively, a ~45% increase in core-flood yield for CO₂-NBs and 55% for oil–water separation efficiency for air-NBs, a rough doubling of magnesium- and calcium-carbonate formation in produced-water treatment via CO₂-NB addition, and air-NBs boosting diesel combustion efficiency by ~16%. This augurs well for NBs being a potent agent for sustainability in the oil and fuels sector (whether up-, mid-, or downstream), not least in terms of energy efficiency and environmental sustainability. Full article

In the digital age, the mechanisms of power and control have evolved beyond Foucault’s disciplinary societies, giving rise to a new paradigm of algorithmic governance. This study critically reinterprets Foucault’s concept of the human subject in light of contemporary digital surveillance, big data analytics, and algorithmic decision-making. The paper looks at how technology, biopolitics, and subject formation interact. It says that algorithmic control changes people’s choices in ways that have never been seen before through predictive modeling and real-time behavioral modulation. The study starts with a comparison of early Foucauldian frameworks and more recent theories of digital governance. It uses a method that combines philosophy, media studies, and political theory. The results show that while disciplinary societies relied on institutionalized norms and body regulation, algorithmic control works through data-driven anticipatory mechanisms, which make subjectivity less clear and more broken up. This shift raises ethical and ontological questions about autonomy, resistance, and the very notion of the self in a hyper-connected society. The study concludes that rethinking Foucault’s insights in the digital era is essential for understanding and contesting the pervasive influence of algorithmic power on human subjectivity. Full article

Background: Pancreatic stents (PSs) play a crucial role in the management of pancreatic duct obstructions, particularly in the context of endoscopic retrograde cholangiopancreatography (ERCP). However, stent migration remains a significant complication, leading to risks such as pancreatitis, pancreatic duct stenosis, and abscess formation. This study aims to evaluate the efficacy of various endoscopic techniques for retrieving proximally migrated or broken pancreatic stents, highlighting optimal strategies for improving patient outcomes. Methods: A retrospective multicenter review was conducted across six hospitals from 2016 to 2024. Patients with proximally migrated or broken pancreatic stents referred for endoscopic retrieval after failed attempts at other facilities were included. Demographic data, stent characteristics, and retrieval techniques were analyzed. Endoscopic methods included SpyGlass forceps, SpyGlass baskets, Soehendra retriever stents, balloon sweeps, flower baskets, and extension pancreatic sphincterotomy. Procedural success, retrieval times, and post-procedural outcomes were assessed. Results: Twelve patients underwent endoscopic retrieval, including two with broken stents. All procedures were successful, with retrieval times averaging 30 to 45 min. Two patients developed pancreatic duct narrowing, requiring balloon dilation. All patients had new stents placed to maintain duct patency, and no major complications were observed. Follow-up evaluations confirmed complete resolution of migration-related issues, with all stents removed. Conclusions: Endoscopic retrieval of migrated pancreatic stents is highly effective, with specialized techniques ensuring a 100% success rate in this study. Early intervention and the selection of appropriate retrieval methods are critical in minimizing complications. Further research is needed to refine retrieval strategies and standardize protocols to enhance clinical outcomes. Full article

The study aimed to determine the physical and physicochemical properties of soybean grains using NIR spectroscopy coupled with multivariate data analysis. The experiment was carried out in two stages: first, individual characterization of defects and healthy grains; then, analyses of samples classified into different types (type I, type II, basic standard, and out of type). The centesimal composition of the grains (crude protein, lipids, water content, crude fiber, starch, and ash) was determined by NIR spectroscopy, and the data were analyzed by ANOVA, Scott-Knott test, principal component analysis (PCA), k-means clustering, and Pearson correlation. The results showed significant variations between defects and commercial types in all the variables evaluated (p < 0.05), with an emphasis on germinated grains (higher protein content) and broken grains (higher fiber content). The PCA explained 66.6% of the total variance in the defect sets and 52.2% of the types, allowing the formation of groups defined by the clustering algorithms. Pearson correlations indicated important interactions between the chemical variables, such as the negative correlation between protein and crude fiber (r = −0.73) and between lipids and water content (r = −0.66). It is concluded that the NIR method combined with multivariate modeling allows for the rapid assessment of soybean grain quality in real time, optimizing, reducing waste in, and increasing the efficiency of post-harvest processes. Full article

Understanding the coupled evolution mechanisms of stress, fracture, and seepage fields in overburden strata is critical for preventing water inrush disasters during fully mechanized mining in deep coal seams, particularly under complex hydrogeological conditions. To address this challenge, this study integrates laboratory experiments with FLAC3D numerical simulations to systematically investigate the multi-field coupling behavior in the Luotuoshan coal mine. Three types of coal rock samples—raw coal/rock (bending subsidence zone), fractured coal/rock (fracture zone), and broken rock (caved zone)—were subjected to triaxial permeability tests under varying stress conditions. The experimental results quantitatively revealed distinct permeability evolution patterns: the fractured samples exhibited a 23–48 × higher initial permeability (28.03 mD for coal, 13.54 mD for rock) than the intact samples (0.50 mD for coal, 0.21 mD for rock), while the broken rock showed exponential permeability decay (120.32 mD to 23.72 mD) under compaction. A dynamic permeability updating algorithm was developed using FISH scripting language, embedding stress-dependent permeability models (R² > 0.99) into FLAC3D to enable real-time coupling of stress–fracture–seepage fields during face advancement simulations. The key findings demonstrate four distinct evolutionary stages of pore water pressure: (1) static equilibrium (0–100 m advance), (2) fracture expansion (120–200 m, 484% permeability surge), (3) seepage channel formation (200–300 m, 81.67 mD peak permeability), and (4) high-risk water inrush (300–400 m, 23.72 mD stabilized permeability). The simulated fracture zone height reached 55 m, directly connecting with the overlying sandstone aquifer (9 m thick, 1 MPa pressure), validating field-observed water inrush thresholds. This methodology provides a quantitative framework for predicting water-conducting fracture zone development and optimizing real-time water hazard prevention strategies in similar deep mining conditions. Full article

Passenger car tires (PCTs) usually consist of a silica/silane-filled Butadiene Rubber (BR) or Solution Styrene Butadiene (SSBR) tread compound. This system is widely used due to improvements observed in rolling resistance (RR) as well as wet grip compared to carbon black-filled compounds. However, the covalent bond that couples silica via silane with the rubber increases the challenge of recycling these products. Furthermore, this strong covalent bond is unable to reform once it is broken, leading to a deterioration in tire properties. This work aims to improve these negative aspects of silica-filled compounds by developing a novel coupling system based on non-covalent interactions, which exhibit a reversible feature. The formation of this new coupling was accomplished by reacting silica with silane and a phenolic resin in order to obtain simultaneous π–π interactions and hydrogen bonding. The reaction was performed using two different silanes (amino and epoxy silane) and an alkyl phenol–formaldehyde resin. The implementation of the new coupling resulted in improved crosslink density, better mechanical performance, superior fatigue behavior, and a similar rolling resistance indicator. Full article

Applying physical modification methods to raise the resistant starch content is a feasible strategy for developing foods with a low glycemic index (GI) and regulating postprandial hyperglycemia. Here, broken rice starch (C) was modified via ultrasound and quercetin complexation (US-Q). The structure, physicochemical properties, and in vitro digestibility of the US-Q product were subsequently determined. Scanning electron microscopy (SEM) images showed that the modification changed the starch granules’ morphology, forming a more compact and stable structure. Fourier transform infrared (FTIR) spectroscopy images revealed the interaction between the starch and quercetin. An X-ray diffraction (XRD) analysis demonstrated that the crystallinity of the US-Q was lower than that of the C, indicating that the combined modification with ultrasound and quercetin disrupted the long-range ordered structure of the starch and facilitated the formation of a short-range ordered structure from amylose. Size exclusion chromatography (SEC) images showed that both the molecular weight (from 72,080.96 kDa to 85,141.95 kDa) and amylose content (from 15.94% to 26.76%) increased significantly, while the branching degree and average degree of polymerization of amylopectin decreased, suggesting that the ultrasonic treatment processing method had a significant impact on the formation of the quercetin–starch complexes. In terms of in vitro digestion, the resistant starch content of the US-Q was significantly increased from 6.57% to 20.23%, whereas the hydrolysis rate was decreased from 92.6% to 78.35%, indicating that the presence of quercetin reduced the digestibility of the starch complexes by inhibiting the starch-hydrolyzing enzyme activity. Overall, this study improves the understanding of ultrasound and quercetin dual treatment of broken rice starch, providing a theoretical basis for the development of low-GI starch foods for industrial applications. Full article

We investigate the time evolution of the quark condensate toward a chiral symmetry broken phase in hot and dense quark matter using a field-theoretic quark model with nonlocal chiral-invariant four-fermion coupling. By purposely selecting a parameter set in which inhomogeneous phases are energetically disfavored, we nonetheless observe the emergence of metastable patterned configurations that appear to persist for remarkably long timescales. These findings suggest that even when not fully stable, inhomogeneous phases may play a significant role in the dynamics of chiral symmetry breaking and restoration. To gain deeper insight into these phenomena, we also analyze the impact of the dimensionality of coordinate space on both the formation and stability of inhomogeneous chiral condensates. Full article

Groundwater is a critical resource in arid regions such as Khamis Mushayt, located in southwestern Saudi Arabia, where surface water availability is limited. This study integrates various geospatial and environmental datasets to delineate groundwater potential zones (GWPZs) using Geographic Information Systems (GISs) and remote sensing (RS) techniques. Key parameters considered include lithology, slope, drainage density, precipitation, soil type, and vegetation index (NDVI). The influence of each theme and subunit/class on groundwater recharge was evaluated by weighted overlay analysis, including previous studies and field data. The results reveal three distinct groundwater potential zones: poor, moderate, and good. Areas with good groundwater potential account for 8.2% of the study area (16.3 km²) and are predominantly located in the eastern and central parts of the study area, in valleys and low-lying regions with permeable geological formations such as alluvial deposits, supported by higher drainage density and favorable precipitation. Conversely, poor-potential zones represent 27.6% (54.50 km²), corresponding to areas with steep slopes and impermeable rock formations. Moderate-potential zones include places where infiltration is possible but limited, such as gently sloping terrain or regions with slightly broken rock structures, and account for 64.2% (127.0 km²). Validation using existing well data demonstrates strong agreement between the identified potential zones and actual groundwater availability. These findings provide a strong framework for sustainable water resource management, urban planning, and agricultural development in Khamis Mushayt and similar arid regions. Full article

The direct hot modification and subsequent preparation of qualified building materials from molten slag has gained significant attention at present due to its characteristics of saving energy and reducing CO₂ emissions. Molten silicomanganese slag, discharged at 1500–1600 °C with high content of SiO₂ and Al₂O₃ (above 50 mass%), was suitable for the preparation of casting stone. To ensure a qualified casting stone, the study focused on improving the crystallization properties and fluidity of molten silicomanganese slag by modifying of its composition, crystallization, structure, and viscosity. The raw slag and two modified slags were compared, and the physical properties of their final cast stone were discussed. The results showed that after being modified by addition of 10 mass% chromite and serpentine or 20 mass% ferrochrome slag into the silicomanganese slag, both the crystallization ability and fluidity of the molten slag were improved simultaneously. Augite and spinel precipitated in the modified slag, compared with glass phase in the raw slag. The precipitation of spinel, on the one hand, acted as a nucleation agent, dynamically promoting the formation of augite, and on the other hand, increased the proportion of SiO₂ and its polymerization of [SiO₄] structural units in the residual liquid slag, further promoting the generation of augite in the composition and structure. The gradual precipitation of crystals effectively mitigated sudden viscosity fluctuations resulting from crystallization, contributing to a smooth casting process for molten slag. Both cast stones from the modified slag exhibited qualified physical properties, compared with the broken glass from the raw slag. This indicated the feasibility of low-cost modification during the discharging process of molten silicomanganese slag by blending 10 mass% cold modifiers or 20 mass% molten ferrochrome slag into it. Full article

Kernel breakage and fungi-induced hot spots can easily lead to potential safety hazards in maize storage. The objective of this study was to focus on the formation and development of hot spots in maize bulk with two different broken kernels contents (BKCs), i.e., 4.26% (BKC_4.26) and 6.14% (BKC_6.14), and a moisture content of 16.3% under the same storage conditions. A multifunctional simulation system was developed to simulate the heat and moisture transfer process in stored grain bulk, and a new method was proposed to evaluate the effect of local hot spots on the storage safety of maize bulk with different BKCs. The results showed that there are differences in fungal respiration rates in the maize bulk with two different BKCs, and the temperature impact range caused by hot spots under the same storage conditions was different. The maximum temperature caused by fungal growth in BKC_4.26 and BKC_6.14 was 37.47 °C and 38.81 °C, and the proportion of high-temperature areas caused was 64.2% and 62.3%. The relative humidity at local hot spots continued to decrease, reaching 64.8% and 71.7% when stored for 1800 h in BKC_4.26 and BKC_6.14. The CO₂ concentration at hot spots in BKC_6.14 was higher than that of BKC_4.26, while the O₂ concentration was lower than BKC_4.26. Dry matter loss (DML) at the hot spots in BKC_6.14 was higher than that in BKC_4.26. A nonlinear model was developed to predict temperature changes of fungi-induced hot spots in maize bulk considering the storage time, temperature, relative humidity, and CO₂ concentration at the hot spots, and the model fit the experimental data reasonably well. Full article

Contrails form as a result of water vapor bonding with soot emitted from jet engines at cruise altitudes, leading to contrail formation in Ice Supersaturated Regions (ISSRs). Contrails are estimated to contribute approximately 2% to total anthropogenic global warming. Some researchers have developed simulation models to estimate the frequency, duration, and spatial distribution of contrails. Other researchers have identified issues with the accuracy of the data for predicting the timing and precise geographic positioning of ISSRs. This study presents a systematic review of 22 peer-reviewed articles that included detailed models of ISSR identification, identifying three atmospheric data sources, four parameters, and two equations for calculating the parameters derived. A further analysis revealed differences in the temperature and RH_W readings across the three databases, resulting in differences in the RH_I calculations and the identification of ISSRs. Over an 18-month period in Sterling, Virginia, USA, the radiosonde data and two atmospheric forecast databases identified the ISSR conditions on 44%, 47%, and 77% of days, respectively. Broken down by a flight level between 30,000 and 39,999 feet in altitude, these differences are highlighted further. The forecast databases overestimated the presence of ISSRs compared to the radiosonde data. These findings underscore the variability inherent in atmospheric datasets and the conversion methods, highlighting potential areas for refinement in ISSR prediction, notably in the development of ensemble forecasts based on several atmospheric databases. The implications of these results, the limitations of this study, and future work are discussed. Full article

Fersmite ([Ca,Ce,Na][Nb,Ta,Ti]₂[O,OH,F]₆) from the Mount Brussilof magnesite deposit, British Columbia, Canada occurs as accessory brittle, black, submetallic to vitreous lustre, acicular to platy crystals up to 2 cm long, developed in sparry dolomite, which lines cavities in sparry magnesite. Fersmite also occurs as smaller crystals (<3 mm) enclosed by dolomite, where it is commonly fractured or broken, formed during the final stage of dolomite crystallisation. Electron microprobe (WDS) major element data indicate that the grains confirmed to be fersmite by X-ray diffraction contain >50% Nb and are atypically Ta-poor. Fersmite contains significant U and Th (up to 4700 ppm and 6 wt.%, respectively) and therefore is a viable mineral for U-Pb geochronology. A series of laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) spot analyses and maps were collected on fersmite grains. Although the fersmite grains have considerable common Pb and have experienced Pb loss, the U-Pb spot data suggest growth or pervasive resetting at ca. 190 Ma. Some ⁴⁰Ar/³⁹Ar ages (two of four samples) are consistent with the ~190 Ma U-Pb date. Electron microprobe and LA-ICP-MS mapping indicate that the fersmite is middle to heavy rare earth element-rich. The ~190 Ma fersmite age estimate provides an approximate upper time constraint on the age of sparry magnesite mineralisation, sparry dolomitisation, and, indirectly, on the formation of MVT deposits in the Kicking Horse Rim area and possibly elsewhere in southeastern British Columbia. Full article