Search Results (3,949)

The effect of water on the dynamics and ionic conductivity of the ionic liquids 1-ethyl-1-methylpyrrolidinium levulinate ([C₂C₁Pyr]Lev) and 1-butyl-1-methylpyrrolidinium levulinate ([C₄C₁Pyr]Lev) was investigated using differential scanning calorimetry (DSC) and broadband dielectric spectroscopy (BDS) over a wide temperature range. Although both ILs share the same levulinate anion, water induces markedly different dynamical responses depending on cation structure. In both systems, water acts as a plasticizer, lowering the glass transition temperature; however, the extent of plasticization and the resulting relaxation dynamics are cation-dependent. Stronger water–cation interactions are observed in [C₂C₁Pyr]Lev, whereas in [C₄C₁Pyr]Lev, water primarily disrupts alkyl-chain packing, enhancing ionic mobility. Increasing hydration shifts the main relaxation to higher frequencies and increases liquid fragility, while translational ionic motion remains decoupled from structural relaxation. These results demonstrate that water plays a cation-specific and mechanistically distinct role in levulinate-based ILs, providing new insights into hydration-controlled glassy dynamics and charge transport relevant to the design of IL-based electrolytes under non-anhydrous conditions. Full article

This article concerns the issue of contactless estimation of the complex electrical permittivity of masonry materials by means of a microwave technique in the frequency domain. The main aim of the study was to develop a method enabling the determination of the real part of relative permittivity and the electrical conductivity of ceramic building materials using microwave reflection measurements, as well as to assess the applicability of the proposed approach for moisture diagnostics in porous media. The research was performed using a reflection-mode measuring setup comprising a vector network analyser and a broadband horn antenna, while measurements were carried out in the frequency range from 1 to 6 GHz on samples of solid ceramic brick with six gravimetric moisture levels. A one-dimensional model of electromagnetic wave propagation in the material was developed, considering complex permittivity, impedance transformation, and a calibration procedure compensating for the influence of the antenna and free-space propagation. Based on the fitting of the magnitude and phase characteristics of the reflection coefficient, the electrical parameters of the tested samples were estimated. The results obtained showed an increase in both permittivity and conductivity with increasing moisture content and revealed very good agreement with the reference values determined using the time-domain method. It can be concluded that the frequency-domain microwave approach may be effectively applied for contactless and non-destructive diagnostics and estimation of the dielectric properties and moisture content in ceramic materials. Full article

We demonstrate a sideband Pound–Drever–Hall (SPDH) locking scheme that enables the simultaneous narrow-linewidth stabilization and continuous broadband frequency tuning of a laser referenced to an ultra-stable cavity. The method employs dual-frequency modulation applied to a fiber electro-optic modulator, where high-frequency modulation generates tunable sidebands and low-frequency modulation provides the error signal. We experimentally stabilize a 922 nm seed laser to the cavity and achieve a laser linewidth of 85(1) kHz with frequency noise suppression of up to 25 dB. The residual amplitude modulation (RAM) remains below 0.08% across the full tuning range. In addition, we demonstrate a continuous frequency tuning range of 1.4 GHz for a frequency-doubled 461 nm laser, with scan rates up to 317 MHz/s, while preserving stable locking to the cavity. This approach avoids complex waveform generation and provides a simple and robust solution for broadband laser frequency control. Full article

Herein, we present the analysis, design, optimization, and fabrication of a broadband, stepped-impedance Wilkinson power divider. The proposed structure employs stepped-impedance transmission lines and open-circuited stubs, achieving a simple and compact implementation while maintaining a wideband frequency response. Initially, transmission-line-based circuit analysis was performed to extract the design equations, followed by simulation and optimization to enhance impedance matching and output-port isolation over a broad bandwidth. Finally, the proposed divider was fabricated using microstrip-line technology, and experimental measurements were conducted using the Agilent E5071C vector network analyzer. The simulation and measurement results showed efficient wideband operation over the 1–4 GHz frequency range. Specifically, the measured return loss at the input port was <−10 dB; the corresponding return loss at the output ports was <−15 dB. The measured insertion loss was −3.73 ± 0.42 dB. The isolation between the output ports was <−10 dB, reaching approximately −30 dB at 2.1 GHz and −25 dB at the center operating frequency (f₀ = 2.5 GHz). The amplitude and phase imbalances were 0 ± 0.2 dB and 0^o ± 0.8^o, respectively. Furthermore, the overall size of the proposed wideband Wilkinson power divider was 0.35λg × 0.21λg. Compared to previous designs, the divider proposed in this study exhibits an improved and more symmetric frequency response, as well as a substantially reduced size, making it suitable for several modern wireless technologies such as Wi-Fi, Bluetooth, GPS, DCS, WCDMA, and sub-6 GHz 5G communication systems. Full article

Monitoring dissolved carbon dioxide (CO₂) in aquatic and sediment systems is critical for understanding carbon cycling and climate feedback. This study develops and characterizes a compact, low-cost microbolometer-based attenuated total reflectance (ATR) mid-infrared sensor for direct dissolved CO₂ measurement in liquid and soil-water environments. The system integrates a ZnSe ATR crystal with custom suspended SiN membrane microbolometers and uses evanescent-wave absorption at 4.26 μm with a broadband LED source and computational spectral reconstruction, eliminating the need for an interferometer. Calibration shows excellent linearity (R² ≈ 0.99) over 50–1000 ppm CO₂, with a practical limit of detection (LOD) of ~26–35 ppm at 5–25 °C. UV-induced CO₂ generation from soil-water mixtures was investigated across UV wavelengths, revealing UV-C (254 nm) as optimal, producing net ΔCO₂ ≈ 339 ppm above ambient levels in 30 min. Environmental factors (temperature 5–35 °C, pH 5–11, pressure 1–1.5 ATM, dissolved organic carbon) were systematically evaluated, confirming robust sensor performance (accuracy >90%, correlation r > 0.98 with reference instrument). This sensor represents the first integration of MEMS microbolometer detectors with ATR evanescent-wave spectroscopy for liquid-phase dissolved CO₂, enabling real-time monitoring and rapid sediment organic carbon assessment in a field-deployable platform. Full article

Amplified Spontaneous Emission (ASE) sources are widely employed as highly stable broadband sources in fields such as high-precision navigation and optical detection. Erbium-doped fiber (EDF), as the core active component in ASE sources, has long been a key subject of thermal stability research. We fabricated a low-doped EDF with an 80 μm-cladding using the vapor phase doping (VPD) technique. This EDF was compared with a commercial 125 μm-cladding EDF using a double-pass forward (DPF) optical path configuration with a narrowband filter. We investigated the temperature-dependent characteristics of the ASE spectra generated by the two EDFs with different parameters. The temperature drift performance of the two EDFs was analyzed based on three critical indicators of the spectrum: mean wavelength, spectral bandwidth, and output power. In comparison with the commonly used EDF, the results show that a properly designed small-cladding EDF with an appropriate length can deliver higher ASE output power and exhibit a lower mean-wavelength temperature drift. This study provides an important guideline for promoting the miniaturization of high-precision fiber-optic sensing devices. Full article

Van der Waals (vdW) heterostructures are attractive for optoelectronic devices due to their lattice-mismatch tolerance and tunable band structures. Here, we report a gate-tunable Au/MoS₂/WSe₂ dual junction photodetector featuring competing asymmetric built-in electric fields. Spatially resolved photocurrent measurements reveal that selective utilization of these built-in electric fields decouples the transport dynamics of dark and photogenerated carriers. Such decoupling allows for independent modulation of the dark current and photocurrent, enabling the concurrent realization of the ultralow dark current and high photocurrent. Moreover, gate-voltage modulation enhances the photoresponse by ~245%, yielding a detectivity of 1.98 × 10¹² Jones over the 532–940 nm range. Imaging and optical communication further verify the device’s practical potential. These results provide a viable route toward high-sensitivity and electrically reconfigurable broadband photodetectors. Full article

Terahertz technology has demonstrated immense potential across a wide range of applications, particularly in the realm of THz photodetection. However, state-of-the-art detectors typically face fundamental trade-offs among sensitivity, response speed, operating temperature, and spectral bandwidth. While previous studies have shown that graphene field-effect transistors (GFETs) exhibit a broadband, room-temperature photoresponse to THz radiation—often attributed to photothermoelectric (PTE) and plasma-wave rectification effects—the similar functional dependence of these mechanisms on the gate voltage has historically made it challenging to disentangle their individual contributions. In this study, we leverage monolayer graphene as the photoactive material to overcome these limitations within a single device architecture. We present a novel THz photodetector driven predominantly by the PTE effect, facilitated by a precisely designed counterclockwise spiral antenna. The demonstrated device achieves exceptional room-temperature sensitivity, featuring a minimum noise equivalent power (NEP) of 80.7 $\mathrm{p}\mathrm{W}/\sqrt{\mathrm{H}\mathrm{z}}$ alongside a rapid response time of less than 11 μs. Furthermore, by systematically analyzing the temporal response dynamics, we unambiguously identify the PTE effect as the dominant operating mechanism. These results provide a robust strategy for the development of high-performance, room-temperature THz optoelectronics, paving the way for advanced practical applications in high-capacity wireless communications and real-time THz imaging. Full article

Proportional, fair scheduling in OFDM-based vehicle-to-everything (V2X) uplink causes the resource-block allocation of each vehicle to vary from slot to slot, yet conventional semantic encoders produce a fixed number of output tokens regardless of the instantaneous channel capacity. When the encoder output exceeds the slot budget, transmitted features are truncated and the resulting federated learning gradient is corrupted—a problem that affected 23% of training rounds for non-line-of-sight vehicles in our experiments. The difficulty is worsened by a spatial pattern common in urban deployments: vehicles at congested intersections suffer the poorest propagation conditions while carrying the training data most relevant to safety, and throughput-driven client selection excludes them in favor of vehicles with strong channels but uninformative scenes. We address both issues within a single framework for OFDM-based V2X federated learning. On the transmission side, a Sensing-Guided Adaptive Modulation (SGAM) module derives a per-slot token budget from the current resource-block allocation and selects tokens through differentiable Gumbel-TopK pruning with a hard capacity clip, so the transmitted token count stays within the slot budget. On the scheduling side, a Channel-Decoupled Federated Learning (CDFL) module partitions clients independently by channel quality and data complexity, selects diverse representatives per partition via facility location optimization, and corrects for partition-size imbalance through inverse propensity weighting during model aggregation. Experiments on NuScenes with 20 non-IID vehicular clients under realistic OFDM channel simulation demonstrate a Macro-F1 of 0.710 (+8.7 points over the Oort-adapted baseline), zero budget violations throughout training, and a 75% reduction in training variance; the worst-class F1 more than doubles relative to FedAvg. Full article

A novel broadband ultrasonic transducer design based on a non-uniform-thickness double-layer piezoelectric structure and a variable-thickness matching layer is proposed to overcome the limitations of conventional thickness-mode piezoelectric ultrasonic transducers, such as weak even-order harmonic responses and restricted bandwidth. The implementation of a non-uniform-thickness double-layer piezoelectric structure enables the simultaneous excitation and reception of ultrasonic signals containing both fundamental and second-harmonic frequencies. Furthermore, through the integration of variable-thickness matching layers with a backing material of non-uniform acoustic impedance, the dual resonant frequency responses are effectively merged into a broad bandwidth. The broadband transducer prototype is manufactured and characterized through electrical input impedance, time-domain pulse-echo signals, and corresponding frequency spectrum. Experimental results indicate a center frequency of 411.5 kHz, with dual resonant peaks observed near 298.6 kHz and 585.6 kHz, achieving a −6 dB relative bandwidth of 116%. The findings demonstrate that the self-developed broadband transducer is capable of effectively generating and receiving broadband signals containing both fundamental and second-harmonic components, thereby offering a new design strategy for broadband piezoelectric transducers. Full article

Multi-link terrestrial backhauls create a shared transport environment in which heterogeneous multipath protocols compete for the same forwarding resources while reacting to congestion with different control logics. In this paper, we investigate this problem in a 5G Integrated Access and Backhaul (IAB) scenario where an IAB node aggregates traffic from multiple User Equipments (UEs) and forwards it toward the core network over two terrestrial backhaul paths. We focus on the coexistence of Multipath TCP (MPTCP) and Multipath QUIC (MPQUIC), evaluating how cross-protocol Congestion Control (CC) pairings affect performance. Specifically, all feasible BBR, CUBIC, and Reno cross-pairings are assessed under symmetric and asymmetric dual-backhaul conditions, considering Enhanced Mobile Broadband (eMBB) and dense low-rate traffic regimes representative of mMTC-like operation. The analysis considers throughput, Jain’s fairness index, jitter , and packet loss to identify the trade-offs of each CC pairing. Results show that CC selection is a first-order design factor in MPTCP/MPQUIC coexistence over shared backhauls. No single pairing is uniformly optimal across all metrics: some configurations provide more balanced throughput sharing, others improve fairness, while the most favorable solutions for jitter do not necessarily maximize transport efficiency. These findings identify CC pairing as a tuning dimension for multi-link backhaul systems based on heterogeneous multipath transports. Full article

Semiconductor lasers have been widely employed in chaos-based information processing due to their ability to generate enhanced chaotic bandwidths. In this study, we investigate broadband polarization chaos in optically injected QD spin-VCSELs and their ability to act as high-speed physical entropy sources for random number generation (RNG). We achieve chaotic bandwidths approaching 50 GHz per polarization mode using elliptical injection. With optimized conditions and post-processing, we demonstrate RNG at rates of up to 240 Gb/s. The quality of the generated random sequences is evaluated using multiple statistical metrics, including entropy estimation based on the NIST SP800-90B framework, uniqueness analysis using Hamming distance, and bias assessment through autocorrelation and histogram analysis. In addition, the influence of different polarization injection schemes on randomness is examined using the NIST SP800-22 statistical test suite. These results highlight the potential of QD spin-VCSELs as compact and ultrafast sources for RNG in secure communication systems. Full article

Rural hospitals are essential access points for healthcare delivery in the United States, yet they continue to experience disproportionate rates of closure and service disruption that threaten community health, economic stability, and equity. This rapid systematic review synthesizes recent peer-reviewed evidence examining rural hospital closures and service disruptions, with emphasis on financial, policy, workforce, and performance-related factors and their downstream impacts. Guided by PRISMA methodology, four databases were searched for U.S.-based studies published between January 2024 and June 2025. Following screening and consensus-based review, 59 articles met inclusion criteria. Across studies, financial vulnerability, characterized by revenue instability, low patient volumes, unfavorable payer mix, and reliance on non-operating revenue, emerged as a dominant precursor to closure and service reductions. Policy context, particularly Medicaid expansion status, telehealth and broadband infrastructure, and reimbursement adequacy, strongly shaped hospital sustainability. Closures and service disruptions were consistently associated with increased travel distances, reduced access to maternal, surgical, mental health, and chronic care services, higher prices at surviving hospitals, and increased strain on remaining providers. Workforce shortages further compounded these challenges. Collectively, findings demonstrate that rural hospital closures reflect interconnected structural weaknesses rather than isolated organizational failure. Coordinated policy action, targeted financial stabilization, workforce development, and technology-enabled care models are necessary to mitigate continued erosion of rural healthcare access. Full article

Deep-sea mining systems are a critical pathway for acquiring key strategic resources such as nickel and cobalt. The core conveying component, the mining rigid pipe, is susceptible to transverse vibrations under complex wave excitation, which threaten system safety, necessitating the development of efficient and reliable vibration control solutions. This paper proposes an improved Triple-spring nonlinear energy sink (TS-NES). An integrated dynamic model coupling the mining rigid pipe and the TS-NES is established using the vector form intrinsic finite element method and solved via the central difference method. The effectiveness and superiority of the TS-NES are verified through displacement, time–frequency, energy, and phase analyses. Subsequently, a systematic parameter sensitivity study is conducted. The results indicate that under both single-frequency and multi-frequency wave excitations, the TS-NES exhibits broadband, high-efficiency vibration suppression performance superior to that of the conventional tuned mass damper (TMD). It can substantially and uniformly dissipate vibration energy and maintain an approximately 90° phase lag with the primary structure. Parameter studies reveal that installing the TS-NES in the upper section of the pipe yields significant vibration reduction. The device is insensitive to stiffness variations, and appropriately increasing its mass, damping, and inclination angle can further enhance the vibration suppression effect. Full article

All-optical logic gates have emerged as a critical technology for enabling broadband, low-loss, and high-speed communication systems, addressing the inherent bandwidth limitations of electronic counterparts. Here, we propose a Y-shaped structure leveraging unidirectional modes in the terahertz regime, which enables the realization of multifunctional all-optical logic gates within the lower- and upper-frequency bandwidth regions, including, but not limited to, AND, OR, NOT, and XNOR gates. Numerical simulations and theoretical analyses confirm that the proposed logic gates exhibit robust one-way propagation characteristics, with electromagnetic signals demonstrating complete immunity to backscattering even in the presence of structural defects. Furthermore, nonlocal effects are found to have a negligible impact on the operational bandwidths of our design. Building upon this Y-shaped configuration, we further develop an all-optical digital logic system (AODLS) capable of supporting bifrequency multi-input and multi-output logic operations. When lower- and upper-frequency signals are injected into separate input ports, their corresponding output signals remain fully independent, eliminating cross-talk and enabling true parallel computation. This dual-band parallel processing capability represents a significant advance over conventional single-band all-optical logic systems, opening new avenues for high-throughput all-optical computing and integrated photonic circuits. Full article