Search Results (1,408)

Photoluminescent liquid crystals with photoluminescence (PL) and liquid-crystalline (LC) properties have attracted attention as PL-switching materials owing to their thermally induced phase transitions, such as crystal → smectic A/nematic → isotropic phase transitions. Our group previously developed tetrafluorinated tolane mesogenic dimers linked by flexible alkylene-1,n-dioxy spacers, demonstrating that the position of the tetrafluorinated aromatic ring critically influences the LC behavior. However, these compounds exhibited very weak fluorescence owing to an insufficient D–π–A character of the π-conjugated mesogens, which facilitated internal conversion from emissive ππ* to non-emissive πσ* states. We designed and synthesized derivatives in which the mesogen–spacer linkage was modified from ether to ester, thereby enhancing the D–π–A character. Thermal and structural analyses revealed spacer-length parity effects: even-numbered spacers induced nematic phases, whereas odd-numbered spacers stabilized smectic A phases. Photophysical studies revealed multi-state PL across solution, crystal, and LC phases. Strong blue PL (Φ_PL = 0.39–0.48) was observed in solution, while crystals exhibited aggregation-induced emission enhancement (Φ_PL = 0.48–0.77) with spectral diversity. In LC states, Φ_PL values up to 0.36 were maintained, showing reversible intensity and spectral shifts with phase transitions. These findings establish design principles that correlate spacer parity, phase behavior, and PL properties, enabling potential applications in PL thermosensors and responsive optoelectronic devices. Full article

Interior space quality in certified office buildings is key in supporting the health and well-being of occupants. Daylight, which regulates the human circadian rhythm and affects physiological processes and productivity, is crucial. This study’s objective was to determine how a building’s architecture and selected elements of its interior such as partitions and finishing material parameters affect sunlight distribution in workspaces and its biological effectiveness, as measured using Equivalent Melanopic Lux (EML). The environment’s impact on the non-visual potential of a space was also assessed (in relation to the M/P ratio). To achieve these objectives, we used a 3D model of an office building floor to simulate natural lighting in various configurations, for a cool temperate climate using Solemma’s ALFA 2025 software. This research was conducted using simulations only, with no in situ measurements. The study assessed melanopic light intensity for specific zones and workstation groups. The impact of ceiling colors and the five colors given to partitions of different heights located between desks was also determined. The study evaluated the relationship between photopic and melanopic intensity and found that, as the height of the partitions increased, especially with cloudy skies, the importance of these planes’ colors increased. Blues had a positive effect on the space’s non-visual potential, while oranges showed significant decreases in EML relative to lux, by up to 25%. This research underscores the importance of light’s non-visual impact and the consideration of these aspects at every design stage, especially interior design, to provide a comfortable work environment and its long-term benefits. We also proposed natural light exposition optimization strategies that can support proper circadian rhythm. Full article

The study aimed to investigate the effect of UV radiation on the chemical and physical changes in pine and birch wood surfaces impregnated with graphene oxide. The samples were exposed to UV radiation with an intensity of 550 W/m² for 16, 32, and 48 h. FTIR analysis revealed photodegradation of lignin in both wood species. It was indicated that graphene oxide impregnation may slow down the rate of lignin oxidation. Graphene oxide impregnation also affected the change in the surface contact angle, with the differences being more pronounced in birch wood than in pine. Color measurements showed that graphene oxide impregnation significantly altered the initial color of the wood (darkening and a shift towards green and blue), and UV radiation intensified the color changes, especially in birch wood. Full article

Myofibrillar protein (MP) aggregation in solutions with NaCl concentrations below 0.3 M results in poor solubility. Ultrasound-assisted glutaminase treatment (UGT) was applied to improve MP solubility in a low-salt solution (containing 0.1 M NaCl). The solubility increased with ultrasonic power and time, peaking at 44.34% (480 W, 15 min) and reaching 61% after UGT. Subsequently, the effect of post-sonication heat treatment (60 °C, 30 min) on the physicochemical and structural characteristics of ultrasound-enzyme treated MP (UEMP), prepared under specific ultrasonic conditions (480 W, 20 min), was systematically investigated. The findings revealed that UEMP exhibited higher hydrophobicity, sulfhydryl content, and turbidity, but reduced particle size, ζ-potential, and fluorescence, suggesting disulfide disruption and exposure of hydrophobic residues. Sodium dodecyl sulfate-polyacrylamide gel electrophoresis revealed weakened high-molecular weight bands and intensified low-molecular weight bands. Fourier-transform infrared spectroscopy confirmed these structural rearrangements, with a blue-shifted amide A band and decreased amide I intensity. Heating further increased the hydrophobicity and fluorescence without altering the size, ζ-potential, or molecular weight. The red shift in the amide A band suggests reinforced local ordering. Rheology analysis showed non-Newtonian shear-thinning behavior, which was unchanged by UGT or heating. Collectively, UGT with moderate heating enhances MP solubility and thermal stability by disrupting stabilizing bonds and modulating the structure. Full article

Background: Opioid use disorder (OUD) and associated overdose deaths have reached epidemic proportions worldwide over the past two decades, with death rates for men consistently reported at twice the rate for women. We have recently reported sex-specific differences in electrocortical activity in persons with OUD in a visual object recognition task. The mesolimbic dopamine (DA) system is implicated in OUD but also plays a critical role in some disorders of visual attention and a modulatory role in the processing of visual stimuli in the blue cone pathway of the retina. We hypothesized that electrocortical responses to color stimuli would be affected differentially in men and women with OUD. Methods: Using a controlled, cross-sectional, age-matched (18–56 years) design, we evaluated color processing in male and female subjects recruited from a community-based, high-intensity residential substance abuse and detoxification treatment program. We evaluated electroencephalogram (EEG) event-related potentials (ERPs) and reaction time (RT), in male and female participants with OUD (n = 38) vs. sex- and age-matched non-OUD control participants (n = 37) in a simple color recognition Go/No-Go task, as well as perceptual and behavioral responses in physiological and neuropsychological tests. Results: N200, P300, and late potential (LP) Relevant stimulus-induced ERPs were evoked by the task and were well-differentiated from Irrelevant distractor stimuli. P300 amplitudes were significantly greater and N200 and LP latencies were significantly shorter in male vs. female non-OUD controls in this task. There were significant sex differences in N200, P300, and LP amplitudes and latencies between male vs. female non-OUD subjects and OUD differences with blue color as the Relevant stimulus. In the Binocular Rivalry Test, there were shorter dwell times for perceiving a blue stimulus in male OUD subjects and there were significant sex and OUD differences in neuropsychological tests including Finger Tapping, Trails A/B, and Symbol Digit Modalities Test. Conclusions: These findings suggest that there are significant sex-related physiological, perceptual, and cognitive differences in color processing that may result from deficits in DA production in the retina that mirror deficits in mesolimbic DA transmission correlating with OUD, suggesting that blue color processing has the potential to be an effective biomarker for brain DA and for diagnosis and monitoring of treatment efficacy in substance use disorders. Full article

Climate change or even the natural occurrence of periods of low suitability for the production of forage species are obstacles to maintaining adequate animal nutrition. Indoor green fodder production is an alternative to this problem; however, advances in technologies capable of improving this system still need to be studied in depth. The objective of this study was to evaluate the qualitative and quantitative characteristics of hydroponic green fodder production of millet and sorghum under varying monochromatic light supplementation and nicotinamide application. Eight treatments were defined by lighting (LS—Led Full Spectrum; LS + Ultraviolet LED; LS + Red LED; LS + Blue LED), and combined with the application of nicotinamide (with and without) at a concentration of 200 mg L⁻¹. Cultivation under conditions of light supplementation with UV radiation or monochromatic lights results in increased light intensity by modifying the wavelength spectrum received by the plant, modification of the quality of photons received in relation to the energy level that leads to luminous stress and, consequently, lower green fodder development concerning height and fresh mass. Nicotinamide acts as a bioprotectant, attenuating the stressful effects and enabling greater productive efficiency in the production of hydroponic green fodder, particularly in vertical cultivation, which provides increased height and fresh mass for millet and sorghum green fodder. In contrast, the stress resulting from light supplementation can be used as a tool to increase carotenoid levels in plants and may be indicated for production systems that have this objective for biofortification of forages with bioactives with antioxidant effects. Full article

Lapis lazuli is a valued gemstone that displays a wide spectrum of blue hues, yet the quantitative link between its color and internal sulfur speciation remains unresolved. This study integrates colorimetry with electron probe microanalysis and UV-Vis, Raman, and X-ray photoelectron spectroscopy to establish this relationship and build a robust grading framework within the CIE 1976 L*a*b* color space. X-ray diffraction was employed to determine the mineral composition and confirm that the chromogenic elements originated from lazurite. K-means clustering with Fisher’s discriminant validation classifies samples into four grades: Fancy Blue, Fancy Intense Blue, Fancy Deep Blue, and Fancy Dark Blue. Multimodal analyses identify three sulfur species—[S₃]^·−, S²⁻, and ${\mathrm{SO}}_4^{2-}$—and show that higher sulfur content correlates with lower lightness, reduced chroma, and a violetish-blue shift. [S₃]^·− is confirmed as the dominant chromophore, producing the strong 600 nm absorption that defines the blue hue. A weak absorption band observed near 400 nm in some samples can be attributed to S²⁻ and ${\mathrm{SO}}_4^{2-}$ species, but no visually perceptible effect of this band on the overall color was detected. Full article

KY₃F₁₀:Yb³⁺, Tm³⁺ upconversion microparticles (UCMPs) with varying Mn²⁺ doping concentrations were synthesized via a hydrothermal method. Under 980 nm laser excitation, the sample with 3 mol% Mn²⁺ doping demonstrated markedly enhanced luminescence performance, exhibiting a significant intensity increase compared to undoped samples. The as-synthesized UCMPs were successfully incorporated into an anti-counterfeiting ink. Target information was encrypted using a hash function to generate a QR code, which was then screen-printed onto substrate materials. Under 980 nm laser irradiation, the printed QR code exhibited visible blue fluorescence with high stability, confirming its anti-counterfeiting capability. Furthermore, an image recognition system for anti-counterfeiting, based on a hybrid Convolutional Neural Network-Bidirectional Long Short-Term Memory (CNN-BiLSTM) architecture, was developed on the Matlab platform. The system achieved 100% recognition accuracy for the luminescent QR code patterns, providing valuable insights for the development of deep learning-based image anti-counterfeiting technologies. Full article

As a core component of emerging quantum-dot display technology, the stability of quantum-dot materials is crucial to determining the performance of quantum-dot photoluminescent diffuser plates. This study successfully synthesized high-stability thick-shell CdZnSeS/CdZnS/ZnS core–shell structured green-alloy quantum dots suitable for photoluminescent diffuser plates, providing an innovative solution for performance breakthroughs in this field. Through orthogonal experimental design, the synthesis parameters of the CdZnSeS alloy core were precisely optimized to achieve an ideal balance in emission wavelength, full width at half maximum (FWHM), and quantum yield (QY). Furthermore, by systematically adjusting ligands and synthesis parameters, a thick-shell CdZnSeS/CdZnS/ZnS core–shell structure was constructed, significantly improving the stability of the quantum dots. Critically, the replacement of the original oleic-acid ligands with tetradecylphosphonic-acid (TDPA) ligands at high temperature doubled the stability of the quantum-dot diffuser plates. Under extreme accelerated-aging conditions such as intense blue light, high temperature, and high humidity, the T90 lifetime of the diffuser plate exceeded 1000 h, and the xy chromaticity coordinate shift was strictly controlled within 1%, fully meeting the stringent commercial requirements. This achievement not only overcomes the stability bottleneck of quantum dots in the application of photoluminescent diffuser plates but also paves the way for their large-scale commercialization, promising to promote the development of display technology toward higher color gamut and longer lifetimes. Full article

The transition to low-carbon energy systems necessitates innovative design strategies for decarbonizing hydrogen production, particularly in industrial-scale applications where steam methane reforming (SMR) remains predominant. This study proposes a novel, integrated process design for blue hydrogen production that addresses both energy and environmental sustainability through process intensification and resource valorization. A hybrid system was developed that combines solar thermal energy input with the catalytic potential of industrial waste, specifically, red mud, a byproduct of alumina refining. A solar parabolic dish (SPD) was engineered to contribute 10% of the heat demand, generating superheated steam at 477 °C. This work serves as a proof-of-concept, demonstrating the technical viability of integration at a bench scale. In parallel, red mud was characterized, thermochemically activated, and formulated into a low-cost catalyst for the SMR process. The integrated system includes solar-assisted steam generation, red mud-based catalytic reforming, CO₂ capture using methyl diethanolamine (MDEA), and hydrogen purification via pressure swing adsorption (PSA). The full process was modeled and optimized using ASPEN Plus, ASPEN Adsorption, and COMSOL Multiphysics^® Under optimal conditions (900 °C, 25 bar, steam-to-carbon ratio of 3), the system produced 1070 kg/h of hydrogen, achieving 95% CO₂ capture efficiency and 99.99% hydrogen purity. Techno-economic analysis revealed the red mud-derived catalyst costs 3.89 SAR/g (1.04 USD/g), a 77% cost reduction compared to conventional Ni-based catalysts. The integration of solar thermal energy, while offering modest direct economic savings of approximately 9500 SAR (2530 USD) annually, primarily demonstrates the technical feasibility of renewable heat integration for reducing the carbon intensity of hydrogen production. Full article

This study evaluated the effects of dietary supplementation with three silicate minerals (bentonite, zeolite, and illite) on the growth performance, whole-body composition, hematological and immune parameters, and apparent digestibility of Pacific white shrimp (Litopenaeus vannamei). Four isonitrogenous (35% crude protein) and isoenergetic (17.0 MJ kg⁻¹) diets were formulated: a control (CON) and three experimental diets containing 5% bentonite (BE), zeolite (ZE), or illite (IL), in which an equivalent amount of starch was replaced. Juvenile shrimp specimens (initial weight: 0.02 g) were reared for nine weeks and assessed for growth performance, feed efficiency, survival, biochemical indices, immune responses, and apparent digestibility. Shrimp specimens fed the illite-supplemented diet exhibited significantly higher final body weight (5.95 ± 0.97 g), weight gain, specific growth rate, and protein efficiency ratio than the other groups (p < 0.05). The feed conversion ratios were significantly better in the IL (1.10 ± 0.03) and ZE (1.16 ± 0.02) groups than that in the BE (1.26 ± 0.05) and CON (1.32 ± 0.04) groups (p < 0.05). The whole-body crude protein content was significantly higher in the ZE and IL groups. Hemolymph glutamic-oxaloacetic transaminase (GOT) and glutamic-pyruvate transaminase (GPT) activities were significantly reduced in the ZE and IL groups, indicating improved hepatic health. Non-specific immune responses, including nitro blue tetrazolium (NBT), phenoloxidase (PO), glutathione peroxidase (GPx), and lysozyme activities, were most enhanced in shrimp fed the IL diet. Apparent crude protein digestibility peaked in the IL group (93.3 ± 0.70%) followed sequentially by the CON (87.3 ± 0.92%), BE (87.8 ± 0.88%), and ZE (89.1 ± 1.11%) groups (p < 0.05). These findings demonstrate that dietary supplementation with illite significantly improves the growth performance, feed efficiency, hepatic condition, innate immune response, and protein digestibility of L. vannamei. Illite appears to be a promising candidate for functional feed supplementation aimed at enhancing productivity and health in intensive shrimp aquaculture. Full article

Plant species sensitive to desiccation or vegetatively propagation are difficult to store and transport in the germplasm for space travel. Applying plant tissue culture can help to create a Plant Germplasm Bank for this species. For this purpose, the Compact Growth Chamber (CGC) was created to store and transport in vitro explants, maintaining them for long periods in Slow-Grown Storage (SGS). Explants under SGS have reduced growth metabolism to complete space missions. This study aimed to evaluate the CGC efficacy in the long term of in vitro storage of explant of Taioba (Xanthosoma sagittifolium), a tropical species that vegetatively propagates and has high nutritional value. For this, three CGCs were connected, side by side, with different LED light spectra (CGC1: Red spectrum; CGC2: 50% Red + 50% Blue spectra-control; CGC3: Blue spectrum), each one containing nine test tubes with taioba explants (one per test tube), and LED lights intensity adjusted for 30 µmol m⁻² s⁻¹. The CGCs were maintained for 120 days in the darkroom, at 25 ± 2 °C temperature and 50–60% humidity, and, at the end, the growth and morphological parameters of taioba plantlets were evaluated. These results demonstrate that the explant storage in CGC3 showed lower root numbers and root lengths than in CGC1 and CGC2. In addition, the Blue spectrum in CGC3 reduced the root oxidation and browning, resulting in 100% live explants. This study provides that the CGC fulfilled its proposed function of transporting and storing the in vitro explants for space travel. Full article

Candida viswanathii has been sporadically reported in Asia and South America but not in Europe. This study reports the first European outbreak of C. viswanathii in a paediatric hospital, outlining diagnostic challenges and containment measures. Fifteen C. viswanathii isolates were recovered from blood cultures of consecutive pediatric patients admitted to intensive care units between April and August 2025. Identification was performed using MALDI-TOF MS, chromogenic media, Fourier-transform infrared (FT-IR) spectroscopy, and whole-genome sequencing (WGS). Antifungal susceptibility testing was performed by broth microdilution. All isolates were initially misidentified as C. tropicalis by MALDI-TOF MS and undetected by the FilmArray BCID2 panel. WGS confirmed C. viswanathii, and FT-IR analysis revealed clonally related strains, indicating an outbreak. Colonies displayed a distinct deep-blue color on chromogenic CHROMagar™ medium. Elevated fluconazole minimum inhibitory concentrations were observed, while isolates remained susceptible to echinocandins and amphotericin B. A multidisciplinary infection-control response halted transmission within four weeks. This investigation documents the first C. viswanathii outbreak in Europe, highlighting diagnostic limitations of current commercial tools and the need for updated databases. Integration of FT-IR spectroscopy and WGS facilitated outbreak detection and containment, underscoring the importance of advanced diagnostics and surveillance for emerging fungal pathogens. Full article

Mushrooms are commercially cultivated in controlled environment agriculture facilities in which the parameters of temperature, humidity, and CO₂ are closely controlled. In contrast to plant production, variable lighting is generally not a parameter that mushroom producers utilize. In this study, P. ostreatus, the pearl oyster mushroom, was cultivated under one of three LED light spectra: blue (450 nm), red (625 nm), or white (broad spectrum) at an intensity of 5 μmol m⁻² s⁻¹. Substrates used for production consisted of a 70/30 mixture of straw/cottonseed or straw/mesquite bean pod, all of which were locally sourced in Arizona. Bioefficiency (BE), nutrient profile, and morphology were assessed post-production. Light spectra had no significant effect on BE, beta glucan, total amino acids, or total antioxidant content. However, red light exposure increased the number of caps per cluster by 197% and reduced cap diameter by 55%. The straw/cottonseed substrate significantly increased BE by 77% over the straw/mesquite substrate, increased levels of total protein by 9%, and increased levels of glutamic acid, arginine, and histidine by 11%, 24%, and 33% respectively. Interestingly, the straw/mesquite substrate resulted in a significant increase in total amino acid and beta glucan content over the straw/cottonseed substrate by 8 and 18%, respectively. These results illustrate how light spectra and substrate mixture can significantly impact nutritional value and production qualities of oyster mushrooms. Full article

Arthrospira platensis (commonly known as Spirulina platensis) is a blue-green microalga increasingly used in skincare due to its antioxidant and dermo-protective properties, primarily attributed to components such as phycocyanin and carotenoids. However, the intense blue color of phycocyanin can limit its cosmetic appeal. In this study, we investigated the antioxidant, anti-inflammatory, skin lightening and photoprotective activity of Elixspir^®, a novel light-colored aqueous extract of Spirulina, using both 2D and 3D skin cell models. We demonstrated that Elixspir^® exerts strong antioxidant and cytoprotective effects by reducing intracellular ROS levels and modulating cellular thiol redox state. Its anti-pigmentation potential was supported by tyrosinase inhibition, while anti-inflammatory activity was principally due to ability to reduce PGE2 levels. Finally, we demonstrated an unprecedented photoprotective effect of Elixspir^®, highlighting its potential as a novel active ingredient for skin defense against environmental stressors. Overall, these results provide a molecular-level understanding of Elixspir^® multifunctional bioactivity and support its application as a skin-lightening, anti-inflammatory, antioxidant, and photoprotective ingredient in the formulation of innovative skin anti-aging treatments. Full article