Search Results (12)

Application of CFA-treated biosolids (NVS) offers multiple benefits to agricultural soils, including fertilizer replacement, soil rehabilitation, and disinfection. It also poses a heavy metal(loid)s threat to the agro-environment. NVS (and CFA to some extent) was tested in lysimeter and field trials, using soils differing in physicochemical properties and a large selection of crops. Consistently, As, Pb, and Cd concentrations in leachate were at or below detection limit, and these and other heavy metal(loid)s (and P) were within the permitted range in plant tissue. Foliage Mo (occasionally also Se, P) concentrations often increased significantly, especially in crops (legumes, potatoes) grown on marginal soils, which also displayed significantly higher yields. CFA and NVS reduced lettuce and legumes foliage Mn (and occasionally Zn) concentrations, which remained, however, adequate. NVS (214 and 642 mT ha⁻¹), digested sewage sludge (ADS) and its compost (24 and 72 mT ha⁻¹), temporarily increased the DTPA-extractability of some elements (NVS: B, Cr; ADS: Cu, Ni, Zn; Compost: Zn) 10–30-fold. The extractabilities of Fe and P increased by up to six times. These increases vanished soon after additive application, supporting the hypothesis of ‘self-attenuation’ by applied biosolids. Our data indicate that long-term application of NVS (and CFA) to calcareous soils poses no heavy metal(loid)s-related threat to the agro-environment. Full article

Per- and polyfluoroalkyl substances (PFAS) have been reported to contaminate soil as a result of improper management of waste, wastewater, landfill leachate, biosolids, and a large and indiscriminate use of aqueous film-forming foams (AFFF), posing potential risks to human health. However, their high chemical and thermal stability pose a great challenge for remediation. As a result, there is an increasing interest in identifying and optimizing very effective and sustainable technologies for PFAS removal. This review summarizes both traditional and innovative remediation strategies and technologies for PFAS-contaminated soils. Unlike existing literature, which primarily focuses on the effectiveness of PFAS remediation, this review critically discusses several techniques (based on PFAS immobilization, mobilization and extraction, and destruction) with a deep focus on their sustainability and scalability. PFAS destruction technologies demonstrate the highest removal efficiencies; however, thermal treatments face sustainability challenges due to high energy demands and potential formation of harmful by-products, while mechanical treatments have rarely been explored at full scale. PFAS immobilization techniques are less costly than destruction methods, but issues related to the regeneration/disposal of spent sorbents should be still addressed and more long-term studies conducted. PFAS mobilization techniques such as soil washing/flushing are hindered by the generation of PFAS-laden wastewater requiring further treatments, while phytoremediation is limited to small- or medium-scale experiments. Finally, bioremediation would be the cheapest and least impactful alternative, though its efficacy remains uncertain and demonstrated under simplified lab-scale conditions. Future research should prioritize pilot- and full-scale studies under realistic conditions, alongside comprehensive assessments of environmental impacts and economic feasibility. Full article

Leachates generated from the degradation of green waste and biosolids from urban wastewater treatment plants (WWTPs) pose significant environmental concerns due to high concentrations of organic pollutants and heavy metals. This study proposes a hybrid treatment strategy combining electrocoagulation (EC) and UVC-activated TiO₂ photocatalysis to remediate leachates produced in laboratory-scale biocells. Initial characterization revealed critical pollutant levels: COD (1373 mg/L), BOD₅ (378 mg/L), total phosphorus (90 mg/L), ammoniacal nitrogen (201 mg/L), and metals such as Ni, Pb, and Mn levels all exceeding those set out in the Ecuadorian discharge regulations. Optimized EC achieved removal efficiencies of 62.6% for COD, 44.4% for BOD₅, 89.8% for phosphorus, and 86.2% for color. However, residual contamination necessitated a subsequent photocatalytic step. Suspended TiO₂ under UVC irradiation removed up to 81.8% of the remaining COD, 88.7% of the ammoniacal nitrogen, and 94.4% of the phosphorus. Levels of heavy metals such as Zn, Fe, Pb, Mn, and Cu were reduced by over 80%, while Cr⁶⁺ was nearly eliminated. SEM–EDS analysis confirmed successful TiO₂ immobilization on sand substrates, revealing a rough, porous morphology conducive to catalyst adhesion; however, heterogeneous titanium distribution suggests the need for improved coating uniformity. These findings confirm the potential of the EC–TiO₂/UVC hybrid system as an effective and scalable approach for treating complex biocell leachates with reduced chemical consumption. Full article

This study explores the potential of non-hazardous wastes for crafting an engineered soil-like material (Technosol) suitable for landfill capping applications. Three distinct materials—waste foundry sand (WFS), washing aggregate sludge (WAS), and composted biosolids (CBS)—were strategically combined to develop this innovative Technosol. The formulation process involved a comprehensive analysis of their physical–chemical properties, mineral composition, leachate quality, and a series of geotechnical assessments to ensure compliance with landfill top cover construction standards. The blend 90WFS/10WAS showed optimal geotechnical properties for constructing a protective layer, including maximum dry density (1.77 g cm⁻³), void ratio (0.4), CBR index (23.2), cohesive strength (40 kPa), internal friction (ϕ = 30°), and permeability coefficient (k = 1.48 × 10⁻⁶ cm s⁻¹). Further enhancement was achieved by adding 10% CBS, resulting in the development of a functional organo-mineral topsoil horizon (81WFS/9WAS/10CBS). Importantly, leachate analysis confirmed the negligible environmental footprint of this Technosol. Moreover, a pot-based experiment with Brassica juncea planting validated its capacity to support plant growth and establish a vegetative cover on the landfill surface. Full article

This study aims to understand the potential of using biosolids produced from the world’s largest gas-to-liquid (GTL) plant for water treatment applications. The metal fractionization of the two samples: raw biosolid (BS) and the pyrolyzed biosolid-BS char (BSC) (temperature: 450 °C, heating rate: 5 °C/min, residence time: 30 min) into exchangeables (F₁), reducible (F₂), oxidizable (F₃), and residual (F₄) were carried out following the Community Bureau of Reference (BCR) procedure. Characterization showed an increased carbon content and reduced oxygen content in the biochar sample. Additionally, the presence of calcium, magnesium, and iron were detected in smaller quantities in both samples. Based on the extraction results for metals, the environmental risk analysis was determined based on RAC (Risk Assessment Code) and PERI (Potential Ecological Risk Index) indices. Furthermore, leaching studies following the TCLP (Toxicity Characteristic Leaching Procedure) were conducted. The results prove that pyrolyzing stabilizes the metals present in the raw material as BS sample had high F₁ fractions, and the BS char had a greater F₄ fraction. While the RAC and PERI indices show that the pyrolyzed BS has a ‘low risk’, much reduced compared to the original BS sample, this is confirmed by the leaching studies that displayed minimal leaching from the pyrolyzed sample. Overall, this study proves that the GTL biosolids can best be applied for water treatment after pyrolysis. Full article

An appropriate handling and use of urban and agricultural biosolids on soils are the best means to protect them from erosion, prevent the loss of nutrients due to runoff and washing, and preserve and restore soil productivity. Heavy metal concentrations in biosolids are one of the decisive factors when using this type of waste on soil, due to potentially being harmful to crops and reaching the human food chain. There is a clear need to study the incidence of these metals in agricultural practices in Mediterranean soils. Research for this article was performed as a controlled study using leaching columns. Three treatments were performed by applying different amounts of biosolids (T₅₀: 50,000 kg ha⁻¹, T₉₀: 90,000 kg ha⁻¹, T₁₃₀: 130,000 kg ha⁻¹), as well as a blank test or control treatment (T0). The presence of macronutrients (K, Na, Ca and Mg), micronutrients (Fe, Cu, Mn and Zn) and three contaminating heavy metals (Cr, Cd and Ni) in lixiviated water was analyzed. Relevant amounts of metals in the wash water were not found. This indicates that, under the watering conditions used, the contaminants and micronutrients analyzed are not a relevant source of water contamination on a common calcareous soil of the Mediterranean Basin. Full article

Biosolid application is an effective strategy, alternative to synthetic chemicals, for enhancing plant growth and performance and improving soil properties. In previous research, biosolid application has shown promising results with respect to tomato resistance against Fusarium oxysporum f. sp. radicis-lycopersici (Forl). Herein, we aimed at elucidating the effect of biosolid application on the plant–microbiome response mechanisms for tomato resistance against Forl at a molecular level. More specifically, plant–microbiome interactions in the presence of biosolid application and the biocontrol mechanism against Forl in tomato were investigated. We examined whether biosolids application in vitro could act as an inhibitor of growth and sporulation of Forl. The effect of biosolid application on the biocontrol of Forl was investigated based on the enhanced plant resistance, measured as expression of pathogen-response genes, and pathogen suppression in the context of soil microbiome diversity, abundance, and predicted functions. The expression of the pathogen-response genes was variably induced in tomato plants in different time points between 12 and 72 h post inoculation in the biosolid-enriched treatments, in the presence or absence of pathogens, indicating activation of defense responses in the plant. This further suggests that biosolid application resulted in a successful priming of tomato plants inducing resistance mechanisms against Forl. Our results have also demonstrated that biosolid application alters microbial diversity and the predicted soil functioning, along with the relative abundance of specific phyla and classes, as a proxy for disease suppression. Overall, the use of biosolid as a sustainable soil amendment had positive effects not only on plant health and protection, but also on growth of non-pathogenic antagonistic microorganisms against Forl in the tomato rhizosphere and thus, on plant–soil microbiome interactions, toward biocontrol of Forl. Full article

Biosolids made from municipal sludge are an attractive solution instead of chemical fertilization. Nevertheless, their effects on the ecosystem should always be considered. In the present study, anaerobically digested sludge was subjected to two leaching methods (EN 12457-2 and NEN 7341) and the main physicochemical parameters were measured in the leachates. The aquatic organisms Daphnia magna and Vibrio fischeri were exposed to the leachates in order to test for adverse effects. Mixtures of biosolid/solid, simulating the high dose of 80 tn/ha, were also created, and the same parameters were measured for EN 12457-2 leachates. The results show a strong seasonal variation for the results for the municipal sludge, even though the sludge did not originate from a touristic area. The biosolid/solid mixtures did not produce toxic responses to the organism tested. Nevertheless, the parameters nitrites and nitrates in the leachates were increased in relation to control and they continued to increase even at Day 40 post-application. This increase was soil-type-dependent. The biosolids in question could be used for field fertilization, however measures should be taken against underground water nitrate pollution. Full article

Millions of tonnes of leftover biosolids are increasingly stockpiled every year around the globe. Biosolids are a product of the wastewater sludge treatment process. Stockpiles necessitate the use of large areas of increasingly valuable land. Biosolids have many beneficial uses and are currently utilised in agricultural and land rehabilitation applications. However, it is estimated that 30% of biosolids are unused and stockpiled. A second and seemingly unrelated environmental issue is the massive excavation of virgin soil for brick production. The annual production of 1500 billion bricks globally requires over 3.13 billion cubic metres of clay soil—equivalent to over 1000 soccer fields dug 440 m deep or to a depth greater than three times the height of the Sydney Harbour Bridge. This paper investigates and proposes a practical solution for the utilisation of the world’s excess biosolids in fired–clay bricks. The physical, chemical and mechanical properties of fired–clay bricks incorporating 25%, 20%, 15% and 10% biosolids have been tested. Bricks were produced from three different biosolids samples collected at Melbourne’s Eastern Treatment Plant (ETP 22) and the Western Treatment Plant (WTP 10 & WTP 17–29). Compressive strength testing indicated results ranging between 35.5 MPa and 12.04 MPa for the biosolids-amended bricks. Leachate analysis was conducted on the bricks before and after firing, and the results demonstrate that between 43 and 99% of the heavy metals tested were immobilised inside the fired bricks compared to the heavy metals tested in the raw mixture. All leachate concentrations were found to be insignificant for the biosolids-incorporated bricks tested in this study. Biosolids can have significantly different chemical characteristics depending on the origin of the wastewater and the treatment procedure. Suitable leachate analysis should be undertaken on biosolids and test bricks before large-scale production is approved. Scanning Electron Microscopy (SEM) images illustrate that biosolids-amended bricks have a higher porosity than the control bricks, which corresponds to the lower thermal conductivity values recorded for biosolids-amended bricks. In addition, brick firing energy demands are estimated to decrease by up to 48.6% for bricks incorporating 25% WTP 17–29 biosolids due to the higher organic content of the mixture containing biosolids. The emissions study and comparative Life Cycle Assessment results show that the incorporation of biosolids into bricks is a positive and sustainable alternative approach with respect to all environmental impacts arising from the stockpiling of biosolids and brick manufacturing. Based on the results found in this comprehensive study, this paper proposes the inclusion of a minimum of 15% biosolids content into 15% of brick production in order to completely recycle all the approximately 5 million tonnes of annual leftover biosolids production in Australia, New Zealand, the EU, the USA and Canada. This is a practical and sustainable proposal for recycling all the leftover biosolids worldwide. Utilisation of only 15% of biosolids in brick production would reduce the carbon footprint of brick manufacturing whilst satisfying all the environmental and engineering requirements for bricks. Full article

The effective control and treatment of acid mine drainage (AMD) from sulfide-containing mine wastes is of fundamental importance for current and future long-term sustainable and cost-effective mining industry operations, and for sustainable management of legacy AMD sites. Historically, AMD management has focused on the use of expensive neutralising chemicals to treat toxic leachates. Accordingly, there is a need to develop more cost-effective and efficient methods to prevent AMD at source. Laboratory kinetic leach column experiments, designed to mimic a sulfide-containing waste rock dump, were conducted to assess the potential of organic waste carbon supplements to stimulate heterotrophic microbial growth, and supress pyrite oxidation and AMD production. Microbiological results showed that the addition of biosolids was effective at maintaining high microbial heterotroph populations and preventing AMD generation over a period of 80 weeks, as verified by leachate chemistry and electron microscopy analyses. This research contributes to the ongoing development of a cost effective, multi-barrier geochemical-microbial control strategy for reduced mineral sulfide oxidation rates at source. Full article

Biochemical reactors (BCRs) using complex organics for bioremediation of mine-influenced water must operate successfully year round. In cold climates, where many mines in Canada are located, survival of the important microorganisms through the winter months is a concern. In this work, broad phylogenetic surveys, using metagenomics, of the microbial populations in pulp mill biosolids used to remediate metal leachate containing As, Zn, Cd and sulfate were performed to see if the types of microorganisms present changed over the seasons of one year (August 2008 to July 2009). Despite temperature variations between 0 and 17 °C the overall structure of the microbial population was fairly consistent. A cyclical pattern in relative abundance was detected in certain taxa. These included fermenter-related groups, which were out of phase with other taxa such as Desulfobulbus that represented potential consumers of fermentation byproducts. Sulfate-reducers in the BCR biosolids were closely related to psychrotolerant species. Temperature was not a factor that shaped the microbial population structure within the BCR biosolids. Kinetics of organic matter degradation by these microbes and the rate of supply of organic carbon to sulfate-reducers would likely affect the metal removal rates at different temperatures. Full article

Column-leaching and pilot-scale experiments were conducted to evaluate the use of biosolids (sewage sludges) to control the mobilization of metals from contaminated soils with smelting slags. The pilot-scale experiments using amended soils showed that Cu, Pb and Sb were retained, decreasing their concentrations from 250 mg/L, 80 mg/L and 6 mg/L, respectively in the leachates of contaminated soils, to <20 mg/L, 40 mg/L and 4 mg/L, respectively, in the amended material. Hydrogeochemical modeling of the leachates using Minteq revealed that the degree of complexation of Cu rose 56.3% and 57.6% in leachates of amended soils. Moreover, Cu may be immobilized by biosolids, possibly via adsorption by oxyhydroxides of Fe or sorption by organic matter. The partial retention of Pb coincides with the possible precipitation of chloropyromorphite, which is the most stable mineral phase in the pH-Eh conditions of the leachates from the amended material. The retention of Sb may be associated with the precipitation of Sb₂O₃, which is the most stable mineral phase in the experimental conditions. The organic amendments used in this study increased some metal and metalloid concentrations in the leachates (Fe, Mn, Ni, As and Se), which suggests that the organic amendments could be used with caution to remediate metal contaminated areas. Full article