Search Results (99)

The thermal transformation mechanism of pyrite in coal, which governs sulfur emissions and ash deposition, remains highly controversial. There are significant discrepancies in reported activation energies (E_a) (60–310 kJ/mol) and conflicting reaction pathways. To resolve these long-standing controversies, this study proposes a competition-coupling mechanism: pyrolysis and oxidation compete under local O₂ and temperature gradients, while coupling through microstructural evolution. Specifically, pyrolysis generates a porous Fe_1−XS that facilitates oxidation, which in turn can form a passivating oxide/sulfate layer that promotes further pyrolysis. This mechanism reconciles longstanding kinetic controversies by showing that the apparent activation energy is not a fixed value but instead a dynamic parameter, shifting along a continuous curve that bridges pyrolysis and oxidation-dominated regimes. Furthermore, we construct a unified phase diagram by incorporating the competition-coupling mechanism into classical thermodynamic equilibria. This diagram uses the molar ratio FeS₂/(FeS₂ + O₂) and temperature to categorize the transformation process into four distinct regions—pyrolysis-dominated, competition-coupling, oxidation-dominated, and melt-dominated. The key contribution of this work lies in the diagram which offers a practical framework for optimizing combustion and roasting systems, allowing for improved control over sulfur emissions and ash-related issues such as slagging and fouling. Full article

This study investigates the combustion characteristics and ash behavior of coal–biomass co-combustion using Zhujixi coal and corn straw in a fixed-bed system. The research analyzes combustion stage division, gas release patterns, and mineral evolution of ash under varying blending ratios. Results indicate that biomass addition modifies the dynamic features of the combustion process by advancing the CO₂ release peak; extending the release of CO, CH₄, and H₂; and enhancing the completeness of char oxidation. At moderate blending levels (20–60%), oxygen utilization is significantly improved and combustion stability is strengthened. Ash fusion temperatures exhibit a consistent decline with increasing biomass proportion due to the formation of low-melting eutectic phases such as KAlSiO₄ and K, Ca-based phosphates. Mineralogical analysis further reveals that coal ash components promote the immobilization of alkali metals, thereby suppressing potassium volatilization. A blending ratio of 40% demonstrates the most favorable balance between burnout performance, oxygen efficiency, and alkali fixation, surpassing both pure coal and high-ratio biomass conditions. This optimized ratio not only improves energy conversion efficiency but also reduces slagging and corrosion risks, offering practical guidance for cleaner coal power transformation, stable boiler operation, and long-term reduction of carbon and pollutant emissions. Full article

Blending kaolin is an effective method to alleviate fouling and slagging during the combustion of Zhundong coal. The influence of blending kaolin with varying particle sizes on the adsorption behavior of alkali metal sodium and the ash fusion characteristics was studied using sodium capture experiments and ash fusion temperature tests. The results indicate that kaolin particle size is a critical factor influencing sodium retention. As the particle size decreases, the sodium retention rate increases accordingly. In the absence of kaolin, the sodium retention rate was only 28.03%. However, when 75–100 µm particles of kaolin were added, the retention rate increased to 43.49%. Further reducing the particle size to 20–63 µm resulted in an additional increase of 10.51%. Additionally, decreasing the kaolin particle size contributed to the noticeable increase in ash fusion temperatures. After 75–100 µm kaolin was blended, the DT and FT of the ash were 1137 °C and 1161 °C, respectively. With 20–63 µm kaolin, the DT increased by 42 °C, and the FT increased by 36 °C. This trend is attributed to the enhanced decomposition and transformation of sulfates in the ash, which promotes the formation of high-melting-point feldspar minerals such as anorthite and gehlenite. These findings provide important data support for understanding the influence of kaolin particle size on the ash fusion behavior during the combustion of Zhundong coal. Full article

In this research, thermoplastic waste (polyethylene and propylene) from waste electrical and electronic equipment (WEEE) was used to manufacture polymer composite materials that included talc, fly ash, and elastomers, with tailored electromagnetic interference shielding properties, for the potential use for electric car components. A distribution of inorganic components within the polymer structures without particle clustering were observed, illustrating an effective melt compounding process. The gradual replacement of talc with fly ash lowered both the fluidity index and the softening temperature values. The increase in fly ash content resulted in higher values of both permittivity and dielectric loss factor. The novelty was related to a significant increase in both dielectric characteristics at increased quantities of fly ash at higher temperatures, an aspect more relevant at higher frequencies where they approached a steady value. The permittivity values surpassed five, and the dielectric loss factor values exceeded 0.04, fulfilling the requirements for their application in electrical equipment. The recipes containing 10% fly ash may guarantee an electromagnetic shielding effectiveness of at least 99% within the frequency domain of 0.1–4 GHz. Composites with greater amounts of fly ash can conduct heat more efficiently, leading to improved diffusivity and thermal conductivity values, with significant thermal conductivity values surpassing 0.2 W/(m*K). Finally, it was concluded that the composites with 10% talc, 10% fly ash, and elastomer using recycled high-density polyethylene might be the best choice for electric vehicle parts, in line with all required standards for these uses. Full article

In light of the environmental impact of disposable products made from petroleum-based plastics, this study focused on developing biodegradable foam trays made from a starch (PS) derived from potato waste and beer malt flour (BMBF). The objective of this study was to evaluate the effect of the concentration of BMBF on the physical and mechanical properties of potato starch-based foam trays prepared by the thermoforming process at temperatures of 150 °C (upper plate) and 145 °C (lower plate) for 5 min and 40 s. The results showed that increasing the BMBF concentration from 0 to 40% reduced the moisture content from 4.68% to 3.42%, increased the thickness from 2.63 cm to 4.77 cm, and decreased the density from 0.28 g.cm⁻³ to 0.15 g.cm⁻³. Meanwhile, the water absorption capacity increased from 38.7% to 69.7%. In terms of mechanical properties, increasing the BMBF concentration in the PS foam tray resulted in a decrease in hardness from 5.61 N to 2.87 N, a decrease in tensile strength from 2.92 MPa to 0.85 MPa, and a decrease in elongation from 1.42% to 0.59%. Meanwhile, fracturability increased from 2.04 mm to 3.68 mm. FTIR analysis revealed interactions between BMBF and PS in the composite foam tray. Thermogravimetric analysis (TGA) showed two thermal events: one between 20.96 °C and 172.89 °C, and another between 189.14 °C and 517.69 °C, with weight losses of 5.53% and 74.23%, leaving an ash residue of 20.24%. Differential calorimetry analysis (DSC) showed a glass transition at 152.88 °C and a melting at 185.94 °C, with an enthalpy of fusion of 74.11 J.g⁻¹. Higher concentrations of BMBF (>10%) decreased the water resistance, mechanical strength, and flexibility of the PS foam trays. Therefore, a formulation of 90% PS and 10% BMBF was better for producing a foam tray with improved mechanical properties and water resistance, which could be used as a sustainable alternative to conventional single-use plastic. Full article

Co-combustion of coal and biomass for power generation technology could not only realize the effective utilization of biomass energy, but also reduce the emission of greenhouse gases. In this study, a system of a settling furnace with high temperature is applied to study the ash deposition of the co-combustion of coal and salix. The effects of salix blending ratio, flue gas temperature, and wall temperature on ash deposition are studied. The micro-morphology, elemental content, and compound composition of the ash samples are characterized by scanning electron microscopy and energy-dispersive spectroscopy (SEM-EDS) and X-Ray Diffraction (XRD), respectively. The results show that with the biomass blending ratio increasing from 5% to 30%, the content of Ca in ash increases from 8.92% to 20.59%. In particular, when the salix blending ratio exceeds 20%, plenty of the low-melting-point compounds of Ca aggravate the melting adhesion of ash particles, causing serious ash accumulation. Therefore, the salix blending radio is recommended to be limited to no more than 20%. With the increase in flue gas temperature, ash particles melt and stick, forming ash accumulation. Under the condition of flue gas temperature ≥ 1200 °C, a serious ash particle melting flow occurs, and CaO covers the surface of the ash particles, making the ash particles adhere to each other, which makes them difficult to remove. Therefore, controlling the flue gas temperature below 1200 °C is necessary. When the temperature crosses the threshold range of 500–600 °C, the Ca and K contents increase by 35.6% and 41.9%, respectively, while the Si content decreases by 9.7%. The increase in K and Ca content leads to the thickening of the initial layer of the ash deposit, which facilitates the formation of the sintered layer of the deposited ash. Meanwhile, the reduction in Si content leads to the particles’ adhesion, which markedly increases the degree of ash slagging. Once the wall temperature exceeds 600 °C, severe ash slagging becomes a threat to the safe operation of the boiler. Therefore, the wall temperature should not exceed 600 °C. Full article

In the domain of metal casting, investment casting is recognized for its proficiency in producing high-quality castings. This method involves the utilization of a melt out, burnout, or soluble patterns to create ceramic molds. The present investigation explored the potential of utilizing fused deposition modeling (FDM) patterns fabricated from polyvinyl alcohol (PVA). An examination of the structural characteristics and properties of several commercially available PVA filaments, along with an evaluation of the as-printed samples, were provided in this study. It was demonstrated that commercial PVA filaments may contain additives that can lead to elevated ash content following pattern burnout and reduced strength in as-printed samples. Experiments on PVA dissolution in water revealed that, for high dissolution rates of the pattern, not only high temperature, but also water medium mixing was necessary. The colloidal silica binder, a common component in ceramic mold manufacturing, exhibited effective wetting properties of the patterns, while generally preventing significant dissolution, which can adversely impact pattern quality. The PVA filaments under investigation were utilized to fabricate patterns for the impeller cast parts. Subsequent to this, ceramic molds were obtained, and castings made of nickel superalloy were produced. The investigation revealed that the Bambu Lab filament, which is PVA without additives, exhibited the lowest defect rate in both the mold and the casting. In summary, this study demonstrates that the 3D printing of investment casting patterns holds considerable promise as a rapid casting technique. Full article

New data, including Raman spectroscopy, characterize unusual mineral assemblages from rocks of the Naylga and Khamaryn–Khyral–Khiid combustion metamorphic complexes in Mongolia. Several samples of melilite–nepheline paralava and other thermally altered (metamorphosed) sedimentary rocks contain troilite (FeS), metallic iron Fe⁰, kamacite α-(Fe,Ni) or Ni-bearing Fe⁰, taenite γ-(Fe,Ni) or Ni-rich Fe⁰, barringerite or allabogdanite Fe₂P, schreibersite Fe₃P, steadite Fe₄P = eutectic α-Fe + Fe₃P, wüstite FeO, and cohenite Fe₃C. The paralava matrix includes a fragment composed of magnesiowüstite–ferropericlase (FeO–MgO solid solution), as well as of spinel (Mg,Fe)Al₂O₄ and forsterite. The highest-temperature mineral assemblage belongs to a xenolithic remnant, possibly Fe-rich sinter, which is molten ash left after underground combustion of coal seams. The crystallization temperatures of the observed iron phases were estimated using phase diagrams for the respective systems: Fe–S for iron sulfides and Fe–P ± C for iron phosphides. Iron monosulfides (high-temperature pyrrhotite) with inclusions of Fe⁰ underwent solid-state conversion into troilite at 140 °C. Iron phosphides in inclusions from the early growth zone of anorthite–bytownite in melilite–nepheline paralava crystallized from <1370 to 1165 °C (Fe₂P), 1165–1048 °C (Fe₃P), and <1048 °C (Fe₄P). Phase relations in zoned spherules consisting of troilite +Fe⁰ (or kamacite + taenite) +Fe₃P ± (Fe₃C, Fe₄P) reveal the potential presence of a homogeneous Fe–S–P–C melt at T~1350 °C, which separated into two immiscible melts in the 1350–1250 °C range; namely, a dense Fe–P–C melt in the core and a less dense Fe–S melt in the rim. The melts evolved in accordance with cooling paths in the Fe–S and Fe–P–C phase diagrams. Cohenite and schreibersite in the spherules crystallized between 988 °C and 959 °C. The crystallization temperatures of minerals were used to reconstruct redox patterns with respect to the CCO, IW, IM, and MW buffer equilibria during melting of marly limestone and subsequent crystallization and cooling of melilite–nepheline paralava melts. The origin of the studied CM rocks was explained in a model implying thermal alteration of low-permeable overburden domains in reducing conditions during wild subsurface coal fires, while heating was transferred conductively from adjacent parts of ignited coal seams. The fluid (gas) regime in the zones of combustion was controlled by the CCO buffer at excess atomic carbon. Paralava melts exposed to high-temperature extremely reducing conditions contained droplets of immiscible Fe–S–P–C, Fe–S, Fe–P, and Fe–P–C melts, which then crystallized into reduced mineral assemblages. Full article

Thermal decomposition (pyrolysis) of coal bottom ash (collected after lignite combustion in coal-fired power plant TEKO-B, Republic of Serbia) was investigated, using the simultaneous TG-DTG techniques in an inert atmosphere, at various heating rates. By using the XRD technique, it was found that the sample (CBA-TB) contains a large amount of anorthite, muscovite, and silica, as well as periclase and hematite, but in a smaller amount. Using a model-free kinetic approach, the complex nature of the process was successfully resolved. Thermodynamic analysis showed that the sample is characterized by dissociation reactions, which are endothermic with positive activation entropy changes, where spontaneity is achieved at high reaction temperatures. The model-based method showed the existence of a complex reaction scheme that includes two consecutive reaction steps and one single-step reaction, described by a variety of reaction models as nucleation/growth phase boundary-controlled, the second/n-th order chemical, and autocatalytic mechanisms. It was established that an anorthite I1 phase breakdown reaction into the incongruent melting product (CaO·Al₂O₃·2SiO₂) represents the rate-controlling step. Autocatalytic behavior is reflected through chromium-incorporated SiO₂ catalyst reaction, which leads to the formation of chromium(II) oxo-species. These catalytic centers are important in ethylene polymerization for converting light olefin gases into hydrocarbons. Adiabatic T_D24 prediction simulations of the process were also carried out. Based on safety analysis through validated kinetic parameters, it was concluded that the tested sample exhibits high thermal stability. Applied thermal treatment was successful in promoting positive changes in the physicochemical characteristics of starting material, enabling beneficial end-use of final products and reduction of potential environmental risks. Full article

As the world shifts towards more sustainable and eco-friendly practices, industrial hemp (Cannabis sativa L.) is gaining recognition as a versatile crop with numerous applications. The Baltic Sea region is well-suited for hemp cultivation, with its temperate climate and varied soil types. This study evaluates the suitability of various hemp varieties for the region, focusing on their ability to produce high-quality biomass, fibers, seeds, and dual-purpose products. The findings will contribute to the development of a thriving hemp industry in the region. Five years of research was conducted to investigate the productivity of 12 industrial hemp varieties, including 7 varieties mainly developed for seed production and 5 varieties mainly designed for fiber production. The results showed significant differences in yields among the varieties, with ‘Bialobrzeskie’ exhibiting the highest biomass yield (47.2 t ha⁻¹) and ‘Futura 75’ producing the highest fiber yield (10.8 t ha⁻¹). ‘Henola’ demonstrated the highest seed yield (3.5 t ha⁻¹), while ‘KA-2-2011’ and ‘USO-31’ were identified as dual-purpose varieties suitable for fiber (3.4 and 6.4 t ha⁻¹, respectively) and seed production (2.2 and 1.3 t ha⁻¹, respectively). The calorific value of hemp shives is comparable to wood fuels, indicating their potential as a viable fuel source. The results offer farmers a crucial tool for selecting the best-suited varieties for their specific region, promoting sustainable agriculture practices. Full article

In this work, dry carbonization (DC) and hydrothermal carbonization (HTC) of refuse-derived fuel (RDF) pellets were conducted to evaluate the physical, chemical, and fuel properties of the produced chars. In the dry carbonization tests, biomass sawdust was incorporated in different proportions on the samples to minimize agglomeration caused by the melting of the plastic fraction. The experiments were carried out in a temperature of 400 °C (DC) and 250–300 °C (HTC), in a residence time of 30 min. The respective chars and hydrochars were characterized according to their mass yield, apparent density, proximate, elemental, and mineral composition, chlorine content, high heating value, thermogravimetric profile, and surface functional groups. The results showed that the dry carbonization of RDF pellets with biomass incorporation, followed by a washing step, resulted in the production of chars with improved properties such as higher fixed carbon and higher heating value (HHV) (25–26 MJ/kg) and lower ash and chlorine content. Additionally, the HTC experiments demonstrated that hydrochars showed improved properties without the need for biomass addition and washing, however, with no significant difference in the HHV (20–21 MJ/kg). Therefore, DC of RDF pellets with 10% biomass incorporation seems to be a promising option to overcome the constraints of RDF utilization as an alternative fuel. Full article

This study focuses on the sintering phenomenon that easily occurs during the direct combustion of molded fuel made from fungus bran (FB). To investigate the key factors influencing sintering, experiments are designed and conducted using a muffle furnace and a high-temperature drop furnace. The experimental results show that the combustion temperature is the primary factor triggering the sintering phenomenon. To effectively mitigate this issue, this study proposes two improvement strategies: water washing pretreatment and the use of additives. The analysis shows that water washing pretreatment effectively removes K and Mg elements, with the removal rates increasing as the washing temperature and time increase. Specifically, the removal rate of K ranges from 37.68% to 55.91%, and that of Mg ranges from 33.16% to 58.52%. Water washing pretreatment also reduces the degree of sintering; at 1400 °C, the TSF (tendency to slag formation) of the fuel increases by 25–40% after pretreatment, with a greater increases observed at higher washing temperatures and longer durations. Kaolin, used as an additive, significantly raises the ash melting point of FB and alleviates sintering, while P₂O₅ exacerbates it. Increasing the proportion of kaolin does not significantly enhance the TSF of high-temperature ash, but raising the P₂O₅ content from 5% to 10% lowers the TSF by 10–20% at the corresponding temperature. Full article

This study presents the first U-Pb (CA-ID-TIMS) radioisotopic dating of zircon grains extracted from tonsteins within the uppermost Permian coal interval of the Minusinsk Coal Basin (Siberia, Russia). Petrographic, structural, and mineralogical analyses confirm the volcanic ash origin of the tonsteins. The parent pyroclastic materials are identified as rhyolite–pantellerite for tonstein I-22 and dacite–rhyodacite for tonstein I-12. Morphological analysis of zircon crystals, along with cathodoluminescence and melt inclusion studies, confirms their volcanic origin and crystallisation temperatures of 700–900 °C. New radioisotopic dates of 261.4 ± 0.7 Ma and 261.3 ± 0.4 Ma clarify the age of the Izykh Formation, enabling its direct correlation with the Capitanian Stage of the International Chronostratigraphic Chart. The results emphasise the possible discontinuity of the coal-bearing succession of Siberian palaeocontinent and highlight the potential for further stratigraphic refinement through continued radioisotopic dating of tonsteins. Full article

In order to reduce heat loss and diffusion of underground heating pipelines, this research incorporated phase change material (PCM) into the controlled low-strength material (CLSM) to prepare a pipeline backfill material with temperature control performance. In response to the problem that PCM leaks easily, a new type of paraffin–rice husk ash composite PCM (PR-PCM) was obtained by adsorbing melted paraffin into rice husk ash. Through mixing PR-PCM with dredged sediment (DS) and ordinary Portland cement (OPC), a controlled low-strength material (CLSM) with temperature control performance was prepared. The flowability, mechanical properties, microscopic characteristics, thermal characteristics, and durability of CLSM were analyzed through flowability, unconfined compressive strength (UCS), X-ray diffraction (XRD), scanning electronic microscopy (SEM), differential scanning calorimetry (DSC), and phase change cycle tests. The results show that when water consumption is constant, as the PR-PCM content increases, the flowability of CLSM increases, and the strength decreases. The CLSM has an obvious paraffin diffraction peak in the XRD pattern, and its microstructure is dense with few pores. The melting point of CLSM is 50.65 °C and the latent heat is 4.10 J/g. Compared with CLSM without PR-PCM, the maximum temperature difference during the heating process can reach 3.40 °C, and the heat storage performance is improved by 4.1%. The strength of CLSM increases and the melting point decreases after phase change cycles. CLSM containing PR-PCM has the characteristics of phase change temperature control, which plays a positive role in reducing heat loss by heating pipelines and temperature change in backfill areas. Full article

Due to the diversity of plastic film waste streams available on the market and the associated variety of contaminants’ size and number, the use of melt filtration is necessary. Currently, single and double filtration systems are state of the art in the plastic recycling industry, depending on the application of the produced post-consumer recyclate (PCR). Using PCR for thin films demands small contamination sizes, which are easier to reach using a second filtration step. In the case of relatively clean post-consumer input materials, it must be investigated whether the additional load from the second filter has a counterproductive effect on the material and whether single filtration would be sufficient. For this paper, polyethylene (PE) film waste stemming from a separate post-consumer collection in Austria was processed using an industrial-sized recycling machine with different combinations of filter sizes and systems. Melt flow rate (MFR), ash content, oxidation onset temperature (OOT), and optical contaminant detection were measured to investigate the influence of single and double filtration systems. The investigation showed that, even though the contamination amount and size were reduced, the second filter had a distinct effect on specific properties. Full article