Search Results (1,922)

Urbanisation-driven housing demand and the environmental burden of sewage sludge disposal highlight the need for low-carbon, circular construction materials. This study evaluates incinerated sanitary sludge ash (ISSA) as a supplementary cementitious material in stabilised earth blocks, aiming to reduce the use of cement and lime while valorising waste sludge. Lateritic soil blocks were produced with a binder-to-soil ratio of 1:7 by mass, in which ISSA partially replaced the primary stabilising binder (cement or lime) at a replacement level of 10–40% within the binder fraction. ISSA’s mineralogical characteristics were analysed using XRD and XRF. The compressive strength and density of earth blocks were measured at 7 and 28 days under curing conditions (29–36 °C; 60–75% humidity). Cement-stabilised blocks were water-cured to support cement hydration, whereas lime-stabilised blocks were air-cured to promote carbonation and pozzolanic reactions. The results, therefore, compared practical binder-specific curing regimes rather than strictly identical curing environments. ISSA exhibited moderate pozzolanic potential, and its incorporation enabled substantial partial replacement of both binders. Cement-stabilised blocks achieved higher strengths, up to 7.7 MPa, after 28 days of curing, whereas lime-stabilised blocks developed strength more gradually, reaching 4.8 MPa. Optimal mixtures were identified at 40% cement + 60% ISSA and 30% lime + 70% ISSA, balancing mechanical performance and binder reduction. A positive density–strength relationship was observed, but chemical bonding predominated over densification effects. ISSA-based stabilised earth blocks show promising structural performance and reduced binder use, but durability and life-cycle assessment need further evaluation before large-scale implementation. Full article

To tackle the intermittency of renewable energy and realize the repurposing of abandoned oil and gas wells, this study proposes a compressed air energy storage (CAES)-based cogeneration system integrated with geothermal energy and abandoned oil and gas wells, and conducts a five-dimensional comprehensive analysis covering exergy, exergoeconomic, exergoenvironmental, economic and environmental performance. The optimal operating parameters are determined as air compressed to 200 bar, an ORC turbine inlet pressure of 16 bar and an inlet temperature of 110 °C. The system’s annual total power generation is 2,971,416.5 kWh during low-power daytime operation, and 20,131,785 kWh during high-power nighttime operation. Compared with conventional CAES systems, the proposed system reduces total exergy destruction by 4121.35 kW and increases exergy efficiency from 48.49% to 63.38%. Coolers, geothermal heat exchangers and compressors are the main sources of exergy destruction cost and capital investment, while COM1, HE1 and HOT1 are the key components causing environmental impacts. The system realizes cogeneration of power, hydrogen and pure water, with a static payback period of about 5.4 years and significantly reduced TEWI value at elevated turbine inlet pressure. This system achieves multi-objective synergies in energy efficiency, economy and environment, providing a feasible scheme for the green repurposing of abandoned oil and gas wells and cascaded utilization of renewable energy. Full article

Recent advances in ozone-assisted combustion for both compression ignition and spark ignition engines are discussed. Ozone, which can be produced by an electrical discharge in air or pure oxygen, decomposes at high temperature to yield highly oxidizing oxygen atoms, which enhance fuel/air reactions. As a result, flames are faster and more stable, ignition is enhanced and low-temperature chemistry is promoted. In the literature, the beneficial influence of ozone on standard and innovative fuels, including low-carbon (syngas) and zero-carbon (hydrogen and ammonia) fuels, has been assessed. In addition, the impact of ozone seeding on new combustion strategies has also been discussed. Ozone enables better control of ignition in Homogeneous Charge Compression Ignition (HCCI) engines, and improves the combustion stability in low-load Gasoline Compression Ignition (GCI) engines, as well as in lean Spark-Assisted Compression Ignition (SACI) and spark ignition (SI) engines, thus broadening the operating range of these engines. Full article

The transition toward carbon-neutral energy systems has accelerated interest in hydrogen-fueled combustion technologies, where efficient fuel–air mixing is essential for stable and clean combustion. In the present study, the mixing characteristics of under-expanded supersonic jets injected into a pressurized environment are numerically investigated using validated computational fluid dynamics simulations. Two nozzle configurations are examined: a straight nozzle and sudden-expansion nozzles with different expansion ratios and expansion locations. The governing compressible flow equations are solved using the rhoCentralFoam solver with the SST k–ω turbulence model. The numerical framework is validated against Sod’s shock tube solution and experimental data for under-expanded supersonic free jets. The results show that sudden-expansion nozzles significantly modify the shock-wave structure, jet penetration, and lateral spreading compared with the straight nozzle. Among the investigated configurations, nozzles with intermediate expansion-section lengths exhibited pronounced Mach-disk oscillations with a dominant frequency of approximately 10 kHz. The normalized supersonic core length decreased from 17.79 for the straight nozzle to 5.50 for the best-performing sudden-expansion configuration, while the normalized jet half-width increased from 0.82 to 1.70, indicating substantially enhanced mixing performance. The findings demonstrate that nozzle geometry strongly governs the trade-off between flow stability and mixing enhancement in high-pressure supersonic jets. Full article

Black tea quality is governed by aroma chemistry: terpene alcohols (linalool, geraniol, nerolidol), methyl salicylate, and short-chain aldehydes whose abundance and release kinetics from the polyphenol-rich leaf matrix shape perceived grade. Grade information lies not only in the average headspace concentration but in the temporal shape of volatile organic compound (VOC) release under controlled heating. Conventional electronic noses obscure this signal: they rely on multi-sensor arrays, compress each response into summary statistics, and report accuracy only at the level of individual measurements. Whether a single low-cost metal–oxide–semiconductor (MOS) gas sensor can recover grade-defining aroma chemistry, and whether waveform-level modeling can exploit it, was therefore investigated. A portable electronic nose built around a Bosch BME688 sensor recorded 90 time series, each comprising four directly measured channels (temperature, humidity, pressure, gas sensor resistance) and a derived indoor-air-quality (IAQ) proxy computed from them by the on-chip BSEC library, from 16 commercial Turkish black teas across three quality grades. Two representations were compared on the same data: a feature-based pipeline reducing 25 statistical descriptors to seven principal components for six classifiers (best F1-macro = 0.624, MLP), and a raw-waveform Multi-Scale 1D-CNN with Squeeze–Excitation and temporal self-attention (MS-CNN-Attention). Under product-grouped cross-validation, the deep model reached F1-macro = 0.811 (+30%) and graded 14 of 16 products correctly by majority vote, against 11 of 16 for the MLP, with the largest gain in the medium grade (F1: 0.52 → 0.79), where summary-statistic compression destroys the release-kinetic signal. The contributions are threefold: one programmable MOS sensor operated as a thermal-desorption profiler rather than a sensor array; a direct comparison of feature-based classical learning against raw-waveform deep learning on the same small, non-normally distributed dataset; and a product-level decision-consistency metric suited to batch screening. Pairing a low-cost MOS sensor with waveform-level modeling offers a rapid, non-destructive route to aroma-chemistry-based tea quality screening. Full article

The aim of this study is to provide a preliminary assessment of the feasibility of using a three-arm buoy as a small-scale point-absorber wave energy converter under the moderate hydrodynamic conditions of the Baltic Sea. The analysed concept combines an axisymmetric three-floater geometry with two energy-conversion pathways: an electric generator and a pneumatic energy-storage subsystem based on compressed air. The study defines the geometrical and buoyancy parameters of the structure and applies two complementary modelling levels: a simplified screening-level energy estimate and a first-order heave-response model. The extended analysis includes the influence of effective operational density, added mass, PTO damping, conversion-path efficiency, heave RAO and hydrostatic stability. The baseline screening estimate indicates that the total daily energy output may amount to approximately 0.409 kWh under average wave conditions and approximately 0.920 kWh for higher waves. The first-order heave-response model shows that, for an assumed electrical conversion efficiency of 10%, the daily electrical energy estimate ranges from approximately 0.88 kWh/day for the lightweight configuration to approximately 4.12 kWh/day for the most heavily ballasted analysed case. The RAO analysis indicates that increasing the operational mass shifts the natural period towards longer wave periods, although the system remains outside resonance tuning for the reference wave period of 6 s. The hydrostatic analysis indicates that the three-arm configuration increases the waterplane second moment of area compared with a single circular buoy of the same waterplane area and provides a more directionally balanced stability response. The results should be interpreted as conceptual and parametric estimates rather than experimentally validated wave-to-wire performance. Further work should include BEM/CFD-based hydrodynamic coefficients, irregular-wave modelling, multi-degree-of-freedom dynamics, mooring-system coupling and laboratory validation. Full article

Acid-generating mining waste and polymer waste are two of the most persistent environmental problems facing the mining and manufacturing sectors, respectively. We have investigated the co-recovery of these disparate waste streams for the production of unfired cementitious paving blocks. We established a statistically optimized formulation using response surface methodology (RSM) and a central composite design (CCD). We systematically evaluated three process variables: air-curing time (4–37 days), dosage of the waste mixture (5–68% by weight of dry solids: acid-generating mining waste, hydrated lime, and recycled polymer in a waste-to-polymer mass ratio of 1:1), and type of polymeric aggregate (recycled PET flakes versus granulated rubber). Compressive strength ranged from 4.5 to 42.1 MPa across the 40 experimental conditions. The resulting quadratic model was clearly significant (F = 186.31, p < 0.0001) with solid predictive parameters (R² = 0.9796; R²pred = 0.9627; adequate precision = 42.47). Desirability-based optimization, which limited air curing to industrially feasible timeframes (7–28 days) and maximized waste utilization within a 10–50% by weight, identified PET with 12.4 days of curing and a 50% by weight waste mixture as the optimal configuration, predicting a compressive strength of 37.3 MPa. This value exceeds the 32 MPa threshold for Type I heavy-traffic paving blocks; however, confirmatory tests yielded 34.09 ± 1.08 MPa, indicating that production-scale use should include control of moisture content, compaction, and batch homogeneity. Scanning electron microscopy with energy-dispersive spectroscopy (SEM/EDS) and X-ray diffraction (XRD) demonstrated that PET inclusions promoted a denser and more continuous interfacial transition zone than shredded rubber, driven by physical entanglement and the pronounced microfilling effect of the fine waste particles. Full article

Internal combustion engines are a well-established, efficient and dispatchable solution for distributed power generation and they are widely used in various sectors including grid balancing, data centers and combined heat and power systems. Current research efforts focus on further increasing efficiency, enabling decarbonization through renewable fuels and improving responsiveness to electricity demand in the presence of variable renewable energy sources. In this context, the free-piston linear generator (FPLG) stands out as a highly promising technology, as it directly converts piston motion into electricity, offering high efficiency, reduced mechanical complexity and seamless grid integration. Initially explored for its high-efficiency potential with homogeneous charge compression ignition combustion at extreme compression ratios, opposed-piston FPLGs are now commercially available for distributed power generation, delivering global efficiencies exceeding 45%, near-zero emissions and multi-fuel capability. Building on the detailed studies conducted by Svrcek and co-authors, this work investigates the power-generation potential of low-temperature homogeneous combustion using CFD simulations with detailed chemical kinetics. First, rapid compression machine (RCM) experiments with methane were reproduced in simulations to validate the proposed methodology and to consolidate experimental findings on the maximum achievable efficiency. Subsequently, an extensive RCM simulation campaign supported the identification of optimal operating conditions in terms of air–fuel ratio using methane as fuel. The RCM results enabled the definition of a preliminary methane-fueled opposed-piston FPLG configuration. Full-cycle simulations including gas exchange, mixing and combustion demonstrated an indicated efficiency of 58% at an equivalence ratio $\varphi =0.5$ and a compression ratio of 50. The key novelties of this study are the development of a novel RCM-2 configuration that more closely reproduces the dynamic behavior of an opposed-piston FPLG including air-spring effects and the introduction of a divided intake port strategy to simultaneously reduce fuel slip and mitigate knocking behaviour through charge stratification. The simulation results for the proposed configuration confirm the potential of opposed-piston FPLGs for high-efficiency power generation and highlight key parameters affecting performance and emissions formation. Full article

This study aimed to use intact mineral trioxide aggregate (MTA) as a root canal sealer by hydrophilizing the gutta-percha (GP) surface. The GP specimens were treated with atmospheric air plasma, cetylpyridinium chloride (CPC), or a combination of both. The wettability and surface chemical properties were evaluated using contact angle measurements and X-ray photoelectron spectroscopy (XPS). The physicochemical properties of MTA mixed with water or 100 mM of CPC solution were evaluated using setting time, flowability, compressive strength, and X-ray diffraction (XRD) analyses. Sealing ability was assessed by evaluating the dye penetration in obturated single-rooted teeth. Combined plasma and CPC treatment significantly decreased the contact angle of GP compared to that of the untreated group (p < 0.05) and showed the least hydrophobic recovery after 8 weeks. The XPS analysis confirmed the adsorption of CPC onto the GP surface. The XRD and compressive strength results indicated that the CPC did not interfere with the setting reaction of intact MTA, although the setting time was prolonged (p < 0.05). Dye penetration was significantly reduced in the plasma- and CPC-treated GP groups compared to the untreated GP group (p < 0.05), with a sealing ability comparable to that of the zinc oxide-based sealer. Full article

The current need for thermal insulation building materials has led to the development of new materials and technologies, which are necessary to reduce carbon emissions. Lignocellulose materials are promising options for thermal insulation materials in construction, offering appropriate mechanical and environmental properties. While recent reviews focus primarily on material properties, a critical gap remains in the technical analysis of processing parameters and the comparative evaluation of alternative fabrication methods. This study provides a semi-systematic overview of manufacturing processes for lignocellulose-based thermal insulation, highlighting key production methods at the development stage: the most common hot pressing and compression molding, as well as less used hot drying, air-laid, wet-laid, needle-punching, and biological fabrication (mycelium-based). The results show that there is no single ideal method due to a fundamental trade-off: hot pressing provides superior mechanical strength, mycelium and needle-punching provide optimal thermal insulation, while room-temperature drying and blow-molding methods are the most environmentally friendly due to their minimal energy consumption. The key factors determining material performance are the material density, size, and type of raw material, which are strictly regulated by processing parameters. Full article

At present, research on the long-term stability of multi-cavern coordinated injection–production operations for salt cavern compressed air energy storage (CAES) remains limited. Large-capacity energy storage utilizing multiple interconnected salt caverns has become an inevitable development trend for modern CAES power stations, highlighting the necessity and importance of stability evaluation and design optimization for underground salt cavern storage clusters. Based on the Anning 350 MW CAES demonstration project, this paper takes the abandoned salt caverns of the project as research objects. A three-dimensional geological and cavern model is established using the FLAC3D numerical simulation method, and stability analysis is carried out under static conditions and three long-term gas injection and production scenarios (the pressure conditions are provided by ground-based equipment). The characteristics of the plastic zone, displacement, stress distribution, and volume shrinkage of the caverns are systematically investigated. The results show that under static conditions, the internal pressure significantly controls the development of the plastic zone, and the caverns are generally stable at pressures above 4 MPa. During long-term operation, the plastic zones of each cavern gradually expand, displacements accumulate continuously, and stresses tend to stabilize after an initial accumulation period. After 30 years of operation, no through-going plastic zones appear in any cavern, and all volume shrinkage rates are below 30%. Among the three cases, Case 1 exhibits the best stability, while enhanced monitoring is required for local high-stress regions in Case 3. This study verifies that the salt cavern development for the Anning CAES project is safe and controllable during long-term operation. The layout spacing of caverns is reasonably designed and fully satisfies the stability requirements of salt cavern CAES power stations. The research results can provide a technical guarantee for the construction of the first CAES power station in Yunnan Province and also offer a reliable reference for the design and construction of similar multi-cavity salt cavern CAES projects. Full article

Combining oxygen-enriched combustion CO₂ capture technology and CO₂ hydrogenation with methanol technology, a new power–chemicals cogeneration (PCC) design is proposed for thermal power stations with CO₂ capture and utilization under the power-to-liquid concept. For material integration, CO₂ from an oxygen-enriched thermal power station and H₂ from water electrolysis using renewable power serve as raw materials for the methanol production process. O₂ from water electrolysis using renewable power is supplied to the oxygen-enriched thermal power station; thus, electricity can be saved and investment in an air separation unit can be beneficial. For energy integration, power for gas compression and heat for methanol rectification in the methanol production process are supplied by an oxygen-enriched thermal power station. The energy released from the methanol production process is fully recovered for extra power generation. Energy analysis results show that a high CO₂ capture and utilization ratio, which is defined as the ratio of the captured and utilized CO₂ to the total CO₂ generation, of 78.1% could be achieved. By integrating the system in a 600 MW thermal power station, the net power generation and methanol production of the proposed design reaches 473.1 MW and 56.1 kg/s, respectively. Economic analysis results show that the power cost is estimated to be 62.8 $/MWh, which has great market competitiveness compared to the conventional thermal power station with CO₂ capture. Due to the saved material expense and power and heat expense, the methanol cost is reduced from 1.33 $/kg to 1.20 $/kg. The H₂ expense by water electrolysis using renewable power has a decisive influence on the methanol cost. Full article

Background: The aim of this study was to assess the effectiveness of supplemental low-flow oxygen on emergency clinicians in improving their quality and length of performance of external chest compressions (ECCs) on a resuscitation manikin. Methods: This was a double-blinded randomized crossover trial. Participants were emergency medicine doctors, nurses, or paramedics working at large emergency departments or ambulance services in Victoria, Australia. The intervention was oxygen and air via nasal cannula during external cardiac compressions. The primary outcome measure was ‘time to inadequate CPR’. Secondary outcome measures included compression rate and compression depth and global rating on a 10-point ordinal scale reporting their ‘comfort’ and ‘convenience’ ratings. Results: There was no statistical or clinical difference between the three study arms with respect to time to inadequate CPR or compression rates per minute. There was a statistically significant difference in the median depth of compression between the control (51.5 mm; IQR 43–58) and air study arms (48.0 mm; IQR 40–55; p = 0.015). Conclusions: Administration of supplemental oxygen (or air) to clinicians performing ECC on a manikin does not improve their performance when measured against internationally accepted guidelines. Supplemental oxygen or air to rescuers performing ECC was not supported. Full article

Ceramic nanofiber-based materials have wide applicability in high-temperature management and protection. The transformation of conventional two-dimensional ceramic nanofibrous membranes into three-dimensional nanofiber-based bulks can effectively improve their thermal insulation performance and expand their range of applications. Herein, lamellar-structured Al₂O₃-SiO₂ nanofibrous aerogels (LASO NFAs) with varying inorganic binder contents were prepared via a sequence of processes involving face-to-face stacking, impregnation, and calcination, using flexible Al₂O₃-SiO₂ nanofibrous membranes (ASO NFMs) as building units and aluminum dihydrogen phosphate as an inorganic binder. Varying the inorganic binder content in the aerogel matrix enables effective control over the compressive properties and interlayer spacing of the resulting aerogels. Specifically, the optimized LASO-20 NFAs demonstrated relatively good compression resilience, with a plastic deformation of 22.1% after undergoing 500 compressive cycles at a compressive strain of 50%. Moreover, profiting from the high-temperature resistance of ASO NFMs and substantial air content present within nanofiber interlayers, the LASO-20 NFAs with a thickness of 20 mm could effectively insulate against surface temperatures of 1000 °C down to 224 °C. Moreover, LASO-20 NFAs exhibited a room-temperature thermal conductivity of approximately 0.043 W·m⁻¹·K⁻¹, illustrating a favorable high-temperature thermal insulation characteristic. Furthermore, the LASO-20 NFAs presented promising service performance in extreme environments, providing a novel perspective in the development of new types of ceramic aerogels. Full article

To address the issues of poor network coverage, low data transmission efficiency, and high power consumption in traditional soybean field monitoring, this paper proposes an intelligent monitoring solution that integrates BeiDou positioning with a low-power joint data compression algorithm. The system employs a dual-mode communication architecture combining ZigBee 3.0 and LoRa, enabling round-the-clock real-time collection and transmission of key soybean growth parameters, including air temperature and humidity, light intensity, soil temperature and humidity, soil electrical conductivity, and ph. Leveraging the BeiDou satellite navigation system, monitoring nodes can obtain precise spatial coordinates, providing a reliable geographic basis for spatial data analysis and addressing the shortcomings of traditional monitoring methods regarding insufficient spatial resolution. To overcome bandwidth limitations in long-distance wireless transmission and reduce system power consumption, this paper proposes a hybrid lossless compression algorithm based on bit-field packing, LZW coding, and Huffman coding. This algorithm offers high compression efficiency while ensuring data integrity and accuracy, significantly improving transmission efficiency and reducing the long-term energy consumption of field sensor nodes. Communication performance and power consumption test results confirm that the system delivers stable long-distance transmission and demonstrates excellent low-power performance. Error analysis of the multidimensional monitoring parameters revealed that the overall measurement error for all environmental and soil indicators was kept within 5%, meeting the requirements for high-precision monitoring throughout the entire soybean growth cycle. Full article