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Search Results (23)

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Keywords = agro-industrial valorisation

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17 pages, 1307 KiB  
Review
Starch Valorisation as Biorefinery Concept Integrated by an Agro-Industry Case Study to Improve Sustainability
by Maider Gomez Palmero, Ana Carrasco, Paula de la Sen, María Dolores Mainar-Toledo, Sonia Ascaso Malo and Francisco Javier Royo Herrer
Sustainability 2025, 17(15), 6808; https://doi.org/10.3390/su17156808 - 27 Jul 2025
Viewed by 369
Abstract
The production of bio-based products for different purposes has become an increasingly common strategy over the last few decades, both in Europe and worldwide. This trend seeks to contribute to mitigating the impacts associated with climate change and to cope with the ambitious [...] Read more.
The production of bio-based products for different purposes has become an increasingly common strategy over the last few decades, both in Europe and worldwide. This trend seeks to contribute to mitigating the impacts associated with climate change and to cope with the ambitious objectives established at European level. Over recent decades, agro-industries have shown significant potential as biomass suppliers, triggering the development of robust logistical supply chains and the valorization of by-products to obtain bio-based products that can be marketed at competitive prices. However, this transformation may, in some cases, involve restructuring traditional business model to incorporate the biorefinery concept. In this sense, the first step in developing a bio-based value chain involves assessing the resource’s availability and characterizing the feedstock to select the valorization pathway and the bio-application with the greatest potential. The paper incorporates inputs from a case study on PATURPAT, a company commercializing a wide range of ready-prepared potato products, which has commissioned a starch extraction facility to process the rejected pieces of potatoes and water from the process to obtain starch that can be further valorized for different bio-applications. This study aims to comprehensively review current trends and frameworks for potatoes processing agro-industries and define the most suitable bio-applications to target, as well as identify opportunities and challenges. Full article
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25 pages, 1919 KiB  
Article
Valorisation of Beetroot Peel for the Development of Nutrient-Enriched Dehydrated Apple Snacks
by Ioana Buțerchi, Liliana Ciurlă, Iuliana-Maria Enache, Antoanela Patraș, Gabriel-Ciprian Teliban and Liviu-Mihai Irimia
Foods 2025, 14(15), 2560; https://doi.org/10.3390/foods14152560 - 22 Jul 2025
Viewed by 388
Abstract
Beetroot peel, an underutilised by-product of the food industry, has significant potential for valorisation due to its high content of bioactive compounds and natural pigments. This study aimed to sustainably reintroduce beetroot peel into the food chain by enriching the nutritional value of [...] Read more.
Beetroot peel, an underutilised by-product of the food industry, has significant potential for valorisation due to its high content of bioactive compounds and natural pigments. This study aimed to sustainably reintroduce beetroot peel into the food chain by enriching the nutritional value of dehydrated apple snacks. Five experimental formulations of apple slices were developed: dipped in 5% RBPP in water, dipped in 10% RBPP in water, dipped in 5% RBPP in 50% lemon juice, dipped in 10% RBPP in 50% lemon juice all seasoned with cinnamon powder, and a control formulation. The biochemical analysis showed that the total phenolic content (2780.01 ± 68.38 mg GAE/100 g DM) and antioxidant activity of apple snacks significantly increased (503.96 ± 1.83 µmol TE/g DM). Sensory evaluation indicated that snacks with beetroot peel powder and lemon juice achieved the highest scores in colour, flavour, and acceptability. These results demonstrate that the valorisation of beetroot peel has the potential to reduce agro-industrial waste and also enhance the nutritional and functional quality of apple snacks. It is recommended that beetroot peel be further explored as a cost-effective natural ingredient to develop healthier, value-added snack products within a circular economy framework. Full article
(This article belongs to the Section Nutraceuticals, Functional Foods, and Novel Foods)
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21 pages, 2431 KiB  
Article
Up-Cycling Broccoli Stalks into Fresh-Cut Sticks: Postharvest Strategies for Quality and Shelf-Life Enhancement
by Nieves García-Lorca, José Ángel Salas-Millán and Encarna Aguayo
Foods 2025, 14(14), 2476; https://doi.org/10.3390/foods14142476 - 15 Jul 2025
Viewed by 279
Abstract
Broccoli stalks are considered an agro-industrial by-product that, in the context of fresh consumption, is undervalued, as only broccoli florets are typically marketed. This study evaluated the up-cycling of broccoli stalks into a value-added fresh-cut product through postharvest preservation strategies. Stalks were peeled, [...] Read more.
Broccoli stalks are considered an agro-industrial by-product that, in the context of fresh consumption, is undervalued, as only broccoli florets are typically marketed. This study evaluated the up-cycling of broccoli stalks into a value-added fresh-cut product through postharvest preservation strategies. Stalks were peeled, cut into sticks (8 × 8 mm × 50–100 mm), sanitised, packaged under modified atmosphere conditions, and stored at 5 °C. Treatments included (a) calcium ascorbate (CaAsc, 1% w/v), (b) trehalose (TREH, 5% w/v), (c) hot water treatment (HWT, 55 °C, 1 min), and several combinations of them. HWT alone was highly effective in reducing browning, a key factor for achieving an extended shelf-life, controlling microbial growth and respiration, and obtaining the highest sensory scores (appearance = 7.3 on day 11). However, it was less effective in preserving bioactive compounds. The HWT + CaAsc treatment proved to be the most effective at optimising quality and retaining health-promoting compounds. It increased vitamin C retention by 78%, antioxidant capacity by 68%, and total phenolic content by 65% compared to the control on day 11. This synergistic effect was attributed to the antioxidant action of ascorbic acid in CaAsc. TREH alone showed no preservative effect, inducing browning, elevated respiration, and microbial proliferation. Overall, combining mild thermal and antioxidant treatments offers a promising strategy to valorise broccoli stalks as fresh-cut snacks. An 11-day shelf-life at 5 °C was achieved, with increased content of health-promoting bioactive compounds, while supporting circular economy principles and contributing to food loss mitigation. Full article
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20 pages, 1635 KiB  
Article
Pyrolysis of Rice Husk for the Production of Bioactive Compounds with Potential in Green Chemistry and Sustainable Agriculture
by Matheus de Paula Goularte, Ávila Ferreira de Sousa, Camila Cholant, Lucas Romano, Jalel Labidi, André Luiz Missio, Andrey Acosta and Darci Alberto Gatto
Molecules 2025, 30(13), 2754; https://doi.org/10.3390/molecules30132754 - 26 Jun 2025
Viewed by 540
Abstract
The objective of this study was to investigate the chemical composition of the obtained products, as well as the antioxidant activity and bio-stimulant potential of the liquid fractions. The biomass was subjected to pyrolysis in a pilot-scale reactor, followed by distillation of the [...] Read more.
The objective of this study was to investigate the chemical composition of the obtained products, as well as the antioxidant activity and bio-stimulant potential of the liquid fractions. The biomass was subjected to pyrolysis in a pilot-scale reactor, followed by distillation of the pyroligneous liquid to separate volatile compounds and enrich bioactive fractions. The samples were analysed by FTIR, TGA/DTG, and GC-MS. Antioxidant activities were assessed through DPPH, FRAP, and total phenolic content assays, while the bio-stimulant potential was evaluated through germination and growth tests of lettuce and arugula seeds. The results showed that the distilled fraction had lower acidity, greater chemical stability, and high antioxidant activity, with the presence of industrially valuable compounds such as methoxylated phenols and furfural. Furthermore, application of the distilled liquid at 0.1% concentration stimulated early seedling development—especially in arugula—while higher concentrations demonstrated inhibitory effects. These findings show that distillation of pyroligneous liquid is an effective strategy to enhance its bioactive properties, enabling its use as a natural antioxidant and plant bio-stimulant. Full article
(This article belongs to the Special Issue 10th Anniversary of Green Chemistry Section)
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17 pages, 3745 KiB  
Article
Preliminary Analysis on Bio-Acidification Using Coffee Torrefaction Waste and Acetic Acid on Animal Manure from a Dairy Farm
by Grazia Cinardi, Serena Vitaliano, Alessandro Fasciana, Ferdinando Fragalà, Emanuele La Bella, Luciano Manuel Santoro, Provvidenza Rita D’Urso, Andrea Baglieri, Giovanni Cascone and Claudia Arcidiacono
Agriculture 2025, 15(9), 948; https://doi.org/10.3390/agriculture15090948 - 27 Apr 2025
Cited by 1 | Viewed by 478
Abstract
This study investigates bio-acidification as a method to decrease the pH of animal manure in dairy farms through the application of coffee silverskin (i.e., a coffee torrefaction waste) and acetic acid. The aim was to focus on the preliminary analysis needed to assess [...] Read more.
This study investigates bio-acidification as a method to decrease the pH of animal manure in dairy farms through the application of coffee silverskin (i.e., a coffee torrefaction waste) and acetic acid. The aim was to focus on the preliminary analysis needed to assess the suitability of using this mitigation strategy. This analysis was carried out by developing a three-step methodology. The first step included the identification of the appropriate proportions of coffee silverskin and acetic acid at the laboratory scale; in the second step, the best treated proportions were analysed in field conditions to compare the statistical differences among the pH of the control and treated samples. In the third step, territorial evaluation was carried out to verify the availability of the coffee waste in the territory based on the use of a Geographic Information System (GIS). Based on the results, a reduction of 38% and 31% in pH was observed in samples treated with acetic acid and coffee silverskin at the laboratory scale and in field conditions, respectively. The territorial analysis showed that it is possible to valorise this agro-industrial waste while minimising environmental impacts due to transportation if the coffee industry is located within a 75 km distance. Full article
(This article belongs to the Section Farm Animal Production)
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22 pages, 621 KiB  
Article
From Waste to Sustainable Animal Feed: Incorporation of Olive Oil By-Products into the Diet of Bísaro Breed Pigs
by Jessica Paié-Ribeiro, Victor Pinheiro, Cristina Guedes, Maria José Gomes, José Teixeira, Alfredo Teixeira and Divanildo Outor-Monteiro
Sustainability 2025, 17(7), 3174; https://doi.org/10.3390/su17073174 - 3 Apr 2025
Cited by 2 | Viewed by 726
Abstract
The olive oil agro-industry generates large quantities of by-products, such as olive cake (OC), whose sustainable valorisation in animal feed can contribute to the principles of circular economy, waste reduction, and resource efficiency. This study evaluated the effects of incorporating OC into the [...] Read more.
The olive oil agro-industry generates large quantities of by-products, such as olive cake (OC), whose sustainable valorisation in animal feed can contribute to the principles of circular economy, waste reduction, and resource efficiency. This study evaluated the effects of incorporating OC into the diets of growing Bísaro pigs, focusing on productive parameters and the apparent total tract digestibility (ATTD). Two trials were carried out. In the first trial, 25 pigs were fed five diets containing 0, 5, 10, 15, and 20% exhausted OC (EOC) for 15 days. The results showed a linear decrease in ATTD with increasing EOC levels (p < 0.001), but the increased feed intake compensated for the reduced digestibility, and growth performance was maintained. The initial and final live weight (LW), average daily gain (ADG), average daily feed intake (ADFI), and feed conversion ratio (FCR) were not affected (p > 0.05). In the second trial, 40 pigs were fed five diets for 82 days: a control diet and four diets incorporating 10% crude OC, 10% two-phase OC, 10% EOC, and 10% EOC with 1% olive oil. No significant differences were observed in final weight, ADG, ADFI, FCR, or the digestibility of DM, OM, CP, CF, and NDF. The results suggest incorporating moderate levels of OC into Bísaro pig diets could be a viable strategy for valorising by-products, reducing agro-industrial waste and increasing sustainability in animal production. In addition, the inclusion of OC had no negative impact on animal performance, highlighting the potential of OC as a sustainable ingredient for animal feed, which aligns with the objectives of the circular economy and sustainable livestock farming practices. Full article
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13 pages, 1669 KiB  
Article
Effluent from Winery Waste Biorefinery: A Strategic Input for Biomass Generation with Different Objectives to Add Value in Arid Regions
by Pedro Federico Rizzo, Germán Darío Aguado, Iván Funes-Pinter, Laura Elizabeth Martinez, Florencia Noemí Ferrari, Federico De Biazi, Pablo Martín, Gustavo Flores, Antoni Sánchez and Ernesto Martin Uliarte
Appl. Sci. 2025, 15(3), 1435; https://doi.org/10.3390/app15031435 - 30 Jan 2025
Viewed by 955
Abstract
Agro-industrial activities generate significant amounts of organic waste and a variety of effluents thus posing environmental challenges. Viticulture in Argentina, which covered 204,847 ha in 2023, faces water scarcity as a limiting factor conditioning its production. This industry produces large volumes of grape [...] Read more.
Agro-industrial activities generate significant amounts of organic waste and a variety of effluents thus posing environmental challenges. Viticulture in Argentina, which covered 204,847 ha in 2023, faces water scarcity as a limiting factor conditioning its production. This industry produces large volumes of grape marc, sediments, and stalks, which can be valorised into products like alcohol, tartaric acid, and compost. However, these valorisation processes generate effluents with high organic load and salinity, further stressing water resources. This study explores the potential of utilising these effluents to cultivate plant biomass in arid regions (sorghum or perennial pasture), which could serve as bioenergy, animal feed, or composting co-substrates, contributing to circular bioeconomy principles. The combined use of effluent as a water resource and the sowing of sorghum and pasture increased soil organic matter content and led to a slight reduction in pH (depth: 0.30–0.60 m) compared to the control treatment. The sorghum plots showed better establishment and higher dry biomass yield (32.6 Tn/ha) compared to the pasture plots (6.5 Tn/ha). Sorghum demonstrated better tolerance to saline soils and high salinity effluents, aligning with previous studies. Although pasture had a lower biomass yield, it was more efficient in nutrient uptake, concentrating more NPK, ash, and soluble salts. Sorghum’s higher yield compensated for its lower nutrient concentration. For biomass production, sorghum is preferable, but if nutrient capture from effluents is prioritised, summer polyphytic pastures are more suitable. These results suggest that the final selection between plant biomass alternatives highly depends on whether the goal is biomass generation or nutrient capture. Full article
(This article belongs to the Special Issue Bioenergy and Bioproducts from Biomass and Waste)
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13 pages, 951 KiB  
Review
Regenerative Food Innovation: The Role of Agro-Food Chain By-Products and Plant Origin Food to Obtain High-Value-Added Foods
by Charles Stephen Brennan
Foods 2024, 13(3), 427; https://doi.org/10.3390/foods13030427 - 28 Jan 2024
Cited by 5 | Viewed by 3527
Abstract
Food losses in the agri-food sector have been estimated as representing between 30 and 80% of overall yield. The agro-food sector has a responsibility to work towards achieving FAO sustainable goals and global initiatives on responding to many issues, including climate pressures from [...] Read more.
Food losses in the agri-food sector have been estimated as representing between 30 and 80% of overall yield. The agro-food sector has a responsibility to work towards achieving FAO sustainable goals and global initiatives on responding to many issues, including climate pressures from changes we are experiencing globally. Regenerative agriculture has been discussed for many years in terms of improving our land and water. What we now need is a focus on the ability to transform innovation within the food production and process systems to address the needs of society in the fundamental arenas of food, health and wellbeing in a sustainable world. Thus, regenerative food innovation presents an opportunity to evaluate by-products from the agriculture and food industries to utilise these waste streams to minimise the global effects of food waste. The mini-review article aims to illustrate advancements in the valorisation of foods from some of the most recent publications published by peer-reviewed journals during the last 4–5 years. The focus will be applied to plant-based valorised food products and how these can be utilised to improve food nutritional components, texture, sensory and consumer perception to develop the foods for the future. Full article
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18 pages, 2485 KiB  
Article
Subcritical Water Extraction for Valorisation of Almond Skin from Almond Industrial Processing
by Pedro A. V. Freitas, Laia Martín-Pérez, Irene Gil-Guillén, Chelo González-Martínez and Amparo Chiralt
Foods 2023, 12(20), 3759; https://doi.org/10.3390/foods12203759 - 13 Oct 2023
Cited by 11 | Viewed by 3226
Abstract
Almond skin (AS) is an agro-industrial residue from almond processing that has a high potential for valorisation. In this study, subcritical water extraction (SWE) was applied at two temperatures (160 and 180 °C) to obtain phenolic-rich extracts (water-soluble fraction) and cellulose fibres (insoluble [...] Read more.
Almond skin (AS) is an agro-industrial residue from almond processing that has a high potential for valorisation. In this study, subcritical water extraction (SWE) was applied at two temperatures (160 and 180 °C) to obtain phenolic-rich extracts (water-soluble fraction) and cellulose fibres (insoluble fraction) from AS. The extraction conditions affected the composition and properties of both valorised fractions. The dry extracts obtained at 180 °C were richer in phenolics (161 vs. 101 mg GAE. g−1 defatted almond skin (DAS)), with greater antioxidant potential (1.063 vs. 1.490 mg DAS.mg−1 DPPH) and showed greater antibacterial effect (lower MIC values) against L. innocua (34 vs. 90 mg·mL−1) and E. coli (48 vs. 90 mg·mL−1) than those obtained at 160 °C, despite the lower total solid yield (21 vs. 29%) obtained in the SWE process. The purification of cellulose from the SWE residues, using hydrogen peroxide (H2O2), revealed that AS is not a good source of cellulose material since the bleached fractions showed low yields (20–21%) and low cellulose purity (40–50%), even after four bleaching cycles (1 h) at pH 12 and 8% H2O2. Nevertheless, the application of a green, scalable, and toxic solvent-free SWE process was highly useful for obtaining AS bioactive extracts for different food, cosmetic, or pharmaceutical applications. Full article
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13 pages, 22747 KiB  
Article
Sustainable Cosmetics: Valorisation of Kiwi (Actinidia deliciosa) By-Products by Their Incorporation into a Moisturising Cream
by Sandra M. Gomes, Rita Miranda and Lúcia Santos
Sustainability 2023, 15(19), 14059; https://doi.org/10.3390/su151914059 - 22 Sep 2023
Cited by 6 | Viewed by 4273
Abstract
The growing population has intensified food processing, increasing the generation of agro-industrial waste. This waste is rich in bioactive compounds; therefore, it can be valorised by extracting their compounds of biological interest and incorporating them into cosmetic products. In this work, an extract [...] Read more.
The growing population has intensified food processing, increasing the generation of agro-industrial waste. This waste is rich in bioactive compounds; therefore, it can be valorised by extracting their compounds of biological interest and incorporating them into cosmetic products. In this work, an extract was obtained from kiwi peels and characterised regarding its biological properties and phenolic composition. Results demonstrated that the extract presented antioxidant activity against DPPH and ABTS radicals (IC50 values of 244 mg/L and 58 mg/L, respectively) and antibacterial activity against Staphylococcus aureus. Catechin and epicatechin (flavonoids), as well as chlorogenic acid (phenolic acid), were the main phenolic compounds identified. Subsequently, the kiwi peel extract was incorporated into cosmetic formulations and their antioxidant properties and stability were evaluated. An increase in the antioxidant activity of the moisturising cream was observed upon the extract’s addition. Also, no microorganisms were present in any formulation prepared, attesting to their microbial safety. Finally, the results from the stability analysis revealed that the moisturising creams remained relatively stable for two weeks. These findings suggest that extracts from kiwi peels have the potential to be used as natural additives to produce value-added cosmetic products in a more sustainable manner. Full article
(This article belongs to the Special Issue Biosustainability and Waste Valorization)
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31 pages, 3339 KiB  
Article
Chemical and Bioactive Screening of Green Polyphenol-Rich Extracts from Chestnut By-Products: An Approach to Guide the Sustainable Production of High-Added Value Ingredients
by Daniele Bobrowski Rodrigues, Lavínia Veríssimo, Tiane Finimundy, Joana Rodrigues, Izamara Oliveira, João Gonçalves, Isabel P. Fernandes, Lillian Barros, Sandrina A. Heleno and Ricardo C. Calhelha
Foods 2023, 12(13), 2596; https://doi.org/10.3390/foods12132596 - 4 Jul 2023
Cited by 10 | Viewed by 3082
Abstract
Opportunities for the valorisation of agro-industrial residues of the chestnut (Castanea sativa Mill.) production chain have been fostered with the production of multifunctional polyphenol-rich extracts with the potential to be introduced as natural additives or active components in several products. Nonetheless, it [...] Read more.
Opportunities for the valorisation of agro-industrial residues of the chestnut (Castanea sativa Mill.) production chain have been fostered with the production of multifunctional polyphenol-rich extracts with the potential to be introduced as natural additives or active components in several products. Nonetheless, it is crucial to explore the feasibility of different extracts from the various by-products for these applications through the exhaustive study of their composition and bioactivities without losing sight of the sustainable character of the process. This work aimed at the screening of the phenolic compound composition and bioactivities of different green extracts of chestnut burs, shells and leaves, as the first step to establish their potential application as natural ingredients, primarily as food preservatives. To this end, maceration (MAC) as a conventional extraction method besides ultrasound and microwave-assisted extractions (UAE and MAE) was employed to obtain the extracts from chestnut by-products using water (W) and hydroethanolic solution (HE) as solvents. Phenolic compounds were analysed by HPLC-DAD-(ESI-)MS/MS; the antioxidant capacity was assessed by colourimetric assays, and the antimicrobial activity was evaluated against several strains of food-borne bacteria and fungi. The leaf extracts obtained by MAC-HE and UAE-HE presented the highest concentration of phenolic compounds (70.92 ± 2.72 and 53.97 ± 2.41 mg.g−1 extract dw, respectively), whereas, for burs and shells, the highest recovery of total phenolic compounds was achieved by using UAE-HE and UAE-W (36.87 ± 1.09 and 23.03 ± 0.26 mg.g−1 extract dw, respectively). Bis-HHDP-glucose isomers, chestanin and gallic acid were among the most abundant compounds. Bur extracts (MAC-HE and UAE-HE) generally presented the highest antioxidant capacity as measured by TBARS, while the best results in DPPH and reducing power assays were found for shell extracts (MAE-W and MAC-HE). Promising antibacterial activity was noticed for the aqueous extracts of burs, leaves and hydroethanolic extracts of shells, with emphasis on the MAE-W extract of burs that showed bactericidal activity against E. cloacae, P. aeruginosa and S. aureus (MBC 5 mg.mL−1). Overall, it can be concluded that chestnut by-products, including burs, shells and leaves, are sources of polyphenolic compounds with significant antioxidant and antimicrobial activities. The choice of extraction method and solvent greatly influenced the composition and bioactivity of the extracts. These findings highlight the potential of chestnut by-products for the development of natural additives, particularly for food preservation, while also emphasizing the importance of sustainable utilization of agricultural waste materials. Further research is warranted to optimize extraction techniques and explore additional applications for these valuable bioactive compounds. Full article
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24 pages, 5183 KiB  
Review
Wastewater Treatment Using Photosynthetic Microorganisms
by Cristian A. Sepúlveda-Muñoz, Ignacio de Godos and Raúl Muñoz
Symmetry 2023, 15(2), 525; https://doi.org/10.3390/sym15020525 - 16 Feb 2023
Cited by 22 | Viewed by 8058
Abstract
Wastewaters are mainly classified as domestic, industrial and agro-industrial based on their production source. Piggery wastewater (PWW) is a livestock wastewater characterized by its high concentrations of organic matter and ammonium, and by its odour nuisance. Traditionally, PWW has been treated in open [...] Read more.
Wastewaters are mainly classified as domestic, industrial and agro-industrial based on their production source. Piggery wastewater (PWW) is a livestock wastewater characterized by its high concentrations of organic matter and ammonium, and by its odour nuisance. Traditionally, PWW has been treated in open anaerobic lagoons, anaerobic digesters and activated sludge systems, which exhibit high greenhouse gas emissions, a limited nutrients removal and a high energy consumption, respectively. Photosynthetic microorganisms can support a sustainable wastewater treatment in engineered photobioreactors at low operating costs and with an efficient recovery of carbon, nitrogen and phosphorous. These microorganisms are capable of absorbing solar irradiation through the photosynthesis process to obtain energy, which is used for their growth and associated carbon and nutrients assimilation. Purple phototrophic bacteria (PPB) represent the photosynthetic microorganisms with the most versatile metabolism in nature, whereas microalgae are the most-studied photosynthetic microorganisms in recent years. This review describes the fundamentals, symmetry and asymmetry of wastewater treatment using photosynthetic microorganisms such as PPB and microalgae. The main photobioreactor configurations along with the potential of PPB and microalgae biomass valorisation strategies are also discussed. Full article
(This article belongs to the Special Issue Photosynthetic Microorganisms: Cultivation and Application)
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15 pages, 2097 KiB  
Article
Optimization of Autohydrolysis of Olive Pomaces to Obtain Bioactive Oligosaccharides: The Effect of Cultivar and Fruit Ripening
by Laura Freitas, Rita Simões, Isabel Miranda, Fátima Peres and Suzana Ferreira-Dias
Catalysts 2022, 12(7), 788; https://doi.org/10.3390/catal12070788 - 18 Jul 2022
Cited by 15 | Viewed by 2614
Abstract
The valorisation of agro-industrial residues presents a challenge in obtaining economically sustainable and environmentally friendly industrial processes. Olive pomace is a by-product generated in large quantities, from olive oil extraction. This residue mostly consists of lignocellulosic materials. The aim of this study was [...] Read more.
The valorisation of agro-industrial residues presents a challenge in obtaining economically sustainable and environmentally friendly industrial processes. Olive pomace is a by-product generated in large quantities, from olive oil extraction. This residue mostly consists of lignocellulosic materials. The aim of this study was to evaluate the potential use of extracted olive pomaces (EOP) obtained from olives with different ripening indexes (RI) and from different cultivars (Cobrançosa; RI = 2.5; 3.3 and 4.7; and Galega Vulgar; RI = 1.8; 2.9 and 4.8), to produce bioactive oligosaccharides from hemicelluloses by autohydrolysis. The hydrothermal treatment conditions were optimized by Response Surface Methodology, following a central composite rotatable design (CCRD), as a function of temperature (T: 142–198 °C) and time (t: 48–132 min), corresponding to severity factor (SF) values from 3.2 to 4.9. For all pomace samples, soluble sugar production was described by concave surfaces as a function of temperature and time. Autohydrolysis with SF equal or higher than 4.0 produced higher sugar yields, with maximum values around 180 g glucose equivalent/kg EOP for SF of 4.7 (190 °C/120 min) or 4.9 (198 °C/90 min). These values were similar for both cultivars and were not dependent on the ripening stage of the olives. Maximum oligosaccharide (OS) yields of 98% were obtained by autohydrolysis with SF of 4.0. The increase in SF to 4.9 resulted in a decrease in OS yield to 86–92%, due to the release of monomeric sugars. The monosaccharides were mostly xylose (55.8–67.7% in Galega; 50.4–69.0% in Cobrançosa liquid phases), and glucose, galactose, arabinose and rhamnose, in smaller quantities. Therefore, the production of bioactive xylo-oligosaccharides (XOS) from olive pomaces mainly depends on the hydrothermal conditions used. Full article
(This article belongs to the Special Issue Catalysis in Biorefinery)
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21 pages, 1880 KiB  
Review
Current Options in the Valorisation of Vine Pruning Residue for the Production of Biofuels, Biopolymers, Antioxidants, and Bio-Composites following the Concept of Biorefinery: A Review
by Meirielly Jesus, Aloia Romaní, Fernando Mata and Lucília Domingues
Polymers 2022, 14(9), 1640; https://doi.org/10.3390/polym14091640 - 19 Apr 2022
Cited by 37 | Viewed by 4323
Abstract
Europe is considered the largest producer of wine worldwide, showing a high market potential. Several wastes are generated at the different stages of the wine production process, namely, vine pruning, stalks, and grape marc. Typically, these residues are not used and are commonly [...] Read more.
Europe is considered the largest producer of wine worldwide, showing a high market potential. Several wastes are generated at the different stages of the wine production process, namely, vine pruning, stalks, and grape marc. Typically, these residues are not used and are commonly discarded. Portugal generates annually approximately 178 thousand metric tons of wine production waste. In this context, the interest in redirecting the use of these residues has increased due to overproduction, great availability, and low costs. The utilization of these lignocellulosic biomasses derived from the wine industry would economically benefit the producers, while mitigating impacts on the environment. These by-products can be submitted to pre-treatments (physical, chemical, and biological) for the separation of different compounds with high industrial interest, reducing the waste of agro-industrial activities and increasing industrial profitability. Particularly, vine-pruning residue, besides being a source of sugar, has high nutritional value and may serve as a source of phenolic compounds. These compounds can be obtained by bioconversion, following a concept of biorefinery. In this framework, the current routes of the valorisation of the pruning residues will be addressed and put into a circular economy context. Full article
(This article belongs to the Special Issue Advances and Current Challenges in Cellulase Recycling)
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16 pages, 2060 KiB  
Article
Sustainability in Skin Care: Incorporation of Avocado Peel Extracts in Topical Formulations
by Sara M. Ferreira, Zizina Falé and Lúcia Santos
Molecules 2022, 27(6), 1782; https://doi.org/10.3390/molecules27061782 - 9 Mar 2022
Cited by 26 | Viewed by 8529
Abstract
The avocado peel is an agro-industrial by-product that has exhibited a massive increase in its production in the last few years. The reuse and valorisation of this by-product are essential since its disposal raises environmental concerns. In the present study, ethanolic extracts of [...] Read more.
The avocado peel is an agro-industrial by-product that has exhibited a massive increase in its production in the last few years. The reuse and valorisation of this by-product are essential since its disposal raises environmental concerns. In the present study, ethanolic extracts of avocado peels of the Hass variety were obtained, for three extraction times (1.5 h, 3 h and 4 h) and analysed for their antioxidant and antibacterial properties. Antioxidant evaluations of the extracts revealed that the extraction time of 1.5 h exhibited the best results amongst the three, with a DPPH inhibition percentage of 93.92 ± 1.29 and an IC50 percentage, the necessary concentration of the extract to inhibit 50% of DPPH, of 37.30 ± 1.00. The antibacterial capacity of the extracts was evaluated and it was revealed that they were able to inhibit the growth and development of bacteria of the Staphylococcus family. The obtained extract was incorporated in two types of cosmetic formulations (oil-in-water and water-in-oil) and their stability was evaluated and compared with formulations containing synthetic preservatives (BHT and phenoxyethanol). The results of the stability evaluation suggest that the avocado peel extract has the potential to be incorporated in both types of emulsions, acting as an antioxidant and antibacterial agent, proving it to be a viable option to reduce/replace the use of synthetic preservatives. Furthermore, the avocado peel extract proved to be more effective and stable in oil-in-water emulsions. These results highlight the possibility of obtaining sustainable cosmetics, significantly reducing the negative impacts on the environment by the incorporation of extracts sourced from the avocado peel, an interesting source of phenolic compounds, an abundant and low-cost by-product. Full article
(This article belongs to the Special Issue New Trends in Skin Care: Topical Delivery of Cosmeceutical Molecules)
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