Search Results (403)

Newton’s law of cooling requires a reference temperature ($T_{ref}$) to define the heat-transfer coefficient ($h$). For external flows with multiple temperatures in the freestream, obtaining $T_{ref}$ is a challenge. One widely used method, referred to as the adiabatic-wall (AW) method, obtains $T_{ref}$ by requiring the surface of the solid exposed to convective heat transfer to be adiabatic. Another widely used method, referred to as the linear-extrapolation (LE) method, obtains $T_{ref}$ by measuring/computing the heat flux ($q_s^{\prime \prime }$) on the solid surface at two different surface temperatures ($T_s$) and then linearly extrapolating to $q_s^{\prime \prime }=0$. A third recently developed method, referred to as the state-space (SS) method, obtains $T_{ref}$ by probing the temperature space between the highest and lowest in the flow to account for the effects of $T_s$ or $q_s^{\prime \prime }$ on $T_{ref}$. This study examines the foundation and accuracy of these methods via a test problem involving film cooling of a flat plate where $q_s^{\prime \prime }$ switches signs on the plate’s surface. Results obtained show that only the SS method could guarantee a unique and physically meaningful $T_{ref}$ where $T_s=T_{ref}$ on a nonadiabatic surface $q_s^{\prime \prime }=0$. The AW and LE methods both assume $T_{ref}$ to be independent of $T_s$, which the SS method shows to be incorrect. Though this study also showed the adiabatic-wall temperature, $T_{AW}$, to be a good approximation of $T_{ref}$ (<10% relative error), huge errors can occur in $h$ about the solid surface where $|T_s-T_{AW}|$ is near zero because where $T_s=T_{AW}$, $q_s^{\prime \prime }\ne 0$. Full article

Growing environmental concerns have driven increased interest in solid-state thermal technologies based on the elastocaloric properties of shape memory alloys (SMA). This work examines the elastocaloric effect (eCE) in Ni-Ti SMA sheets subjected to cyclic bending, providing quantitative thermal characterization of their behavior under controlled loading conditions. The experimental investigation employed passive thermography to analyze the thermal response of Ni-Ti sheets under two deflection configurations at 1800 rpm loading. Testing revealed consistent adiabatic temperature variations (ΔT_ad) of 4.14 °C and 4.26 °C for the respective deflections during heating cycles, while cooling phases demonstrated efficient thermal homogenization with temperature gradients decreasing from 4.13 °C to 0.13 °C and 4.43 °C to 0.68 °C over 60 s. These findings provide systematic thermal documentation of elastocaloric behavior in bending-loaded Ni-Ti sheet elements and quantitative data on the relationship between mechanical loading parameters and thermal gradients, enhancing the experimental understanding of elastocaloric phenomena in this configuration. Full article

Atmospheric climate science lacks the capacity to integrate thermodynamics with the gravitational potential of air in a classical quantum theory. To what extent can we identify Carnot’s ideal heat engine cycle in reversible isothermal and isentropic phases between dual temperatures partitioning heat flow with coupled work processes in the atmosphere? Using statistical action mechanics to describe Carnot’s cycle, the maximum rate of work possible can be integrated for the working gases as equal to variations in the absolute Gibbs energy, estimated as sustaining field quanta consistent with Carnot’s definition of heat as caloric. His treatise of 1824 even gave equations expressing work potential as a function of differences in temperature and the logarithm of the change in density and volume. Second, Carnot’s mechanical principle of cooling caused by gas dilation or warming by compression can be applied to tropospheric heat–work cycles in anticyclones and cyclones. Third, the virial theorem of Lagrange and Clausius based on least action predicts a more accurate temperature gradient with altitude near 6.5–6.9 °C per km, requiring that the Gibbs rotational quantum energies of gas molecules exchange reversibly with gravitational potential. This predicts a diminished role for the radiative transfer of energy from the atmosphere to the surface, in contrast to the Trenberth global radiative budget of ≈330 watts per square metre as downwelling radiation. The spectral absorptivity of greenhouse gas for surface radiation into the troposphere enables thermal recycling, sustaining air masses in Lagrangian action. This obviates the current paradigm of cooling with altitude by adiabatic expansion. The virial-action theorem must also control non-reversible heat–work Carnot cycles, with turbulent friction raising the surface temperature. Dissipative surface warming raises the surface pressure by heating, sustaining the weight of the atmosphere to varying altitudes according to latitude and seasonal angles of insolation. New predictions for experimental testing are now emerging from this virial-action hypothesis for climate, linking vortical energy potential with convective and turbulent exchanges of work and heat, proposed as the efficient cause setting the thermal temperature of surface materials. Full article

This work investigates the effect of nanoclay addition—specifically natural montmorillonite (MMT) and organo-modified montmorillonite (O-MMT)—on the elastocaloric performance of natural rubber (NR), a promising material for solid-state cooling due to its non-toxicity, low cost, and ability to exhibit large adiabatic temperature changes under moderate stress (~a few MPa). Despite these advantages, the cooling efficiency of NR remains lower than that of conventional vapor-compression systems. Therefore, improving the cooling capacity of NR is essential for the development of solid-state cooling technologies competitive with existing ones. To address this, two series of NR-based nanocomposites, containing 1, 3, and 5 phr nanofiller, were prepared by melt compounding and hot pressing and characterized in terms of morphology, thermal, mechanical, and elastocaloric properties. The results highlighted that the better dispersion of the organoclays within the rubber matrix promoted not only a better mechanical behavior (in terms of stiffness and strength), but also a significantly enhanced cooling performance compared to MMT nanofilled systems. Moreover, NR/O-MMT samples demonstrated up to a ~45% increase in heat extracted per refrigeration cycle compared to the unfilled NR, with a coefficient of performance (COP) up to 3, approaching the COP of conventional vapor-compression systems, typically ranging between 3 and 6. The heat extracted per refrigeration cycle of NR/O-MMT systems resulted in approx. 16 J/cm³, higher with respect to the values reported in the literature for NR-based systems (ranging between 5 and 12 J/cm³). These findings emphasize the potential of organoclays in enhancing the refrigeration potential of NR for novel state cooling applications. Full article

The performance of the turbine in a variable geometry turbocharger (VGT) may be affected by changes in the vane operating angle and heat transfer loss during operation. However, existing studies have been conducted under the assumption of an adiabatic process. In this study, we investigated the effect of heat transfer between all working fluids and a VGT structure when using computational fluid dynamics to evaluate turbine performance. Through this study, we confirmed that when heat transfer was considered, the turbine efficiency decreased by approximately 2–6%, depending on the vane position angle change, compared to when heat transfer was not considered. In addition, the total entropy production ratio, which represented the flow loss in the turbine during operation, increased by approximately 0.2–0.5% when heat transfer was considered. In conclusion, the findings confirmed that the heat transfer phenomenon directly affected the efficiency and flow loss during the turbine performance evaluation process. Full article

To ensure the inherent safety of fine chemical nitration processes, the nitration reaction of benzotriazole ketone was selected as the research object. The thermal decomposition and reaction characteristics of the nitration system were studied using a combination of differential scanning calorimetry (DSC), reaction calorimetry (RC1), and accelerating rate calorimetry (ARC). The results showed that the nitration product released 455.77 kJ/kg of heat upon decomposition, significantly higher than the 306.86 kJ/kg of the original material, indicating increased thermal risk. Through process hazard analysis based on GB/T 42300-2022, key parameters such as the temperature at which the time to maximum rate is 24 h under adiabatic conditions (T_D24), maximum temperature of the synthesis reaction (MTSR), and maximum temperature for technical reason (MTT) were determined, and the reaction was classified as hazard level 5, suggesting a high risk of runaway and secondary explosion. Process intensification strategies were then proposed and verified by dynamic calorimetry: the adiabatic temperature increase (ΔT_ad) was reduced from 86.70 °C in the semi-batch reactor to 19.95 °C in the optimized continuous process, effectively improving thermal safety. These findings provide a reliable reference for the quantitative risk evaluation and safe design of nitration processes in fine chemical manufacturing. Full article

In the automotive industry, the increasing stringent standards to reduce fuel consumption and pollutant emissions has driven significant advancements in turbocharging systems. The centrifugal compressor, as the most widely used power-absorbing machinery, plays a crucial role but remains one of the most complex components to study and design. While most numerical studies rely on adiabatic models, this work analyses several Computational Fluid Dynamics (CFD) models with conjugate heat transfer (CHT) of varying complexity, incorporating real solid components. This approach allowed a sensitivity analysis of the performance obtained from the different models compared to the adiabatic case, highlighting the effects of internal heat exchange losses. Moreover, an analysis of the temperature distribution of the wheel was conducted, along with a thermal assessment of the various heat flux contributions across the different components, to gain a deeper understanding of the performance differences. The impact of including the seal plate has been evaluated and different boundary conditions on the seal plate have been tested to assess the uncertainty in the results. Finally, the influence of heat exchange between the shroud and the external environment is also examined to further refine the model’s accuracy. One of the objectives of this work is to obtain a correct temperature profile of the rotor for a subsequent thermo-mechanical analysis. Full article

This study proposes an RBF-PSO hybrid framework for efficient inversion analysis of hydration heat parameters in mass concrete temperature fields, addressing the computational inefficiency and accuracy limitations of traditional methods. By integrating a Radial Basis Function (RBF) surrogate model with Particle Swarm Optimization (PSO), the method reduces reliance on costly finite element simulations while maintaining global search capabilities. Three objective functions—integral-type (F₁), feature-driven (F₂), and hybrid (F₃)—were systematically compared using experimental data from a C40 concrete specimen under controlled curing. The hybrid F₃, incorporating Dynamic Time Warping (DTW) for elastic time alignment and feature penalties for engineering-critical metrics, achieved superior performance with a 74% reduction in the prediction error (mean MAE = 1.0 °C) and <2% parameter identification errors, resolving the phase mismatches inherent in F₂ and avoiding F₁’s prohibitive computational costs (498 FEM calls). Comparative benchmarking against non-surrogate optimizers (PSO, CMA-ES) confirmed a 2.8–4.6× acceleration while maintaining accuracy. Sensitivity analysis identified the ultimate adiabatic temperature rise as the dominant parameter (78% variance contribution), followed by synergistic interactions between hydration rate parameters, and indirect coupling effects of boundary correction coefficients. These findings guided a phased optimization strategy, as follows: prioritizing high-precision calibration of dominant parameters while relaxing constraints on low-sensitivity variables, thereby balancing accuracy and computational efficiency. The framework establishes a closed-loop “monitoring-simulation-optimization” system, enabling real-time temperature prediction and dynamic curing strategy adjustments for heat stress mitigation. Robustness analysis under simulated sensor noise (σ ≤ 2.0 °C) validated operational reliability in field conditions. Validated through multi-sensor field data, this work advances computational intelligence applications in thermomechanical systems, offering a robust paradigm for parameter inversion in large-scale concrete structures and multi-physics coupling problems. Full article

This study numerically examines laminar natural convection within a square cavity that has a horizontally attached adiabatic fin on its heated vertical wall. The analysis employed the finite element method to investigate how fin position, length, thickness, and thermal conductivity affect heat transfer behavior over a broad spectrum of Rayleigh numbers (Ra = 10 to 10⁶) and Prandtl numbers (Pr = 0.1 to 10). The findings indicate that the geometric configuration and the properties of the fluid largely influence the thermal disturbances caused by the fin. At lower Ra values, conduction is the primary mechanism, resulting in minimal impact from the fin. However, as Ra rises, convection becomes increasingly significant, with the fin positioned at mid-height (Y_fin = 0.5), significantly improving thermal mixing and flow symmetry, especially for high-Pr fluids. Extending the fin complicates vortex dynamics, whereas thickening the fin improves conductive heat transfer, thereby enhancing convection to the fluid. A new fluid-focused metric, the normalized Nusselt ratio (NNR), is introduced to evaluate the true thermal contribution of fin geometry beyond area-based scaling. It exhibits a non-monotonic response to geometric changes, with peak enhancement observed at high Ra and Pr. The findings provide practical guidance for designing passive thermal management systems in sealed enclosures, such as electronics housings, battery modules, and solar thermal collectors, where active cooling is infeasible. This study offers a scalable reference for optimizing natural convection performance in laminar regimes by characterizing the interplay between buoyancy, fluid properties, and fin geometry. Full article

With the enhancement of thermodynamic cycle parameters and heat dissipation constraints in aero-engines, effective thermal management has become a critical challenge to ensure safe and stable engine operation. This study developed a transient temperature evaluation model applicable to the entire flight envelope, considering fluid–solid coupling heat transfer on both the main flow path and fuel systems. Firstly, the impact of heat transfer on the acceleration and deceleration performance of a low-bypass-ratio turbofan engine was analyzed. The results indicate that, compared to the conventional adiabatic model, the improved model predicts metal components absorb 4.5% of the total combustor energy during cold-state acceleration, leading to a maximum reduction of 1.42 kN in net thrust and an increase in specific fuel consumption by 1.18 g/(kN·s). Subsequently, a systematic evaluation of engine thermal management performance throughout the complete flight mission was conducted, revealing the limitations of the existing thermal management design and proposing targeted optimization strategies, including employing Cooled Cooling Air technology to improve high-pressure turbine blade cooling efficiency, dynamically adjusting low-pressure turbine bleed air to minimize unnecessary losses, optimizing fuel heat sink utilization for enhanced cooling performance, and replacing mechanical pumps with motor pumps for precise fuel supply control. Full article

The performance of a quantum Otto engine is analyzed with regard to the constraints on the modulation of energy gaps relative to the changes in probability distributions at the two given heat reservoirs. We performed a detailed analysis with a generic three-level system (3LS), which serves as a non-trivial working medium with two energy gaps. A three-level Otto engine becomes feasible if at least one energy gap shrinks during the first quantum adiabatic stage. The operating regimes are derived for each allowed energy gap modulation, and majorization is observed to play a crucial role in determining the engine operation. This results in an enhanced Otto efficiency when the probability distributions fulfill the majorization condition. Finally, we show that our formalism applies to a swap engine based on a working medium composed of two 3LSs. Full article

Carbon monoxide (CO) is classified as a simple fuel that contains one carbon and one oxygen atom. The oxidation of CO with an oxidizer is relatively unusual, with the oxidation of CO having a slow reaction time. The addition of a small amount of “hydrogenous” species, such as H₂, H₂O, and CH₄, will substantially increase the reaction time. This study numerically investigated and compared the effects of different hydrogenous species addition on the premixed CO/air flames, which act as the initiation of a CO/air flame, on the adiabatic flame temperature, laminar flame speed, and heat release rates at standard conditions (298 K and 1 atm pressure) using San Diego Mechanism. The results showed that the addition of critical hydrogenous species distinguished the difference between dry and wet CO/air oxidation, in which different hydrogenous species have an identical critical value. Adding different hydrogenous species and different addition ratios has an indistinguishable adiabatic flame temperature, while adding CH₄ has a higher laminar flame speed distribution compared with H₂ and H₂O addition, respectively. Furthermore, the laminar flame speed positively correlates with the net heat release rate, which adding CH₄ has a noticeable increase on the net heat release rate. Adding more hydrogenous species makes the reactant more reactive and moves the reaction zone upstream. Finally, the dominant reactions to the heat release rate are identical in different hydrogenous species addition, where R23: CO + O (+M) ⇌ CO₂ (+M) becomes the most contributed reaction. Full article

This study presents a comprehensive dynamic model of a small-scale, solar-powered hydraulic gas compression energy storage system tailored for renewable energy applications. Addressing the intermittency of renewable energy sources, the model incorporates mass, momentum, and energy conservation principles and is implemented using GT-Suite simulation software v2025.0. The system, based on a liquid piston mechanism, was analyzed under both adiabatic and isothermal compression scenarios. Validation against experimental data showed maximum deviations under 10% for pressure and 5 °C for temperature. Under ideal isothermal conditions, the system stored up to 8 MJ and recovered 6.1 MJ of energy, achieving a round-trip efficiency of 76.3%. In contrast, adiabatic operation yielded 52.6% efficiency due to thermal losses. Sensitivity analyses revealed the importance of heat transfer enhancement, with performance varying by over 15% depending on spray cooling intensity. These findings underscore the potential of thermally integrated hydraulic systems for efficient, scalable, and cost-effective energy storage in distributed renewable energy networks. Full article

Sodium-ion batteries (SIBs) share similar working principles with lithium-ion batteries while demonstrating cost advantages. However, the current understanding of their safety characteristics remains insufficient, and the thermal runaway mechanisms of different SIB systems have not been fully elucidated. This study investigated the following two mainstream sodium-ion battery systems: polyanion-type compound (PAC) and layered transition metal oxide (TMO) cathodes. Differential scanning calorimetry (DSC) was employed to evaluate the thermal stability of cathodes and anodes, examining the effects of state of charge (SOC), cycling, and overcharging on electrode thermal stability. The thermal stability of electrolytes with different compositions was also characterized and analyzed. Additionally, adiabatic thermal runaway tests were conducted using an accelerating rate calorimeter (ARC) to explore temperature–voltage evolution patterns and temperature rise rates. The study systematically investigated heat-generating reactions during various thermal runaway stages and conducted a comparative analysis of the thermal runaway characteristics between these two battery systems. Full article

In this study, we characterize electrocaloric lead scandium tantalate (PST) samples by means of the adiabatic temperature change $\Delta T_{\mathrm{ad}}$ and the dissipative heat $q_{\mathrm{diss}}$ with a direct thermal method. The figure of merit ($FOM$), defined as the ratio between the adiabatic temperature change and the thermal hysteresis, quantifies the losses of the material. Additionally, it is also possible to draw conclusions on the efficiency of a caloric cooling system based on the regenerator or cascaded approach. The maximum adiabatic temperature change of the measured samples results in $\Delta T_{\mathrm{ad},\max }=(1.39\pm 0.02)$ K and the dissipative heat yields $q_{\mathrm{diss}}=(0.39\pm 0.05) \mathrm{J}/(\mathrm{k}\mathrm{g} \mathrm{K})$, resulting in an $FOM=(5.1\pm 0.2)$. The efficiency for an ideal cascaded system is given by ${\eta }_{\mathrm{cas}}=0.56$, and for the ideal regenerator, the efficiency is given by ${\eta }_{\mathrm{reg}}=0.84$. The results demonstrate that the PST material in this study exceeds the maximum $FOM$ in the literature by 34%. Full article